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花岗岩浆侵位与结晶固化时差的研究与构造意义:以南岭骑田岭花岗岩基为例 总被引：4，自引：0，他引：4
通过对南岭中段骑田岭花岗岩基地质-岩石地球化学特征研究, 判明了该岩基的侵位深度（5.5 km）、围岩温度（196℃）及岩浆初始温度（950 ℃ ）,建立起骑田岭花岗岩基的数学计算模型,计算得出： 骑田岭花岗岩熔体侵位后,其初始温度降低至结晶温度所需的时间（Δt col） 为4.1 Ma;由于结晶潜热释放而使结晶过程延长的时间（Δt L）为2.6 Ma; 由于骑田岭花岗岩基放射性元素含量 （U-15.3×10-6,Th-51.35×10-6,K2O-5.02%）是世界平均花岗岩放射性元素含量（U-5×10-6,Th-20×10-6,K2O-2.66%）的2~3 倍,骑田岭花岗岩浆侵位后产生的放射成因热使结晶过程延长的时间（Δt A） 为35.4 Ma,远长于世界平均花岗岩计算的Δt A（2.93 Ma） 。因此, 骑田岭花岗岩基的岩浆侵位- 结晶固化时差 （Δt ECTD）为42.1 Ma, 结合锆石U-Pb 年龄值（161 Ma）, 通过反演计算得出骑田岭花岗岩基侵位年龄值（t E ）为203.1 Ma,从而为骑田岭花岗岩基属于印支期侵位提供了重要的岩浆动力学佐证。 相似文献
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《矿物学报》2016,(1)
斜长石是岩浆岩中最主要的造岩矿物之一,它在岩浆演化过程中扮演着重要角色。通过高温高压实验途径可以确定斜长石在岩浆中的结晶条件、探讨斜长石的生长动力学。近年来,较多学者对斜长石的结晶作用进行了实验研究,这些研究对理解斜长石的结晶条件和岩浆的结晶过程都有重要意义。本文从以下两个方面对斜长石结晶作用的实验研究做了系统的总结:(1)斜长石晶体的生长及其制约因素,包括熔体组分、温度、压力和H2O含量等条件对斜长石结晶的影响。熔体组分能够影响斜长石的液相线温度及结晶斜长石的An含量;温度对斜长石的成核生长、成分以及形态均有影响;压力对斜长石成核生长的影响比较复杂;H2O含量能够显著降低斜长石的结晶温度,影响结晶斜长石的晶体大小。(2)斜长石结晶作用实验研究的地质应用。对结晶斜长石成分、结构、晶体大小的研究,能够揭示岩浆在其演化过程中物理化学条件的变化。 相似文献
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对花岗闪长质熔体在500MPa～2000MPa,650℃～750℃和一定水含量条件下结晶作用实验的结果表明,斜长石在500MPa和水饱和条件下的结晶温度为675℃,斜长石的结晶及其成分明显受温度、压力和熔体水含量影响。花岗闪长质熔体有斜长石结晶时残余熔体的SiO2含量高于无斜长石结晶的情况。花岗闪长质熔体发生角闪石、黑云母和斜长石结晶后的残余熔体在主量元素组成上与典型的A型花岗岩基本一致,也与初始物产地的A型花岗岩接近。因此,实验研究初步从主量元素上证明,东准噶尔A型花岗岩浆可以来源于花岗闪长质岩浆的分异结晶作用。 相似文献
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华南富锂氟含稀有金属花岗岩的成冈分析 总被引：3，自引：0，他引：3
雪球结构的产出特征、钠长石电子探针分析及其它间接证据都说明,雪球结构是在岩浆结晶过程中形成的。雪球结构形成与否主要与岩浆熔体中Ｎａ２Ｏ／Ｋ２Ｏ比值和Ｆ、Ｈ２Ｏ含量有关。较大的Ｎａ２Ｏ／Ｋ２Ｏ比值（〉１）例钠长石首先从熔体中晶出;较高的Ｆ含量使岩浆固相线温度大大降低,有利于岩浆分异演化并形成接近端员组分的钠长石和钾长石同的Ｈ２Ｏ含量有利于石英以较快的速度生长并逐渐包裹钠长石形成雪球结构。自形的α－石英斑晶、接近各自端员组分的甲和工石和钠长石等说明该类花岗岩形成温度较低,众多的地质、地球化学依据都证明了,华南富锂氟含稀有金属花岗岩是从过铝富氟富钠的残余熔体中直接结晶而成的。 相似文献
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锂（Li）是一种战略关键金属,岩浆阶段主要在花岗质岩石中得到富集和结晶。由于具有不相容和富挥发性等性质,锂对花岗岩的成岩成矿具有重要的制约。文章利用电子探针、LA-ICP-MS 等分析手段,对湖南香花岭地区癞子岭和尖峰岭花岗岩进行系统岩相学、主微量和矿物学研究,结果表明：（1）花岗质岩浆结晶分异过程中,Li 含量逐渐升高,大幅度降低了熔体粘度,增大了结晶温度区间,花岗质岩浆得到充分结晶分异,导致花岗岩的垂直分带;（2）花岗岩中Li 与稀有金属含量呈正相关关系,Li 与Ta、Nb、Sn 等稀有金属具有协同成矿作用;（3）花岗岩中云母类矿物具有向富Li 演化的趋势,以铁锂云母为主,随着铁锂云母的结晶,Nb、Ta、Sn 等稀有金属相继析出,导致晚期云母中Ta、Nb 等含量降低。熔体中H2O、F 等对花岗质岩浆的性质和结晶分异有较大影响,但不足以致使花岗岩呈垂直分带。 相似文献
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通过对南岭西段金鸡岭花岗岩体地质-岩石地球化学特征研究,判明该岩体的侵位深度(7.5km)、围岩温度(270℃)及岩浆初始温度(950℃),建立起金鸡岭花岗岩体的数学计算模型,分别计算得出:金鸡岭花岗岩熔体侵位后,其初始温度降低至结晶温度所需的时间(Δtcol)为3.91Ma;由于结晶潜热释放而使结晶过程延长的时间(ΔtL)为2.92Ma;由于金鸡岭花岗岩体放射性元素含量(U——16.5×10-6,Th——51.3×10-6,K2O——4.82%)是世界平均花岗岩放射性元素含量(U——5×10-6,Th——20×10-6,K2O——2.66%)的3倍左右,金鸡岭花岗岩熔体侵位后产生的放射性成因热使结晶过程延长的时间(ΔtA)为34.5Ma,远长于按世界花岗岩平均放射性元素含量计算的ΔtA*(2.82Ma)。金鸡岭花岗岩体的侵位-结晶时差(ΔtECTD)为41.3Ma,结合锆石U-Pb年龄值(156Ma),通过反演计算得出金鸡岭花岗岩体侵位年龄值(tE)为197.3Ma,从而为该岩体属于印支期侵位提供了重要的岩浆动力学证据。 相似文献
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磷对过铝质岩浆液相线温度影响的实验研究 总被引：2，自引：1，他引：1
以宜春414岩体中的钠长花岗岩作为实验初始物,利用"RQV-快速内冷淬火"高温高压装置实验研究了100MPa压力、含5%H2O条件下,P对过铝质花岗岩液相线温度的影响.实验结果表明,碱性长石是最早结晶的矿物;随着体系中P2O5含量从0.27%增加到7.71%,液相线温度从最初的810℃降低到740℃,表明P有效地降低了过铝质岩浆体系的液相线温度.在过铝质岩浆体系中,P5+与Al3+的结合形成AlPO4,降低了熔体中碱性长石组分的活度,很可能是液相线温度降低的机制. 相似文献
