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1.
A background indoor air study has been completed which includes the collection of indoor air samples from office buildings and schools. The anonymous study was designed with input from the U.S. Environmental Protection Agency and the Massachusetts Department of Environmental Protection. The sampling was implemented in 2013, 2014, and 2015 and included the collection of 25 school building samples and 61 office building samples. The study generated 14,668 new indoor air background data points, with samples collected from buildings located in 26 cities in 18 states, including Arizona, California, Connecticut, Indiana, Kansas, Maine, Massachusetts, Minnesota, Montana, New Hampshire, New Jersey, New York, Nevada, North Carolina, Ohio, Texas, Utah, and Washington. Indoor air background concentrations of target compound volatile organic compounds (VOCs) ranged from less than the laboratory method reporting limit of 0.044 μg/m3 to concentrations up to 1190 μg/m3, with hydrocarbon ranges from less than the reporting method limit of 10 μg/m3 to concentrations up to 3000 μg/m3. Some VOCs were identified ubiquitously in indoor air background, and some were identified at concentrations which exceeded risk-based regulatory screening levels. These study results provide useful and updated information on indoor air background and air quality in offices and schools and can be used in future regulatory guidance update considerations, for further examination of relationships between these data and residential study data, in human health risk assessments and risk communication, and in planning future studies.  相似文献   

2.
Subslab or shallow soil-gas data are often compared with indoor air concentration data in vapor intrusion (VI) evaluations. If no indoor air data are available or confounding sources are present, or if future scenarios are considered, the soil-gas data may be used to estimate the indoor air concentrations due to VI. The typical approach in risk assessments is to use the 95th percentile values from a set of concentration data. For VI studies, however, this rarely is an option because the data sets tend to be quite small. Therefore, various guidance documents urge the use of maximum soil-gas values. This may be reasonable for small residential buildings, but can lead to very conservatively biased estimates if applied to large industrial buildings with localized areas of contamination, especially given that the sampling locations may not be randomly selected and instead are biased toward worst-case locations. By this approach, VI guidance implicitly tolerates a large percentage of false positive decision errors to minimize the number of false negative decision errors. In this paper, implications of using maximum values are discussed and illustrated with data sets from a number of large industrial buildings at various sites. An alternative approach to using maximum soil-gas values is proposed that serves to reduce the number of false positive results while controlling the number of false negatives to an acceptable level.  相似文献   

3.
Heating, ventilating, and air‐conditioning (HVAC) systems ensure indoor air quality and provide a comfortable environment. However, the conventional HVAC systems only provide indoor ventilation and adjust temperature and humidity. This work removes indoor volatile organic compounds (VOCs) using a feasible and novel air‐cleaning for an HVAC system, to remove indoor VOCs. An activated carbon‐fiber (ACF) filter calcined with copper oxide (CuO) catalyst, called a CuO/ACF catalyst filter, was the developed kit. Formaldehyde, a major VOC, was chosen as the target pollutant. Experiments were performed to confirm the filtration ability of the CuO/ACF catalyst filter in removing formaldehyde in a stainless‐steel chamber equipped with a simplified HVAC system. Total air exchange rate (ACH) was controlled at 0.5 and 1.0 h−1, the fresh ACH was 0.15 and 0.30 h−1, and relative humidity (RH) was set at 30 and 70%. A first‐order decay of formaldehyde existed in the controlled chamber when the two pretreated CuO/ACF catalyst filters were employed. Experimental results demonstrate that the CuO/ACF catalyst filters removed formaldehyde effectively. The decay constant was 0.425 and 0.618 h−1 for 0.5 and 2.0 ppm formaldehyde, respectively. Moreover, the formaldehyde decay rate increased as total ACH, fresh ACH, RH, and the Cu(NO3)2 concentration for calcination of CuO/ACF catalyst filter increased.  相似文献   

