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1.
克兰河岩体中含白云母的强过铝花岗岩锆石的LA-ICP-MS U-Pb年龄为(387.4±1.3)Ma(MSWD=0.72),属中泥盆世岩浆活动产物。岩石具高硅(73.55%~74.14%)、高碱(7.99%~8.31%)、富Al_2O_3(14.48%~14.56%)、富P_2O_5(0.32%~0.39%)和低(FeO+MgO)(0.45%~0.59%)、低CaO/Na_2O值(均值小于0.3),高A/NCK值(1.18~1.21),高Al_2O_3/Ti2O(120.6~181),属高压强过铝质S型花岗岩;岩体不同程度富集Rb,Th,U,P,K,贫Ba,Sr,Zr,Ti,高场强元素Nb,Ta无明显异常。岩石富集轻稀土元素,并具Eu(δEu=0.42~0.49)的显著负异常。结合阿尔泰区域地质背景综合分析,推测该岩体可能形成于陆-陆碰撞造山过程中局部陆壳加厚的高压环境,是陆壳泥质岩石部分熔融的产物,可能揭示了由俯冲增生到碰撞的过程。  相似文献   

2.
西藏改则扎嘎尔勒尖A型花岗岩体侵位于晚石炭世拉嘎组碎屑岩夹碳酸盐岩地层中,呈独立岩株产出,内部可见较多闪长质包体,岩性以正长花岗岩为主,少量二长花岗岩。岩体LA-ICP-MS锆石U-Pb年龄为(53.60±0.38)Ma,时代为早始新世。岩石具富SiO_2(72.40%~77.49%)、K2O(4.91%~5.62%),贫Al2O3(11.88%~15.58%)、Mg O(0.076%~0.384%)、TiO_2(0.088%~0.237%)、P_2O_5(0.019%~0.071%),高Al_2O_3、Na_2O和低TiO_2、Mg O、Mn O特征,属准铝质-弱过铝质碱性系列。稀土元素总量为106.39×10~(-6)~161.45×10~(-6),(La/Yb)_N为6.91~18.12,δEu=0.15~0.89,在球粒陨石标准化稀土元素分布模式上表现为右倾海鸥型。在原始地幔标准化蛛网图上,富集Rb,Th,Zr,Hf和Y等高场强元素,亏损Nb,Ta,Sr,Ba,Ti和P。岩石地球化学特征表明,扎嘎尔勒尖岩体为A1型花岗岩。初步认为,扎嘎尔勒尖A型花岗岩产出于碰撞高峰之后的短暂应力松驰阶段,形成于该阶段的造山带岩石圈地幔刚刚发生拆离之时,是新特提斯洋板片发生断离、拆沉,软流圈物质透过板片断离窗上涌,诱发地幔楔、上覆加厚的镁铁质下地壳熔融、侵位而形成的。  相似文献   

3.
内蒙古西乌旗石匠山A型花岗岩位于贺根山缝合带内,侵位于早石炭世迪彦庙-白音布拉格蛇绿岩带和下二叠统寿山沟组与大石寨组中,岩性为二长花岗岩。石匠山A型花岗岩富硅(SiO_2=74.18%~77.16%)、富钾(K_2O=4.31%~5.07%)、富碱(Na_2O+K_2O=8.44%~9.16%),贫Al_2O_3、CaO、MgO、TiO_2、P_2O_5、Sr、Ba、Eu、Ti和P,具有较高的Ga/Al(3.98~6.09)、(Na_2O+K2O)/CaO、K_2O/MgO、TFeO/MgO、Rb/Nb、Y/Nb、Sc/Nb值,稀土元素配分曲线为典型的海鸥式分布,δEu为0.01~0.19,负Eu异常显著,明显不同于I、S和M型花岗岩,为典型的铝质A型花岗岩。在地球化学分类判别图解上,石匠山A型花岗岩显示A_2型后造山铝质花岗岩特征,反映其形成于后造山伸展环境。LA-ICP-MS锆石U-Pb测年结果表明,该花岗岩的侵位年龄为159.8±1.3Ma、143.1±1.3Ma、136.20±0.69Ma,即形成时代为晚侏罗世-早白垩世,揭示贺根山缝合带在晚侏罗世-早白垩世为后造山伸展阶段。  相似文献   

4.
内蒙古镶黄旗乌兰哈达岩体位于华北克拉通北缘中段,岩性以中细—中粗粒碱长花岗岩为主。LA-ICP-MS锆石U-Pb定年结果表明,该花岗岩的侵位年龄为265.1Ma±1.5Ma(MSWD=1.5),形成于中二叠世。该花岗岩富硅(SiO2为73.63%~75.47%),富碱(Na2O+K2O介于9.25%~9.49%)之间。在SiO2-K2O图中,样品多数落入高钾钙碱性系列。A/CNK值在1.00~1.03之间,属弱过铝质花岗岩。稀土元素含量高(∑REE=94×10-6~383×10-6),轻重稀土元素分异明显,(La/Yb)N=6.59~13.20,具有明显的负Eu异常(δEu=0.22~0.38)。相对亏损Ba、Sr、Nb、P、Ti元素,而高场强元素含量高(Zr+Nb+Ce+Y>350×10-6),且具有较高的10000×Ga/Al比值(2.36~2.79)。地球化学特征暗示了乌兰哈达碱长花岗岩具有典型的A型花岗岩特征。相对低的Nb的含量进一步暗示了该岩体具有A2型属性。构造环境R1-R2判别图和构造环境(Y+Nb)-Rb判别图解显示,该岩体可能形成于后碰撞的拉张环境。结合乌兰哈达岩体的大地构造位置、构造环境及侵位时代,初步推断研究区内华北板块北缘与西伯利亚板块南缘碰撞缝合时代应早于265.1Ma。  相似文献   