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大型硅质火山作用(喷发体积约102～104km~3)的岩浆系统是地壳尺度的,经历了复杂的起源、运移、存储、补给和喷发等过程。揭示岩浆从起源到喷发过程中的结晶分异、堆晶、晶体-熔体分离、地壳混染、岩浆补给、晶粥活化等岩浆作用的细节是认识硅质火山岩浆系统演化的关键。锆石中Th、U、Ti、Hf和REE等微量元素的含量和系统变化反映了锆石结晶熔体的成分、温度、氧逸度和水含量等以及共生的矿物相特征,对示踪火山岩浆系统的演化过程具有重要研究意义。随着岩浆温度降低过程中结晶分异作用的进行,锆石微量元素呈现出Hf含量升高、Ti含量降低以及Th/U、Eu/Eu~*和Zr/Hf等比值降低的趋势,这些元素含量和比值可以作为岩浆分异演化程度的指标。成矿斑岩中的锆石一般具有高的Ce~(4+)/Ce~(3+)和Eu/Eu~*值,反映了岩浆具有高的氧逸度和水含量。火山岩锆石可能经历多阶段结晶过程,因而形成复杂的核-边结构特征,核部具有熔蚀现象,边部CL较亮并具有低的Hf、U和高的Ti含量以及Eu/Eu~*值等,反映了岩浆补给作用和晶粥活化过程。由于锆石颗粒比较微小,在晶体-熔体分离过程可能随提取的熔体进入喷发岩浆房,从而可以连续记录岩浆成分的变化,或者残留在晶粥中记录晶体-熔体的分离。锆石微量元素结合高精度年代学分析,可以精细制约火山岩浆系统的多阶段演化过程及其时间尺度。在锆石微量元素数据的解释和筛选过程中,需注意扇形分区、锆石褪晶化和其他矿物包裹体对分析结果的影响,并同时开展岩相学研究,结合锆石产状和共生矿物组合特征,为制约火山岩浆系统的演化过程提供可靠信息。 相似文献
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Summary The strongly peraluminous, P- and F-rich granitic system at Podlesí in the Krušné Hory Mountains, Czech Republic, resembles
the zonation of rare element pegmatites in its magmatic evolution (biotite → protolithionite → zinnwaldite granites). All
granite types contain disseminated Nb-Ta-Ti-W-Sn minerals that crystallized in the following succession: rutile + cassiterite
(in biotite granite), rutile + cassiterite → ferrocolumbite (in protolithionite granite) and ferrocolumbite → ixiolite →
ferberite (in zinnwaldite granite). Textural features of Nb-Ta-Ti-W minerals indicate a pre-dominantly magmatic origin with
only minor post-magmatic replacement phenomena. HFSE remained in the residual melt during the fractionation of the biotite
granite. An effective separation of Nb + Ta into the melt and Sn into fluid took place during subsequent fractionation of
the protolithionite granite, and the tin-bearing fluid escaped into the exocontact. To the contrast, W contents are similar
in both protolithionite and zinnwaldite granites.
Although the system was F-rich, only limited Mn-Fe and Ta-Nb fractionation appeared. Enrichment of Mn and Ta was suppressed
due to foregoing crystallization of Mn-rich apatite and relatively low Li content, respectively. The content of W in columbite
increases during fractionation and enrichment in P and F in the melt. Ixiolite (up to 1 apfu W) instead of columbite crystallized
from the most fluxes-enriched portions of the melt (unidirectional solidification textures, late breccia). 相似文献
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《Russian Geology and Geophysics》2015,56(9):1292-1307
Miarolitic granite pegmatites are a unique natural object that makes it possible to study magmatic processes that lead to the formation of ore-forming media and systems. This paper summarizes modern views on phase transformations in aqueous silicate systems at parameters close to those of the transition from magmatic to hydrothermal crystallization. Comparison of phase diagrams and the results of study of pegmatite-forming media permits making conclusions about the crystallization of the water-saturated magmas of miarolitic granite pegmatites. The fluid regime of aqueous granite systems of simple composition, not enriched in fluxing components, is determined mainly by magma degassing or the supply of volatiles with flows of transmagmatic fluids. These processes cause the separation of essentially carbon dioxide or essentially hydrous fluid. During the evolution of such magmas, crystallization from silicate melt is separated