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1.
Lemnaceae or duckweed is an aquatic plant that can be used to recover nutrients from wastewaters. The grown duckweed can be a good resource of proteins and starch, and utilized for the production of value‐added products such as animal feed and fuel ethanol. In the last eleven years we have been working on growing duckweed on anaerobically treated swine wastewater and utilizing the duckweed for fuel ethanol production. Duckweed strains that grew well on the swine wastewater were screened in laboratory and greenhouse experiments. The selected duckweed strains were then tested for nutrient recovery under laboratory and field conditions. The rates of nitrogen and phosphorus uptake by the duckweed growing in the laboratory and field systems were determined in the study. The mechanisms of nutrient uptake by the duckweed and the growth of duckweed in a nutrient‐limited environment have been studied. When there are nutrients (N and P) available in the wastewater, duckweed takes the nutrients from the wastewater to support its growth and to store the nutrients in its tissue. When the N and P are completely removed from the wastewater, duckweed can use its internally stored nutrients to keep its growth for a significant period of time. A modified Monod model has been developed to describe nitrogen transport in a duckweed‐covered pond for nutrient recovery from anaerobically treated swine wastewater. Nutrient reserve in the duckweed biomass has been found the key to the kinetics of duckweed growth. Utilization of duckweed for value‐added products has a good potential. Using duckweed to feed animals, poultry, and fish has been extensively studied with promising results. Duckweed is also an alternative starch source for fuel ethanol production. Spirodela polyrrhiza grown on anaerobically treated swine wastewater was found to have a starch content of 45.8% (dry weight). Enzymatic hydrolysis of the duckweed biomass with amylases yielded a hydrolysate with a reducing sugar content corresponding to 50.9% of the original dry duckweed biomass. Fermentation of the hydrolysate using yeast gave an ethanol yield of 25.8% of the original dry duckweed biomass. These results indicate that the duckweed biomass can produce significant quantities of starch that can be readily converted into ethanol.  相似文献   

2.
Cryoturbated Upper Chalk is a dichotomous porous medium wherein the intra‐fragment porosity provides water storage and the inter‐fragment porosity provides potential pathways for relatively rapid flow near saturation. Chloride tracer movement through 43 cm long and 45 cm diameter undisturbed chalk columns was studied at water application rates of 0·3, 1·0, and 1·5 cm h?1. Microscale heterogeneity in effluent was recorded using a grid collection system consisting of 98 funnel‐shaped cells each 3·5 cm in diameter. The total porosity of the columns was 0·47 ± 0·02 m3 m?3, approximately 13% of pores were ≥ 15 µm diameter, and the saturated hydraulic conductivity was 12·66 ± 1·31 m day?1. Although the column remained unsaturated during the leaching even at all application rates, proportionate flow through macropores increased as the application rate decreased. The number of dry cells (with 0 ml of effluent) increased as application rate decreased. Half of the leachate was collected from 15, 19 and 22 cells at 0·3, 1·0, 1·5 cm h?1 application rates respectively. Similar breakthrough curves (BTCs) were obtained at all three application rates when plotted as a function of cumulative drainage, but they were distinctly different when plotted as a function of time. The BTCs indicate that the columns have similar drainage requirement irrespective of application rates, as the rise to the maxima (C/Co) is almost similar. However, the time required to achieve that leaching requirement varies with application rates, and residence time was less in the case of a higher application rate. A two‐region convection–dispersion model was used to describe the BTCs and fitted well (r2 = 0·97–0·99). There was a linear relationship between dispersion coefficient and pore water velocity (correlation coefficient r = 0·95). The results demonstrate the microscale heterogeneity of hydrodynamic properties in the Upper Chalk. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