5.
本文对江西彭山锡多金属矿集区隐伏花岗岩体进行了详细的锆石U-Pb年代学、Hf同位素组成和岩石地球化学研究。SHRIMP和LA-ICP-MS锆石U-Pb定年表明,该岩体年龄为128~129Ma,属燕山晚期岩浆活动的产物。详细的地球化学分析显示,彭山隐伏花岗岩体具有高硅(SiO2=75.42%~76.46%)、富碱(Na2O+K2O=7.93%~8.35%,K2O/Na2O=1.32~1.61)的特征,极度贫Mg(普遍MgO=0~0.07%),贫Ca(CaO=0.37%~0.69%),弱过铝质(A/CNK=1.04~1.11),富集Rb、Th、U等大离子亲石元素及Hf、Nb等高场强元素,强烈亏损Sr、Ba、Eu、P、Ti。稀土总量偏低(∑REE=41.18×10-6~85.06×10-6),强烈的Eu负异常(Eu/Eu*=0.05~0.11)。104×Ga/Al比值变化于2.75~4.04,平均值为3.19。这些特征均不同于典型的A型和S型花岗岩。岩石学和地球化学特征指示该岩体可能是一个高分异的I型花岗岩。该花岗岩中锆石εHf(t)值偏高,主要集中在-0.6~-4.5,显示在成岩过程中有地幔组分的参与,属壳幔混源花岗岩,推测该岩体的形成可能与燕山晚期华南岩石圈伸展拉张环境有关。  相似文献   

6.
对北秦岭宝鸡地区鸡冠崖花岗岩进行了LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。结果显示,锆石206Pb/238Pb加权平均年龄为(435±2)Ma(MSWD=0.13,n=22),限定该岩体的形成时代为早志留世。鸡冠崖花岗岩具有高硅(w(SiO2)=72.77%~77.71%)、富钾(w(K2O)=3.51%~6.32%)、低铁(w(Fe2OT3)=0.71%~1.30%,Fe2OT3/MgO=2.71~7.29)、低镁(w(MgO)=0.14%~0.31%)、低磷(w(P2O5)=0.05%~0.10%)的特征,A/CNK=0.94~1.10,AR=2.95~4.10,属准铝质至弱过铝质、钙碱性系列。鸡冠崖花岗岩稀土元素质量分数较低(32×10-6~102×10-6),铕异常明显(δEu=0.22~13.83),富集Rb、U、Th、Nd、Zr、Hf等微量元素,贫Ba、Nb、P、Ti等元素,分异程度较高(DI=89~93),整体表现出高分异I型花岗岩特征。结合区域资料,认为鸡冠崖花岗岩形成于同碰撞构造环境,为下地壳物质部分熔融成因。  相似文献   

7.
西准阿克巴斯陶铝质A型花岗岩厘定及意义   总被引:3,自引:0,他引:3  
岩石学和元素地球化学研究表明,阿克巴斯陶岩体属铝质A型花岗岩.该岩体以富硅(SiO2=74.51%~78.39%)、富碱(Na2O+K2O=7.87%~8.53%)和铝(Al2O3=11.8%~13.33%)、贫镁(MgO=0.15%~0.46%)、贫钙(CaO=0.45%~1.02%)和磷(P2O5=0.01%~0.06%),氧化指数变化较大(W=0.22~0.57),高FeOt/MgO比值(2.76~9.24,平均5.83)为特征.其K2ONa2O,NK/A=0.60~0.68,A/NCK=1.00~1.06,均大于1,属弱过铝质岩石.微量和稀土元素组成上,岩石富高场强元素(Zr和Hf等),亏损Ba,Nb,Ta,Y等元素.Zr+Nb+Ce+Y元素组合平均值(368.3×10-6)大于A型花岗岩下限值(350×10-6).在FeOt/MgO-Zr+Nb+Ce+Y和Rb/Ba-Zr+Ce+Y两类地球化学判别图解上均落入A型花岗岩区.δEu为0.038~0.130,铕强烈亏损,稀土分布曲线为"V"字型.上述特征表明,阿克巴斯陶岩体与国内外铝质A型花岗岩十分相似.在Nb-Y-Ce、AR-R1和R1-R2构造环境判别图上,显示出后造山花岗岩特征.阿克巴斯陶铝质A型花岗岩的厘定,对探讨西准噶尔地区构造演化问题具有重要意义.  相似文献   