in PT-space and, possibly, in time from the crystallization from aqueous or mixed carbon dioxide-aqueous super- and subcritical solutions. The evolution of chambers of water-saturated granitic and pegmatitic magma enriched in F, B, and alkali metals presupposes the formation of a heterogeneous mineral-forming medium in which crystallization occurs in the magmatic melt at high-temperature stages; as temperature decreases, crystallization can proceed in hydrous fluid, hydrosilicate, and/or hydrosaline liquids simultaneously. Hydrothermal crystallization can also take place in a heterogeneous medium consisting of aqueous solutions of different salinities and vapor or vapor-carbon dioxide gas mixture. The relationship between different fluid regimes during the evolution of volatile-saturated granitic and pegmatitic magmas determines the variety of postmagmatic rocks accompanying granite massifs. 相似文献
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The tungsten distribution in rocks of the Kukulbei Complex in eastern Transbaikal region results in a high potential of rare-metal peraluminous granites (RPG) for W mineralization and displays a different behavior of W in Li–F and “standard” RPG. These subtypes differ in the behavior of W in melt, spatial localization of mineralization, and the timing of wolframite crystallization relative to the age of the parental granitic rocks. The significant of W concentration is assumed to be due to fractionation of the Li–F melt; however, wolframite mineralization in Li–F enriched granite is not typical in nature. The results of experiments and our calculations of W solubility in granitic melt show that wolframite hardly ever crystallizes directly from melt; it likely migrates in the fluid phase and is then removes from the magma chamber to the host rocks, where secondary concentration takes place in exocontact greisens and quartz–cassiterite–wolframite veins. At the same time, the isotopic age of accessory wolframite (139.5 ± 2.1 Ma) within the Orlovka massif of Li–F granite is close to the formation age of the massif (140.6 ± 2.9 Ma). A different W behavior is recorded in the RPG subtype with a low lithium and fluorine concentration, exemplified by the Spokoininsky massif. There is no significant W gain in the melt. All varieties of wolframite mineralization in the Spokoininsky massif are derived from greisens, veins, and pegmatoids yielding the same crystallization ages (139.5 ± 1.1 Ma), which are 0.9–1.8 Ma later (taking into account the mean-square weighted deviation) than the Spokoininsky granite formation (144.5 ± 1.4 Ma). Perhaps this period corresponds to the time of transition from the magmatic stage to hydrothermal alteration. Comparison of the isotope characteristics (Rb–Sr and Sm–Nd isotope systems) of rocks and the associated ore minerals (wolframite, cassiterite) from all examined deposits shows a depletion in εNd values for ore minerals relative to the rock and the opposite behavior for the intial Sr isotope ratios. This may indicate the specific nature of ore matter, where the effect of the juvenile component is definitely expressed. Our geochronological results show that tantalum and tungsten mineralization