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1.
Influence of Marble’s Texture on its Mechanical Behavior 总被引：1，自引：1，他引：0
This research work studied the influence of texture on the mechanical properties of crystalline rocks at the scale of the laboratory sample. The experiments were performed on a marble varying in texture, so that the study was conducted on homogeneous (entirely xenoblastic or totally granoblastic) and heterogeneous (mix of the two textures) specimens. The mechanical behavior of the homogeneous and heterogeneous samples was investigated with static and dynamic, destructive and nondestructive tests, in natural conditions, at the laboratory temperature, and at higher temperatures. The specimens were heated to 100, 200, and 300 °C, in order to examine the effect of heating temperature on the elastic modulus and P-waves velocity. As a result, the pure granoblastic marble exhibits values of the elastic modulus, P-waves velocity, and strengths, both in natural conditions and on heated specimens, lower than xenoblastic samples. Such different behavior can be explained by a higher grain boundaries porosity of the granoblastic marble. On heterogeneous samples, only the Rock Impact Hardness Number (RIHN) appears able to highlight the dependence of the mechanical properties on the rock texture. In particular, the impact strength improves with increasing the percentage of xenoblastic texture inside the specimen. 相似文献
2.
3.
K-feldspar crystals >5 cm in greatest dimension are common in calc-alkaline granites and granodiorites worldwide. Such megacrysts are generally interpreted as having grown to large sizes early in a magma’s crystallization history while they were largely molten, owing to field relations such as megacryst alignment and megacryst-rich clusters and to crystallographic features such as zonally arranged inclusions and sawtooth Ba zoning. These features are consistent with early growth but do not require it. In contrast, experimental petrology, mineral compositions, and natural examples of partial melting of granite demonstrate that K-feldspar is typically the last major phase to crystallize and that most K-feldspar growth occurs after the magma crosses the rheologic lock-up threshold of ~50 % crystals. The near-absence of K-feldspar phenocrysts in dacite lavas and tuffs, even in highly crystalline ones, demonstrates that natural magmas do not precipitate significant K-feldspar while they are mobile. The highly potassic compositions of megacrysts (and indeed, of K-feldspar in non-megacrystic granites as well) require exsolution of albite component down to temperatures of ~400 °C. The low Ca contents of megacrysts cannot result from exsolution of anorthite and must represent recrystallization of the crystals at low temperature. These mineralogical and experimental constraints require that K-feldspar megacrysts indicate widespread and thorough recrystallization of the host granites and granodiorites. 相似文献
4.
利用岩石薄片和扫描电镜分析等测试技术, 可以将济阳坳陷罗家地区古近系沙河街组页岩段储集空间分为孔隙和裂缝两大类。孔隙又可以分为黏土矿物晶间孔、碳酸盐矿物晶间孔、黄铁矿晶间微孔、碎屑颗粒溶孔和砂质粒间微孔5个亚类;裂缝分为成岩裂缝和构造裂缝两大类, 成岩裂缝又可以分为层间裂缝和粒缘裂缝两类。裂缝与基质孔隙之间, 存在一个微米尺度的重合带, 反映了储集空间发育继承性的特点, 油气聚集在以层间裂缝为中心, 粒缘裂缝等次级裂缝和较大的碳酸盐晶间孔为骨架, 以各类晶间孔隙、黏土微孔和溶蚀孔隙为基质的储集空间网络中。储集空间发育与岩性关系密切, 纹层状泥质灰岩物性较好, 相应的页岩物性具有基质渗透率极低和裂缝导流能力较强的特点。 相似文献
5.
