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1.
对出露于南秦岭陕西省凤县境内的花红树坪花岗闪长岩体进行LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究,获得岩体表面年龄为214.3±2.7Ma(MSWD=2.6),表明其形成时代为晚三叠世。岩体的SiO_2=61.45%~65.10%,TiO_2=0.52%~0.63%;Al_2O_3=14.97%~15.74%,Mg O=2.33%~3.02%,Mg#=51.31~53.61,高Sr(485×10-6~563×10-6)和Sr/Y(28.2~30.4),低Y(17.0×10-6~19.1×10-6)和Yb(1.46×10-6~1.83×10-6),微弱负Eu异常(δEu=0.83~0.99),具有明显高镁埃达克岩地球化学特征。结合区域地质背景,认为花红树坪岩体是后碰撞构造环境下加厚下地壳拆沉熔融与先存地幔岩浆交代混染作用下的产物,其可能与凤太矿集区多金属矿成矿关系密切。 相似文献
2.
柴达木盆地北缘西端埃达克质花岗岩的发现及地质意义 总被引：1，自引：0，他引：1
盐场北山英云闪长岩位于柴达木盆地北缘西端青海冷湖地区。岩体Si2O56%(62.86%~64.83%),A12O315%,MgO3%(含量为1.73%~1.96%),Mg#=33.4~37.0,小于50。Sr400×10-6(平均为409×10-6),Y18×10-6(Y=3.09×10-6~6.6×10-6),Yb1.9×10-6(Yb=0.4×10-6~0.58×10-6),具有埃达克岩地球化学特征;Na2O/K2O=2.39~2.73,富Na贫K,Eu、Sr正异常(δEu=1.22~1.44),属O型埃达克岩。岩体富集大离子亲石元素(K、Rb、Sr、Ba),亏损高场强元素(Nb、Ta、P),具火山弧型花岗岩特征。LA-ICP-MS锆石U-Pb测年结果表明,岩体形成于263±2 Ma。结合区域地质背景和岩石地球化学特征,认为柴达木盆地北缘西端埃达克质花岗岩可能产于与俯冲有关的活动大陆边缘火山弧环境,是俯冲板片直接熔融的产物。进而揭示中二叠世末柴达木盆地北缘地区处于洋陆俯冲的构造演化阶段。 相似文献
3.
《矿物岩石》2015,(4)
都伦河东岩体位于西准噶尔达尔布特断裂西南端,岩性主要为石英闪长岩和花岗闪长岩,岩体内接触带有较强硅化、黄铁矿化等矿化特征显示。岩石富w(Na2O)(3.63%~4.70%),贫w(K2O)(0.56%~2.91%),Na2O/K2O比值为1.33~6.75,w(SiO2)多56%(54.57%~69.67%),w(A12O3)多15%(14.53%~18.03%),w(MgO)多3%,个别高于6%,Mg#值51.62~66.60,低Y18×10~(-6)(仅1样19.88×10~(-6))和Yb1.9×10~(-6)(仅1样2.05×10~(-6)),Sr均400×10~(-6)(466×10~(-6)~1066×10~(-6)),Sr/Y均20(23.43~83.74);富集LREE而亏损HREE,Eu多具正异常,少数弱负异常(δEu=0.81~1.24),大离子亲石元素Rb,Ba,Sr和Th相对富集,高场强元素Nb,Ta,Ti,Zr相对亏损,因而显示典型的埃达克质岩属性,近同于包古图一带含矿小斑岩体地球化学特征,显示良好的与埃达克岩相关的找矿信息,为区域晚古生代埃达克质岩浆活动和Cu,Au成矿作用研究提供新佐证。 相似文献
4.
