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1.
Katsumi  Ueno  Satoe  Tsutsumi 《Island Arc》2009,18(1):69-93
This paper deals with a Lopingian (Late Permian) foraminiferal faunal succession of the Shifodong Formation in the Changning–Menglian Belt, West Yunnan, Southwest China, which has been geologically interpreted as one of the closed remnants in East Asia of the Paleo‐Tethys Ocean. The Shifodong Formation is the uppermost stratigraphic unit in thick Carboniferous–Permian carbonates of the belt. These carbonates rest upon bases consisting of oceanic island basalt and are widely accepted as having a Paleo‐Tethyan mid‐oceanic (seamount‐ or oceanic plateau‐top) origin. Sixteen taxa of fusuline foraminifers and 37 taxa of smaller (non‐fusuline) foraminifers are recognized from the type section of the Shifodong Formation located in the Gengma area of the northern part of the Changning–Menglian Belt. Based on their stratigraphic distribution, three fusuline zones can be established in this section: they are, in ascending order, the Codonofusiella cf. C. kwangsiana Zone, Palaeofusulina minima Zone, and Palaeofusulina sinensis Zone. These three biozones are respectively referable to the Wuchiapingian, early Changhsingian, and late Changhsingian, of which the Wuchiapingian is first recognized in this study in the Changning–Menglian mid‐oceanic carbonates. The present study clearly demonstrates that the foraminiferal fauna in a Paleo‐Tethyan pelagic shallow‐marine environment still maintained high faunal diversity throughout the almost entire Lopingian, although the very latest Permian fauna in the upper part of the Palaeofusulina sinensis Zone of the Shifodong section records a sudden decrease in both faunal diversity and abundance. Moreover, the Shifodong faunas are comparable in diversity with those observed in circum‐Tethyan shelves such as South China. The present Paleo‐Tethyan mid‐oceanic foraminiferal faunas are definitely more diversified than coeval mid‐oceanic Panthalassan faunas, which are typically represented by those from the Kamura Limestone in a Jurassic accretionary complex of Southwest Japan. It is suggestive that the Paleo‐Tethyan mid‐oceanic buildups presumably supplied a peculiarly hospitable habitat for foraminiferal faunal development in a pelagic paleo‐equatorial condition.  相似文献   

2.
Abstract We review the carbon‐isotope data for finely disseminated carbonates from bioaltered, glassy pillow rims of basaltic lava flows from in situ slow‐ and intermediate‐spreading oceanic crust of the central Atlantic Ocean (CAO) and the Costa Rica Rift (CRR). The δ13C values of the bioaltered glassy samples from the CAO show a large range, between ?17 and +3‰ (Vienna Peedee belemnite standard), whereas those from the CRR define a much narrower range, between ?17‰ and ?7‰. This variation can be interpreted as the product of different microbial metabolisms during microbial alteration of the glass. In the present study, the generally low δ13C values (less than ?7‰) are attributed to carbonate precipitated from microbially produced CO2 during oxidation of organic matter. Positive δ13C values >0‰ likely result from lithotrophic utilization of CO2 by methanogenic Archaea that produce CH4 from H2 and CO2. High production of H2 at the slow‐spreading CAO crust may be a consequence of fault‐bounded, high‐level serpentinized peridotites near or on the sea floor, in contrast to the CRR crust, which exhibits a layer‐cake pseudostratigraphy with much less faulting and supposedly less H2 production. A comparison of the δ13C data from glassy pillow margins in two ophiolites interpreted to have formed at different spreading rates supports this interpretation. The Jurassic Mirdita ophiolite complex in Albania shows a structural architecture similar to that of the slow‐spreading CAO crust, with a similar range in δ13C values of biogenic carbonates. The Late Ordvician Solund–Stavfjord ophiolite complex in western Norway exhibits structural and geochemical evidence for evolution at an intermediate‐spreading mid‐ocean ridge and displays δ13C signatures in biogenic carbonates similar to those of the CRR. Based on the results of this comparative study, it is tentatively concluded that the spreading rate‐dependent tectonic evolution of oceanic lithosphere has a significant control on the evolution of microbial life and hence on the δ13C biosignatures preserved in disseminated biogenic carbonates in glassy, bioaltered lavas.  相似文献   

