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1.
苏北盆地溱潼凹陷油气运聚模式 总被引：2，自引：0，他引：2
通过对苏北盆地溱潼凹陷不同构造带部分具代表性油藏原油的饱和烃、芳烃生物标志物和吡咯类含氮化合物分布特征的分析,结合油区构造研究和油源对比成果,讨论了研究区油气的运移方向与运聚模式。结果表明,研究区不同构造带原油中吡咯类含氮化合物分馏效应存在差别,处于断阶带南侧的成熟原油运移效应明显,来源于其西北侧的俞垛次凹始新统阜宁组二段烃源岩;断阶带北侧的原油运移分馏效应较差,推测其主要来源于北侧的储家楼次凹阜宁组二段烃源岩,以短距离侧向运移为主;内斜坡带原油主要来自于储家楼深凹阜宁组二段烃源岩,沿其构造带上倾方向自西南到东北方向,含氮化合物分馏效应明显;坡垒带与外斜坡带阜宁组三段原油成熟度偏低,吡咯类含氮化合物浓度较高,原油自东北向西南方向以短距离运移为主,主要来自于深凹的低熟烃源岩。不同构造带的油气成藏模式也不一致,断阶带为阶梯状断块油气聚集模式,内斜坡带与坡垒带主要分布受断层控制的断块—岩性油藏,外斜坡带为反向正断层垒块控油模式。 相似文献
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基于圈闭形成时间法推测潜江凹陷潜江组油气藏形成的最早时间为上始新统潜二段沉积初期,利用烃源岩生排烃史法分析潜江凹陷潜江组油气成藏的最早时间为晚始新世,应用流体包裹体资料揭示潜江凹陷潜江组共经历了晚始新世-早渐新世(37~32 Ma)、早渐新世-中中新世(32~14 Ma)及中上新世-现今(3~0 Ma)共3期油气充注过程,并以第2期早渐新世-中中新世油气充注最为重要,且自蚌湖向斜带和潜北陡坡带至周矶向斜带再至斜坡带,油气充注时间有逐渐变晚的趋势。由此得出,综合应用流体包裹体法、圈闭形成时间法、烃源岩生排烃史法等多种方法可较为有效地确定具有复杂构造-沉积背景与演化历史的含油气盆地(凹陷)的油气成藏期次与时间。 相似文献
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根据原油和烃源岩中三芳甾烷及甲基三芳甾烷组成特征,结合稳定碳同位素值,分析了苏北盆地溱潼凹陷红庄油田古近系凝析油的油源特征。结果表明,红庄油田凝析油主要来源于溱潼凹陷深部烃源岩,而并非来自于古近系烃源岩。应用储层岩石流体包裹体测试技术,根据油气包裹体特征及盐水包裹体均一化温度,结合地层埋藏史,分析了红庄油田S245井戴一段砂岩储层流体成藏期次。研究表明,与烃类包裹体共生的盐水包裹体均一化温度分布范围主要介于80～110℃,油气充注时期为新近纪中新世晚期,开始充注的时间大约为6 Ma。 相似文献
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江苏高邮凹陷永安气藏烃类流体包裹体特征和天然气成藏条件 总被引：4，自引：1，他引：4
利用先进的流体包裹体测试技术，对永安油气包裹体进行了剖析。油气地球化学特征表明，母源输入中以高等植物蜡贡献为主，沉积水体环境介质以缺氧还原性占优势，油气注入储层前处于成熟演化状态，多因素生物标志物参数组合气源对比反映出永安天然气与阜宁组四段源岩具很好的相关性。成藏条件分析表明，永安气藏气源岩生烃早，与储集接触好；油气注入从距今45Ma开始几乎持续至今，充注时间长；一些鼻状构造或断鼻、断块构造圈闭的形成略早于或同步于油气的注入，利于油气聚集；处在沉凹带的气藏，上部有20m厚的泥质岩，在断层对盘为阜宁组四段泥岩，而且后期辉绿岩的侵入也成为其有效的盖层，水动力条件以水体交替缓慢带和停滞带为主，具有良好的封盖条件，油气成藏为典型的下生上储模式。 相似文献
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溱潼凹陷断阶带断裂系统发育,控制油气聚集的断层主要有F1、Ⅲ、F2、F3及其相应的分支断层,将断阶带分为北部的草舍扭动断裂带与南部的祝庄扭动断裂带。在断层封闭性定量评价与封闭史研究的基础上,结合研究区生排烃史、油源分布特征、油气成藏期以及含氮化合物示踪分析研究表明,断阶带Ⅲ、F2、F3断层在不同的研究区封闭性存在明显的差异,祝庄断阶带Ⅲ号断层垂向封闭性较好,不能成为油气运移的通道,使得角墩子地区的原油主要来源于阜四段源岩,没有阜二段与泰州组源岩的贡献;而F3断层活动期短,侧向封闭性差,也不为油气的运移通道;相比之下,F2断层活动期长,断层垂向封闭性差,而侧向封闭性好,为祝庄地区主要的运移通道,与油气成藏期具有较好的匹配关系,流体包裹体分布与含氮化合物示踪分析也证明了这一点。研究还表明草舍断阶带F2断层活动期短,垂向封闭性好,侧向封闭性弱,不是油气运移的通道;相比之下,F3断层活动期长,垂向封闭性较弱,可以作为油气运移的主要通道,后期主要通过砂体和不整合面运移聚集成藏,与生排烃史、油气成藏期和含氮化合物示踪也具有较好的匹配关系。 相似文献
