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近年来对东天山地区有色、贵金属矿床成矿年代学研究表明,成矿作用主要发生于海西期—印支期,成矿作用高峰期为晚石炭世—早二叠世。笔者最近对白山铼钼矿区南西1.2 km处出露的黑云母斜长花岗岩和含矿石英脉作了系统的年代学研究,分别获得岩体SHRIMP锆石微区原位U - Pb和谐年龄为181±3Ma(n=13,MSWD=1.10 ) ,含矿石英脉石英的Rb- Sr等时线年龄为187±7Ma(95 %可信度;MSWD=3.5 2 ) ,4 0 Ar- 39Ar坪年龄为182±1.6 Ma,三种不同定年方法所获得的年龄值基本一致,表明东天山地区存在燕山期成岩成矿事件,矿化作用可能与矿区内出露的黑云母斜长花岗岩岩浆活动有关。 相似文献
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江西新余良山钼矿锆石U-Pb和辉钼矿Re-Os年龄 总被引：1，自引：1，他引：0
良山钼矿是钦杭成矿带近年发现的大中型矿床,在矿化特征分析的基础上,对其进行了成岩成矿年代学研究。采用LAICP-MS锆石U-Pb测年技术,得到矿区内石英闪长斑岩的成岩年龄为168.2±2.3Ma。通过矿床辉钼矿Re-Os同位素分析,获得其等时线年龄为168.9±1.4Ma。指示成岩作用与成矿作用同时发生,含矿热液活动与岩浆活动有密切的关系,岩浆活动可能是形成良山钼矿床的重要因素。良山钼矿床的成矿时间与钦杭成矿带内华南燕山期第一阶段大规模多金属矿化时间(170Ma)吻合。良山钼矿床形成于同一区域成矿背景下,是区域构造岩浆作用的产物,为华南燕山期成矿作用的组成部分。 相似文献
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内蒙古西沙德盖钼矿床锆石U-Pb和辉钼矿Re-Os年龄及其地质意义 总被引：3，自引：0，他引：3
内蒙古西沙德盖钼矿是华北地台北缘成矿带上的一处中型斑岩钼矿床。采用锆石LA-ICP-MS铀-铅同位素测年技术,针对其含矿钾长花岗岩和矿石进行的成岩成矿年代学测定。获得西沙德盖似斑状钾长花岗岩体的成岩年龄为245 Ma±10 Ma;通过对7件辉钼矿样品进行Re-Os同位素分析,获得同位素模式年龄介于223.2 Ma~232.6 Ma,等时线年龄为225.4 Ma±2.6 Ma(MSWD=0.30);两种方法获得的年龄相近(成矿年龄略小于成岩年龄),成岩与成矿作用均发生于中三叠世末,属印支期碰撞后伸展环境下构造?岩浆活动的产物。结合对已有年龄资料的归纳和分析,认为区内在印支期曾发生过重要的岩浆-(金钼)成矿事件,该事件虽可能遭受了燕山期构造-岩浆活动的改造或破坏,但在一定区域和一定程度上仍有记录或保留。 相似文献
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福建霞浦大湾钼铍矿区碱长花岗岩LA-ICP-MS锆石U-Pb测年研究 总被引：2，自引：1，他引：1
福建霞浦大湾钼铍矿床产于火山岩区,但成矿作用可能与岩浆活动和裂隙构造关系密切。为查清矿区隐伏的钠长石化碱长花岗岩与钼铍矿成矿作用之间的关系,本文运用激光剥蚀电感耦合等离子体质谱法(LA-ICP-MS)对碱长花岗岩进行锆石U-Pb测年研究,获得年龄结果为93. 0±0. 6 Ma,与矿区的辉钼矿成矿年龄(92. 2±1. 3 Ma)一致,表明碱长花岗岩与钼铍矿成矿作用时空上具有密切的成因联系,岩浆活动可能为矿区钼铍矿的形成提供了成矿物质和成矿流体。结合区域上的成岩成矿年代学数据,本研究认为福建省燕山期岩浆活动时代与钼铍矿成矿时代都具有从西向东逐渐变新的时空分布规律,钼铍矿的成矿地质构造背景为燕山期华南岩石圈伸展环境。 相似文献
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云南格咱岛弧地苏嘎成矿岩体LA-ICP-MS
锆石U-Pb年龄及地质意义 总被引：1，自引：1，他引：0
利用锆石LA-ICP-MS U-Pb定年法对格咱岛弧中部的地苏嘎成矿岩体中不合矿和含矿2类石英闪长玢岩进行了年代学研究,获得不合矿石英闪长玢岩的形成年龄为203.03Ma±0.54Ma,含矿石英闪长玢岩的年龄分为2组217.25Ma±0.89Ma和208.5Ma±1.0Ma,限定了地苏嘎岩体的岩浆活动时限为217～203Ma,而与成矿作用相关的热液事件主要发生在208Ma.研究表明,地苏嘎成矿岩体的成岩成矿时代均发生在印支晚期,岩浆作用和成矿作用时代基本吻合,但岩浆作用的时限已接近燕山期,这对探讨格咱岛弧构造岩浆演化及成岩成矿作用的研究具有重要意义. 相似文献
