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1.
Zinc is a fairly abundant metal, it has been estimated that zinc represents 0.004 percent of the earth's crust and is twenty-fifth in the order of abundance. Its concentrations in surface waters vary greatly with locality; the highest concentrations of zinc have been observed in areas with acid mine drainage, but zinc enters surface waters in many other ways. Chemical thermodynamic calculations summarized by solubility graphs are given. The zinc solubility may be significantly controlled by stream sediments; Zn concentrations of sediments from various areas are given. Many techniques for extraction from sediments have been developed, they differ in efficiency.  相似文献   

2.
Analysis of hexane-extractable hydrocarbons in zooplankton collected off Bermuda in August 1979, and their faecal pellets, gave an estimated removal rate of hydrocarbons from surface waters by ‘grazing’ of 16–46 μg m?2 for a 4 h period. With a number of assumptions, this can be translated to 8–23 mg m?2 yr?1. When compared to the annual input due to petroleum discharge in the currents feeding the Sargasso Sea (18–70 mg m?2 yr?1 hexane-extractable hydrocarbons), this result implies that zooplankton are an important factor in the short-term removal of petroleum residues from open ocean surface waters.  相似文献   

3.
The Mississippi River (MR) freshwater outflow is a major circulation forcing mechanism for the Northern Gulf of Mexico. We investigate the transport and fate of the brackish waters under flood conditions. The largest outflow in history (45,000 m3/s in 2011) is compared with the second largest outflow in the last 8 years (41,000 m3/s in 2008). Realistically forced simulations reveal the synergistic effect of enhanced discharge, winds, stratification of ambient shelf waters, and offshore circulation over the transport of plume waters. The strongest impact is attributed to the evolution of the Loop Current (LC) and associated frontal cyclonic eddies and anticyclonic rings, which exhibited distinctly different influence during the two study periods. The northward LC intrusion in the summer of 2011 weakened and blocked the buoyancy-driven downstream (westward) transport of brackish waters. The 2011 flood was thus characterized by upstream (eastward) flow and an extensive coverage of the Mississippi–Alabama–Florida shelf. An immediate response between the LC and the brackish offshore eastward spreading is computed during and after this historic event. The absence of a LC northward intrusion during the 2008 flood, in combination with wind effects, promotes downstream advection of MR waters towards the Louisiana–Texas shelf; large amounts of buoyant waters are also retained near the Delta, subject to local offshore advection under the synergistic action of LC-associated counter-rotating eddies.  相似文献   

4.
Natural tracers (alkalinity and silica) were used to infer groundwater–surface‐water exchanges in the main braided reach of the River Feshie, Cairngorms, Scotland. Stream‐water samples were collected upstream and downstream of the braided section at fortnightly intervals throughout the 2001–2002 hydrological year and subsequently at finer resolution over two rainfall events. The braided reach was found to exert a significant downstream buffering effect on the alkalinity of these waters, particularly at moderate flows (4–8 m3 s?1/?Q30–70). Extensive hydrochemical surveys were undertaken to characterize the different source waters feeding the braids. Shallow groundwater flow systems at the edge of the braided floodplain, recharged by effluent streams and hillslope drainage, appeared to be of particular significance. Deeper groundwater was identified closer to the main channel, upwelling through the hyporheic zone. Both sources contributed to the significant groundwater–surface‐water interactions that promote the buffering effect observed through the braided reach. Their impact was less significant at higher flows (>15 m3 s?1/>Q10) when acidic storm runoff from the peat‐covered catchment headwaters dominated, as well as under baseflow conditions (<4 m3 s?1/<Q70), when upstream alkalinity was already buffered owing to headwater groundwater sources assuming dominance. The significant temporally and spatially dynamic influence of these groundwater–surface‐water interactions was therefore seen to have important implications for both catchment functioning and instream ecology. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

