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1.
运用单颗粒锆石逐层蒸发法和角闪石40Ar/39Ar阶段加热法研究了河南洛宁太华岩群斜长角闪岩的同位素年龄.获得锆石207Pb/206Pb年龄为2675±2 Ma,角闪石40Ar/39Ar坪年龄和等时线年龄分别为2372.98±47.46 Ma和2349.10±46.98 Ma.锆石207Pb/206Pb年龄代表了斜长角闪岩原岩的形成时代,而角闪石40Ar/39Ar年龄则为其变质时代,与Sm-Nd等时线年龄(2351±103Ma)相一致.上述年龄数据表明河南洛宁地区太华岩群形成于新太古代,在古元古代遭受过一次角闪岩相变质作用.  相似文献   

2.
内蒙古北山交叉沟地区变质火山岩Sm-Nd同位素研究   总被引:7,自引:0,他引:7  
聂凤军  江思宏  刘妍  张义 《地质学报》2004,78(6):807-812
交叉沟变质杂岩套主要由斜长角闪岩、片麻岩、长英片岩、绿片岩和条带状混合岩组成 ,为中国西北北山造山带红石山—黑鹰山地体的重要组成部分。长期以来 ,由于缺少可信的同位素年代学数据 ,该套变质岩的形成时代、成岩环境和物质来源尚不清楚。笔者等首次对交叉沟变质杂岩套代表性变质岩进行了 Sm- Nd同位素研究 ,其中斜长角闪岩 Sm- Nd同位素等时线年龄为 12 6 4± 11Ma、其 1 43Nd/ 1 44 Nd初始值为 0 .5 11375± 13,εNd(t)为 7.2 4± 0 .0 2 (2 σ)。与斜长角闪岩样品相比 ,各类片麻岩的 εNd(12 6 4 Ma)值明显偏低 ,变化范围为 1.18~ - 5 .17。依据上述Sm- Nd同位素数据 ,并且结合野外地质证据和岩相学特征 ,认为交叉沟地区斜长角闪岩的原岩为基性火成岩 ,属于幔源基性岩浆活动的产物 ,成岩时代为中元古代 ,而片麻岩的原岩则多为中酸性火成岩 ,其形成过程与古元古代或太古宙古陆壳岩层的再造作用有关。  相似文献   

3.
大别核部杂岩单元中斜长角闪岩的地球化学特征对于认识大别核部杂岩单元的特征及归属有着十分重要的意义。本文对大别核部杂岩单元中斜长角闪岩的岩石地球化学特征及Sm-Nd 同位素特征进行了较系统研究。斜长角闪岩的 Nd亏损地幔模式年龄(t_(DM))有3个不连续年龄段,它们分别为2.50~2.92Ga(平均2.71Ga);1.79~2.47Ga(平均2.14Ga);1.07~1.57Ga(平均1.38Ga)。模式年龄为中元古代、古元古代的斜长角闪岩的等时线年龄分别为1444±180Ma、2220±210Ma,其模式年龄与等时线年龄在误差范围内一致。表明至少模式年龄为元古宙的斜长角门岩的t_(DM)可代表其原岩的近似形成年龄,从而证明大别核部杂岩单元中存在着古元古代、中元古代两期自亏损地幔分异的基性火山岩变质形成的斜长角闪岩。而模式年龄为新太古代的斜长角闪岩,其模式年龄能否代表其形成年龄还需要进一步研究。各期斜长角闪岩在地球化学特征上的差异表现得不明显。通过对其原岩性质研究表明:原岩主要为拉斑玄武岩,少数为钙碱性玄武岩。大别核部杂岩中斜长角闪岩原岩ε_(Nd)(t)反映出大别核部杂岩地区上地幔自古元古代到中元古代一直沿着亏损地幔 Nd 同位素的演化线演化发展,这种性质及演化趋势与扬子北缘及南秦岭早期上地幔 Nd 同位素性质及演化趋势十分  相似文献   