took place within a narrow age interval, almost synchronously with the crystallization of associated granites. The coeval development of peraluminous magmatism enriched in lithophile rare elements and volatiles with ore complexes located in different structural settings and separated by a considerable distance from each other (up to 500 km) suggests a regional and deep-seated magma source. Rifting and increased thermal flux from the mantle, manifestations of which have been recorded during this period in the territory, may be a deep-seated process. 相似文献
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Sheila J. Seaman Helle Gylling John P. Hogan Frank Karner G. Christopher Koteas 《Contributions to Mineralogy and Petrology》2011,162(6):1291-1314
The Tunk Lake pluton of coastal Maine, USA is a concentrically zoned granitic body that grades from an outer hypersolvus granite
into subsolvus rapakivi granite, and then into subsolvus non-rapakivi granite, with gradational contacts between these zones.
The pluton is partially surrounded by a zone of basaltic and gabbroic enclaves, interpreted as quenched magmatic droplets
and mushes, respectively, as well as gabbroic xenoliths, all hosted by high-silica granite. The granite is zoned in terms
of mineral assemblage, mineral composition, zircon crystallization temperature, and major and trace element concentration,
from the present-day rim (interpreted as being closer to the base of the chamber) to the core (interpreted as being closer
to the upper portions of the chamber). The ferromagnesian mineral assemblage systematically changes from augite and hornblende
with augite cores in the outermost hypersolvus granite to hornblende, to hornblende and biotite, and finally, to biotite only
in the subsolvus granite core of the pluton. Sparse fine-grained basaltic enclaves that are most common in the outermost zone
of the pluton suggest that basaltic magma was present in the lower portions of the magma chamber at the same time that the
upper portions of the magma chamber were occupied by a granitic crystal mush. However, the slight variations in initial Nd
isotopic ratio in granites from different zones of the pluton suggest that contamination of the granitic melt by basaltic
melt played little role in generating the compositional gradation of the pluton. The zone of basaltic and gabbroic chilled
magmatic enclaves, and gabbroic xenoliths, hosted by high-silica granite, that partially surround the pluton is interpreted
as mafic layers at the base of the pluton that were disrupted by invading late-stage high-silica magma. These mafic layers
are likely to have consisted of basaltic lava layers and basalt that chilled against granitic magma to produce coarse-grained
gabbroic mush. Basaltic and gabbroic magmatic enclaves and gabbroic xenoliths are hornblende-bearing, suggesting that their
parent melts were relatively hydrous. The water-rich nature of the underplating mafic magmas may have prevented extensive
invasion of the granitic magma by these magmas, owing to the much greater viscosity of the granitic magma than the mafic magmas
in the temperature range over which magma interaction could have occurred. 相似文献
16.