5.
Pitambar  Gautam  Ulrich  Blaha  Erwin  Appel 《Island Arc》2005,14(4):424-435
Abstract Soil profiles of the Kathmandu urban area exhibit significant variations in magnetic susceptibility (χ) and saturation isothermal remanence (SIRM), which can be used to discriminate environmental pollution. Magnetic susceptibility can be used to delineate soil intervals by depth into normal (< 10?7 m3/kg), moderately enhanced (10?7–< 10?6 m3/kg) and highly enhanced (≥ 10?6 m3/kg). Soils far from roads and industrial sites commonly fall into the ‘normal’ category. Close to a road corridor, soils at depths of several centimeters have the highest χ, which remains high within the upper 20 cm interval, and decreases with depth through ‘moderately magnetic’ to ‘normal’ at approximately 30–40 cm. Soils in the upper parts of profiles in urban recreational parks have moderate χ. Soil SIRM has three components of distinct median acquisition fields (B1/2): soft (30–50 mT, magnetite‐like phase), intermediate (120–180 mT, probably maghemite or soft coercivity hematite) and hard (550–600 mT, hematite). Close to the daylight surface, SIRM is dominated by a soft component, implying that urban pollution results in enrichment by a magnetite‐like phase. Atomic absorption spectrometry of soils from several profiles for heavy metals reveals remarkable variability (ratio of maximum to minimum contents) of Cu (16.3), Zn (14.8) and Pb (9.3). At Rani Pokhari, several metals are well correlated with χ, as shown by a linear relationship between the logarithmic values. At Ratna Park, however, both χ and SIRM show significant positive correlation with Zn, Pb and Cu, but poor and even negative correlation with Fe (Mn), Cr, Ni and Co. Such differences result from a variety of geogenic, pedogenic, biogenic and man‐made factors, which vary in time and space. Nevertheless, for soil profiles affected by pollution (basically traffic‐related), χ exhibits a significant linear relationship with a pollution index based on the contents of some urban elements (Cu, Pb, Zn), and therefore it serves as an effective parameter for quantifying the urban pollution.  相似文献   

6.
A survey of dissolved zinc, copper, oxygen and biochemical oxygen demand in Belfast Lough has been carried out. Zinc and to a lesser extent copper occur at elevated levels compared with a non-industrialized area of the Irish Sea. Zinc levels are particularly high in the marginal waters of the north shore of the lough. Dissolved oxygen and biochemical oxygen demand levels indicate that pollution of the lough by oxygendemanding wastes is not a serious problem.  相似文献   

7.
Wind-driven processes exert an important impact on aquatic ecosystems, especially on shallow reservoirs. Flow and heat transport under wind in the Douhe reservoir in China were simulated by a two-dimensional mathematical model. Areas corresponding to different temperature rises were calculated for different wind speed conditions with high frequency. It is shown that high temperature rise areas increase for maximum wind speed conditions while low temperature rise areas keep constant for various wind speed conditions. The concentration of Chl.a decreases with the increase of wind speed, indicating that low wind speed is suitable for algae blooming in the Douhe reservoir. The effects of wind on Bacillariophyta biomass growth become more obvious with the increase of temperature rise areas. The influenced areas of lower temperature rise (0.2–1.49 °C) and higher temperature rise (1.5–2 °C) zone are 8.57 × 106 m2 and 5.18 × 106 m2, respectively, and corresponding total variation amounts of Bacillariophyta biomass are 2.24 × 105/m2 and 0.42 × 105/m2, respectively. Results show that wind has a significant impact on ecological effects due to thermal discharge from thermal power plant into shallow reservoirs.  相似文献   

8.
The drainage networks of catchment areas burned by wildfire were analysed at several scales. The smallest scale (1–1000 m2) representative of hillslopes, and the small scale (1000 m2 to 1 km2), representative of small catchments, were characterized by the analysis of field measurements. The large scale (1–1000 km2), representative of perennial stream networks, was derived from a 30‐m digital elevation model and analysed by computer analysis. Scaling laws used to describe large‐scale drainage networks could be extrapolated to the small scale but could not describe the smallest scale of drainage structures observed in the hillslope region. The hillslope drainage network appears to have a second‐order effect that reduces the number of order 1 and order 2 streams predicted by the large‐scale channel structure. This network comprises two spatial patterns of rills with width‐to‐depth ratios typically less than 10. One pattern is parallel rills draining nearly planar hillslope surfaces, and the other pattern is three to six converging rills draining the critical source area uphill from an order 1 channel head. The magnitude of this critical area depends on infiltration, hillslope roughness and critical shear stress for erosion of sediment, all of which can be substantially altered by wildfire. Order 1 and 2 streams were found to constitute the interface region, which is altered by a disturbance, like wildfire, from subtle unchannelized drainages in unburned catchments to incised drainages. These drainages are characterized by gullies also with width‐to‐depth ratios typically less than 10 in burned catchments. The regions (hillslope, interface and channel) had different drainage network structures to collect and transfer water and sediment. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