3.
Tetsuji  Onoue  Hiroyoshi  Sano 《Island Arc》2007,16(1):173-190
Abstract   The Sambosan accretionary complex of southwest Japan was formed during the uppermost Jurassic to lowermost Cretaceous and consists of basaltic rocks, carbonates and siliceous rocks. The Sambosan oceanic rocks were grouped into four stratigraphic successions: (i) Middle Upper Triassic basaltic rock; (ii) Upper Triassic shallow-water limestone; (iii) limestone breccia; and (iv) Middle Middle Triassic to lower Upper Jurassic siliceous rock successions. The basaltic rocks have a geochemical affinity with oceanic island basalt of a normal hotspot origin. The shallow-water limestone, limestone breccia, and siliceous rock successions are interpreted to be sediments on the seamount-top, upper seamount-flank and surrounding ocean floor, respectively. Deposition of the radiolarian chert of the siliceous rock succession took place on the ocean floor in Late Anisian and continued until Middle Jurassic. Oceanic island basalt was erupted to form a seamount by an intraplate volcanism in Late Carnian. Late Triassic shallow-water carbonate sedimentation occurred at the top of this seamount. Accumulation of the radiolarian chert was temporally replaced by Late Carnian to Early Norian deep-water pelagic carbonate sedimentation. Biotic association and lithologic properties of the pelagic carbonates suggest that an enormous production and accumulation of calcareous planktonic biotas occurred in an open-ocean realm of the Panthalassa Ocean in Late Carnian through Early Norian. Upper Norian ribbon chert of the siliceous rock succession contains thin beds of limestone breccia displaced from the shallow-water buildup resting upon the seamount. The shallow-water limestone and siliceous rock successions are nearly coeval with one another and are laterally linked by displaced carbonates in the siliceous rock succession.  相似文献   

4.
Stable carbon isotope measurements of the organic matter associated with the carbonate globules and the bulk matrix material in the ALH84001 Martian meteorite indicate that two distinct sources are present in the sample. The delta 13C values for the organic matter associated with the carbonate globules averaged -26% and is attributed to terrestrial contamination. In contrast, the delta 13C values for the organic matter associated with the bulk matrix material yielded a value of -15%. The only common sources of carbon on the Earth that yield similar delta 13C values, other then some diagenetically altered marine carbonates, are C4 plants. A delta 13C value of -15%, on the other hand, is consistent with a kerogen-like component, the most ubiquitous form of organic matter found in carbonaceous chondrites such as the Murchison meteorite. Examination of the carbonate globules and bulk matrix material using laser desorption mass spectrometry (LDMS) indicates the presence of a high molecular weight organic component which appears to be extraterrestrial in origin, possibly derived from the exogenous delivery, of meteoritic or cometary debris to the surface of Mars.  相似文献   

5.
Along the Proterozoic stratigraphic sections of Jixian, Tianjin, the δ13C values of carbonates are mostly negative in the Changchengian (Changcheng System), varying approximately within a range of (0±1 )‰in the Jixianian (Jixian System), and have commonly positive values of (2±2)‰ in the Qingbaikouan (Qingbaikou System). From Chuanlinggou Formation to Dahongyu Formation, i.e. from ca. 1700 Ma to 1600 Ma, the δ13C values of carbonates increase from about -3‰ to 0‰, but oscillate with large excursion in Dahongyu Formation. Two large excursions occur in the Jixianian, one in Yangzhuang Formation and the other in the third sub-member of Wumishan Formation overlaying. These integrated and continuous records of carbon isotope reflect secular variations of δ13C value in ancient seawater from ca. 1700 Ma to ca. 800 Ma. The increase and subsequent oscillation of seawater δ13C value occurring from the ages of ca. 1700 to ca. 1600 Ma and <1300 Ma may signify two correlative global tectonic events.  相似文献   