3.
Understanding transpiration and plant physiological responses to environmental conditions is crucial for the design and management of vegetated engineered covers. Engineered covers rely on sustained transpiration to reduce the risk of deep drainage into potentially hazardous wastes, thereby minimizing contamination of water resources. This study quantified temporal trends of plant water potential (ψp), stomatal conductance (gs), and transpiration in a 4‐year‐old evergreen woody vegetation growing on an artificial sandy substrate at a mine waste disposal facility. Transpiration averaged 0.7 mm day?1 in winter, when rainfall was frequent, but declined to 0.2 mm day?1 in the dry summer, when the plants were quite stressed. In winter, the mean ψp was ?0.6 MPa at predawn and ?1.5 MPa at midday, which were much higher than the corresponding summer values of ?2.0 MPa and ?4.8 MPa, respectively. The gs was also higher in winter (72.1–95.0 mmol m?2 s?1) than in summer (<30 mmol m?2 s?1), and negatively correlated with ψp (p < 0.05, r2 = 0.71–0.75), indicating strong stomatal control of transpiration in response to moisture stress. Total annual transpiration (147.2 mm) accounted for only 22% of the annual rainfall (673 mm), compared with 77% to 99% for woody vegetation in Western Australia. The low annual transpiration was attributed to the collective effects of a sparse and young vegetation, low moisture retention of the sandy substrate, and a superficial root system constrained by high subsoil pH. Amending the substrate with fine‐textured materials should improve water storage of the substrate and enhance canopy growth and deep rooting, while further reducing the risk of deep drainage during the early stages of vegetation establishment and in the long term. Overall, this study highlights the need to understand substrate properties, vegetation characteristics, and rainfall patterns when designing artificial ecosystems to achieve specific hydrological functions. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

4.
We investigated greenhouse gas emissions (CO2, CH4, and N2O) from reservoirs located across an altitude gradient in Switzerland. These are the first results of greenhouse gas emissions from reservoirs at high elevations in the Alps. Depth profiles were taken in 11 reservoirs located at different altitudes between the years 2003 and 2006. Diffusive trace gas emissions were calculated using surface gas concentrations, wind speeds and transfer velocities. Additionally, methane entering with the inflowing water and methane loss at the turbine was assessed for a subset of the reservoirs. All reservoirs were emitters of carbon dioxide and methane with an average of 970?±?340?mg?m?2?day?1 (results only from four lowland and one subalpine reservoir) and 0.20?±?0.15?mg?m?2?day?1, respectively. One reservoir (Lake Wohlen) emitted methane at a much higher rate (1.8?±?0.9?mg?m?2?day?1) than the other investigated reservoirs. There was no significant difference in methane emissions across the altitude gradient, but average dissolved methane concentrations decreased with increasing elevation. Only lowland reservoirs were sources for N2O (72?±?22???g?m?2?day?1), while the subalpine and alpine reservoirs were in equilibrium with atmospheric concentrations. These results indicate reservoirs from subalpine/alpine regions to be only minor contributors of greenhouse gases to the atmosphere compared to other reservoirs.  相似文献   

5.
Bulk hydrocarbon deposition rates have been measured over a 15 month period at four stations in south-eastern Virginia surrounding the lower Chesapeake Bay. A nearly linear trend of atmospheric particulate deposition was recorded. Deposition rates at the urban station (195 μg m?2 day?1) were aproximately three times greater than those recorded for nonurban and coastal locations (mean value 69 μg m?2 day?1). The increased levels at the urban location were attributed to localized source inputs. Anthropogenic hydrocarbons accounted for approximately 50% of the total deposition at all stations. Significant biogenic inputs were indicated by the odd/even n-alkane distribution. A minimum flux to the water surface, based on mean nonurban deposition rates (24 mg yr?1), indicated an annual particulate hydrocarbon flux of +275 metric tons. Little information is available for the comparison of additional source inputs; however, the data reported here indicate that the aerial deposition of hydrocarbons is of the same order of magnitude as the input from municipal wastewater facilities and accidental discharge and is a potentially significant source of hydrocarbon pollution to the Chesapeake Bay Estuary.  相似文献   

6.
Conservation management for the water dependent desert‐oasis ecotone in arid northwest China requires information on the water use of the dominant species. However, no studies have quantified their combined water use or linked species composition to ecotone transpiration. Here, the water use of three dominant shelterbelt shrubs (Haloxylon ammodendron, Nitraria tangutorum, and Calligonum mongolicum) within an ecotone was measured throughout the full leaf‐out period for three shrub species from 30 May to 16 October 2014, with sap flow gauges using the stem heat balance approach. Species‐specific transpiration was estimated by scaling up sap flow velocities measured in individual stems, to stand area level, using the frequency distribution of stem diameter and assuming a constant proportionality between sap flow velocity and basal cross‐sectional area for all stems. The mean peak sap flux densities (Jsn) for H. ammodendron, N. tangutorum, and C. mongolicum, were 40.12 g cm?2 h?1, 71.33 g cm?2 h?1, and 60.34 g cm?2 h?1, respectively, and the mean estimated daily area‐averaged transpiration rates (Tdaily) for the same species were 0.56 mm day?1, 0.34 mm day?1, and 0.11 mm day?1. The accumulative stand transpiration was approximately 140.8 mm throughout the measurement period, exceeding precipitation by as much as 42.1 mm. Furthermore, Tdaily of these shrubs appeared to be much less sensitive to soil moisture as compared to atmospheric drivers, and the relationship between Jsn and atmospheric drivers was likely uninfluenced by soil moisture regimes in the whole profile (to 1‐m depth), especially for H. ammodendron and C. mongolicum. Results indicate that these shrubs may use deep soil water recharged by capillary rise, or may directly access shallow groundwater. This study provides quantitative data offering important implications for ecotone conservation and water and land resource management. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