对辽宁兴城尖山火山机构的岩性--岩相学特征进行了分析,并对角闪安山岩进行了岩石地球化学研究。结果表明角闪安山岩SiO_2=58.42%~60.42%,Al_2O_3=16.17%~17.5%,MgO=1.39%~3.08%,Mg~#=31~50,Sr=(387~1 325)×10~(-6),Yb=(1.15~1.57)×10~(-6),Y=(12.1~16.8)×10~(-6)。岩石富集轻稀土元素及大离子亲石元素,亏损高场强元素,高Sr和Sr/Y比值,低Y和Yb,显示出埃达克岩的地球化学特征,但其Mg~#较低,表明该类火山岩可能是加厚的基性下地壳部分熔融的产物,可能与早白垩世太平洋板块的俯冲构造背景有关。 相似文献
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鄂东南地区龙角山—付家山斑岩体成因及其对成矿作用的指示 总被引：1，自引：0，他引：1
龙角山铜钨矿床是鄂东南地区典型的层控式矽卡岩型矿床。本文利用LA-ICP-MS锆石U-Pb法及辉钼矿Re-Os法对该矿床进行了详细的年代学研究。结果表明,矿区内的花岗闪长斑岩形成于144±1Ma,成矿作用发生于144.7±2.9Ma,成岩成矿作用近于同时发生,均为早白垩世。这意味着成矿作用与花岗闪长斑岩的演化存在密切联系。龙角山—付家山花岗闪长斑岩为高钾钙碱性系列,具有高Al2O3(14.99%~16.16%)、Sr(751×10-6~1382×10-6)含量和Sr/Y(65~99)、La/Yb(40~48)比值,以及低Y(12×10-6~15×10-6)、Yb(0.93×10-6~1.23×10-6)含量,与典型埃达克质岩的地球化学特征基本一致。全岩(87Sr/86Sr)i值为0.70603,εNd(t)值为-5.1,锆石εHf(t)值介于-0.5~-4.8之间。元素地球化学、全岩Sr-Nd同位素及锆石Hf同位素特征一致表明龙角山—付家山花岗闪长斑岩主要来源于富集岩石圈地幔的部分熔融作用,在成岩过程中可能伴随着镁铁质矿物的分离结晶作用。此外,与铜山口成矿斑岩体相比,龙角山—付家山花岗闪长斑岩具有较低的氧逸度,这很可能是导致两斑岩体在矿化类型上(前者以铜钼矿化为主,后者以铜钨矿化为主)存在差异的主要原因。 相似文献
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大战场花岗岩岩体位于贺兰山中南段,属钙碱性系列,具岛弧花岗岩特征.岩石地球化学分析结果表明,这些岩石富Na2O、贫K2O、Na2O/K2O比值为0.73~1.41,SiO2含量大于56%,Al2O3含量为15.32%~17.23%,多数大于15%,MgO含量均小于3%,低Y和Yb,Sr的含量高,Sr/Y 25.98~97.15,大于20~40.稀土元素含量较低,为47.58×10-6~70.29×10-6,轻重稀土分馏不明显,呈弱的Eu正异常,大离子亲石元素(Rb,Ba,Th,Sr)相对富集,高场强元素(Nb,Ta,Hf)相对亏损.在岩石地球化学特征上,大战场花岗岩类似于C型埃达克质岩石,岩浆产生于增厚地壳物质的部分熔融,表明该花岗岩类可能属埃达克质岩.该套埃达克岩的厘定,对研究贺兰山构造带中生代构造演化、地球动力学特征具重要意义. 相似文献
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西藏冈底斯带广泛分布晚白垩世埃达克质岩,其岩石成因一直存在争论,并且对于成矿潜力的研究也十分有限.为此对谢通门县斯弄多-加多捕地区具铜矿化的黑云母二长花岗岩开展了锆石U-Pb定年、全岩地球化学以及锆石微量元素地球化学特征的研究,以探明岩石成因及成矿潜力.结果表明黑云母二长花岗岩侵位时间为晚白垩世（83.1±1.6 Ma）.岩石具有相对高的SiO2含量（60.21%~62.54%）、MgO（2.19%~3.02%）、Mg#（41.25~50.73）值.较低含量的Y（15.9×10-6~17.8×10-6）、Yb（1.46×10-6~1.73×10-6）及较高的Sr/Y（35.0~47.6）、La/Yb（29.6~38.6）比值,表现出高硅型埃达克质岩亲和性.岩石属高钾钙碱性、准铝质系列（A/CNK值为0.84~0.92）,富集LREE、大离子亲石元素（LILE）、亏损高场强元素（HFSE）,如Nb、Ta等.锆石微量元素具较高的V/Sc、Ce/Ce*、10 000×（Eu/Eu*）和Eu/Eu*比值.通过对比冈底斯带晚白垩世典型的埃达克岩,认为斯弄多黑云母二长花岗岩是新特提斯洋俯冲洋壳部分熔融的产物,岩浆氧逸度较高,显示出斯弄多黑云母二长花岗岩具有良好的Cu-Au成矿潜力. 相似文献
8.