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吉林延边天宝山矿集区的叠加成矿——来自同位素年代学证据 总被引：1，自引：1，他引：0
天宝山大型多金属矿集区位于兴蒙造山带东缘,西拉木伦-长春断裂带与敦(化)-密(山)断裂带交汇部位的北东侧,已发现矽卡岩型Pb-Zn-Ag矿化(如立山和选厂后山)、隐爆角砾岩中的Pb-Zn-Ag矿化(如新兴)、沉积变质-热液改造型CuPb-Zn矿化(如东风南山)和热液脉型Mo矿化(如东风北山)等多种矿化类型。为建立该区的成岩成矿年代学格架,采用LAICP-MS单颗粒锆石U-Pb法,对立山成矿闪长岩与东风北山含矿黑云母石英闪长岩开展了同位素测年研究;并对东风北山钼矿床开展了辉钼矿Re-Os法测年。结果表明,立山闪长岩体与东风北山黑云母石英闪长岩体中锆石的加权平均年龄分别为266.2±3.9Ma(MSWD=14)和278.4±1.8Ma(MSWD=2.9),两岩体均属海西晚期岩浆事件的结果;东风北山钼矿床中6件辉钼矿样品的Re-Os模式年龄介于190.3±3.1Ma~194.6±2.8Ma,等时线年龄为192±3.1Ma,表明钼的成矿作用发生于燕山早期。立山铅锌矿化属接触交代型,成矿岩体的年龄基本代表成矿时代,所以立山铅锌矿床形成于海西晚期;东风北山钼矿床为热液脉型,虽然含矿岩体的侵位时代为海西期,但钼矿化发生于燕山早期,成矿与矿区深部或外围的燕山早期侵入体有关。因此,天宝山矿集区至少发生过海西期和燕山期两期大规模岩浆成矿事件。不同期次构造-岩浆-成矿作用的叠加应是该矿床矿化类型复杂、矿种多和规模大的主因。 相似文献
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江西铜坑嶂钼矿和红山铜矿含矿斑岩锆石U-Pb定年及其地质意义 总被引：10，自引：2，他引：8
江西铜坑嶂钼矿和红山铜矿是在武夷山成矿带中最近发现的两个斑岩型矿床。本文利用LA-ICP-MS锆石U-Pb定年方法对铜坑嶂花岗斑岩和红山含矿花岗斑岩分别进行了年代学研究,获得铜坑嶂岩体中花岗斑岩的锆石年龄为138±1Ma,代表斑岩体侵位的年龄;红山矿区含矿斑岩的锆石年龄,分作两期,分别为99Ma和49Ma,两期不同的年龄可能代表了两期热事件。研究表明,铜坑嶂钼矿的成岩成矿时代均发生在白垩纪,其岩浆作用与成矿作用基本吻合。综合前人资料,认为铜坑嶂钼矿区的斑岩和红山铜矿区的斑岩可能分别形成于大陆弧后伸展带和岩石圈伸展环境。 相似文献
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长兴钾长混合花岗岩体与何宝山金矿床的成矿作用关系密切。何宝山金矿床的成矿作用表现出多期次、多阶段的特点,加里东晚期长兴岩体的侵入活动促进了金矿床成矿物质早期的迁移和富集,印支晚期—燕山早期的构造-岩浆活动叠加成矿。文中对区内加里东期主要侵入岩体进行了锆石LA-ICP-MS U-Pb同位素定年研究,得出长兴岩体的成岩年龄为(437.1±1.3)Ma,黑云母石英闪长岩成岩年龄为(436.6±1.1)Ma,黑云母花岗闪长岩脉成岩年龄为(427.1±1.4)Ma,从而确定金矿床成矿期上限,为进一步成矿作用研究提供科学依据。 相似文献
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河南省嵩县大石门沟钼矿床是近年来在豫西地区新发现的大型钼矿床,采用辉钼矿Re-Os精细测年技术,对与成矿相关的5个含辉钼矿角砾岩样品、3个含辉钼矿的破碎石英样品进行同位素年代学测定,获得了模式年龄:模式年龄变化范围(156.1±3.4)~(228.0±4.1)Ma,模式年龄明显分为2组:一组为(208.4±3.1)~(228.0+4.1)Ma,平均年龄(218.07±4.3)Ma,加权平均年龄(217.1±8.5)Ma,另一组为(156.1±3.4)~(160.9±3.3)Ma,平均年龄(158.6±3.35)Ma,加权平均年龄(158.6±4.7)Ma。结果表明,大石门沟钼矿成矿时代为印支期、燕山晚期。2个期次的成矿作用又与该区隐爆角砾岩的两次隐爆有关。印支期的成岩成矿发生在东秦岭钼矿带碰撞造山后的构造体制从挤压到伸展的转折期,上地幔、下地壳的部分熔融产物上涌在地壳薄弱的NW向与NE向构造交叉部位隐爆产生。燕山晚期成矿作用继承、改造和叠加印支期成矿作用,两者一起构成东秦岭钼矿带中生代成矿作用大爆发的完整旋回。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
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岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献