Textural and chemical evolution of a fractionated granitic system: the Podlesí stock, Czech Republic
The Podlesí granite stock (Czech Republic) is a fractionated, peraluminous, F-, Li- and P-rich, and Sn, W, Nb, Ta-bearing rare-metal granite system. Its magmatic evolution involved processes typical of intrusions related to porphyry type deposits (explosive breccia, comb layers), rare-metal granites (stockscheider), and rare metal pegmatites (extreme F–P–Li enrichment, Nb–Ta–Sn minerals, layering). Geological, textural and mineralogical data suggest that the Podlesí granites evolved from fractionated granitic melt progressively enriched in H2O, F, P, Li, etc. Quartz, K-feldspar, Fe–Li mica and topaz bear evidence of multistage crystallization that alternated with episodes of resorption. Changes in chemical composition between individual crystal zones and/or populations provide evidence of chemical evolution of the melt. Variations in rock textures mirror changes in the pressure and temperature conditions of crystallization. Equilibrium crystallization was interrupted several times by opening of the system and the consequent adiabatic decrease of pressure and temperature resulted in episodes of nonequilibrium crystallization. The Podlesí granites demonstrate that adiabatic fluctuation of pressure (“swinging eutectic”) and boundary-layer crystallization of undercooled melt can explain magmatic layering and unidirectional solidification textures (USTs) in highly fractionated granites. 相似文献
17.
南岭地区钨锡花岗岩的成矿矿物学：概念与实例 总被引：7，自引：0，他引：7
南岭地区的钨锡成矿作用与花岗岩岩浆活动有十分密切的关系。花岗岩的物源与成矿元素的初始富集、花岗岩的分异程度和花岗岩中流体性质与活动性集中体现了花岗岩对成矿的控制能力,即花岗岩的成矿能力。初步建立了南岭地区钨锡花岗岩的成矿矿物学研究体系。黑云母、榍石、锆石、锡石、金红石、黑钨矿、白钨矿和钨铁铌矿等是讨论的重点矿物,它们可用于判别花岗岩的成矿能力。首先以矿物晶体化学为基础,介绍了上述矿物在钨锡花岗岩中的岩相学特征、内部构造和矿物化学及其变化,并分别论证了花岗岩原始含矿性、花岗岩结晶演化和花岗岩中成矿元素活动性的矿物学标志;其次,系统对比了南岭地区三类钨锡花岗岩（准铝质含锡花岗岩、过铝质含锡花岗岩和过铝质含钨花岗岩）的成矿矿物学特征。以湖南骑田岭花岗岩复式岩体为实例,进行了芙蓉- 菜岭含锡花岗岩和新田岭含钨花岗岩的成矿矿物学对比研究。前者以黑云母、榍石为典型含锡矿物,它们在流体富集阶段,经热液蚀变作用,导致锡的淋滤和结晶富集作用;后者则以出现岩浆白钨矿和黑钨矿为特征。提出的钨锡花岗岩成矿矿物学研究体系有助于深化矿床学研究和矿床勘探工作,并将在今后工作中进一步完善。 相似文献
18.