Sandstone alterations triggered by fire-related temperatures 总被引：1，自引：1，他引：0
Z. Kompaníková M. Gomez-Heras J. Michňová T. Durmeková J. Vlčko 《Environmental Earth Sciences》2014,72(7):2569-2581
The aim of the study was to identify and describe changes in two different sandstone types when undergoing different environmental and extreme temperature regimes to assess the possibility of finding insolation weathering and how these sandstones would behave during and after a fire. The first step was the simulation in the laboratory of temperature regimes up to 60 °C which would correspond to extreme events that could be found in insolation cycles even in Central Europe and the second one was the temperature above 200 °C simulating in laboratory conditions the thermal regime of a potential fire situation at temperatures up to 200, 400, 600 and 800 °C. Heating the samples above 400 °C led to gradual changes in mineral composition, colour, surface roughness and physical properties reaching, eventually, total rock breakdown through spalling and granular disaggregation. The different behaviour of sandstones exposed to high temperatures is mainly caused by their different mineral composition with various ratios of minerals that are more or less chemically stable at high temperatures as well as by the differences in the porosity. 相似文献
6.
Mohamed Abdel-Moneim Mohamed 《Arabian Journal of Geosciences》2013,6(10):4021-4033
Rare-metal granites of Nuweibi and Abu Dabbab, central Eastern Desert of Egypt, have mineralogical and geochemical specialization. These granites are acidic, slightly peraluminous to metaaluminous, Li–F–Na-rich, and Sn–Nb–Ta-mineralized. Snowball textures, homogenous distribution of rock-forming accessory minerals, disseminated mineralization, and melt inclusions in quartz phenocrysts are typical features indicative of their petrographic specialization. Geochemical characterizations are consistent with low-P-rare metal granite derived from highly evolved I-type magma in the late stage of crystallization. Melt and fluid inclusions were studied in granites, mineralized veins, and greisen. The study revealed that at least two stages of liquid immiscibility played an important role in the evolution of magma–hydrothermal transition as well as mineral deposition. The early stage is melt/fluid case. This stage is represented by the coexistence of type-B melt and aqueous-CO2 inclusions in association with topaz, columbite–tantalite, as well as cassiterite mineral inclusions. This stage seems to have taken place at the late magmatic stage at temperatures between 450 °C and 550 °C. The late magmatic to early hydrothermal stage is represented by vapor-rich H2O and CO2 inclusions, sometimes with small crystallized silicic melt in greisen and the outer margins of the mineralized veins. These inclusions are associated with beryl, topaz, and cassiterite mineralization and probably trapped at 400 °C. The last stage of immiscibility is fluid–fluid and represented by the coexisting H2O-rich and CO2-rich inclusions. Cassiterite, wolframite ± chalcopyrite, and fluorite are the main mineral assemblage in this stage. The trapping temperature was estimated between 200 °C and 350 °C. The latest phase of fluid is low-saline, low-temperature (100–180 °C), and liquid-rich aqueous fluid. 相似文献
7.
We report unusual occurrence of glass shards with diverse morphologies and compositions in the volcanic ash associated with the early Neogene marine stratigraphic succession (early Miocene to early middle Miocene) of Andaman-Nicobar Islands, Northeast Indian Ocean. These small, ash-size (200 to 800 μm) broken pieces of glass shards when viewed under Scanning Electron Microscope (SEM), represent distinctive — platy, sickle, bicuspate, concentric, angular, horn shape and slivers with broken angular bubble wall — morphologies. Glass shards are colourless. But, a few are grey or reddish-brown, indicate high Fe content. Chilled, juvenile, angular and blocky shards show fragments of highly viscous, silicic magma. Spindle and ribbon-shape shards form from a low viscosity basalt and rhyolite. Electron Probe Micro Analyzer (EPMA) was used to measure low concentration variations of major oxides within individual amorphous silicate solid glass shards whose disordered atomic structure is that of a liquid derived from a silicate melt. Major elemental chemistry of early Miocene glass shards from Colebrook island show low silica, alkalis, high FeO(T) MgO and CaO, whereas, early middle Miocene glass shards from Inglis island show high silica, alkalis, low FeO(T), MgO and CaO contents. These data-sets when plotted on ternary TotalAlkali-Silica and Na2O+K2O-MgO-FeO(T) diagrams show that their data plots lie within the basaltic-andesite, tephri-phonolite, rhyolite and trachyte fields. These glass shards which were present in the provenance, formed by explosive eruption of lavas, ranging in composition from basalt to rhyolite with andesite/ basalt-andesite being the most common magma types erupted sub-areally, implying island arc type of tectono-magmatic setting for the formation of these lavas. However, more evolutionary variant rhyolite was most likely formed by crystal fractionation. 相似文献
8.