4.
Emissions from construction products may have a significant impact on the quality of indoor air, particularly in energy‐efficient buildings, where the normal rate of air exchange with fresh ambient air may be limited. In this context, reduction strategies to mitigate the concentration of chemicals in the indoor environment have become even more important. German authorities wanted to foster the development of low‐emission products, and as a result it was necessary to quantify and qualify these emissions in a reliable and objective manner. The core principles for evaluation of the standardized measurements in emission tests were established by the “Committee for Health‐Related Evaluation of Building Products” (AgBB) and published in the so‐called “AgBB scheme”. Relevant for evaluation are: (i) Assessment of the emission levels of substances with known toxicological properties; (ii) limits for non‐assessable or unknown substances; (iii) limits for the total amount of chemical emissions. This review describes the stepwise implementation of the test procedure in Germany and the experience gained in evaluation of product emissions over the years. A comprehensive overview of the philosophy, history, current practices, and future directions of the German AgBB scheme for VOC emissions is also provided. Special emphasis is given to the evaluation of a list of about 170 single substances which have an agreed “lowest concentration of interest” (LCI) value for the indoor environment – values that are updated periodically according to present toxicological knowledge.  相似文献   

5.
Reservoirs are man‐made lakes that severely impact on river ecosystems, and in addition, the new lake ecosystem can be damaged by several processes. Thus, the benefits of a reservoir, including energy production and flood control, must be measured against their impact on nature. New investigations point out that shallow and tropical reservoirs have high emission rates of the greenhouse gases CO2 and CH4. The methane emissions contribute strongly to climate change because CH4 has a 25 times higher global warming potential than CO2. The pathways for its production include ebullition, diffuse emission via the water‐air interface, and degassing in turbines and downstream of the reservoir in the spillway and the initial river stretch. Greenhouse gas emissions are promoted by a eutrophic state of the reservoir, and, with higher trophic levels, anaerobic conditions occur with the emission of CH4. This means that a qualitative and quantitative jump in greenhouse gas emissions takes place. Available data from Petit Saut, French Guinea, provides a first quantification of these pathways. A simple evaluation of the global warming potential of a reservoir can be undertaken using the energy density, the ratio of the reservoir surface and the hydropower capacity; this parameter is mainly determined by the reservoir's morphometry but not by the hydropower capacity. Energy densities of some reservoirs are given and it is clearly seen that some reservoirs have a global warming potential higher than that of coal use for energy production.  相似文献   

6.
Energy dissipation devices are necessary for base‐isolated buildings to control the deformation in the isolation system and to dissipate the earthquake‐induced energy. U‐shaped steel dampers (also known as U‐dampers) dissipate energy through plastic deformation of specially designed U‐shaped steel elements. This type of device can be installed at several locations in the isolation system. U‐dampers have been widely used in Japan for different types of isolated structures, such as hospitals, plants and residential buildings, since the 1995 Kobe Earthquake. Previous research has used static tests to estimate the performance of U‐dampers. However, the ultimate plastic deformation capacities and hysteretic behaviors of full‐scale U‐dampers under dynamic excitations still remain unclear. In addition, it is unclear whether the initial temperature has an effect on the hysteretic behavior and plastic deformation capacity of U‐dampers. In this paper, two series of dynamic loading tests of U‐dampers were conducted to evaluate the issues described earlier. The major findings of the study are (i) the loading speed has little effect on the plastic deformation capacity of U‐dampers; (ii) method to evaluate the ultimate plastic deformation capacities of U‐shaped steel dampers of different sizes is established using a Manson–Coffin relation‐based equation that is based on the peak‐to‐peak horizontal shear angle γt, which is defined as the lateral deformation amplitude (peak‐to‐peak amplitude) divided by the height of the dampers; (iii) the loading rate and the initial temperature have a minimal effect on the hysteretic behavior of the U‐dampers; and (iv) a bilinear model is proposed to simulate the force‐deformation relationships of the U‐dampers. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