7.
We have investigated the contributions of three dominant macrophyte species, Deyeuxia angustifolia, Carex lasiocarpa, and Carex pseudocuraica (covering about 10 304 km2), to carbon (C), nitrogen (N), and phosphorus (P) stocks in the largest freshwater marsh (17 300 km2) in China for a 3‐year period (from 2002 to 2004). The monthly biomass, seasonal, and annual net primary productivity (NPP), and nutrient concentrations of three species were measured. All three plant species showed rapid growth in the rainy season. The maximum and minimum production rates in the freshwater marsh were ～36.19 and ～9.92 g m?2 day?1, respectively. The total NPP accounts 1900–2700 g m?2 year?1 in the studied area. Total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP) concentrations in roots were higher than those in stem and leaf tissues. The vast beds of the three studied species comprise 80% of the grass covered marsh of Sanjiang plain, contributing annual nutrient stocks of ～10.99 × 106, ～788.36 × 103, and ～18.10 × 103 t (tonnes) for TOC, TN, and TP, respectively. Our results suggest that the nutrient bioaccumulation capacity in freshwater marshes depend mainly on plant species, which are decided by hydrological conditions. The nutrient stocks in the Sanjiang plain marsh have been greatly reduced because some of the area occupied by C. lasiocarpa was replaced by D. angustifolia as a result of succession caused by the changes of water table.  相似文献   

8.
Ambient air polycyclic aromatic hydrocarbon (PAH) samples were collected at a suburban (n = 63) and at an urban site (n = 14) in Izmir, Turkey. Average gas‐phase total PAH (∑14PAH) concentrations were 23.5 ng m?3 for suburban and 109.7 ng m?3 for urban sites while average particle‐phase total PAH concentrations were 12.3 and 34.5 ng m?3 for suburban and urban sites, respectively. Higher ambient PAH concentrations were measured in the gas‐phase and ∑14PAH concentrations were dominated by lower molecular weight PAHs. Multiple linear regression analysis indicated that the meteorological parameters were effective on ambient PAH concentrations. Emission sources of particle‐phase PAHs were investigated using a diagnostic plot of fluorene (FLN)/(fluorine + pyrene; PY) versus indeno[1,2,3‐cd]PY/(indeno[1,2,3‐cd]PY + benzo[g,h,i]perylene) and several diagnostic ratios. These approaches have indicated that traffic emissions (petroleum combustion) were the dominant PAH sources at both sites for summer and winter seasons. Experimental gas–particle partition coefficients (KP) were compared to the predictions of octanol–air (KOA) and soot–air (KSA) partition coefficient models. The correlations between experimental and modeled KP values were significant (r2 = 0.79 and 0.94 for suburban and urban sites, respectively, p < 0.01). Octanol‐based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. However, overall there was a relatively good agreement between the measured KP and soot‐based model predictions.  相似文献   