9.
Radioecological studies were carried out in a territory polluted by 90Sr delivered by groundwater after leakage from a tank in a near-surface radioactive waste repository. The layer-by-layer vertical distribution of 90Sr in soil down to 3 m is analyzed. The area of radioactive pollution above the minimal significant activity level (1 Bq/kg by NRB-99/2009) in the examined soil layers decrease with depth as follows: 1808 m2 at 0–5 cm, 302 m2 at 5–10 cm, and 181 m2 at 10–15 cm. The accumulation of 90Sr takes place at a natural sorption geochemical barrier—a swampy area in a near-terrace depression. The radiation dozes were calculated for terrestrial mollusk of Bradybaena fruticum, accumulating strontium in its shell; the doses are in excess of the screening value of 2.4 μGr/day in 41% of the territory. This is higher than the acceptable risk level (5%) for this mollusk population. An excess of the intervention level for 90Sr was recorded in both subsurface and surface waters in this geosystem during winter and summer dry seasons and autumn showers.  相似文献   

10.
— Atmospheric particulate concentration for total suspended particles (TSP) and for PM10 (particulate matter under 10 micron) was measured in Jalan Braga and ITB campus, Bandung. Six samples were collected over one- or two-day time periods using High Volume Sampler (HVS) for TSP and Low Volume Sampler (LVS) or Anderson Cascade Impactor for PM10. Samples were further analyzed to determine concentrations of metals, sulfate and nitrate. Concentration of NOx (NO and NO2) was also measured hourly and simultaneously during the sampling period. The results from this study show that the atmospheric particulate concentration in Jalan Braga for TSP ranged from 304.04 to 363.17, and for PM10 concentration ranged from 277.02 to 336.44 μg/m3. The lead concentrations were 1.42–2.37 μg/m3 in the TSP and 0.81–1.57 μg/m3 in the PM10. The nitrate concentrations were 5.89–6.51 μg/m3 and 2.27–3.45 μg/m3 for the TSP and PM10, respectively. The hourly NOx concentration varied between 0.14–0.35 ppm. The total elements (metals, sulfate and nitrate) found in the samples contribute from 20 to 25% of the total particulate concentration.  相似文献   

11.
Upper layer circulation, hydrography, and biological response of Andaman waters during winter monsoon are assessed based on the observations carried out onboard FORV Sagar Sampada during January 2009 and November–December 2011. Cool and dry air carried by the moderate winds (6 m/s) from north and northeast indicates the influence of northeast monsoon (NEM) in the area during the observation time. The characteristics of physical parameters and the water mass indicate that the southeastern side is dominated by the less saline water from South China Sea intruded through the Malacca Strait, whereas the northeast is influenced by the freshwater from Ayeyarwady-Salween river system. The western side of the Andaman and Nicobar Islands exhibits similar properties of Bay of Bengal (BoB) water as evidenced in the T-S relation. Circulation pattern is uniform for the upper 88 m and is found to be more geostrophic rather than wind driven. Magnitude of the current velocity varies between 100 and 900 mm/s in November–December 2011 with strong current (900 mm/s) near Katchal and Nancowry islands and 100 and 1000 mm/s in January 2009 recording strong current (1000 mm/s) near the Little Nicobar Island. The Andaman waters are observed as less productive during the season based on the satellite-derived surface chl-a (0.1–0.4 mg/m3) and column-integrated primary productivity (PP) (100–275 mgC/m2/d).  相似文献   

