共查询到19条相似文献，搜索用时 171 毫秒
1.
减薄CdS窗口层是提高CdS/CdTe太阳电池转换效率的有效途径之一,减薄窗口层会对器件造成不利的影响,因此在减薄了的窗口层与前电极之间引入过渡层非常必要.利用反应磁控溅射法在前电极SnO2:F薄膜衬底上制备未掺杂的SnO2薄膜形成过渡层,并将其在N2/O2=4 ∶1,550 ℃环境进行了30 min热处理,利用原子力显微镜、X射线衍射仪、紫外分光光度计对复合薄膜热处理前后的形貌、结构、光学性能进行了表征,同时分析了复 相似文献
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采用实验生态学方法研究了不同规格近江牡蛎的呼吸和排泄生理生态学参数。结果显示,近江牡蛎耗氧率RO随软体干重(W )的增加而减小, 体重对近江牡蛎耗氧率(RO)的影响达极显著水平,RO = 1.8232W-0.7600, (R2= 0.8313 , P <0.01); 近江牡蛎的排氨率(RN)和排磷率(RP)随软体干重的增加而降低,呈负相关关系;而氧氮比O/N和氮磷比N/P在各组间未达显著水平(P >0.05) , RN = 0.0930W-0.6582 (R2 = 0.7444, P <0.01)、RP = 0.0126W-0.8874 (R2 = 0.9224,P <0.01);各组不同规格近(大小)江牡蛎的O/N值较高,而N/P值则随规格增大而呈上升趋势,但差异也不显著(P >0.05)。这些研究结果对牡蛎养殖密度和环境关系分析及牡蛎健康养殖具有重要参考价值。 相似文献
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利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO3结构Cu3N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu3N的弹性常数,Poisson比等,并分析出Cu3N在零温零压下是稳定的. 通过准谐Debye模型计算Cu3N的热力学性质,得到了Cu3N的晶格常数、等压比热容、等容比热 相似文献
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在纯净空气与H2O/ CO2污染空气来流对比试验结果基础上,采用数值计算方法和化学动力学方法,研究了H2O和CO2污染组分对煤油燃料超声速燃烧的影响,获得了试验手段难以得到的燃烧室流场参数和性能数据。完成了相应的煤油燃料超声速燃烧室二维数值计算,其中匹配了进口总温、总压、马赫数、氧气摩尔分数和工作当量油气比。将数值计算结果与相应试验测量值进行了对比分析,并结合燃烧室流场数据、性能参数分析了H2O和CO2污染的动力学影响、以及对燃烧室性能的影响。研究表明:(1)数值计算结果与实验测量值总体上吻合,两种手段均体现了纯净空气来流时不同煤油当量油气比的燃烧室性能,并反映了一致的“污染效应”影响趋势;(2) H2O污染、H2O+ CO2污染的存在降低了煤油燃料超声速燃烧室性能,体现在燃烧诱导压升、燃烧效率、流向冲量增量的下降,而且随着污染组分含量的增加,燃烧室性能下降越加显著。 相似文献
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通过采用Car-Parrinello分子动力学方法对掺杂Ti前后的NaAlH4(001)2×2×1超晶胞表面晶体在333 K(60 ℃)温度条件催化脱氢的空间构型做了理论研究,发现掺杂Ti的合金中AlH4团的其中两个Al—H键长分别从约1.64 (1 =0.1 nm)增大至1.74和1.93 ,而未掺杂合金表面中AlH4团的4个Al—H键长基本不变,这意味着掺杂Ti相对未掺杂的合金更易于放氢.但在模拟温度条件下并未发现Ti-Al成键趋 相似文献
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利用固相反应法制备了Bi0.5Ca0.5Mn1-xCoxO3(0≤x≤0.12)系列多晶样品.研究了Co掺杂对Bi0.5Ca0.5MnO3电荷有序的影响.结果表明,Co掺杂导致电荷有序相逐渐融化、铁磁相互作用的增强;当x≥0.08时,电荷有序转变峰完全消失,但残留的反铁磁电荷有 相似文献
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本研究利用三价钛还原法将标准样品、海水、湖水和雨水中硝酸根转化为N2O测试其氮氧同位素值,并优化实验条件（NO-3浓度、试剂量、反应时间和温度等）。结果表明：4 cm3硝酸根水样（浓度约为20 μmol/dm3）,加入100 mm3TiCl3溶液（浓度为150 g/dm3）,25 ℃反应24 h,NO-3还原为N2O的平均转化率为86.3%（n=5）。5种丰度硝酸根氮氧同位素标样校准曲线斜率分别为0.947和0.617,相关系数R2分别为0.999和0.994;方法检出限的NO-3浓度为2.5 μmol/dm3,其δ15N的标准偏差小于0.7‰(n=5),δ18OVSMOW值的标准偏差小于2.5‰(n=5);20 μmol/dm3硝酸根样品δ15N的标准偏差小于0.5‰（n=5),δ18OVSMOW值的标准偏差小于1.0‰（n=5）。该方法测定3种不同类型水样δ15N的标准偏差分别为0.3‰、0.6‰和0.5‰;δ18OVSMOW的标准偏差分别为2.1‰、2.0‰和1.6‰。三价钛还原法分析水体中硝酸根氮氧同位素操作步骤简单,测试效率高,但氧同位素结果需要系统校正。 相似文献
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This paper calculates the structural parameters, electronic and optical properties of orthorhombic distorted perovskite-type TbMnO3 by first principles using density functional theory within the generalised gradient approximation. The calculated equilibrium lattice constants are in a reasonable agreement with theoretical and experimental data. The energy band structure, density of states and partial density of states of elements are obtained. Band structures show that TbMnO3 is an indirect band gap between the O 2p states and Mn 3d states, and the band gap is of 0.48 eV agreeing with experimental result. Furthermore, the optical properties, including the dielectric function, absorption coefficient, optical reflectivity, refractive index and energy loss spectrum are calculated and analysed, showing that the TbMnO3 is a promising dielectric material. 相似文献
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采用化学沉淀法成功制备了Cu2+/SnO2复合纳米光催化剂,采用XRD、SEM等测试手段对复合纳米光催化剂的粒径、形态等进行表征。在紫外光条件下,分别改变催化剂掺杂比、催化剂煅烧温度、催化剂投加量、柴油初始含量和光照时间等单因素,探究不同条件对Cu2+/SnO2复合纳米光催化剂降解海洋柴油污染物的影响。结果表明,自制复合纳米光催化剂可以有效降解海水中的柴油污染物,在紫外光作用下,于400℃下煅烧Cu/Sn掺杂比为0. 03的Cu2+/SnO2复合纳米光催化剂、投加量为0. 2 g/dm3、柴油初始含量为0. 15 g/dm3、H2O2溶液含量为0. 2 g/dm3、溶液的p H为7、光照时间3 h时效果最好,海水中柴油的去除率最高,达到86. 98%。Cu2+/SnO2复合纳米光催化剂用聚丙烯纳米球负载后可以实际应用于海洋中,便于回收。 相似文献