7.
Accompanying economic growth, CO2 emissions have polluted the natural environment worldwide. This study highlights the special problems with stock market development and CO2 emissions in 25 Organization for Economic Cooperation and Development (OECD) countries during 1971–2007 to trace the trend of CO2 emissions while countries grow their economies. A panel‐data model is applied to analyze the relationships between stock market (SM) development, energy consumption, gross domestic product (GDP), and CO2 emissions in 25 OECD countries. Low‐GDP countries show different results from high‐GDP countries in the trends of SM development and CO2 emissions, and dynamic effects occur in SM development and CO2 emissions under various GDP conditions. There is a negative relationship between SM development and CO2 emissions if countries enjoy high economic growth, which means that these countries avoid CO2 emissions through SM development. However, a positive relationship is found between SM development and CO2 emissions if countries experience low economic growth, which means that SM development does not show the boycott‐effect relationship with CO2 emissions when countries experience low levels of economic development. This study shows a correlation between SM development and CO2 emissions among OECD countries.  相似文献   

8.
The Jing‐Jin‐Ji (Beijing‐Tianjin‐Hebei) and the surrounding Jin‐Lu‐Yu (Shanxi‐Shandong‐Henan) regions are experiencing severe problems with air pollution. To measure the change in pollutant concentrations over the next few years, the fractional order accumulation grey model is used to forecast the air quality indicators. The results show that the concentrations of fine particulate matter, particulate matter 10, and sulfur dioxide show a downward trend, and 8‐h O3 (annual) and 8‐h O3 (spring and summer) show an upward trend in these areas. There is a slight increase in nitrogen dioxide concentration in Shanxi, but its concentration in other areas shows a slight decline. The results obtained can provide a clear direction for air quality management decisions.  相似文献   

9.
A value of 0.001 is recommended by the United States Environmental Protection Agency (USEPA) for its groundwater‐to‐indoor air Generic Attenuation Factor (GAFG), used in assessing potential vapor intrusion (VI) impacts to indoor air, given measured groundwater concentrations of volatile chemicals of concern (e.g., chlorinated solvents). The GAFG can, in turn, be used for developing groundwater screening levels for VI given target indoor air quality screening levels. In this study, we examine the validity and applicability of the GAFG both for predicting indoor air impacts and for determining groundwater screening levels. This is done using both analysis of published data and screening model calculations. Among the 774 total paired groundwater‐indoor air measurements in the USEPA's VI database (which were used by that agency to generate the GAFG) we found that there are 427 pairs for which a single groundwater measurement or interpolated value was applied to multiple buildings. In one case, up to 73 buildings were associated with a single interpolated groundwater value and in another case up to 15 buildings were associated with a single groundwater measurement (i.e., that the indoor air contaminant concentrations in all of the associated buildings were influenced by the concentration determined at a single point). In more than 70% of the cases (390 of 536 paired measurements in which horizontal building‐monitoring well distance was recorded) the monitoring wells were located more than 30 m (and one up to over 200 m) from the associated buildings. In a few cases, the measurements in the database even improbably implied that soil gas contaminant concentrations increased, rather than decreased, in an upward direction from a contaminant source to a foundation slab. Such observations indicate problematic source characterization within the data set used to generate the GAFG, and some indicate the possibility of a significant influence of a preferential contaminant pathway. While the inherent value of the USEPA database itself is not being questioned here, the above facts raise the very real possibility that the recommended groundwater attenuation factors are being influenced by variables or conditions that have not thus far been fully accounted for. In addition, the predicted groundwater attenuation factors often fall far beyond the upper limits of predictions from mathematical models of VI, ranging from screening models to detailed computational fluid dynamic models. All these models are based on the same fundamental conceptual site model, involving a vadose zone vapor transport pathway starting at an underlying uniform groundwater source and leading to the foundation of a building of concern. According to the analysis presented here, we believe that for scenarios for which such a “traditional” VI pathway is appropriate, 10?4 is a more appropriately conservative generic groundwater to indoor air attenuation factor than is the EPA‐recommended 10?3. This is based both on the statistical analysis of USEPA's VI database, as well as the traditional mathematical models of VI. This result has been validated by comparison with results from some well‐documented field studies.  相似文献   