9.
Surface waters associated with peatlands, supersaturated with CO2 and CH4 with respect to the atmosphere, act as important pathways linking a large and potentially unstable global repository of C to the atmosphere. Understanding the drivers and mechanisms which control C release from peatland systems to the atmosphere will contribute to better management and modelling of terrestrial C pools. We used non‐dispersive infra‐red (NDIR) CO2 sensors to continuously measure gas concentrations in a beaver pond at Mer Bleue peatland (Canada); measurements were made between July and August 2007. Concentrations of CO2 in the surface water (10 cm) reached 13 mg C l?1 (epCO2 72), and 26 mg C l?1 (epCO2 133) at depth (60 cm). The study also showed large diurnal fluctuations in dissolved CO2 which ranged in amplitude from ～1·6 mg C l?1 at 10 cm to ～0·2 mg C l?1 at 60 cm depth. CH4 concentration and supersaturation (epCH4) measured using headspace analysis averaged 1·47 mg C l?1 and 3252, respectively; diurnal cycling was also evident in CH4 concentrations. Mean estimated evasion rates of CO2 and CH4 over the summer period were 44·92 ± 7·86 and 0·44 ± 0·25 µg C m?2s?1, respectively. Open water at Mer Bleue is a significant summer hotspot for greenhouse gas emissions within the catchment. Our results suggest that CO2 concentrations during the summer in beaver ponds at Mer Bleue are strongly influenced by biological processes within the water column involving aquatic plants and algae (in situ photosynthesis and respiration). In terms of carbon cycling, soil‐stream connectivity at this time of year is therefore relatively weak. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

10.
A two‐dimensional variable‐density groundwater flow and transport model was developed to provide a conceptual understanding of past and future conditions of nitrate (NO3) transport and estimate groundwater nitrate flux to the Gulf of Mexico. Simulation results show that contaminant discharge to the coast decreases as the extent of saltwater intrusion increases. Other natural and/or artificial surface waters such as navigation channels may serve as major sinks for contaminant loading and act to alter expected transport pathways discharging contaminants to other areas. Concentrations of NO3 in the saturated zone were estimated to range between 30 and 160 mg?L?1 as NO3. Relatively high hydraulic vertical gradients and mixing likely play a significant role in the transport processes, enhancing dilution and contaminant migration to depth. Residence times of NO3 in the deeper aquifers vary from 100 (locally) to about 300 years through the investigated aquifer system. NO3 mass fluxes from the shallow aquifers (0 to 5.7 × 104 mg?m?2?day?1) were primarily directed towards the navigation channel, which intersects and captures a portion of the shallow groundwater flow/discharge. Direct NO3 discharge to the sea (i.e. Gulf of Mexico) from the shallow aquifer was very low (0 to 9.0 × 101 mg · m?2?day?1) compared with discharge from the deeper aquifer system (0 to 8.2 × 103 mg?m?2?day?1). Both model‐calibrated and radiocarbon tracer‐determined contaminant flux estimates reveal similar discharge trends, validating the use of the model for density‐dependent flow conditions. The modelling approach shows promise to evaluate contaminant and nutrient loading for similar coastal regions worldwide. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

11.
A peatland complex disturbed by berm construction in the 1950s was used to examine the long‐term impact of water table (WT) manipulation on peatland hydraulic properties and moisture retention at three adjacent sites with increasing depth to WT (WET, INTermediate reference and DRY). Saturated hydraulic conductivity (Ks) was found to decrease with depth by several orders of magnitude over a depth of 1–1.5 m at all sites. The depth dependence of WT response to rainfall was similar across sites: WT response increased from 1 : 1 at the surface, to 5 : 1 at 50 cm depth. While surface specific yield (Sy) values were similar across all sites, it decreased with depth at a rate of 0.014 cm?1 in hollows and 0.007 cm?1 in hummocks. Bulk density (ρb) exhibited similar depth‐dependent trends as Sy and explains a high amount of variance (r2 > 0.69) in moisture retention across a range of pore water pressures (?15 to ?500 cm H2O). Because of higher ρb, hollow peat had greater moisture retention, where site effects were minimal. However, the estimated residual water content for surface Sphagnum samples, while on average lower in hummocks (0.082 m3 m?3) versus hollows (0.087 m3 m?3), increased from WET (0.058 m3 m?3) to INT (0.088 m3 m?3) to DRY (0.108 m3 m?3) which has important implications for moisture stress under conditions of persistent WT drawdown. Given the potential importance of microtopographic succession for altering peatland hydraulic structure, our findings point to the need for a better understanding of what controls the relative height and proportional coverage of hummocks in relation to long‐term disturbance‐response dynamics. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

