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1.
云南易门狮子山铜矿基性侵入岩地球化学特征及其地质意义 总被引：2，自引：0，他引：2
针对云南易门狮子山铜矿区基性侵入岩体(以矿区1237m中段层状辉长岩为例)的岩石学和地球化学特征分析,结果表明:SiO2,Na2O和K2O的平均质量分数分别为47.06%,3.91%,2.17%,σ(里特曼指数)平均为9.9;微量元素表现为大离子亲石元素K,Rb,Th明显富集,Sr,Ta,Nb,Yb,Cr,Y等元素亏损,显示了大陆裂谷玄武岩的特征;稀土元素总量为178.60×10-6～404.50×10-6,Eu负异常不明显(0.73～0.97),轻稀土元素富集(LREE/HREE=7.05～16.59,(La/Yb)N=6.56～36.94);研究还认为狮子山基性侵入岩是在大陆初始裂谷背景下形成的,属于深源玄武质岩浆演化形成,可能有壳源物质的混入。 相似文献
2.
岩石地球化学研究表明,华南造山带东段武夷山新元古代蛇绿混杂岩中的玄武岩和安山岩可以分为两种类型:一种为拉斑玄武岩类,TiO2含量为2.26%～2.59%(平均2.43%),轻稀土元素比重稀土元素富集,(La)N/(Yb)N=6.4～9.4(平均7.8),相对富集Nb、Ta和Ti,微量元素特征类似于洋岛玄武岩;另一种岩石属于钙碱系列,TiO2含量为0.69%～0.93%(平均0.83%),表现为轻稀土元素富集,(La)N/(Yb)N=4.2～12.6(平均8.4),略显Eu负异常,并以低Nb、Ta、Ti等元素为特征,富集Ba、Rb、Th、K等大离子亲石元素,具有岛弧玄武岩的特征,属于俯冲作用的产物。蛇绿混杂岩中这两类岩石共生,记录了扬子地块和华夏地块之间古大洋消减闭合和弧-弧碰撞拼贴的历史。 相似文献
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对西天山特克斯西北乌孙山中部地区出露的火山岩进行了地球化学研究,结果表明玄武岩、安山岩均为拉斑质火山岩,LREE较富集[(La/Yb)N介于3.44~11.36之间],具有弱的Eu负异常(δEu=0.79~1.13),安山岩与流纹岩明显富集强不相容元素(如Cs、Rb、Ba、Th、U)和LREE。玄武岩与中酸性岩样品具有轻微的差异,但所有样品具有较明显的Nb、Ta、Ti负异常,并且除了活动性较强的元素(Cs、Rb、Ba)外,其余微量元素均接近于下地壳的含量,(Th/Nb)N介于2.02~8.12之间,(Nb/La)N介于0.40~0.45之间,远远小于1,La/Ba值低(0.01~0.07),Ba/Nb值高(90~410);Zr/Nb值平均为16.48,最为接近原始地幔(15.71)的比值;而Ta/Nb、Hf/Ta、Th/Yb值平均为0.10、3.77、0.64,较为接近上地壳(0.10、3.50、0.48)的比值,Zr含量大于90×10-6,Zr/Y值在4左右,显示了板内玄武岩的特征。结合区域上地质特征,认为该地区在石炭纪时碰撞结束进入碰撞后伸展阶段,局部具有裂谷化特征。样品的Nb、Ta、Ti负异常应为地壳混染引起,火山岩的形成环境为碰撞后伸展的构造环境。 相似文献
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大兴安岭北段塔源地区~330Ma变辉长岩-花岗岩的岩石成因及构造意义 总被引：2，自引：2，他引：0
大兴安岭北段塔源地区石炭纪侵入岩分布于中亚造山带东段,构造上位于额尔古纳-兴安地块拼合处。发育岩体由变辉长岩和花岗岩组成,它们在时空上紧密伴生,变辉长岩中的锆石CL图像呈典型条带状,弱环状结构或面状结构(Th/U值为0.15~1.09,平均0.66),Th和U具有正相关关系;花岗岩的锆石CL图像呈明显岩浆型振荡环带特征(Th/U为值0.22~4.54,平均为1.95)。LA-ICP-MS锆石U-Pb测年指示两者侵位年龄分别为331.0±2.6Ma和329.4±2.4Ma,表明形成于同一构造岩浆作用事件。岩石学和地球化学特征显示它们成因上密切相关,SiO2含量呈双峰式。塔源变辉长岩为中钾钙碱性系列,MgO含量较低(5.41%~6.45%),属于演化岩浆,TiO2、FeOT和P2O5含量较高,富集LREE,Eu异常不明显(δEu=0.71~0.90),稀土元素总量和轻重稀土元素的分馏程度较高(La/Sm=4.61~5.84,Gd/Yb=2.50~2.81),Ti/V、Ti/Y、Zr/Y比值较低,富集大离子亲石元素(LILE)而亏损高场强元素(HFSE),尤其是强烈亏损Nb,形成于板内构造环境。