10.
Numerical studies of existing buildings demonstrate the effectiveness of nonlinear/inelastic rooftop tuned mass damper frames (NRTMDF) used as a retrofit for reducing seismic response. The technique utilizes a rooftop penthouse as a tuned mass damper with mass incorporated as the roof deck of the penthouse while targeted nonlinearity and energy dissipation are introduced through buckling restrained braces (BRBs) linking the penthouse mass to the structure below. The writers summarize numerical studies of ten existing buildings modified with a specifically tuned NRTMDF. The studies demonstrate the effectiveness of the technique that stems from elastic and transient inelastic period shifts enabled by the damper coupled with targeted energy dissipation in the penthouse BRBs. Numerical simulations using response nonlinear time‐history analysis techniques show that for many structures and sites, the NRTMDF decreases peak transient response and overall seismic demand of the original structure. The technique also reduces seismic demand on nonstructural elements and components, manifested as reductions in floor acceleration spectra. Energy methods show that the approach enables significant reductions in energy demand on the original structure through the complete earthquake acceleration history. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

11.
A model is presented for estimating vapor concentrations in buildings because of volatilization from soil contaminated by non- aqueous phase liquids (NAPL) or from dissolved contaminants in ground water. The model considers source depletion, diffusive- dispersive transport of the contaminant of concern (COC) and of oxygen and oxygen-limited COC biodecay. Diffusive-advective transport through foundations and vapor losses caused by foundation cross-flow are considered. Competitive oxygen use by various species is assumed to be proportional to the product of the average dissolved-phase species concentration and a biopreference factor. Laboratory and field data indicate the biopreference factor to be proportional to the organic carbon partition coefficient for the fuel hydrocarbons studied. Predicted indoor air concentrations were sensitive to soil type and subbase permeability. Lower concentrations were predicted for buildings with shallow foundations caused by flushing of contaminants by cross-flow. NAPL source depletion had a large impact on average exposure concentration. Barometric pumping had a minor effect on indoor air emissions for the conditions studied. Risk-based soil cleanup levels were much lower when biodecay was considered because of the existence of a threshold source concentration below which no emissions occur. Computed cleanup levels at NAPL-contaminated sites were strongly dependent on total petroleum hydrocarbon (TPH) content and COC soil concentration. The model was applied to two field sites with gasoline-contaminated ground water. Confidence limits of predicted indoor air concentrations spanned approximately two orders of magnitude considering uncertainty in model parameters. Measured contaminant concentrations in indoor air were within model-predicted confidence limits.  相似文献   

12.
A separation procedure was developed for analysis of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) in urban air, while simultaneously eliminating the interfering compounds. This was carried out by optimization of a column chromatograph with regard to the eluent type (n‐hexane and n‐pentane), volume of eluent, type of sorbent material (silica gel and florisil) and activation level of the sorbent material. The determination of the level of PCBs and PAHs was carried out using gas chromatography (GC) equipped with a mass selective detector (MSD), while determination of the OCPs was carried out by GC equipped with an electron capture detector (μ‐ECD). The use of a silica gel column (10 g, 5% deactivated with H2O) with 70 mL of n‐hexane gave satisfactory separation of PCBs from PAHs and OCPs. After collecting the PCBs with 70 mL of n‐hexane, 3·20 mL of n‐hexane:ethyl acetate, (1:1, v:v) was adequate for elution of the PAHs and OCPs from the column. The primary aim of this study was to develop a multimethod for analyses of PCBs, PAHs, and OCPs in urban air as well as reducing solvent and sorbent consumption and analysis time during the clean‐up procedure compared to the US EPA standard methods (EPA methods TO‐13A for PAHs and TO‐4A for both PCBs and OCPs).  相似文献   

13.
This paper examines the potential development of a probabilistic design methodology, considering hysteretic energy demand, within the framework of performance‐based seismic design of buildings. This article does not propose specific energy‐based criteria for design guidelines, but explores how such criteria can be treated from a probabilistic design perspective. Uniform hazard spectra for normalized hysteretic energy are constructed to characterize seismic demand at a specific site. These spectra, in combination with an equivalent systems methodology, are used to estimate hysteretic energy demand on real building structures. A design checking equation for a (hypothetical) probabilistic energy‐based performance criterion is developed by accounting for the randomness of the earthquake phenomenon, the uncertainties associated with the equivalent system analysis technique, and with the site soil factor. The developed design checking equation itself is deterministic, and requires no probabilistic analysis for use. The application of the proposed equation is demonstrated by applying it to a trial design of a three‐storey steel moment frame. The design checking equation represents a first step toward the development of a performance‐based seismic design procedure based on energy criterion, and additional works needed to fully implement this are discussed in brief at the end of the paper. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