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珠江口盆地文昌A凹陷深部的古近系珠海组油气资源丰富,但不同区带油气成藏分布复杂,油气成藏时期的关键证据——包裹体的研究相对薄弱.为了准确厘定文昌A凹陷珠海组烃类充注时期,以研究区珠海组砂岩储层中的烃包裹体及其伴生盐水包裹体为研究对象,利用荧光光谱测定、激光拉曼光谱分析、显微测温等实验测试,结合包裹体捕获压力计算、埋藏史、热演化史、生烃演化史等分析,开展了凹陷中心及近珠三南断裂带油气成藏期次与差异性研究.结果表明,储层砂岩中烃包裹体及其伴生盐水包裹体成分主要为CH4、C2H6、CO2和H2O,同期盐水包裹体均一温度集中分布于95～180℃.断裂带与凹陷中心均存在3期烃类充注,但油气充注时间有差别.其中,凹陷中心第1期发生在21.9～13.9 Ma,第2期油充注发生在12.0～8.9 Ma,第3期油气充注时间7.8～4.8 Ma;断裂带第1期油充注发生在约21.7～10.2 Ma,第2期油充注发生在约9.1～4.9 Ma,第3期油气充注时间约为3.9～1.5 Ma.差异性构造沉降导致的烃源岩埋深的差异,以及多期断裂活动强度及其时空配置关系的不同,是造成凹陷中心及断裂带烃源岩生烃高峰的差异及... 相似文献
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流体包裹体多参数综合划分东营凹陷沙三段油气充注期次及充注时期确定 总被引：5，自引：1，他引：4
对采自东营凹陷沙河街组第三段(1沙三段,E§3)223块流体包裹体薄片进行了有机包裹体产状观察、显微荧光光谱分析和显微测温等流体包裹体系统分析.综合分析这些参数表明沙三段发育3期油气充注:第一期发生在成岩早期,主要为发橙黄色荧光的低成熟油气充注;第二期发生在成岩中期,主要为发淡黄色荧光的成熟油气充注;第三期发生在成岩作用晚期,主要为发蓝白色荧光的高成熟油气充注.在此基础上,运用埋藏史-均-温度投影法确定了这3期油气的充注时期:第一期为36～24 Ma;第二期为13.8～8.0 Ma;第三期为8.0～0 Ma. 相似文献
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利用储层流体包裹体和原油地球化学资料,结合钻井地质和测试分析,对泌阳凹陷古城油田的油气来源、成藏期次、
成藏过程和成藏模式的研究结果表明,东南深凹区核三下、核三上亚段烃源岩沿着古城油田北西构造抬升方向顺层两期供油,
其中廖庄组沉积末期是油气大规模充注成藏时期。核一段沉积末期,泌阳凹陷东南部深凹区核三下亚段烃源岩达到生排烃
高峰,油气从深凹（高势区）沿古城三角洲砂体进入古城鼻状构造（低势区）,形成一定规模的古油藏;廖庄组末期构造抬
升和断层活动,古油藏遭受一定破坏,同时核三上亚段烃源岩达到生排烃高峰,大规模成熟油气沿古城三角洲砂体横穿断
层形成断阶式向上聚敛成藏。 相似文献
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采取伊通盆地鹿乡凹陷星27井、星10井、星3井等3口井双阳组岩芯砂岩样品,对与有机包裹体相伴生的盐水包裹体均一温度进行测试研究,并且对双阳组储层油气成藏期次进行了划分。研究结果表明:伊通盆地鹿乡断陷双阳组存在5~6期热液活动,可划分出4幕油气充注:第一幕次油气充注发生在永吉组沉积末期--万昌组沉积早期,时间为37.8 Ma±;第二幕次油气充注发生在万昌组沉积中期,时间为33.8~30.5 Ma±;第三幕次油气充注发生在齐家组沉积早期,时间为24.9 Ma±;第四幕油气充注发生在齐家组沉积末期--岔路河组沉积早期,时间为19.8~16.8 Ma±。 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
19.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献