花岗岩以TiO2、FeOT和P2O5含量较低为特征,REE配分模式为LREE富集型,其中花岗岩为Eu弱负异常(δEu=0.76~0.92),微量元素蛛网图上类似于A型花岗岩分配模式。不相容元素(如La/Sm、La/Ta、Th/Ta)以及MgO含量等指示原始岩浆受到地壳混染比例较小,以分离结晶作用为主。塔源变辉长岩还显示岩石圈地幔物质的印记,并与石榴石二辉橄榄岩熔融有关,它们被解释成早期地幔源区曾发生过俯冲流体交代。变辉长岩和花岗岩由不同源区熔融形成,基性岩源于受到陆壳混染比例较小的原始地幔,而花岗岩可能来自底侵作用,基性岩浆使其上部地壳发生大规模的部分熔融形成大面积花岗岩。大兴安岭塔源侵入岩的形成是岩石圈伸展减薄背景下玄武质岩浆底侵作用的结果。 相似文献
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云南祥云马厂箐富碱斑岩体的地球化学特征 总被引：8，自引：1，他引：7
云南祥云马厂箐岩体是马厂箐铜钼矿的主要赋矿围岩,处于扬子板块西缘与北西向的金沙江-哀牢山深大断裂带东侧交汇部位,属于哀牢山-金沙江富碱侵入岩带的组成部分.马厂箐岩体主要为花岗斑岩、二长斑岩和正长斑岩.岩石富集大离子亲石元素(Rb、Sr、Ba、Th和U)和轻稀土元素(LREE)、相对亏损高场强元素(Ta、Nb和Ti),且Ta、Nb和Ti具"TNT"负异常;LREE/HREE值为8.04～23.99,8Eu值为0.72～0.88,负Eu异常不明显.岩石的La/Yb和(La/Yb)N比值高,LR/HR、La/Sm和Ce/Yb变化较大.岩体的岩浆起源于壳一幔物质混合的一种所谓EM Ⅱ型富集地幔源;其壳幔混合特征,主要是俯冲进入上地幔的地壳物质与地幔物质发生了源区混合作用的结果;形成于碰撞后的板内构造环境. 相似文献
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北祁连西段双龙一带出露的镁铁质-超镁铁质岩主要由蛇纹石化二辉橄榄岩、辉长岩、辉绿岩及玄武岩组成,这些岩石单元与构造卷入的前寒武纪变质岩系和深海沉积的硅质岩一起构成蛇绿混杂岩带。辉长岩LA-ICP-MS锆石U-Pb年龄为464±2 Ma(MSWD=1.3)。Zr/TiO_2-Nb/Y图解显示辉绿岩为拉斑玄武岩系列,玄武岩为碱性系列,两者均具有低的MgO和相容元素Cr、Ni含量,指示在岩浆作用过程中发生过橄榄石、辉石的分离结晶作用。球粒陨石标准化稀土元素配分模式图显示,辉绿岩呈平坦型,(La/Yb)_N=1.35~1.45,无Eu异常(δEu=1.0~1.1),以及Lu/Yb(~0.15)、Zr/Y(~2.5)、Y/Tb(~39)比值等均类似于N-MORB;但它们又相对富集Ba、Sr,亏损Nb、Ta、Pb,以及Nb/U(~21)、Zr/Nb(~16)、Th/Ta(~5.7)比值则显示了岛弧玄武岩或弧后盆地玄武岩的特征,推测辉绿岩应源于受俯冲流体交代的尖晶石二辉橄榄岩部分熔融的产物。玄武岩地球化学特征明显不同于辉绿岩,表现为相对富集LREE,~8.48,轻微负Eu异常(δEu=0.91),以及Zr/Y(~8)、Y/Tb(~30)、Ta/Yb(~0.6)、Th/Yb(~2.5)比值等类似于OIB,指示玄武岩应源于富集地幔部分熔融的产物,但岩石又表现出富集Rb、Ba、Th、U、Pb、Sr、Zr、Hf,亏损Nb、Ta、Ti、P,以及Th/Ta(~4.8)、Zr/Nb(~14)、Nb/Yb(~10)、Nb/U(~11)比值又具有岛弧或弧后盆地玄武岩的亲缘性,显示了玄武岩应源于地幔深部流体交代的石榴石二辉橄榄岩或尖晶石+石榴石二辉橄榄岩部分熔融的产物,表明早古生代北祁连古大洋在俯冲闭合过程中具有洋岛或海底高原的增生作用。结合区域地质背景,利用全球大数据建立的构造判别图解综合研究认为,北祁连西段熬油沟-玉石沟-双龙-小龙孔-卡瓦-东沟等镁铁质-超镁铁质岩共同构成一条重要的SSZ型蛇绿岩带,为北祁连古大洋向南俯冲形成的弧后盆地的残留体。 相似文献
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西秦岭关子镇蛇绿混杂岩的地球化学和锆石SHRIMP U-Pb年龄 总被引：3，自引：2，他引：3
