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1.
赣南西华山钨矿是与侏罗纪花岗岩有关的大型石英脉型矿床,也是我国南岭成矿带赣南地区典型的钨矿床。本文选取西华山钨矿成矿花岗岩进行了锆石LA-ICP-MS U-Pb定年、微量元素和Hf同位素分析,旨在揭示花岗岩的形成时间并推断岩石成因及其对成矿的指示。锆石U-Pb测年结果表明,西华山中粒黑云母花岗岩锆石206 Pb/238 U加权平均年龄为154.8±6.0 Ma。锆石形态、激光拉曼和地球化学特征表明,该花岗岩受到岩浆热液的影响。锆石的176 Yb/177 Hf和176 Lu/177 Hf比值较高,表明源岩浆有强烈的流体出溶作用。西华山黑云母花岗岩的εHf(t)变化范围较小,呈明显负值(-12.8~-10.8),且集中在华夏地块古老基底范畴内,指示其形成于古老地壳物质的部分熔融。 相似文献
2.
中国东北地区显生宙花岗岩的成因一直是中亚造山带东段研究的热点之一,尤其是小兴安岭-张广才岭地区的花岗岩其成因及形成的大地构造背景一直存在较大争议。本文新获得小兴安岭-张广才岭铁力和依兰地区的二长花岗岩LA-ICP-MS锆石U-Pb年龄分别为188±1 Ma和257±3 Ma。地球化学数据显示,两地区的二长花岗岩均为Ⅰ型花岗岩并且富集大离子亲石元素(Th和U等)和轻稀土元素,亏损高场强元素(Nb和Ta等)和重稀土元素具有弧岩浆岩的地球化学特征。锆石Hf同位素数据显示,铁力地区二长花岗岩的岩浆源区可能来自于中新元古代的下地壳部分熔融。综合前人在小兴安岭-张广才岭地区已发表的花岗岩类岩石的地质年代学和地球化学数据,初步推测小兴安岭-张广才岭地区在晚古生代至中生代期间处于活动大陆边缘环境。同时,小兴安岭-张广才岭地区晚古生代至中生代的岩浆岩具有自东向西形成时代逐渐变年轻的趋势,这可能是由于东侧的牡丹江洋在晚古生代至中生代期间俯冲角度逐渐变缓造成的。 相似文献
3.
华北地台南缘张士英岩体的锆石SHRIMP U-Pb测年、Hf同位素组成及其地质意义 总被引：6，自引：3，他引：3
张士英岩体位于华北地台南缘,岩石类型包括钾长花岗岩、似斑状花岗岩和石英斑岩脉,其中只在钾长花岗岩中发育有暗色岩石包体,在包体和寄主岩中发育反映岩浆混合作用的岩石结构。钾长花岗岩、似斑状花岗岩和石英斑岩脉的SHRIMP锆石U-Pb年龄分别为107.3±2.4Ma、106.7±2.5Ma和101±3Ma。锆石Hf同位素分析结果显示,钾长花岗岩的锆石εHf(t)为-15.96～-20.80,单阶段模式年龄(tDM1)为1396～1643Ma,两阶段模式年龄(tDM2)为1880～2018Ma;似斑状花岗岩的锆石εHf(t)为-18.97～-22.18,tDM1为1512～1640Ma,tDM2为1925～2080Ma;除了一粒年龄为2.6Ga的锆石具有εHf(t)为-0.71、tDM1为2943Ma和tDM2为3036Ma的组成,石英斑岩的锆石εHf(t)为-23.41～-27.95,tDM1为1678～1896Ma,tDM2为2144～2330Ma。这些数据暗示,除了存在少量太古宙地壳物质的贡献外,张士英岩体的物质来源可能主要为1.9～2.3Ga期间形成的新生地壳,但也不排除古老地壳与富集地幔源混合的可能。综合分析前人研究成果表明,在太平洋板块俯冲方向发生转变的过程中,先存断裂带发生拉张。张士英岩体与中国东部同期岩浆活动一起可能形成于这种受断裂带控制的伸展环境。 相似文献
4.