Martina Bestel Timo Gawronski Rainer Abart Dieter Rhede 《Mineralogy and Petrology》2009,97(3-4):173-188
We employ garnet isopleth thermobarometry to derive the P–T conditions of Permian and Cretaceous metamorphism in the Wölz crystalline Complex of the Eastern Alps. The successive growth increments of two distinct growth zones of the garnet porphyroblasts from the Wölz Complex indicate garnet growth in the temperature interval of 540°C to 560°C at pressures of 400 to 500 MPa during the Permian and temperatures ranging from 550°C to 570°C at pressures in the range of 700 to 800 MPa during the Cretaceous Eo-Alpine event. Based on diffusion modelling of secondary compositional zoning within the outermost portion of the first garnet growth zone constraints on the timing of the Permian and the Eo-Alpine metamorphic events are derived. We infer that the rocks remained in a temperature interval between 570°C and 610°C over about 10 to 20 Ma during the Permian, whereas the high temperature stage of the Eo-Alpine event only lasted for about 0.2 Ma. Although peak metamorphic temperatures never exceeded 620°C, the prolonged thermal annealing during the Permian produced several 100 µm wide alteration halos in the garnet porphyroblasts and partially erased their thermobarometric memory. Short diffusion profiles which evolved around late stage cracks within the first garnet growth zone constrain the crack formation to have occurred during cooling below about 450°C after the Eo-Alpine event. 相似文献
9.
There are 10 types of tungsten ore deposits in South China: granite, porphyry, volcanic, pegmatite, skarn, greisen, wolframite-quartz ± microcline veins, stratabound, ferberite-quartz veins and placer. Most are chronologically related to Yenshanian granites. Integrated field, mineralogic, fluid inclusion and geochemical studies were undertaken to determine the characteristics and origin of the ores. Most of the tungsten ore deposits are also spatially related to Yenshanian granites. These granites include several intrusions, isotopically dated at 160–180 m. y. and 70–100 m. y. The concentration of trace elements, especially W Mo, Sn, Ta, Nb, Li, and F are relatively high in the granites. In the granites of South China, the average WO3 is 4.35 ppm, but in Yenshanian granites, which are the youngest of these, the average WO3 is 5.16 ppm. In the youngest of Yenshanian granites, a light mica-albite granite has been identified, whose average WO3 is as high as 242.3 ppm. From this line of evidence, the tungsten ore deposits in South China are considered to be genetically related to Yenshanian granites. Wolframite-sulfide-quartz veins and scheelite skarns provide the bulk of the reserves and production. There are many different kinds of alteration associated with the different tungsten ore deposits, but the principal ones are silicification, greisenization, potash-feldspathization and chloritization. Four types of fluid inclusions were found:
- Liquid-rich;
- Gas-rich;
- Liquid CO2-bearing;
- Polyphase with daughter minerals.
10.
Fluid inclusions in quartz were synthesized by the method of crack healing at 2 kbar and temperatures of 500, 700, 750, and 800°C from solutions containing sodium fluoride (±chloride). Critical phenomena occur in the saturated solution of NaF. Thermometric and cryometric measurements were carried out. Fluid interaciton with quartz was observed under all the parameters of our experiments with the formation of intermediate compounds, which were also sometimes trapped in inclusions. Based on the results of cryometric investigations of inclusions synthesized from solutions of different concentration, the solubility of NaF was estimated as 3.9 wt % at 500°C. It was shown that at temperatures higher than 700°C, heterogeneous entrapment occurred in most cases. Complex unmixing processes took place in the inclusions synthesized under the conditions of the upper heterogeneous region. All our observations suggest that coarse dispersed emulsions of two liquids exist in the upper heterogeneous region: an essentially aqueous phase and a water-rich silicate-dominated phase.At temperatures of 206–389°C, liquid immiscibility occurred in the presence of vapor, and three equilibrium noncrystalline (fluid) phases coexisted. Under the experimental conditions, the addition of NaCl to the fluidgenerating mixture did not exert a significant influence on the phase state of fluorine-bearing fluid. 相似文献
11.