12.
The thorium isotope content of ocean water   总被引：1，自引：0，他引：1  
232Th concentrations of surface and deep Pacific Ocean waters are 0.01–0.02 dpm/1000 kg (60 pgm/kg). The230Th activity is 0.03–0.13 dpm/1000 kg in surface waters and 0.3–2.7 dpm/1000 kg in deep waters. Chemical residence times based on in situ production from parent isotopes are about the same for230Th and228Th in surface waters (1–5 years) but are ten times greater for230Th in deep waters (10–100 years). Apparently there are additional sources of230Th into deep waters. At MANOP site S manganese nodule tops are enriched in Th isotopes by adsorption of Th from seawater and not by incorporation of Th-rich particulates.  相似文献   

13.
The occurrence of thermal/spa waters on Lesvos Island is related to the presence of a major faulting system. Thermal waters are the result of mixing of meteoric and infiltrating seawater at great depth, and their total salinity depends on the percentage of seawater in their composition. According to the diagrams of main elements, trace elements and environmental isotopes, most of the components that determine the chemical composition of thermal waters such as sodium, chloride and sulphates originate from seawaters. On the other hand, the concentration of calcium, magnesium, boron, lithium, etc., was affected by water–rock interaction under high temperature conditions. Moving towards the surface, thermal waters may become polluted by influx of recent seawater, allowing their chemical composition to become similar to that of seawater. The thermal waters of Lesvos Island present relatively high concentrations of ammonia and redox sensitive metals because they are hosted in a reducing environment. They also exhibit low nitrate concentrations due to their mixture with recent fresh water. Finally, they show increased radon concentrations, ranging from 20 to 60 kBq m?3 in the eastern and southern parts of the island, and about 230 kBq m?3 in the north, in the area of Eftalou–Argenos. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

14.
Runoff and sediment lost due to water erosion were recorded for 36 (1 m2) plots with varying types of vegetative cover located on sloping gypsiferous fields in the South of Madrid. 75% of the events had maximum 30‐minute intensity (I30) less than 10 mm h?1 in the period studied (1994–2005). As for the vegetative cover, maximum correlation between runoff and soil loss was found in the least protected plots (0–40% cover) during the most intense rainfall events; however, a significant positive correlation was also observed in plots with greater coverage (40–60%). If coverage exceeded 60%, rainfall erosivity declined. The average amount of sediment produced in high‐intensity events was significantly greater (approximately 7 g m?2 per I30 event >10 mm h?1) than that produced in the rest of the moderate‐intensity events (approximately 3 g m?2 per I30 event <10 mm h?1), but due to the high rate of occurrence of the latter throughout the year sediment loss during the period studied totaled 128 g m?2. By comparison, only 40 g m?2 was produced by the I30 events greater than 10 mm h?1. Even though the amount of soil lost is relatively insignificant from a quantitative standpoint, the organic matter content lost in the sediment (six times more than in the soil) is a permanent loss that threatens the development of the surface of the soil in this area when the vegetative cover is less than 40%. The soil here experiences a chronic loss of 0·02 mm annually as a consequence of frequent, moderate events, in addition to any loss produced by extraordinary events, which, though less frequent, are much more erosive. If moderate events are ignored, an important part of soil loss will be lost in the long run. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

15.
Recently published results of field and laboratory experiments on the seismic/acoustic response to injection of direct current(DC) pulses into the Earth crust or stressed rock samples raised a question on a possibility of electrical earthquake triggering. A physical mechanism of the considered phenomenon is not clear yet in view of the very low current density(10~(-7)–10~(-8) A/m~2) generated by the pulsed power systems at the epicenter depth(5–10 km) of local earthquakes occurred just after the current injection. The paper describes results of laboratory‘‘earthquake' triggering by DC pulses under conditions of a spring-block model simulated the seismogenic fault. It is experimentally shown that the electric triggering of the laboratory ‘‘earthquake'(sharp slip of a movable block of the spring-block system) is possible only within a range of subcritical state of the system, when the shear stress between the movable and fixed blocks obtains 0.98–0.99 of its critical value. The threshold of electric triggering action is about 20 A/m~2 that is 7–8 orders of magnitude higher than estimated electric current density for Bishkek test site(Northern Tien Shan, Kirghizia) where the seismic response to the man-made electric action was observed. In this connection, the electric triggering phenomena may be explained by contraction of electric current in the narrow conductive areas of the faults and the corresponding increase in current density or by involving the secondary triggering mechanisms like electromagnetic stimulation of conductive fluid migration into the fault area resulted in decrease in the fault strength properties.  相似文献   