6.
The fate of linear alkylbenzenesulponates (LAS) in estuaries and coastal areas of the North Sea has been characterized with simple environmental models. The predicted concentration range in the estuaries around the North Sea (0.9-9 microg LAS l(-1)) was validated by monitoring data (1-9 microg LAS l(-1)). In offshore sites of the North Sea, it is estimated--and experimentally verified for a few sites--that the LAS concentration is below analytical detection limit (i.e., 0.5 microg LAS l(-1)). The effects of LAS on marine organisms have been reviewed. For short-term acute tests, there was no significant difference (p = 0.83) between the mean LC50 values of freshwater and marine organisms (mainly pelagic species tested, 4.1 and 4.3 mg LAS l(-1), respectively). For longer-term chronic tests, it appeared that the sensitivity (mean no-observed effect concentration (NOEC) value) of marine and freshwater organisms (0.3 and 2.3 mg LAS l(-1), respectively) was significantly different pt-test = 0.007). The predicted no-effect-concentrations (PNEC) were 360 and 31 microg LAS l(-1), for freshwater and marine pelagic communities, respectively. Given that the maximum expected estuarine and marine concentrations are 3 to > 30 times lower than the PNEC, the risk of LAS to pelagic organisms in these environments is judged to be low.  相似文献   

7.
Mathematical simulation is used to study the biotransformation conditions of compounds of organogenic elements (C, N, P, Si) and oil hydrocarbons in the water of southeastern Sakhalin shelf. The input data for calculations were evaluated with the use of Sakhalin Shelf GIS or taken from the reference literature and materials of expedition studies. The values of water discharges through the boundaries of the zones chosen within the shelf water area and through the interface with the Sea of Okhotsk were derived from the characteristics of currents estimated by means of Bergen University oceanic model based on normal long-term monthly thermohaline parameters obtained from the Sakhalin Shelf GIS. The intraannual variations of the concentrations of organic and mineral compounds of C, N, P, and Si, as well as oil hydrocarbons because of biotransformation of substances by organisms of the community (bacteria, phytoand zooplankton) were evaluated in calculations with CNPSi-model. The results of calculations, revealing the features of the dynamics of substances, the biomass of organisms, and their activity in matter biotransformations were analyzed.  相似文献   

8.
Immediately before the extinction of the end‐Guadalupian (Middle Permian; ca 260 Ma), a significant change to the global carbon cycle occurred in the superocean Panthalassa, as indicated by a prominent positive δ13C excursion called the Kamura event. However, the causes of this event and its connection to the major extinction of marine invertebrates remain unclear. To understand the mutual relationships between these changes, we analyzed the sulfur isotope ratio of the carbonate‐associated sulfate (CAS) and HCl‐insoluble residue, as well as the carbon isotope ratio of bulk organic matter, for the Middle‐Upper Permian carbonates of an accreted mid‐oceanic paleo‐atoll complex from Japan, where the Kamura event was first documented. We detected the following unique aspects of the stable carbon and sulfur isotope records. First, the extremely high δ13C values of carbonate (δ13Ccarb) over +5 ‰ during the Capitanian (late Guadalupian) were associated with large isotopic differences between carbonate and organic matter (Δ13C = δ13Ccarb ? δ13Corg). We infer that the Capitanian Kamura event reflected an unusually large amount of dissolved organic matter in the expanded oxygen minimum zone at mid‐depth. Second, the δ34S values of CAS (δ34SCAS) were inversely correlated with the δ13Ccarb values during the Capitanian to early Wuchiapingian (early Late Permian) interval. The Capitanian trend may have appeared under increased oceanic sulfate conditions, which were accelerated by intense volcanic outgassing. Bacterial sulfate reduction with increased sulfate concentrations in seawater may have stimulated the production of pyrite that may have incorporated iron in pre‐existing iron hydroxide/oxide. This stimulated phosphorus release, which enhanced organic matter production and resulted in high δ13Ccarb. Low δ34SCAS values under high sulfate concentrations were maintained and the continuous supply of sulfate cannot by explained only by the volcanic eruption of the Emeishan Trap, which has been proposed as a cause of the extinction. The Wuchiapingian δ34SCAS–δ13Ccarb correlation, likely related to low sulfate concentration, may have been caused by the removal of oceanic sulfate through the massive evaporite deposition.  相似文献   

9.
The Early Triassic is a critical period in earth his- tory. A series of events such as volcano eruptions[1,2], sea-level fluctuations, changes in environmental con- ditions[3], mass extinctions[4,5] as well as global negative carbon isotope excursions[6-9] have been discovered in the uppermost Permian or across the Permian-Triassic boundary. Large scale sea-level rise[10-12], restoration of environment conditions, re- covery of ecosystem[13], including gradual carbon iso- tope rise[14] occur…  相似文献   