8.
哈密头苏泉哈尔欣巴A型花岗岩厘定   总被引:1,自引:0,他引:1  
初步研究表明新疆哈密头苏泉地区哈尔欣巴花岗岩为A型花岗岩.该岩体富硅(SiO2=71.87%~76.80%)和碱(K2O+N2O=7.39%~8.94%),贫铁、锰、镁(FeOt 0.67%~2.04%;MnO 0.03%~0.06%;MgO 0.10%~0.61%),具较高FeOt/MgO比值,A/NKC=0.78~1.02,属准铝质花岗岩石.在微量元素和稀土元素组成上,岩石富Zr,Rb,Ce等不相容元素,亏损Ni,Co,Cr等元素.10000×Ga/Al为3.12~4.1,大于A型花岗岩下限值(2.6).在Zr,Ce,Nb,Y与10000×Ga/Al,及(Nb+Zr+Ce+Y)/(FeOt/MgO)、SiO2/( FeOt/MgO)图解中大多数点都落在A型花岗岩区域.在A1-A2构造环境判别图上显示后造山花岗岩特征.对头苏泉地区哈尔欣巴A型花岗岩的厘定,为研究该区地壳物质组成及构造演化具重要意义.  相似文献   

9.
前人对扬子地块西缘新元古代I型和S型花岗岩开展了深入的研究工作,但有关A型花岗岩的研究则鲜有报道,其岩石成因及大地构造意义仍存较大争议。文章选择最新发现的泸沽A型花岗岩体为研究对象,开展系统的LA-ICP-MS锆石U-Pb年代学、岩石学和地球化学研究,探讨其成因机制和地质意义。泸沽花岗岩由钾长花岗岩和二长花岗岩组成,LA-ICP-MS锆石U-Pb年代学分析显示其结晶年龄分别为(806±5)Ma和(815±5)Ma,属新元古代岩浆活动产物。岩石具有高硅(SiO_2=71.2%~76.1%)、高碱(K_2O+Na_2O=6.73%~8.95%)、高K_2O/Na_2O比值(1.89~3.60)和强过铝质(A/CNK=1.07~1.49)的特征。[FeO~T/(FeO~T+Mg O)]-SiO_2和[(Na_2O+K_2O)-CaO]-SiO_2图解均指示泸沽花岗岩为铁质碱钙性A型花岗岩。泸沽花岗岩具有较高的稀土元素含量(∑REE=221×10~(-6)~387×10~(-6)),具有轻稀土富集而重稀土亏损的特征((La/Yb)N=3.42~9.69),具有明显Eu的负异常(δEu=0.10~0.34)。泸沽花岗岩具有较高的Zr、Nb、Ce和Y含量,具有较高的Ga/Al、Y/Nb、Yb/Ta和Ce/Nb比值,显示出典型的A2型花岗岩特征。综合元素地球化学及区域地质资料,文章提出泸沽新元古代铝质A2型花岗岩起源于新元古代早期俯冲造山过程中的变泥质岩熔融。  相似文献   

10.
杨高学  李永军  司国辉  吴宏恩  金朝 《地质学报》2010,84(12):1759-1769
新疆东准噶尔卡拉麦里地区是一个重要的锡成矿带,分布有多种类型花岗岩。贝勒库都克岩体位于锡成矿带中部,由黑云母正长花岗岩和黑云母二长花岗岩组成。本文通过精确的LA-ICP-MS锆石U-Pb测年获得贝勒库都克含锡黑云母正长花岗岩年龄为283±2Ma,MSWD=0.14(95%置信度),时代属于早二叠世,这与东准噶尔后碰撞深成岩浆活动的范围(330~265Ma)相吻合。岩石地球化学研究表明,贝勒库都克岩体富硅(SiO2=75.25%~76.67%),低铝(Al2O3=11.91%~12.86%),贫镁(MgO=0.02%~0.18%)和钙(CaO=0.39%~0.89%),富碱(Na2O+K2O=8.08%~8.97%),K2O>Na2O,NK/A=0.86~0.95(平均0.92),A/NCK=0.97~1.02,富集Rb、K等大离子亲石元素及Zr、Hf等高场强元素,Ba,Nb,Sr强烈亏损,δEu=0.01~0.11,其FeOt/MgO(12.71~84.51,平均34.55)和10000Ga/A1(2.97~4.20)值大,HFSE元素(Zr+Nb+Ce+Y=191.8×10-6~353.3×10-6)含量高,明显不同于典型的I型和S型花岗岩,基本属于典型的铝质A型花岗岩。年代学和地球化学综合研究表明,贝勒库都克铝质A型花岗岩是壳幔混合成因,是准噶尔地区后碰撞幔源岩浆底侵作用导致大陆地壳垂向生长过程的记录者。贝勒库都克铝质A型花岗岩Sn的含量高(6.0×10-6~19.5×10-6,个别为80.0×10-6),铝质A型花岗岩是成矿热液的直接母体,而富Sn的流体相最终形成了贝勒库都克锡矿床,锡矿与铝质A型花岗岩是同期地质事件的产物。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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20.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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