西秦岭沿天水武山断裂带产出的关子镇蛇绿混杂岩由变玄武岩、变中-基性深成岩浆岩以及少量蛇纹岩组成。变玄武岩具有平坦或轻稀土略亏损的稀土配分型式((La/Yb)_N=0.63～1.24),且不存在Nb、Ta和Ti的负异常,表明它们形成于洋中脊环境。变中-基性深成岩浆岩包含两种类型:类型Ⅰ显示轻稀土富集((La/Yb)_N>2.2)、具有显著Nb负异常((La/Nb)_N>2.4)的特征,类似于岛弧火山岩;类型Ⅱ显示轻稀土亏损到略富集((La/Yb)_N=0.44～1.38)、无显著Nb负异常((La/Nb)_N<1.5),这些特征与上述变玄武岩类似,表明它们也是关子镇蛇绿岩的组成部分。蛇绿岩中辉长岩和闪长岩(该闪长岩属"大洋斜长花岗岩类")样品的锆石SHRIMP U-Pb年龄分别为534±9Ma和517±8Ma,这反映关子镇蛇绿岩可能为早-中寒武世古洋壳残片。由于西秦岭的天水武山断裂带是东秦岭商丹断裂带的西延并共同被认为是华北和华南陆块之间的主缝合线,上述年龄对理解该带及古秦岭洋的演化提供了重要制约。 相似文献
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小兴安岭北部二龙山林场辉长岩的主量、微量和稀土元素的测试分析结果显示: 二龙山辉长岩为钙碱性系列、偏铝质岩石; δEu 正异常,Sr 元素含量富集明显,具有堆晶辉长岩特征; Rb /Sr、Nb / Ta、LILE/HFSE、Th /Ta、Nb /U 和Nb /La 比值特征均显示,辉长岩岩浆来自受到俯冲流体交代的地幔源区。Nb /Zr、Th /Nb、Th /Ta 和Ta /Hf 比值特征及对Th /Hf --Ta /Hf 构造环境判别图解投点表明,二龙山辉长岩形成于陆内拉张环境。 相似文献
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为充分认识秘鲁北部海岸岩基带始新世以来的构造岩浆演化特征,探讨侵入岩形成时代、岩石成因及其构造环境,在海岸岩基带自西向东系统采集侵入岩样品。锆石U-Pb年代学数据显示侵入岩时代分两期,分别为52～47 Ma和36～28 Ma,具有自西向东逐渐变新的特征。样品岩石地球化学具有钙碱性-高钾钙碱性特征,明显富集Rb、Ba、K、U等大离子亲石元素,相对亏损Nb、Ta、P和Ti高场强元素;球粒陨石标准化稀土元素配分模式均表现为轻稀土元素富集的右倾型,具有弱的Eu负异常。Sr/Y-Y图解和Rb-(Y+Nb)图解显示岛弧岩浆岩的组成;Rb/Sr值和Th/U值接近壳源岩浆组成;Nb/Ta值和Zr/Hf值均接近平均陆壳组成;La/Ba-La/Nb图解指示具有岩石圈地幔源区的特征;A/MF-C/MF图解中多数样品落入基性岩的部分熔融区域。结合Nazca板块向南美大陆板块俯冲的构造背景及样品地球化学和年代学数据特征,认为两期侵入岩的岩浆具有同源特征,岩浆源区可能源于基性下地壳的部分熔融,并有岩石圈地幔物质混染;秘鲁北部在Nazca板块低角度平板俯冲作用下,岩浆弧向东迁移,同时地壳隆升和增厚时限较中南部地区的... 相似文献
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内蒙古东乌珠穆沁旗朝不楞以西及巴润布尔嘎斯台地区出露一套辉长岩。LA-MC-ICPMS锆石U-Pb测年结果显示该辉长岩体侵位于450～461Ma,属于晚奥陶世。样品的Si O_2、K_2O、TiO、MgO含量低,σ=0.10～2.77,总体属低钾拉斑玄武质系列。随着Mg O含量的增加,主要氧化物如Si O_2、CaO、Fe_2O_3含量呈上升趋势,Al2O3、Na2O呈下降趋势。根据稀土和微量元素特征,可将辉长岩分为三类。第一类REE含量最高,具有微弱的Eu正异常,(La/Yb)_N=19.99～20.3,稀土配分曲线明显右倾,富集LILE(Rb、Sr、Ba),相对亏损Nb、Ta。第二类REE含量减少,具有明显的Eu负异常,(La/Yb)_N=4.88～9.68。第三类REE含量最低,具有明显的Eu负异常,(La/Yb)_N=1.33～2.03。后两类辉长岩均亏损Nb、Sr、Ba,富集Rb、Th、U、Zr、Hf,稀土配分曲线弱右倾,岩石形成过程中可能受到陆壳物质混染。三类辉长岩整体兼具MORB型及岛弧玄武岩特征,可能是晚奥陶世古亚洲洋向北俯冲过程中弧后盆地的产物。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
18.
岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献