10.
The stratigraphic and geochemical record of the mid-Cretaceous (Cenomanian–Turonian) Oceanic Anoxic Event 2 (OAE2) has been studied in numerous Tethyan and proto-Atlantic hemi-pelagic/pelagic successions, but little data comes from nearshore carbonate successions from the proto-Pacific region. Here we present the results of a combined stratigraphic and δ13C study of C–T platform carbonates from southern Mexico, which were deposited within the proto-Pacific. Two scales of sedimentary cyclicity are recognized. High-frequency peritidal and subtidal cycles (0.4–8 m) display little evidence of cycle-capping subaerial exposure and are not correlative between sections; these relationships suggest that the amplitudes of high-frequency sea-level changes were minimal during the peak mid-Cretaceous greenhouse. Longer-term transgressive-regressive sequences (18–40+ m) are correlated between sections, and using δ13C trends, can be correlated with sequences developed in northern Europe and India.The Mexican successions were sampled at a high resolution (~ 10 ky) for stable isotopes (inorganic, organic carbon and oxygen), total organic carbon, insoluble residues, and trace metals. The δ13Ccarb curve matches global trends (including 6 distinct isotopic stages) permitting identification of OAE2 despite the lack of characteristic anoxic facies. Using the δ13Ccarb trends, we tie the previously identified ammonite, planktonic foram, and nannofossil biostratigraphy from England and the Western Interior seaway of Colorado into the Mexican sections. The initiation of OAE2, defined by an abrupt positive 3–4‰ δ13C shift, coincides with a long-term sea-level rise, though the sedimentary expression of the deepening is no greater than that observed for any of the other sea-level events across the studied interval. OAE2 termination (transition from gradually decreasing to background δ13C values) is not associated with a particular sea-level trend. Stratigraphic changes in insoluble residues (proxy for continental sediment discharge) across OAE2 are not correlative between sections and do not show consistent systematic relationships with δ13C or sea-level variations, therefore do not support the hypothesis that OAE2 was associated with increased continental-derived nutrient influx. Two peaks in trace metal concentrations coincide with the abrupt increase in δ13C ratios (onset of OAE2) and during the transition from elevated-to-decreasing δ13C values (near the C–T stage boundary). These trends are similar to those recorded in coeval deposits of the Western Interior seaway, and are consistent with the hypothesis that OAE2 development was related to the release of reduced metals during the short-lived (< 1 My) Caribbean oceanic plateau basalt eruption. In this scenario, oxidation of the metals depleted the existing low dissolved-O2 concentrations and thermally-buoyant plumes of seawater enriched in biolimiting elements mixed with surface waters, stimulated primary productivity, and further reduced O2 concentrations leading to widespread anoxia and a large positive δ13C shift.  相似文献   

11.
Concentrations of polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ethers (PBDEs) were measured in 32 species inhabiting the Yellow Sea to assess their bioaccumulation potentials. The concentrations in these samples were lower than those reported for other countries or locations. Relatively high levels of BDE 209 in biota suggest an ongoing source of deca-BDE technical mixing within the Yellow Sea. The accumulation profiles of PCBs were uniform between species, but the concentrations of OCPs and PBDEs varied widely. Pelagic and benthic food-chain components were separated by their δ13C values. Significant positive correlations between δ15N and PCB 153, PCB 138, p,p′-DDE, oxy-chlordane, and trans-nonachlordane were found only for pelagic consumers, indicating that the pelagic food chain is an important bioaccumulation pathway for selected PCB and OCP compounds. The other compounds did not show any biomagnification through benthic and pelagic food chains, suggesting the lower bioaccumulation potentials of these contaminants.  相似文献   