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The generalised gradient approximation based on density functional theory is used to study the structural and electronic properties of the endohedral fullerene dimer (N2@C60)2. Four N atoms sit at the cage centres in the form of two N_2 molecules. The density of states and Mulliken charge analysis explore that the energy levels from -6 to -10 eV are mainly influenced by the N2 molecules. 相似文献
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Masanobu Shimada Hiromi Oaku Yasushi Mitomi Hiroshi Murakami Akira Mukaida Yasuhisa Nakamura Joji Ishizaka Hiroshi Kawamura Tasuku Tanaka Motoaki Kishino Hajime Fukushima 《Journal of Oceanography》1998,54(5):401-416
We present calibration and validation results of the OCTS’s ocean color version-3 product, which mainly consists of the chlorophyll-a concentration (Chl-a) and the normalized water-leaving radiance (nLw). First, OCTS was calibrated for the inter-detector sensitivity difference, offset, and absolute sensitivity using external
calibration source. It was also vicariously calibrated using in-situ measurements for water (Chl-a andnLw) and atmosphere (optical thickness), which were acquired synchronously with OCTS under cloud-free conditions. Second, the
product was validated using selected 17 in-situ Chl-a and 11 in-situnLw measurements. We confirmed that Chl-a was estimated with an accuracy of 68% for Chl-a less than 2 mg/m3, andnLw from 94% (band 2) to 128% (band 4). Geometric accuracy was improved to 1.3 km. Stripes were significantly reduced by modifying
the detector normalization factor as a function of input radiance. 相似文献
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《Deep Sea Research Part I: Oceanographic Research Papers》2001,48(8):1793-1819
Increased values of trichlorofluoromethane (CFC-11), tritium and stable tritium in the depth range from 2500 to 3500 m at the eastern flank of the Mid-Atlantic Ridge at 48°N (WHP section A2) indicate an influence of newly ventilated water. Water with similar Θ, S and tracer properties is found on the WHP section A1 (55°N) situated north of the Gibbs Fracture Zone in the Iceland Basin. The high tracer concentrations are due to the influence of Iceland Scotland Overflow Water (ISOW). The ISOW-influenced water found in the Iceland Basin partially passes by the Gibbs Fracture Zone (52°N) and flows southward along the topography of the Mid-Atlantic Ridge. A quantitative analysis of the transport from the Iceland Basin to the Westeuropean Basin is carried out based on the assumption that the water with enhanced tracer values is a two-component mixture of recirculating North East Atlantic Deep Water from the eastern part of the Westeuropean Basin and ISOW-influenced water as found on A1 in the Iceland Basin (NEADWIB). The composition of the mixture and the transport time for the NEADWIB are deduced from the temporal evolution of the tracer values. From the distance between the two sections and the area with enhanced tracer values, a transport of NEADWIB from the Iceland Basin to the Westeuropean Basin of 1.63±0.32 Sv1 is calculated for the density range 41.37<σ3<41.475. Transports between 2.4 and 3.5 Sv result if the transport in the former density range is extrapolated to 41.35<σ3<41.52 (corresponding to σΘ>27.8) in different ways. 相似文献