4.
通过岩石学、矿物学、稀土及微量元素地球化学和Nd、Sr、Ph、O同位素组成的研究,确定相山斜长角闪岩的原岩为基性火山岩(玄武岩),井形成于岛弧环境,主要衍生于弱亏损地幔源区,并受到地壳物质某种程度的混染。造岩矿物成分具有低角闪岩相变质作用的特征,表明它们是低角闪岩相变质作用的产物,变质作用的温压条件为550℃±,0.69Gpa±。根据斜长角闪岩原岩的形成年龄(1113Ma)及变质年龄值(726.6Ma)结合其地质地球化学特征,确认赣中相山地区存在元古宙岛弧。  相似文献   

5.
阿拉善地区前寒武纪不同岩群、岩组和杂岩中的斜长角闪岩均呈层状产出 ,其原岩多为高铁拉斑玄武岩 ,普遍具有高钾高钛、稀土元素含量高、轻稀土元素富集的地球化学特征 ,与典型的大洋拉斑玄武岩、太古宙的TH1型和TH2 型拉斑玄武岩有较明显的区别。岩石组合特征和多种地球化学判别图解均表明 ,该区的斜长角闪岩主要形成于板内环境 ,属于板内裂陷或大陆边缘裂陷的大地构造环境。初步的同位素年代学研究表明 ,叠布斯格岩群中斜长角闪岩的原岩形成于新太古代 ,含黑云斜长角闪岩中的角闪石3 9Ar_40 Ar坪年龄和等时线年龄分别为 1918Ma和1919Ma ,说明其曾经历了古元古代角闪岩相变质作用的叠加。巴彦乌拉山岩组中斜长角闪岩形成于 2 2 71Ma~2 2 6 4Ma。波罗斯坦庙片麻杂岩中的斜长角闪岩已被 1818Ma和 1839Ma花岗片麻岩侵入 ,根据该杂岩体中斜长角闪岩与巴彦乌拉山岩组中同类岩石的地球化学特征 ,推断其形成于古元古代早期。阿拉善群德尔和通特组中的斜长角闪岩目前尚无确切的同位素年代学数据 ,但相同层位的石榴石二云母石英片岩中锆石离子探针定年已获得平均同位素年龄值为 136 3Ma ,推测它有可能形成于中元古代  相似文献   

6.
浙西南北园八都群石榴斜长角闪岩的变质特征及年代   总被引:3,自引:0,他引:3  
浙西南北园的石榴斜长角闪岩是一次高角闪岩相变质作用的产物,原岩为玄武质火成岩。可分为两个演化过程,其一是高角闪岩相变质作用,变质温度约650±20℃,压力0.9~1.1GPa,形成石榴子石+用闪石+斜长石十单斜辉石±金红石的矿物组合;其二是石榴斜长角闪岩的减压退变质,形成透辉石+更-中长石的筛孔状分解结构及榍石环绕金红石的反应边结构。石榴斜长角闪岩的矿物Sm-Nd等时年龄为1468±19Ma,代表高角闪岩相变质时代,Rb-Sr等时年龄为1083±49Ma,反映退变质时代,它们各自反映了华夏古陆中晚元古代时期两次重要构造事件。  相似文献   

7.
扬子地台西缘结晶基底的时代   总被引:26,自引:0,他引:26  
对扬子地台西缘结晶基底变质地层以及岩浆片麻岩中变质地层残片或包裹体中锆石SHRIMP U-Pb同位素年龄研究表明,在康定地区辉长–闪长质片麻岩中,表壳岩包体—糜棱岩化的长英质片岩和宝兴地区黑云斜长角闪岩的年龄分别为816±8.6 Ma和826±13 Ma,代表了它们的原岩——酸性火山岩和火山凝灰岩的形成年龄;泸定地区变质岩层中长英质糜棱岩和斜长角闪岩的年龄分别为816±9 Ma和818±8 Ma,代表了中性火山岩和基性火山岩的形成时代;茨达地区斜长角闪岩和角闪黑云斜长片麻岩的年龄分别为830±7 Ma和827±10 Ma,代表了其原岩火山–沉积建造的形成时代。以上数据表明,所谓的结晶基底都是新元古代的产物,在形成时间上与盐边群、盐井群等褶皱基底的相一致,只是变质程度上略有差异。因此该区并不存在古老(太古宙—古元古代)的结晶基底。  相似文献   