12.
The present study employs a method for analysis of the sulfur isotopic composition of trace sulfate extracted from carbonates collected in Namibia in order to document secular variations in the sulfur isotopic composition of Neoproterozoic oceanic sulfate and to assess variations in the sulfur cycle that may have accompanied profound climatic events that have been described as the snowball Earth hypothesis. The carbonates in the Otavi Group of Northwest Namibia contain 3-295 ppm sulfate. Positive excursions, to a high of 40‰ (CDT), occur above the lower (Chuos Formation) and upper (Ghaub Formation) glacial intervals in the Rasthof and Maieberg cap carbonates, respectively. Positive excursions at the top of the Rasthof Formation (reaching 51‰) and within the overlying Gruis Formation (34‰) do not appear to correspond to glaciation. The δ34Ssulfate values within the Ombaatjie Formation exhibit shifts over relatively short stratigraphic intervals (tens of meters), varying between ∼15 and 25‰. Cap carbonates from Australia exhibit positive δ34Spyrite trends with amplitudes similar to those of Namibian δ34Ssulfate, although, more data are necessary to firmly establish these δ34S trends as global in nature. δ34Ssulfate excursions found in Namibian cap carbonates are consistent with the snowball Earth hypothesis in that they appear to reflect nearly complete reduction of sulfate in an isolated, anoxic global ocean, although, there are other mechanisms that may have facilitated these large shifts in δ34Ssulfate. Regardless, the low sulfate concentrations in Otavi carbonates, the high amplitude variability of the δ34Ssulfate curve, and the apparently full reduction of sulfate (as implied from δ34Spyrite data), even in strata low in Corg, suggest that Neoproterozoic oceanic sulfate concentrations were much lower than modern values. Additionally, the buildup of ferrous iron and banded-iron formations during the Sturtian glacial event would indicate that Fe supply exceeded sulfide availability during the glacials and/or that all sulfide was fixed and buried. This could be construed as further evidence in support of low oceanic sulfate (and sulfide) at this time.  相似文献   

13.
High-sensitivity stepped extraction reveals two isotopically distinct forms of carbon in submarine basalt glasses: an isotopically light carbon component released by combustion from 200 to 600°C and an isotopically heavy CO2 liberated from vesicles (magmatic carbon) from 600 to 1200°C. The δ13CPDB of the low release temperature carbon varies from −24 to −30‰ and is believed to be surficial organic contamination. A survey of various types of oceanic glasses demonstrates that the δ13C of magmatic CO2 varies from −4.2 to −7.5‰ in mid-ocean ridge basalt (MORB), from −2.8 to −6.7‰ in glasses from Hawaii and Explorer Seamount and from −7.7 to −16.3‰ in glasses from the Scotia Sea and Mariana Trough. Magmatic CO2 in back-arc basin basalts (BABB) is on average 5‰ lighter than equivalent CO2 in MORB and can be explained by the mixing in the source regions for BABB magmas of juvenile (MORB-like) CO2 with an organic carbon component from subducted pelagic sediments. It is inferred that significant amounts of pelagic carbonate carbon (δ13C 0‰) must be recycled into the mantle.  相似文献   

14.
Abstract Carbon isotope fluctuations of sedimentary organic matter along the two geological traverses in the Yezo Group, Hokkaido, northern Japan, elucidate a detailed chemostratigraphy for the Cenomanian Stage on the northwestern Pacific margin. Visual characterization of the kerogen from mudstone samples shows that the major constituents of sedimentary organic matter originated as terrestrial higher plants. The atomic hydrogen/carbon ratios of the kerogen suggest that the original δ13C values of terrestrial organic matter (TOM) have not been affected significantly by thermal diagenesis. The patterns in two δ13CTOM curves are similar and independent of changes in lithology and total organic carbon contents, which suggests that TOM was mixed sufficiently before the deposition in the Yezo forearc basin for the δ13C composition having been homogenized. In addition, this implies that the Hokkaido δ13CTOM profiles represent the averaged temporal δ13C variations of terrestrial higher‐plant vegetation in the hinterlands of northeast Asia during Cenomanian time. Three shorter‐term (ca. 0.1 my duration) positive‐and‐negative δ13CTOM fluctuations of ∼1‰ are present in the Lower to Middle Cenomanian interval in the Yezo Group. On the basis of the age‐diagnostic taxa (ammonoids, inoceramids and planktic foraminifers), these discrete δ13CTOM events are interpreted to be correlated with those in the δ13C curves of pelagic carbonates from European basins. The correlation of δ13C events between the European and Yezo Group sections suggests that the shorter‐term δ13C fluctuations in Cenomanian ocean‐atmosphere carbon reservoirs are useful for global chemostratigraphic correlation of marine strata. In particular, the correlation of δ13C fluctuations of the so‐called ‘Mid‐Cenomanian event’ (MCE) implies: (i) the δ13C variations of global carbon reservoir during the MCE are precisely recorded in the δ13CTOM records; and (ii) the MCE δ13CTOM event is an efficient chronostratigraphic index for the Lower/Middle Cenomanian boundary of the Mid‐Cretaceous sequences.  相似文献   