微裂隙对于岩石的物理性质有重要影响.通过光学显微镜对显微裂隙进行的观察,难以将薄片的制作过程中产生的裂隙同自然裂隙区分;其次,观测的裂隙大小限制在0.1mm或以上数量级,一些重要细节观察不到.扫描电镜的高放大倍数和三维分辨率使其成为适合于裂隙研究的理想工具.利用扫描电镜观测了浙江花岗岩在室温下由51.6MPa压力产生的裂隙的发育过程.观察花岗岩的表面以研究其微裂隙和矿物的解理、晶形及破裂作用.微裂隙分为3种类型:晶体内裂隙(完全发育在颗粒内部),晶体间裂隙(穿过颗粒边界进入其他颗粒中),颗粒边界裂隙(沿颗粒边界发育或与边界重合).本研究中的花岗岩为中-粗粒(1~6mm),经过蚀变,约含40%斜长石,25%钾长石,25%石英,10%镁铁矿物(主要为黑云母和白云母). 相似文献
12.
Weqiang Zhang Qiang Sun Yuliang Zhang Lei Xue Fanfan Kong 《Environmental Earth Sciences》2018,77(9):350
The evolution of porosity and changes in wave velocity in granite after high-temperature treatment has been experimentally investigated in different studies. Statistical analysis of the test results shows that there is a temperature threshold value that leads to variations in porosity and wave velocity. At a temperature that is less than 200 °C, the porosity of granite slowly increases with increases in temperature, while the wave velocity decreases. When the temperature is greater than 200 °C (especially between 400 and 600 °C), the porosity quickly increases, while the wave velocity substantially decreases. The temperature ranges of room temperature to 200 and 200–400 °C correspond to the undamaged state and the micro-damage state, respectively. The results confirm that there is an important link between the variations of physical and mechanical properties in response to thermal treatment. By studying the relationships among rock porosity, wave velocity and temperature, this provides the basis for solving multi-variable coupling problems under high temperatures for the thermal exploitation of petroleum and safe disposal of nuclear waste. 相似文献
13.
微裂隙对于岩石的物理性质有重要影响.通过光学显微镜对显微裂隙进行的观察,难以将薄片的制作过程中产生的裂隙同自然裂隙区分;其次,观测的裂隙大小限制在0.1mm或以上数量级,一些重要细节观察不到.扫描电镜的高放大倍数和三维分辨率使其成为适合于裂隙研究的理想工具.利用扫描电镜观测了浙江花岗岩在室温下由51.6MPa压力产生的裂隙的发育过程.观察花岗岩的表面以研究其微裂隙和矿物的解理、晶形及破裂作用.微裂隙分为3种类型:晶体内裂隙(完全发育在颗粒内部),晶体间裂隙(穿过颗粒边界进入其他颗粒中),颗粒边界裂隙(沿颗粒边界发育或与边界重合).本研究中的花岗岩为中—粗粒(1～6mm),经过蚀变,约含40%斜长石,25%钾长石,25%石英,10%镁铁矿物(主要为黑云母和白云母).(1)石英裂隙表面的石英颗粒具有边界破裂和贯穿颗粒破裂.贯穿石英颗粒的破裂常呈贝壳状断口.变形集中带与滑动面相伴,其上发育有擦痕和沟槽,这是石英典型的脆性破裂类型.石英矿物的贝壳状破裂产状指示其变形作用早期的碎裂作用,在变形作用中发生交代作用.一些平滑的破裂面上没有石英颗粒的微裂隙构造,但在石英表面却有明显的擦痕面,可指示应力的方向.由于石英的各向异性,这些面也是由贯穿颗粒破裂所形成.一些开放的裂隙集中于石英晶体之中或沿 相似文献
14.