12.
Carbon dioxide fluxes and water balance were examined in 43 tundra ponds in the northern portion of the Hudson Bay Lowland near Churchill, Manitoba. Most of the ponds were hydrologically disconnected from their catchments during dry periods throughout the post‐melt season. However, episodic reconnection occurred following large precipitation events where depression storage was exceeded. Significant shifts in pond chemistry were observed following precipitation events, with the degree of CO2 saturation increasing during these periods. Pond CO2 concentrations rapidly fell to pre‐event levels following events, suggesting that hydrological connectivity can affect the magnitude and direction of CO2 gas fluxes in tundra ponds. Atmospheric CO2 invaded ponds with highly organic sediments for most of the summer, suggesting that terrestrially derived inorganic carbon was insufficient to meet the demands of algal net production. In contrast, ponds with highly mineral sediments continued to evade CO2 during the summer. In a subset of 11 ponds, long‐term rates of carbon accumulation in sediment ranged from 0·6 to 2·2 mol C m?2 year?1. Very strong correlations existed between average sediment accumulation rates and pond perimeters and basin areas suggesting that peat may be a major source of sediment carbon. Aeolian transport is also a potentially large source of sediment carbon. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

13.
The wastewater treatment is carried out in two parallel pond groups: South–9200 m3/d, 1748 kg/d BOD5, preliminary clarifier (1.1 ha, 22000 m3), three ponds (9.8 ha, 88000 m3), naturel aeration; North ?5700 m3/d, 2394 kg/d BOD5, Imhoff tank, three ponds (7.9 ha, 71000 m3), the pond 1 artificially aerated by gyroscopic units. The different loads of 15.9 and 33.7 g/m3 d BOD5 results in rates of removal of 11.2 and 22.5 g/m3d BOD5, resp. Therefore, the efficiency of the naturally aerated system is higher than that of the artificially aerated system. In the aerated system mainly the bacterial growth is promoted, a typical algal state being achieved only slowly, whereas the naturally aerated system gains a summer-time algal maximum in the ponds 2 and 3, which is accompanied already by zooplankton populations. In the dynamics of the biomass development, the higher efficiency of the four-stage, naturally aerated system is especially obvious.  相似文献   

14.
This study investigated CO2 degassing and related carbon isotope fractionation effects in the Wiesent River that drains a catchment in the karst terrain of the Franconian Alb, Southern Germany. The river was investigated by physico‐chemical and stable isotope analyses of water and dissolved inorganic carbon during all seasons along 65‐km long downstream transects between source and mouth. Calculated pCO2 values at the source were 21 400 ± 2400 µatm. The pCO2 rapidly decreased in the river water and dropped to an average of 1240 ± 330 µatm near the mouth. About 90% of this decrease occurred within the first 6 km of the river. The river was supersaturated with respect to CO2 over its entire course and must have acted as a continuous year‐round CO2 source to the atmosphere. The average CO2 flux from the karst river was estimated with 450 mmol m?2 day?1 with higher fluxes up to 5680 mmol m?2 day?1 at the source. At the source, δ13CDIC values showed no seasonal variations with an average of ?14.2 ± 0.2‰. This indicated that groundwater retained high pCO2 mainly from soil CO2. The contribution of soil CO2 to dissolved inorganic carbon was estimated at 65% to 72%. The downstream CO2 loss caused a positive shift in δ13CDIC values of 2‰ between source and mouth because of the preferential loss of the 12C isotope during degassing. Considering the findings of this study and the fact that carbonate lithology covers a significant part of the earth's surface, CO2 evasion from karst regions might contribute notably to the annual carbon dioxide release from global freshwater systems. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

15.
In this study, we examined the year 2011 characteristics of energy flux partitioning and evapotranspiration of a sub‐alpine spruce forest underlain by permafrost on the Qinghai–Tibet Plateau (QPT). Energy balance closure on a half‐hourly basis was H + λE = 0.81 × (Rn ? G ? S) + 3.48 (W m?2) (r2 = 0.83, n = 14938), where H, λE, Rn, G and S are the sensible heat, latent heat, net radiation, soil heat and air‐column heat storage fluxes, respectively. Maximum H was higher than maximum λE, and H dominated the energy budget at midday during the whole year, even in summer time. However, the rainfall events significantly affected energy flux partitioning and evapotranspiration. The mean value of evaporative fraction (Λ = λE/(λE + H)) during the growth period on zero precipitation days and non‐zero precipitation days was 0.40 and 0.61, respectively. The mean daily evapotranspiration of this sub‐alpine forest during summer time was 2.56 mm day?1. The annual evapotranspiration and sublimation was 417 ± 8 mm year?1, which was very similar to the annual precipitation of 428 mm. Sublimation accounted for 7.1% (30 ± 2 mm year?1) of annual evapotranspiration and sublimation, indicating that the sublimation is not negligible in the annual water balance in sub‐alpine forests on the QPT. The low values of the Priestley–Taylor coefficient (α) and the very low value of the decoupling coefficient (Ω) during most of the growing season suggested low soil water content and conservative water loss in this sub‐alpine forest. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