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采用密度泛函理论下的第一性原理平面波赝势方法,研究了掺Ga对纤锌矿ZnO电子态密度和光学性质的影响.从晶体配位场理论分析了掺Ga前后ZnO的成键情况及态密度的变化.计算得到掺Ga后电子浓度为2.42×1021 cm-3,ZnO的载流子浓度提高了104倍.比较分析掺Ga前后ZnO的介电函数、复折射率、吸收光谱和反射光谱可得,ZnO光吸收边向高能端移动,光学带隙增大.在可见光区,ZnO光吸收系数与反射率减小,光透过率显著提高,使ZnO:Ga成为 相似文献
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Marieke A. Eleveld Reinold Pasterkamp Hendrik J. van der Woerd Julie D. Pietrzak 《Estuarine, Coastal and Shelf Science》2008
An algorithm is presented for estimating near-surface SPM concentrations in the turbid Case 2 waters of the southern North Sea. The single band algorithm, named POWERS, was derived by parameterising Gordon's approximation of the radiative transfer model with measurements of Belgian and Dutch inherent optical properties. The algorithm was used to calculate near-surface SPM concentration from 491 SeaWiFS datasets for 2001. It was shown to be a robust algorithm for estimating SPM in the southern North Sea. Regression of annual geometric mean SPM concentration derived from remote sensing (SPMrs), against in situ (SPMis) data from 19 Dutch monitoring stations was highly significant with an r2 of 0.87. Further comparison and statistical testing against independent datasets for 2000 confirmed the consistency of this relationship. Moreover, time series of SPMrs concentrations derived from the POWERS algorithm, were shown to follow the same temporal trends as individual SPMis data recorded during 2001. Composites of annual, winter and summer SPMrs for 2001 highlight the three dominant water masses in the southern North Sea, as well as their winter–fall and spring–summer variability. The results indicate that wind induced wave action and mixing cause high surface SPM signals in winter in regions where the water column becomes well mixed, whereas in summer stratification leads to a lower SPM surface signal. The presented algorithm gives accurate near-surface SPM concentrations and could easily be adapted for other water masses and seas. 相似文献
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This paper investigates the electronic and optical properties for pure and Ce3+-doped CaS crystals by using the first-principles total energy calculations. The results show that CaS:Ce has a direct band gap of 2.16 eV, and the top of the valence band is determined by S 3p states and the bottom of the conduction band is determined by Ce 4f states, respectively. Our results validate that the yellow emission from CaS:Ce is produced by doped cerium and the green emission quenches at 12.5% cerium concentration. The Ce-S bond shows more covalent character than the Ca-S bond. 相似文献
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A. V. Rakitin V. S. Kostsov Yu. M. Timofeev 《Izvestiya Atmospheric and Oceanic Physics》2012,48(9):909-917
The problem of reconstructing the temperature distribution along optical paths from satellite measurements of the Earth’s limb radiation in the CO2 15-μm absorption band with a high spectral resolution is formulated and analyzed on the basis of numerical experiments performed in accordance with the MIPAS experiment. It is shown that the two-dimensional temperature field can be obtained through the processing of radiation measurements on paths with different target heights provided that spectral channels with essentially different optical thicknesses are used. The error in the stratospheric temperature determination varies from 1.8 to 5.6 K and depends on the target height of the optical path and the distance from the target point. The best horizontal resolution is 73–100 km, and it is achieved for optical paths with a target height of about 18–20 km. 相似文献