《Resource Geology》2018,68(3):326-335
Fluid inclusion microthermometry was conducted on late‐stage barren comb quartz and the latest stibnite at the Hishikari deposit to characterize the hydrothermal activity responsible for vein formation. Eight fluid inclusion assemblages (i.e. fluid inclusions trapped at the same time, ‘FIAs’) were studied to determine the formation fluid temperatures and salinities for the comb quartz in the Shosen No. 2 vein, Sanjin ore zone, and the stibnite in the Seisen No. 1–1 vein, Yamada ore zone. The average homogenization temperatures (the formation temperatures) of the seven FIAs from the comb quartz were between 207 and 230°C, while the average homogenization temperature (the formation temperature) of an FIA from the stibnite was 113°C. The measured fluid salinities of the seven FIAs from the comb quartz were low, ranging between 0.0 and 1.1 wt% NaCl equiv., indicating that dilute fluids were responsible for the comb quartz formation. By comparison with previous microthermometric data, the formation temperatures of the studied comb quartz were higher than those of columnar adularia and comb quartz at most other veins (generally around 200°C) but were similar to those of columnar adularia at Keisen veins (230°C) in the same ore zone. The higher formation temperatures both in the Shosen and the Keisen veins in the Sanjin ore zone indicate that the fractures corresponding to the vein system at the Sanjin ore zone were main conduits for hot ascending fluids. The low formation temperature of stibnite in the latest stage (113°C) indicates that stibnite precipitation occurred during a waning stage of hydrothermal activity. Combined with previous thermodynamic data on antimony solubilities, the large discrepancy between the formation temperature of the comb quartz (200–230°C) and that of the stibnite suggests that the stibnite may have precipitated as a result of a drastic cooling of the hydrothermal system. 相似文献
15.
Fluid equilibria in the H2O-Na2SO4-SiO2 system were experimentally studied at 700 and 800°C and pressures of 1, 2, and 3 kbar using synthetic fluid inclusions in
quartz. The obtained results indicated a heterogeneous state of fluid within the whole range of experimental parameters of
this study. Sodium sulfate underwent high-temperature hydrolysis, whose products chemically reacted with quartz. As a result,
a noncrystalline phase containing substantial amounts of silica was formed at a temperature of 800°C and a pressure of 3 kbar.
This phase was observed in the inclusions as glass. The thermometric investigation of inclusions that trapped fluid phases
immiscible under experimental conditions showed that they can, in turn, become heterogeneous at temperatures of approximately
200–400°C. Under such conditions, three or four noncrystalline phases can be in equilibrium. 相似文献
16.
Experiments devoted to interaction between the material of ferromanganese crusts (FMC) of Pacific seamounts and hydrogen sulfide
at temperatures ranging from 100 to 600°C unraveled the formation of pyrite microcrystals at 100°C. Upon heating, the pyrite
acquires more perfect crystalline form at 200°C and breaks down at 600°C. The formation and breakdown of magnetite take place
according to the same similar scenario. At 200°C, one can see the formation of lumpy aggregates of the slightly crystallized
alabandine transformed at 600°C into lamellar crystals, which accumulate the whole Mn and part of Fe hosted in rock. At maximal
temperature, platinum and gold are crystallized selectively as lamellar particles and native sulfur is accumulated. The composition
of these newly formed minerals is incomparable with the mineralogy of natural FMCs. This is inconsistent with the assumption
about the possible influence of hypothetic hydrosulfuric emanations on the formation of minerals mentioned above. However,
experimental results demonstrate an extremely high sorption capacity of FMCs relative to hydrogen sulfide, suggesting great
prospects of the practical application of FMCs for the industrial and ecological purposes. 相似文献
17.
William A. Olsson 《Tectonophysics》1974,24(3):277-285
Two fundamentally distinct types of microfractures are present in an experimentally deformed limestone: subaxial microfractures and microfaults. Macroscopic faults are composed of coalesced microfaults and are not related to the subaxial microfractures. A high-temperature mechanical instability occurs at temperatures of 200° C and above when the confining pressure is 600 bars or less. 相似文献
18.