16.
Dioxin‐like compounds from regular, occasional or fugitive airborne sources of emission may fall out on fodders close to be harvested for silage and hay production. In this way, a prolonged long‐term intake of contaminated forages in dairy animals may be envisaged, able to determine a rise of the background contamination in milk. We simulated different risk scenarios taking into account the inventoried bulk dry depositions in rural areas of the aforesaid contaminants, silage and hay biomass production per hectare, forages regimen in dairy animals, and the congeners carry‐over rate (COR) from forages to milk. Considering atmospheric depositions >10 pg I‐TE m?2 day?1 and accounting for a 30% COR, dairy milk could rise up to the PCDD/F level of 3 pg WHO1998‐TE g?1 fat. The modelling indicates that in rural areas bulk emissions should be selectively minimised, accounting for the calendar of the different agricultural practices, because of their potential impact on the fodders. Since environmental factors play a non‐negligible role in food production, a stronger harmonisation between I‐TE and WHO1998–2005‐TE scales with respect to dioxin‐like polychlorobiphenyl congeners inclusion is envisaged. This will allow the prevention of the human indirect exposure to such contaminants when released in the air.  相似文献   

17.
Strategic planning of optimal water use requires an accurate assessment of actual evapotranspiration (ETa) to understand the environmental and hydrological processes of the world's largest contiguous irrigation networks, including the Indus Basin Irrigation System (IBIS) in Pakistan. The Surface Energy Balance System (SEBS) has been used successfully for accurate estimations of ETa in different river basins throughout the world. In this study, we examined the application of SEBS using publically available remote sensing data to assess spatial variations in water consumption and to map water stress from daily to annual scales in the IBIS. Ground‐based ETa was calculated by the advection‐aridity method, from nine meteorological sites, and used to evaluate the intra‐annual seasonality in the hydrological year 2009–2010. In comparison with the advection‐aridity, SEBS computed daily ETa was slightly underestimated with a bias of ?0.15 mm day?1 during the kharif (wet; April–September) season, and it was overestimated with a bias of 0.23 mm day?1 in the rabi (dry; October–March) season. Monthly values of the ETa estimated by SEBS were significantly (P < 0.05) controlled by mean air temperature and rainfall, among other climatological variables (relative humidity, sunshine hours and wind speed). Because of the seasonal (kharif and rabi) differences in the water and energy budget in the huge canal command areas of the IBIS, ETa and rainfall were positively correlated in the kharif season and were negatively correlated during the rabi season. In addition, analysis of the evaporation process showed that mixed‐cropping and rice–wheat dominated areas had lower and higher water consumption rates, respectively, in comparison with other cropping systems in the basin. Basin areas under water stress were identified by means of spatial variations in the relative evapotranspiration, which had an average value of 0.59 and 0.42 during the kharif and the rabi seasons, respectively. The hydrological parameters used in this study provide useful information for understanding hydrological processes at different spatial and temporal scales. Results of this study further suggest that the SEBS is useful for evaluation of water resources in semi‐arid to arid regions over longer periods, if the data inputs are carefully handled. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