15.
北京地区部分碳酸盐糜棱岩和碳酸盐假熔岩碳氧同位素组成的测试结果表明,碳酸盐岩在发生塑性变形时其δ13C、δ18O值均有不同程度的降低。同位素证据表明,碳酸盐糜棱岩的形成温度较低,并具有缓慢冷却的生成环境;碳酸盐假熔岩具有高温淬冷的同位素地球化学特征,它的形成可能与发震断层的迅速破裂过程有关。研究断层面附近产出的碳酸盐岩的稳定同位素组成对确认古地震事件是有意义的  相似文献   

16.
大通湖及东洞庭湖区生物体重金属的水平及其生态评价   总被引:4,自引:0,他引:4  
于2005年11月采集了大通湖及东洞庭湖区湖水和水生生物样品,并测定了水和水生生物样品中重金属(Cd、Pb、Hg、As)的含量,并对湖区生物体重金属进行了污染评价.研究结果表明,大通湖及东洞庭湖区湖水中重金属含量较小,绝大部分采样点水质都属于国家Ⅰ类水标准;水生生物体内CD、Pb含量为虾>螺>鱼,Hg的含量为鱼>螺>虾,As的含量为螺>虾>鱼;而鱼类重金属含量则为底栖鱼类>中上层鱼类,肉食性鱼类>植食性鱼类.大通湖及东洞庭湖区生物体中CD、Pb的污染指数为虾>螺>鱼,Hg的污染指数则为鱼>螺>虾,As的污染指数则为螺>虾>鱼.  相似文献   

17.
南海西南次海盆的地热流特征与分析   总被引:2,自引:1,他引:1       下载免费PDF全文
为系统地了解南海西南次海盆的地热流特征,本文通过对研究区及邻域地热流数据的补充采集、收集整理和统计分析,获得了87个有效的地热流数据、一批热导率和生热率的地热参数资料,地热流测点在空间上覆盖了整个区域.研究区的地热流数据分布结果表明,西南次海盆热流密度的平均值为98.1±14.8 mW·m-2,洋陆过渡带为103.6±19.4 mW·m-2,南沙岛礁区和西部陆缘分别为79.0±15.5 mW·m-2和78.3±15.6 mW·m-2.研究区表层沉积物热导率的平均值0.86±0.06 W·mK-1,生热率的平均值1.11±0.17 μW·m-3,海底温度的平均值为2.43±0.01℃.综合海底地形地貌、地质与地球物理资料,认为研究区的热流特征在空间上具有一定的分布规律,表现为:(1)洋盆区测点的热流密度平均值高于两侧陆缘;(2)东南缘洋陆过渡带上测点的地热流密度值高于邻近海盆和南沙岛礁区的测点,而西北缘这种特征不明显;(3)西北翼的热流密度值总体比东南翼高;(4)沿着古扩张中心方向,西南次海盆热流值具有自东北向西南端方向逐步增大的趋势,表明海盆区同时存在着洋中脊与大陆裂谷两种不同的热状态,西南段裂谷热流值比东北段洋中脊高.对西南次海盆沉积物的热导率和生热率值参数的测量及数据空间分析可见,这两种热参数的空间分布无明显规律性,可能与海盆形成之后复杂的沉积环境相关.根据热流-洋壳年龄之间的关系,在西南次海盆东北段26个测站数据中,发现靠近古扩张中心的数据与理论值呈负偏移,而远离古扩张中心的数据呈正偏移,此现象是海盆内地热流数据受不同类型的地下流体影响所致.  相似文献   