8.
大别造山带南部宿松杂岩中花岗片麻岩和斜长角闪岩的U-Pb锆石年龄和Ar/Ar角闪石年龄测定结果表明,二长花岗片麻岩的形成年龄为2018±73Ma和2010±38Ma,白云斜长片麻岩的形成年龄为741±7Ma,宿松杂岩经过228Ma左右的变质作用。这些结果表明大别山南缘存在较大规模的古元古代花岗质结晶基底,广泛分布在宿松杂岩中的花岗片麻岩和由花岗片麻岩强烈剪切变形而成的白云斜长片麻岩、白云钠长石英片岩形成于新元古代,不整合覆于二长花岗片麻岩之上并被新元古代花岗片麻岩侵入的变质沉积岩形成于中元古代晚期-新元古代早期。由此得出,宿松杂岩主要由古元古代二长花岗片麻岩、中新元古代变质沉积岩和新元古代变质花岗岩和变质基性岩组成,因而也是扬子板块的俯冲陆壳基底的一部分。  相似文献   

9.
内蒙古东部出露的锡林格勒杂岩主要由中元古代原岩为火成岩的黑云母片麻岩和斜长角闪岩透镜体组成。片麻岩显示轻稀土元素富集的中等分异特征 ,具明显的Eu负异常 ,其不相容元素特征与平均地壳类似但相对亏损Ba和Sr。斜长角闪岩构成一条Sm -Nd等时线 ,其年龄值为12 0 2± 6 5Ma ,εNd(1.2 0Ga)值为 6 .8。角闪岩的亏损地幔模式年龄 (tDM,1.2 6~ 1.32Ga)与其Sm -Nd同位素等时线年龄接近。角闪岩的Rb -Sr同位素等时线年龄为 393± 14Ma ,其87Sr/ 86 Sr初始比值为 0 .70 379± 0 .0 0 0 0 7,此Rb -Sr等时线年龄与本区出露的篮片岩Ar-Ar年龄 (~ 383Ma)一致 ,记录了中亚造山带东南部洋壳俯冲结束后由大陆碰撞造山引起的变质作用事件。黑云母片麻岩的Rb -Sr同位素等时线年龄为 2 79.5± 6 .4Ma ,87Sr/ 86 Sr初始比值为 0 .70 85 1± 0 .0 0 0 10 ,此Rb -Sr等时线年龄与本区广泛分布的早二叠世火山岩的Rb -Sr等时线年龄 (~ 2 77± 15Ma)一致 ,因此可能是由大规模岩浆活动诱发的变质作用的记录。锡林格勒杂岩因此不仅记录了Rodinia超大陆聚合的地质事件 ,并且通过对比研究本地区蛇绿岩和晚古生代岩浆岩的演化历史 ,可以恢复从Ro dinia超大陆聚合 (~ 1.2 0Ga)到古亚洲洋关闭 (~ 4 30Ma)、大陆碰撞造山 (~ 39  相似文献   

10.
 乌拉乌苏地区的斜长角闪岩和德言其庙地区的斜长角闪岩变质较深,已达角闪岩相,两者在变质程度、空间展布型式以及岩石学、岩石化学和稀土配分型式上都十分相似,二者形成时代相近,应为同一套变质岩系,具有相同的形成环境和构造成因。样品的εNd(t)值反映了它们来源于中等亏损的地幔,稀土元素配分曲线呈平坦型,与之有关的幔源花岗岩在ACF图解中投影在拉张区,具有拉张过渡壳特征。乌拉乌苏斜长角闪岩和德言其庙斜长角闪岩Sm-Nd同位素全岩等时线年龄分别为(607±46)Ma和(638±14)Ma,这表明华北地台北缘中段晚元古代-早古生代经历了拉张解体的演化阶段,Sm-Nd同位素等时线年龄代表了这一拉张解体演化的开始时间。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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