18.
Manganese transport through a well-developed oxygen minimum was studied off central Mexico (18°N, 108°W) in October–November 1981 as part of the VERTEX (Vertical Transport and Exchange) research program. Refractory, leachable and dissolved Mn fractions associated with particulates caught in traps set at eight depths (120–1950 m) were analyzed. Particles entering the oxygen minimum had relatively large Mn loads; however, as the particulates sank further into the minimum, total Mn fluxes steadily decreased from 190 nmol m?2 day?1 at 120 m to 36 nmol m?2 day?1 at 400 m. Manganese fluxes then steadily increased in the remaining 800–1950 m, reaching rates of up to 230 nmol m?2 day?1 at 1950 m.Manganese concentrations were also measured in the water column. Dissolved Mn levels < 3.0 nmol kg?1 were consistently observed within the 150–600 m depth interval. In contrast, suspended particulate leachable Mn amounts were especially low at those depths, and never exceeded 0.04 nmol kg?1.The combined water column and particle trap data clearly indicate that Mn is released from particles as they sink through the oxygen minimum. Rate-of-change estimates based on trap flux data yield regeneration rates of up to 0.44 nmol kg?1 yr?1 in the upper oxygen minimum (120–200 m). However, only 30% of the dissolved Mn in the oxygen minimum appears to be from sinking particulate regeneration; the other 70% probably results from continental-slope-release-horizontal-transport processes.Dissolved Mn scavenges back onto particles as oxygen levels begin to increase with depth. Scavenging rates ranging from ?0.03 to ?0.09 nmol kg?1 yr?1 were observed at depths from 700 to 1950 m. These scavenging rates result in Mn residence times of 16–19 years, and scavenging rate constants on the order of 0.057 yr?1. Manganese removal via scavenging on sinking particles below the oxygen minimum is balanced by Mn released along continental boundaries and transported horizontally via advective-diffusive processes.Manganese appears to be very weakly associated with particulates. Nevertheless, the amounts of Mn involved with sinking biogenic particles are large, and the resulting fluxes are on the same order of magnitude as those necessary to explain the excess Mn accumulating on the sea floor. The overall behavior of Mn observed in this, and other, studies strongly suggests some type of equilibrium occurring between dissolved and particulate phases. This equilibrium appears to shift in direct or indirect response to dissolved oxygen levels.  相似文献   

19.
Laccase from the white‐rot fungus Pleurotus florida, produced under solid‐state fermentation conditions, was used for the decolorization of reactive dye Remazol Brilliant Blue R (RBBR). RBBR was decolorized up to 46% by P. florida laccase alone in 10 min. In the presence of N‐hydroxybenzotriazole (HBT), the rate of decolorization was enhanced 1.56‐fold. Central composite design of response surface methodology with four variables namely, dye, enzyme, redox mediator concentrations, and time at five levels was applied to optimize the RBBR decolorization. The predicted optimum level of variables for maximum RBBR decolorization (87%) was found to be 52.90 mg L?1 (RBBR), 1.87 U mL?1 (laccase), 0.85 mM (HBT), and 7.17 min (time), respectively. The validation results showed that the experimental value of RBBR decolorization (82%) was close to the predicted one. The disappearance of C–N and C–X groups, and a small shift in N–H groups in Fourier‐transform infra red (FTIR) spectroscopy confirms the degradation of RBBR chromophore by laccase enzyme. The phytotoxicity of RBBR was considerably reduced after the treatment with laccase. RBBR decolorization kinetics; Km and Vmax were calculated to be 145.82 mg L?1 and 24.86 mg L?1 min, respectively.  相似文献   

20.
A large quantity of submarine groundwater discharge (SGD) of about 1000 m3 day?1 m?1 of the 600‐km‐long shoreline of South Atlantic Bight has been estimated by Moore (Global Biogeochemical Cycles, 2010b, 24, GB4005, doi: 10.1029/2009GB003747 ). However, there is great uncertainty in estimating the percentage of net, land‐originated groundwater recharge of SGD. Moreover, most previous studies considered the homogeneous case for the coastal superficial aquifers. Here, we investigated the terrestrial‐originated SGD through a multilayered submarine aquifer system, which comprises two confined aquifers and two semi‐permeable layers. The inland recharge includes a constant part representing the annual average and a periodical part representing its seasonal variation. An analytical solution was derived and used to analyse the distributions of the terrestrial‐originated SGD from the multilayered aquifers along the Winyah Bay transect, South Atlantic Bight. It is found that the width of the zone of SGD from the upper aquifer ranges from ~0.8 to ~8.0 km depending on the leakance of the seabed semi‐permeable layer. A head of the upper aquifer at a coastline 1.0 m higher than the mean sea level will cause a SGD of 1.82– 18.3 m3 day?1 m?1 from that aquifer as the seabed semi‐permeable layer's leakance varies from 0.001 to 0.1 day?1, providing considerable possibility for considerable land‐originated SGD. Seasonal terrestrial‐originated SGD variations predicted by the analytical model provide consistent explanation of the seasonal variation of 226Ra observed by Moore (Journal of Geophysics, 2007, 112, C10013, doi: 10.1029/2007JC004199 ). The contribution of the lower aquifer to SGD is only 1.2–12% of that of the upper aquifer. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

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