18.
Sedimentological, geochemical, and chronological analyses were carried out on 18 carbonate rock samples collected at depths of 938, 1085, and 3354 m on the western slope of Minamitorishima (Marcus Island), which is located near the western margin of the Pacific Plate. Four groups of carbonate rocks were distinguished: a mollusk-rich limestone, a coral-rich dolomite, a foraminiferal-nannofossil packstone, and a phosphatized mudstone/wackestone. The mollusk-rich limestone is characterized by the dominance of bivalves (including rudists) and gastropod shells. Strontium isotope ratios (87Sr/86Sr) and Mesorbitolina ex gr. texana (a large benthic foraminifer) indicate that the shallow-water carbonates were deposited during the late Aptian–early Albian (ca. 123–111 Ma). The coral-rich dolomite is characterized by abundant scleractinian corals and nongeniculate coralline algae associated with encrusting acervulinid foraminifers. The biotic composition is similar to that of the Oligocene–Pleistocene carbonates reported from other seamounts in the northwestern Pacific. Geochemical data show that the coral-rich carbonates were dolomitized at 9.5–6.8 Ma (Tortonian–Messinian) and that normal seawater was the most likely parent fluid. The foraminiferal-nannofossil packstone is a semi-consolidated foraminiferal-nannofossil ooze and was deposited during the Pleistocene (0.99–0.45 Ma). The phosphatized mudstone/wackestone is marked by the absence of macrofossils and the presence of traces of planktic foraminifers. Although its depositional age is not constrained, the Sr isotope ratios indicate that the phosphatization occurred at 33.2–28.9 Ma. After the deposition of the Cretaceous shallow-water carbonates, including the mollusk-rich limestone, Minamitorishima was drowned and its top was covered with a pelagic cap, represented by the mudstone/wackestone. The late Eocene–early Oligocene volcanism (40.2–33.2 Ma) caused episodic uplift and returned the top of Minamitorishima to a shallow-water environment. After the early Oligocene phosphatization of the pelagic cap, coral reefs flourished on the top of this island. The reef limestone was dolomitized during the Tortonian–Messinian.  相似文献   

19.
Marble has a great potential to understand a history of various geological events occurring during tectonic processes. In order to decode metamorphic–metasomatic records on C–O isotope compositions of marble at mid-crustal conditions, we conducted a C–O–Sr isotope study on upper amphibolite-facies marbles and a carbonate–silicate rock from the Hida Belt, which was once a part of the crustal basement of the East Asian continental margin. Carbon and oxygen isotope analyses of calcite from marbles (Kamioka area) and a carbonate–silicate rock (Wadagawa area) show a large variation of δ13C [VPDB] and δ18O [VSMOW] values (from −4.4 to +4.2 ‰ and +1.6 to +20.8 ‰, respectively). The low δ13C values of calcites from the carbonate–silicate rock (from −4.4 to −2.9 ‰) can be explained by decarbonation (CO2 releasing) reactions; carbon–oxygen isotope modeling suggests that a decrease of δ13C strongly depends on the amount of silicate reacting with carbonates. The occurrence of metamorphic clinopyroxene in marbles indicates that all samples have been affected by decarbonation reactions. All δ18O values of calcites are remarkably lower than the marine-carbonate values. The large δ18O variation can be explained by the isotope exchange via interactions between marble, external fluids, and/or silicates. Remarkably low δ18O values of marbles that are lower than mantle value (~+5 ‰) suggest the interaction with meteoric water at a later stage. Sr isotope ratios (87Sr/86Sr = 0.707255–0.708220) might be close to their protolith values. One zircon associated with wollastonite in a marble thin-section yields a U–Pb age of 222 ± 3 Ma, which represents the timing of the recrystallization of marble, triggered by H2O-rich fluid infiltration at a relatively high-temperature condition. Our isotope study implies that the upper amphibolite-facies condition, like the Hida Belt, might be appropriate to cause decarbonation reactions which can modify original isotope compositions of marble if carbonates react with silicates.  相似文献   

20.
Trace elements (TEs) and stable isotope ratios (δ15N and δ13C) were analyzed in fish from deep-water of the Sulu Sea, the Celebes Sea and the Philippine Sea. Concentrations of V and Pb in pelagic fish from the Sulu Sea were higher than those from the Celebes Sea, whereas the opposite trend was observed for δ13C. High concentrations of Zn, Cu and Ag were found in non-migrant fish in deep-water, while Rb level was high in fish which migrate up to the epipelagic zone, probably resulting from differences in background levels of these TEs in each water environment or function of adaptation to deep-water by migrant and non-migrant species. Arsenic level in the Sulu Sea fish was positively correlated with δ15N, indicating biomagnification of arsenic. To our knowledge, this is the first study on relationship between diel vertical migration and TE accumulation in deep-water fish.  相似文献   

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