R. L. Linnen 《Mineralium Deposita》1998,33(5):461-476
The most important tin mineralization in Thailand is associated with the Late Cretaceous to Middle Tertiary western Thai granite
belt. A variety of deposit types are present, in particular pegmatite, vein and greisen styles of mineralization. A feature
common to most of the deposits is that they are associated with granites that were emplaced into the Khang Krachan Group,
which consists of poorly sorted, carbonaceous, pelitic metasediments. Most of the deposits contain low to moderately saline
aqueous fluid inclusions and aqueous-carbonic inclusions with variable CH4/CO2 ratios. Low salinity aqueous inclusions represent trapped magmatic fluid in at least one case, the Nong Sua pegmatite, based
on their occurrence as primary inclusions in magmatic garnet. Aqueous-carbonic inclusions are commonly secondary and neither
the CO2 nor NaCl contents of these inclusions decrease in progressively younger inclusions, implying that they are not magmatic in
origin. Reduced carbon is depleted in the metasediments adjacent to granites and the δD values greisen muscovites are variable,
but are as low as −134 per mil, indicative of fluid interaction with organic (graphitic) material. This suggests that the
aqueous-carbonic fluid inclusions represent fluids that were produced, at least in part, during contact metamorphism-metasomatism.
By comparing the western Thai belt with other Sn-W provinces it is evident that there is a strong correlation between fluid
composition and pressure in general. Low to moderately saline aqueous inclusions and aqueous-carbonic inclusions are characteristic
of mineralization associated with relatively deep plutonic belts. Mineralized pegmatites are also typically of deeper plutonic
belts, and pegmatite-hosted deposits may contain cassiterite that is magmatic (crystallized from granitic melt) or is orthomagmatic-hydrothermal
(crystallized from aqueous or aqueous-carbonic fluids) in origin. The magmatic aqueous fluids (those that were exsolved from
granitic melts) are interpreted to have had low salinities. As a consequence of the low salinities, tin is partitioned in
favour of the melt on vapour saturation. Thus with a high enough degree of fractionation, the crystallization of a magmatic
cassiterite (or different Sn phase such as wodginite) is inevitable. Because tin is not partitioned in favour of the vapour
phase upon water saturation of the granitic melts, it is proposed that relatively deep vein and greisen systems tend to form
by remobilization processes. In addition, many deeper greisen systems are hosted, in part, by carbonaceous pelitic metasediments
and the reduced nature of the metasediments may play a key role in remobilizing tin. Sub-volcanic systems by contrast are
characterized by high temperature-high salinity fluids. Owing to the high chlorinity, tin is strongly partitioned in favour
of the vapour and cassiterite mineralization can form by of orthomagmatic-hydrothermal processes. Similar relationships between
the depth of emplacement and fluid composition also appear to apply to other types of granite-hosted deposits, such as different
types of molybdenum deposits.
Received: 8 September 1997 / Accepted: 28 October 1997 相似文献
19.
Based on the theory of thermal conductivity, in this paper we derived a formula to estimate the prolongation period （AtL） of cooling-crystallization process of a granitic melt caused by latent heat of crystallization as follows：△tL=QL×△tcol/（TM-TC）×CP where TM is initial temperature of the granite melt, Tc crystallization temperature of the granite melt, Cp specific heat, △tcol cooling period of a granite melt from its initial temperature （TM） to its crystallization temperature （Tc）, QL latent heat of the granite melt.
The cooling period of the melt for the Fanshan granodiorite from its initial temperature （900℃） to crystallization temperature （600℃） could be estimated -210,000 years if latent heat was not considered. Calculation for the Fanshan melt using the above formula yields a AtL value of -190,000 years, which implies that the actual cooling period within the temperature range of 900°-600℃ should be 400,000 years. This demonstrates that the latent heat produced from crystallization of the granitic melt is a key factor influencing the cooling-crystallization process of a granitic melt, prolongating the period of crystallization and resulting in the large emplacement-crystallization time difference （ECTD） in granite batholith. 相似文献
The cooling period of the melt for the Fanshan granodiorite from its initial temperature （900℃） to crystallization temperature （600℃） could be estimated -210,000 years if latent heat was not considered. Calculation for the Fanshan melt using the above formula yields a AtL value of -190,000 years, which implies that the actual cooling period within the temperature range of 900°-600℃ should be 400,000 years. This demonstrates that the latent heat produced from crystallization of the granitic melt is a key factor influencing the cooling-crystallization process of a granitic melt, prolongating the period of crystallization and resulting in the large emplacement-crystallization time difference （ECTD） in granite batholith. 相似文献