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吉林延边安图县海沟地区的海沟岩群系1/5万区域地质调查新建的特殊岩石地层单位(Speciallithostrati-graphicunits),由3个岩组构成:团结岩组为碎屑岩夹大理岩;东方红岩组为一套中酸性火山熔岩及其火山碎屑岩夹凝灰质砂岩;四岔子岩组为一套含铁岩系,主要由黑云变粒岩、斜长角闪岩夹磁铁石英岩组成。三者的接触关系均为断层接触,而且四周为元古代、早古生代的花岗岩所侵吞,属华北板块北缘东段残留的的构造岩片堆积产物,其时代为中元古代。这个岩组的建立,对探讨华北板块北缘东段中元古代地层划分和对比、陆缘裂谷的形成演化与成矿作用的关系以及新元古代Rodinia超大陆的形成等均具有重要的意义。 相似文献
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取自大别造山带北缘(北淮阳地区)古生代主要构造一地层岩片中变碎屑岩和碎屑岩的一组元素和Nd同位素地球化学数据与相关资料显示，从早古生代到泥盆纪，再到石炭纪，龟山组、南湾组—佛子岭群和石炭系三个岩片中的碎屑岩类，存在稳定的沉积物源区，源区组成可能相当于北秦岭构造单元中古元古代的秦岭群及秦岭群组分沉积再循环的部分。沉积组分成熟度由高到低和源区剥蚀性质变化的地球化学记录，指示三个岩片代表了华北、扬子两陆块在古生代构造演化过程中，主动大陆边缘一侧一系列构造事件中“俯冲后期-对接-碰撞前奏”的三个片断。这些论证显示，大别造山带北缘不同岩片沉积构造环境和演化的进程完全可以与北秦岭构造单元南部对比，大别造山带北缘应是北秦岭构造单元的东延部分。 相似文献
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北淮阳东段变质构造地层的古构造环境 总被引：1，自引：0，他引：1
关于大别山北麓北淮阳东段原佛子岭岩群的古构造环境问题,存在着认识分歧,其主要原因是将形成构造背景与地质演化历史本不相同的不同构造地层单元混在了一起,不加区分地进行古构造环境分析。根据构造变形、岩相学、岩石地球化学等的综合研究,将原佛子岭岩群解体为被一重要的构造滑脱带所分隔的下部卢镇关构造混杂岩带和上部诸佛庵岩群。通过对新厘定的构造岩石地层单元分别进行沉积建造和岩石化学、地球化学特征的研究发现,下部卢镇关构造混杂岩带形成于被动大陆边缘环境,而上部诸佛庵岩群形成于华北板块南部活动大陆边缘环境。这意味着华北、扬子板块的古生代板块碰撞缝合带的位置应该位于诸佛庵岩群分布区域的南侧,而且板块俯冲-碰撞的极性表现为扬子板块向华北板块之下俯冲。 相似文献
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根据近年来的同位素年代学资料,对分布于辽北地区的一套构造变质岩系（"开原岩群"或"清河镇岩群"）进行了重新认识和划分,并将其重新定义为清河构造混杂岩,由中太古代、新太古代、中元古代、新元古代、二叠纪等不同时代、不同构造环境的地质体组成.其中,中太古代、新太古代、中元古代岩石来自华北克拉通,而新元古代、二叠纪岩石则来自兴蒙造山带.将原沈家堡子岩组重新划分为新太古代变质表壳岩和中-新太古代变质深成岩,原板石沟岩组（或芦家堡子岩组）厘定为中元古代石门岩组,原照北山岩组重新划分为新元古代南平岩片和晚二叠世照北山岩组,将原佟家屯岩组和尖山子火山岩合并为晚二叠世佟家屯岩组.最后,提出了清河构造混杂岩带为华北克拉通与兴蒙造山带的界线以及古亚洲洋在华北板块北缘东段的最终闭合时间为中三叠世早期（约245Ma）的认识. 相似文献
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《吉林大学学报(地球科学版)》2015,(Z1)
<正>吉林东部延边地区大地构造位置上处于华北板块北缘东段,其北侧为华北板块北缘增生带,南侧为龙岗地块,东侧为太平洋板块,是研究古亚洲洋构造域与古太平洋构造域转换时间的理想区域[1]。对延边地区基性岩浆活动的研究有助于深入探讨华北板块北缘东段地质构造演化特征[2],因此我们对出露于延边和龙地区的沙松顶子基性侵入岩的岩相学、同位素年代学、岩石地球化学特征进行了系统的研究,并在此基础上进一步探讨了基性侵入岩岩石成因、构造背景等。 相似文献
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华北板块北缘活动带元古宙构造岩片 总被引：15，自引：3，他引：15
新的研究证实 ,华北板块北缘残存一条元古宙构造岩片堆集带 ,包括古元古代、中元古代、新元古代等多期构造岩片。并相伴有 180 0Ma±、140 0Ma±、10 0 0Ma±、6 5 0Ma±的花岗岩类的侵入活动和构造变质成矿等热事件的年代记录 ,并在华北板块北部金镶边带中保存了相一致的信息 ,揭示了它们是陆缘多期拼贴造山的产物。这为超大陆旋回 ,特别是元古宙两次超大陆的聚合与裂解及其构造演化过程的研究提供了良好的野外实验园地 ,并为元古宙、特别是古元古代大陆的增生及Rodinia超大陆在北半球的存在或构造响应提出新的课题。 相似文献
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西昆仑塔什库尔干混杂岩的地质特征及其大地构造意义 总被引：6，自引：0，他引：6
西昆仑塔什库尔干构造混杂岩带由古元古代基底岩片、震旦纪大陆板内裂谷玄武岩岩片、奥陶纪-志留纪复理石岩片、石炭纪-二叠纪火山弧岩片及高压变质岩片组成.根据高压变质、残余洋盆及岩浆孤的形成时闯进行综合判断,混杂岩带形成于早古生代.该混杂岩带的发现对于确立康西瓦断裂带的性质和认识西昆仑地区的大地构造演化历史具有重要意义.进一步表明西昆仑地区在早古生代曾发生过板块俯冲和碰撞,并暗示麻扎-康西瓦断裂可能代表了原特提斯洋-古特提斯洋俯冲消减并最终闭合的界线. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
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Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献