Wu Zongxu 《中国地球化学学报》1985,4(4):362-379
The formation of ore-bearing granites in the Yenshanian movement in southeast China and the geochemical characteristics of
some RE-bearing granites have been studied through multivariate statistical analysis and physicochemical approach. The main
conclusions have Been drawn as follows: (1) The granites are believed to be products of anatexis of the crustal materials.
The formation temperature of granitic magma is estimated at about 600°C and the crystallization temperatures range from 600°
to 500°C. The temperature of Li-, Fand H2O-rich residual magma in the latest stage of magmatism is probably below 500°C. (2) A rock series from early lepidomelane-granite
through protolithionite-and zinnwalditegranite to lithioniteor lepidolite-granite is considered as a result of actual crystallization.
(3) The mineral paragenesis and fades zonation of granite plutons are mainly controlled by Ph2o, μNa2O and μK2O in the magma. (4) During the magmatic evolution the ore-forming elements (REE, Nb, Ta, etc.) are variable in geochemistry.
REEs, similar to mafic components, were highly concentrated at the early stage of the magmatic evolution and deposited under
favourable conditions in the zinnwaldite-and protolithionite-granites; Nb and Ta have a preference for felsic and volatile
components, thus are mainly concentrated at later stages of the magmatic evolution. Nb ore deposits are formed in the lithionite
and lepidolite granites, for Ta is intimately associated with Na2O, Li2O, F and H2O. 相似文献
19.
Gypsum is one of the most universally distributed salts in weathered materials but little is known about the influence of environmental conditions on the damage generated by gypsum in stones. To quantify the damage induced by gypsum crystallization acoustic emission techniques are employed to record the elastic energy released during salt crystallization cycles in a limestone. Different environmental conditions have been established during the cooling and drying periods in traditional salt crystallization cycles. During drying two different temperatures (50 and 25 °C) and relative humidity (low, 25 % at 50 °C and 65 % at 25 °C, and high, 99 %) have been applied. The acoustic emission signals are filtered by a frequency analysis in order to eliminate signals corresponding to external noise or artifacts. Our experimental results show that acoustic emission activity is higher under high relative humidity conditions than under low relative humidity conditions, and also higher when drying at 50 °C than at room temperature. Microscopic observations on the weathered samples indicated that under high relative humidity conditions and at room temperature, gypsum crystallizes not on the sample surface, like in the other samples, but deeper in the inner part of the sample, in good agreement with previously published data. We show that using acoustic emissions as usually done in rock mechanics is also very useful in the study of stone decay and weathering processes in the laboratory. 相似文献
20.
Tubing Yin Xibing Li Kaiwen Xia Sheng Huang 《Rock Mechanics and Rock Engineering》2012,45(6):1087-1094
The effect of thermal treatment on the dynamic fracture toughness of Laurentian granite (LG) was investigated in this work. Notched semi-circular bend (NSCB) LG specimens are heat treated at temperatures up to 850?°C. The micro-cracks in the rock samples induced by thermal treatment are examined by scanning electron microscope (SEM). The microscopic observations are consistent with the subsequent P-wave velocity measurements, which shows that the P-wave velocity decreases with the treatment temperature monotonically when the temperature is higher than 250?°C. Dynamic fracture toughness measurements are then carried out on these samples with the dynamic load exerted by a modified split Hopkinson pressure bar (SHPB) system. The relationship between fracture toughness and treatment temperature is investigated. Experimental results show that fracture toughness increases with the loading rate but decreases with the treatment temperature. However, when the heating temperature is below 250?°C and above 450?°C, the dependence of dynamic fracture toughness on the temperature is different from other temperatures, which can be explained by the physical processes at the microscopic level of the rock due to heating. At treatment temperatures below 250?°C, the thermal expansion of grains leads to an increase in the toughness of the rock. At treatment temperatures above 450?°C, the sources of weakness such as grain boundaries and phase transition of silicon are depleted, and as a result the decrease in fracture toughness is not as significant as other treatment temperature ranges. 相似文献