14.
The estimation of cyclic deformation demand resulting from earthquake loads is crucial to the core objective of performance‐based design if the damage and residual capacity of the system following a seismic event needs to be evaluated. A simplified procedure to develop the cyclic demand spectrum for use in preliminary seismic evaluation and design is proposed in this paper. The methodology is based on estimating the number of equivalent cycles at a specified ductility. The cyclic demand spectrum is then determined using well‐established relationships between seismic input energy and dissipated hysteretic energy. An interesting feature of the proposed procedure is the incorporation of a design spectrum into the proposed procedure. It is demonstrated that the force–deformation characteristics of the system, the ductility‐based force‐reduction factor Rμ, and the ground motion characteristics play a significant role in the cyclic demand imposed on a structure during severe earthquakes. Current design philosophy which is primarily based on peak response amplitude considers cyclic degradation only in an implicit manner through detailing requirements based on observed experimental testing. Findings from this study indicate that cumulative effects are important for certain structures, classified in this study by the initial fundamental period, and should be incorporated into the design process. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

15.
CO2 has been injected into the saline aquifer Utsira Fm at the Sleipner field since 1996. In order to monitor the movement of the CO2 in the sub‐surface, the seventh seismic monitor survey was acquired in 2010, with dual sensor streamers which enabled optimal towing depths compared to previous surveys. We here report both on the time‐lapse observations and on the improved resolution compared to the conventional streamer surveys. This study shows that the CO2 is still contained in the subsurface, with no indications of leakage. The time‐lapse repeatability of the dual sensor streamer data versus conventional data is sufficient for interpreting the time‐lapse effects of the CO2 at Sleipner, and the higher resolution of the 2010 survey has enabled a refinement of the interpretation of nine CO2 saturated layers with improved thickness estimates of the layers. In particular we have estimated the thickness of the uppermost CO2 layer based on an analysis of amplitude strength together with time‐separation of top and base of this layer and found the maximum thickness to be 11 m. This refined interpretation gives a good base line for future time‐lapse surveys at the Sleipner CO2 injection site.  相似文献   

16.
Past studies of entrapped air dissolution have focused on one‐dimensional laboratory columns. Here the multidimensional nature of entrapped air dissolution was investigated using an indoor tank (180 × 240 × 600 cm3) simulating an unconfined sand aquifer with horizontal flow. Time domain reflectometry (TDR) probes directly measured entrapped air contents, while dissolved gas conditions were monitored with total dissolved gas pressure (PTDG) probes. Dissolution occurred as a diffuse wedge‐shaped front from the inlet downgradient, with preferential dissolution at depth. This pattern was mainly attributed to increased gas solubility, as shown by PTDG measurements. However, compression of entrapped air at greater depths, captured by TDR and leading to lower quasi‐saturated hydraulic conductivities and thus greater velocities, also played a small role. Linear propagation of the dissolution front downgradient was observed at each depth, with both TDR and PTDG, with increasing rates with depth (e.g, 4.1 to 5.7× slower at 15 cm vs. 165 cm depth). PTDG values revealed equilibrium with the entrapped gas initially, being higher at greater depth and fluctuating with the barometric pressure, before declining concurrently with entrapped air contents to the lower PTDG of the source water. The observed dissolution pattern has long‐term implications for a wide variety of groundwater management issues, from recharge to contaminant transport and remediation strategies, due to the persistence of entrapped air near the water table (potential timescale of years). This study also demonstrated the utility of PTDG probes for simple in situ measurements to detect entrapped air and monitor its dissolution.  相似文献   