16.
This paper documents application of an established geostatistical methodology to detect significant changes in a foredune–transgressive dune complex where Parks Canada Agency (PCA) implemented a dynamic restoration program to remove invasive marram grasses (Ammophila spp.) and enhance dynamic dune habitat for an endangered species. Detailed topographic surveys of a 10 320 m2 site in the Wickaninnish Dunes in Pacific Rim National Park, British Columbia, Canada for the first year post‐treatment are compared to a pre‐restoration LiDAR baseline survey. The method incorporates inherent spatial structure in measured elevation datasets at the sub‐landscape scale and models statistically significant change surfaces within distinct, linked geomorphic units (beach, foredune, transgressive dune complex). Seasonal and annual responses within the complex are discussed and interpreted. All geomorphic units experienced positive sediment budgets following restoration treatment. The beach experienced the highest differential volumetric change (+1656 m3) and net sediment influx (+834 m3, 0 · 19 m3 m–2) mostly from supply to the supratidal beach and incipient dune. This sediment influx occurred independent of the restoration effort and was available as a buffer against wave erosion and as supply to the landward dunes. The foredune received +200 m3 (0 · 13 m3 m‐2) and its seaward profile returned to a similar pre‐restoration form following erosion at the crest from vegetation removal and scarping by high water events. Sediment bypassing and minimal change was evident at the mid‐stoss slope with appreciable extension of depositional lobes in the lee. The transgressive dune complex experienced high accretion following restoration activity (+201 m3) and over the year (+284 m3, 0 · 07 m3 m–2) mostly from depositional lobes from the foredune, precipitation ridge growth along the downwind boundary, and growth of existing lobes within the complex. Further integration of this methodology to detect significant geomorphic changes is recommended, particularly for applications where sampling densities are limited or logistically defined. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

17.
We assess the effects of prospective climate change until 2100 on water management of two major reservoirs of Iran, namely, Dez (3.34 × 109 m3) and Alavian (6 × 107 m3). We tune the Poly‐Hydro model suited for simulation of hydrological cycle in high altitude snow‐fed catchments. We assess optimal operation rules (ORs) for the reservoirs using three algorithms under dynamic and static operation and linear and non‐linear decision rules during control run (1990–2010 for Dez and 2000–2010 for Alavian). We use projected climate scenarios (plus statistical downscaling) from three general circulation models, EC‐Earth, CCSM4, and ECHAM6, and three emission scenarios, or representative concentration pathways (RCPs), RCP2.6, RCP4.5, and RCP8.5, for a grand total of nine scenarios, to mimic evolution of the hydrological cycle under future climate until 2100. We subsequently test the ORs under the future hydrological scenarios (at half century and end of century) and the need for reoptimization. Poly‐Hydro model when benchmarked against historical data well mimics the hydrological budget of both catchments, including the main processes of evapotranspiration and streamflows. Teaching–learning‐based optimization delivers the best performance in both reservoirs according to objective scores and is used for future operation. Our projections in Dez catchment depict decreased precipitation along the XXI century, with ?1% on average (of the nine scenarios) at half century and ?6% at the end of century, with changes in streamflows on average ?7% yearly and ?13% yearly, respectively. In Alavian, precipitation would decrease by ?10% on average at half century and ?13% at the end of century, with streamflows ?14% yearly and ?18% yearly, respectively. Under the projected future hydrology, reservoirs' operation would provide lower performance (i.e., larger lack of water) than now, especially for Alavian dam. Our results provide evidence of potentially decreasing water availability and less effective water management in water stressed areas like Northern Iran here during this century.  相似文献   