中亚造山带东段南缘早志留世岩体锆石U-Pb定年、地球化学特征及其地质意义 总被引：6，自引：4，他引：2
本文报道了分布于中亚造山带南缘苏尼特右旗太古生庙地区太古生庙岩体和库伦哈达岩体的岩相学、地球化学和年代学特征,以讨论该岩体的形成时代、岩石成因及其构造环境。锆石U-Pb定年结果显示,太古生庙英云闪长岩结晶年龄为442.6±2.4Ma,库伦哈达石英闪长岩结晶年龄为434.2±2.2Ma,说明太古生庙地区早古生代存在岩浆活动。其中太古生庙岩体地球化学特征类似于典型的埃达克岩,其Si O2含量56%(70.02%~70.51%),Al2O3含量≥15%(15.99%~16.37%),Mg O3%(0.56%~0.83%),Na2O3%(4.33%~4.66%),K2O/Na2O比值0.5(0.3~0.4);在微量元素特征方面,Sr400×10-6(681×10-6~783×10-6),Yb1.9×10-6(0.6×10-6~0.9×10-6),Y18×10-6(5.4×10-6~9.3×10-6),无明显的Eu异常。库伦哈达岩体与太古生庙岩体相比,Si O2含量较低(57.92%~66.78%),Al2O3为相当(14.91%~18.26%),MgO含量为1.17%~2.31%,Na2O含量为3.29%~4.36%,K2O含量为1.43%~3.09%;在微量元素判别图解中,库伦哈达岩体的岩石样品投图位于埃达克岩和典型的岛弧型火山岩的叠加区域,而太古生庙岩体样品全部落入埃达克岩区域内,太古生庙岩体可能是洋壳部分熔融的产物,而库伦哈达岩体可能是早期俯冲的洋壳部分熔融的产物混染了部分熔融的地幔楔之后形成了这种具有正常岛弧岩浆特征的岩石,其形成的环境为岛弧环境。 相似文献
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阿扎朗岩体位于冈底斯岩浆弧中东部的松多地区.岩体的锆石U-Pb定年和全岩地球化学分析结果表明,阿扎朗岩体岩性为石英二长斑岩,形成时代为中新世（17.9±0.2 Ma）,地球化学上表现高Sr（1 052×10-6~1 150×10-6）、低Y（8.51×10-6~9.04×10-6）和Yb（0.85×10-6~0.94×10-6）,高的Sr/Y（118~128）和La/Yb（30.9~40.8）比值,无明显的Eu异常,同时具有较高的K2O（3.17%~3.84%）含量和较低的Cr（6.46×10-6~7.78×10-6）和Ni（5.41×10-6~7.45×10-6）含量,较高的Rb/Sr比值,较高的Mg#值（43.8~49.8）,大离子亲石元素的含量,如Rb、Ba、Th和U明显比LREE高.这些地球化学特征表明其岩石成因可能为增厚的下地壳部分熔融形成,形成于印度－欧亚大陆碰撞造山的后碰撞构造背景下,可能有一定的幔源物质参与.该研究为揭示冈底斯成矿带中新世埃达克岩的成因及成矿地质背景提供重要的制约. 相似文献
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敖仑花斑岩铜钼矿床位于大兴安岭南段西拉木伦河断裂北侧,矿床赋存于花岗闪长斑岩岩体及长英质角岩中.矿区脉岩发育,多形成于花岗闪长斑岩体及成矿之后.岩石地球化学表明,赋矿斑岩具有高Si、富Al、Na,低Ca、Mg和Fe2OT3,A/CNK值小于1.1等特征,为偏钠质的高钾钙碱性Ⅰ型花岗岩;稀土元素具微弱负Eu异常,轻重稀土分异比较明显,LREE/HREE值在11.43～18.33,LaN/YbN值在14.64～37.55;岩石具高Sr(＞400×10-6),低Y(≤18×10-6)和Yb(≤1.9×10-6),显示出典型的埃达克岩特征.矿区后期的脉岩中,流纹斑岩与赋矿斑岩的地球化学特征差别较大,具有低Sr,高Y和Yb,明显的负Eu异常等特征,反映其构造背景为张性环境;英安斑岩具有弱的负Eu异常,轻重稀土分异度高于流纹斑岩,但略低于花岗闪长斑岩.通过分析矿区花岗岩岩类的地球化学特征及形成构造环境,认为敖仑花铜钼矿床具有有利的成矿条件和很大的找矿潜力. 相似文献
11.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
18.
岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献