17.
The modal pushover‐based scaling (MPS) procedure, currently restricted to symmetric‐plan buildings, is extended herein to unsymmetric‐plan buildings. The accuracy of the extended MPS procedure was evaluated for a large set of three‐degree‐of‐freedom unsymmetric‐plan structures with variable stiffness and strength. The structures were subjected to nonlinear response history analysis considering sets of seven records scaled according to the MPS procedure. Structural responses were compared against the benchmark values, defined as the median values of the engineering demand parameters due to 30 unscaled records. This evaluation of the MPS procedure has led to the following conclusions: (i) the MPS procedure provided accurate estimates of median engineering demand parameter values and reduced record‐to‐record variability of the responses; and (2) the MPS procedure is found to be much superior compared to the ASCE/SEI 7‐10 scaling procedure for three‐dimensional analysis of unsymmetric‐plan buildings. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

18.
Air temperature feedback results from the thermal-radiative coupling between the atmosphere and the surface and plays an important role in surface energy balance. This paper reveals the contribution of air temperature feedback to the global warming from 1980 to 2000. The air temperature feedback kernel, evaluated using the ERA-Interim reanalysis data, is used to discuss the physical mechanism for air temperature feedback, the dependency of the strength of air temperature feedback on the climatological spatial distributions of air temperature, water vapor and cloud content, and the contributions of air temperature feedback to rapid global warming. The coupling between temperature feedback and each of the external forcings and individual feedback processes will amplify the anomaly of direct energy flux convergence at the surface induced by the external forcings and individual processes. The air temperature feedback amplifies the initial surface warming due to the increase in CO2 concentration, ice and snow melting, increase in water vapor, and change in ocean heat storage. It also amplifies the surface warming due to the longwave radiaitve forcing associated with the increase in cloud cover, which acts to suppress the cooling of the shortwave effect of cloud forcing. Overall, temperature feedback plays an important role in the global warming from 1980 to 2000, as the net positive contribution to the perturbation of global mean energy flux at the surface from the air temperature feedback is larger than the net negative contribution from external forcing and all non-temperature feedbacks.  相似文献   

19.
A procedure for incorporating record‐to‐record variability into the simplified seismic assessment of RC wall buildings is presented. The procedure relies on the use of the conditional spectrum to randomly sample spectral ordinates at relevant periods of vibration. For inelastic response, displacement reduction factors are then used to relate inelastic displacement demand to the spectral displacement at the effective period for single‐degree‐of‐freedom systems. Simple equations are used to convert back and forth between multi‐degree‐of‐freedom RC wall buildings and equivalent single‐degree‐of‐systems so that relevant engineering demand parameters can be obtained. Consideration is also given to higher‐mode effects by adapting existing modal combination rules. The proposed method is applied to several case study buildings, showing promising results in the examination of inter‐storey drift ratio and shear forces. The proposed method captures the variation in the distribution of structural response parameters that occurs with variations in structural configuration, intensity, engineering demand parameter of interest and site characteristics. Discussion is provided on possible ways to improve the accuracy of the procedure and suggestions for additional future work. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

20.
This study assesses the 3D amplification effects in shallow basins and quantifies the effects of site‐city interaction (SCI) on high‐rise buildings. A regional‐scale 3D spectral element simulation is conducted on the Tuen Mun‐Yuen Long basin, which contains multiple subbasins with heterogeneous and nonlinear soil profiles, while 3D city models with various building layouts are fully integrated into the basin model for our SCI study. We found a good correlation between spectral amplification factors and soil depths. Site response is significantly amplified at basin edges and centers due to surface waves generated at basin edges and the focusing effects stemming from 3D basin geometry. Transfer functions of 3D basins can be up to fourfold at fundamental frequencies as compared to 1D response, and further amplifications occur at high frequencies due to surface waves. In the SCI simulations, we observe wave trapping in the open space amid buildings resulting in energy concentration and up to twofold PGA amplifications. The wave trapping effect diminishes as the space between buildings increase beyond their range of influence (～100 m). The SCI analyses show that destructive kinetic energy in superstructures increases 28% in one horizontal direction but decreases 22% in the other. Our study concluded that, 1D site response analysis can significantly underestimate the seismic demand in shallow basins. Site‐city interaction of high‐rise buildings increases the short‐period spectra of ground motions, leading to an increase in their story accelerations by up to 50% and to a substantial decrease in the seismic safety of short structures in their vicinity.  相似文献   

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