18.
We have used a suite of remotely sensed data, numerical lava flow modeling, and field observations to determine quantitative characteristics of the 1995 Fernandina and 1998 Cerro Azul eruptions in the western Galápagos Islands. Flank lava flow areas, volumes, instantaneous effusion rates, and average effusion rates were all determined for these two eruptions, for which only limited syn-eruptive field observations are available. Using data from SPOT, TOPSAR, ERS-1, and ERS-2, we determined that the 1995 Fernandina flow covers a subaerial area of 6.5×106 m2 and has a subaerial dense rock equivalent (DRE) volume of 42×106 m3. Field observations, ATSR satellite data, and the FLOWGO numerical model allow us to determine that the effusion rate declined exponentially from a high of ~60–200 m3 s-1 during the first few hours to <5 m3 s-1 prior to ceasing after 73 days, with a mean effusion rate of 4–16 m3 s-1. Integrating the ATSR-derived, exponentially declining effusion rate over the eruption duration produces a total (subaerial + submarine) DRE volume of between 27 and 100×106 m3, the range in values being due to differing assumptions about heat loss characteristics; only values in the higher part of this range are consistent with the independently derived subaerial volume. Using SPOT, TOPSAR, ERS-1, and ERS-2 data, we determine that the 1998 Cerro Azul flow is 16 km long, covers 16 km2, and has a DRE volume of 54×106 m3. FLOWGO produces at-vent velocity and effusion rate values of 11 m s-1 and ~600 m3 s-1, respectively. The velocity value agrees well with the 12 m s-1 estimated in the field. The mean effusion rate (total DRE volume/duration) was 7–47 m3 s-1. Dike dimensions, fissure lengths, and pressure gradients along the conduit based on magma chamber depth estimates of 3–5 km produce mean effusion rates for the two eruptions that range over nearly four orders of magnitude, the range being due to uncertainty in the magma viscosity, dike dimensions, and pressure gradient between magma chamber and vent. Although somewhat consistent with mean effusion rates from other techniques, their wide range makes them less useful. The exponentially declining effusion rates during both eruptions are consistent with release of elastic strain being the driving mechanism of the eruptions. Our results provide independent input parameters for previously published theoretical relationships between magma chamber pressurization and eruption rates that constrain chamber volumes and increases in volume prior to eruption, as well as time constants of exponential decay during the eruption. The results and theoretical relationships combine to indicate that at both volcanoes probably 25–30% of the volumetric increase in the magma chamber erupted as lava onto the surface. In both eruptions the lava flow volumes are less than 1% of the magma chamber volume.  相似文献   

19.
The present investigation gives the turnover value and productivity of macrophytes like Eichhornia crassipes, Hydrilla verticillata, Ceratophyllum demersum, Potamogeton crispus and Azolla pinnata for the year 1978 at Koylaghat site of the Champanala channel, a southern side spill channel of the river Ganges. The average annual production of all the macrophytes comes to 3.925 g/m2 · d, which is better than the world average of rice cultivated fields. All the important macrophytes in the present investigation are replaced annually. In contrast to pond and reservoir ecosystems, where the productivity of macrophytes is highest in the rainy season, in the Champanala channel the most of the macrophytes are absent from July to December and maximal productivity was about 4 g/m2 · d from February to April. The difference in the development of macrophytes in standing and flowing waters results from the fact that in the rainy season increasing flow velocity, sudden fluctuations in water column depth and other destabilising factors produce unfavourable conditions for macrophytes in flowing waters.  相似文献   

20.
Karst solution processes are investigated on Oligocene limestones in the Waitomo district, west central North Island, New Zealand. Estimates of the inputs, throughputs and outputs of water and dissolved calcium and magnesium in two drainage basins were used to establish the rate of limestone solution by autogenic waters. The best estimate for solution loss from the basins during the study year is 69 m3/km2. The potential measurement errors inherent in each parameter used in the erosion rate computations were assessed and the probable maximum and minimum erosion rates were estimated to be 88 and 61 m3/km2. In both basins approximately 67 per cent of the annual solute load is transported by flows greater than the mean annual discharge, over 15 per cent being transported by flood flows that are exceeded only 5 per cent of the time. Almost half of the annual load is transported during the three winter months (June-August), but no one month accounts for more than 18 per cent or less than 2.7 per cent of the annual total. Approximately 37 per cent of solution takes place within the soil profile, and most of the remainder is concentrated in 5–10 m of weathered bedrock (the subcutaneous zone) beneath this. Thus, it is likely that at least 85 per cent of the total solutional erosion contributes to the surface lowering of soil and bedrock.  相似文献   

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