通过对兴蒙造山带东段小兴安岭-张广才岭地区张家湾岩体石英闪长岩、正长花岗岩进行的锆石LA-ICP-MS U-Pb年龄分析测试、岩石地球化学的各项分析测试,综合分析研究表明,石英闪长岩形成于早侏罗世(176.2±1.8Ma),具浆混花岗岩特点,属壳幔混合成因;正长花岗岩形成于中侏罗世(166±2.2Ma),具"S"型花岗岩的地球化学属性,属壳源熔融成因。结合该区大地构造背景,认为张家湾岩体很可能是环太平洋增生地体的佳木斯板块与西侧的张广才岭地块碰撞造山作用形成。 相似文献
5.
黑龙江翠宏山铁多金属矿区岩体锆石U-Pb年龄、Hf同位素特征及其地质意义 总被引：1，自引：0，他引：1
黑龙江翠宏山铁多金属矿床位于小兴安岭—张广才岭成矿带北部。该成矿带上分布有大量对成矿起制约作用的岩浆岩体。前人有关矿区成岩、成矿时代的认识差异较大,且缺乏对矿区岩体成因的研究。为了解这些岩体的成岩时代、岩体成因、区域构造背景及其与成矿的关系,本文对其开展了锆石U-Pb年代学和Hf同位素研究。3个花岗岩类样品的锆石LAICP-MS U-Pb年代学和Hf同位素分析结果显示,黑云母花岗岩、花岗斑岩和碱长花岗岩的形成年龄分别为496$1.5Ma、193$1Ma和173$1Ma;黑云母花岗岩的εHf(t)值和tDM2分别为-4.7~0.0和1463~1764Ma,花岗斑岩及碱长花岗岩的εHf(t)值和tDM2值分别为0.2~10.1和781~1184Ma。结合前人的年代学数据,推断矿区至少存在4期岩浆活动,其中二长花岗岩与成矿关系最密切。研究结果也表明松嫩地块在中-新元古代时期曾发生过两次重要的地壳增生事件。 相似文献
6.
湘东北三墩铜铅锌矿区花岗岩的岩石成因——锆石U-Pb测年、岩石地球化学和Hf同位素约束 总被引：1，自引：1，他引：0
对湘东北三墩铜铅锌矿区花岗岩进行了系统的锆石U-Pb年代学、岩石地球化学和Hf同位素分析。LA-ICP-MS锆石U-Pb定年表明,三墩铜铅锌矿区花岗岩成岩年龄为131.9±1.1Ma。三墩铜铅锌矿区花岗岩为一套强过铝质钙碱性系列花岗岩,富集U、Ta、Pb,亏损Ba、Nb、Sr、Zr、Ti等元素,稀土元素配分模式为右倾配分模式,具有弱负Eu异常。Hf同位素分析表明,三墩铜铅锌矿区花岗岩燕山晚期锆石ε_(Hf)(t)值为-5.9~-2.4,Hf同位素二阶段模式年龄为1558~1338Ma,表明其物质来源于中元古代古老地壳岩石部分熔融。749.5Ma继承锆石核的ε_(Hf)(t)值为+4.8,Hf同位素二阶段模式年龄为1355Ma,暗示其物质来源有幔源物质加入。三墩铜铅锌矿区花岗岩可能是由于中下地壳的熔融岩浆形成后,混入少量幔源物质上侵形成的。 相似文献
7.
华北陆块北缘崇礼-赤城地区晚古生代花岗岩类的锆石年龄和Sr-Nd-Hf同位素组成 总被引：7，自引：5，他引：2
本文报道冀北崇礼-赤城地区晚古生代花岗岩类岩石的锆石U-Pb年龄和Sr-Nd-Hf同位素组成特征.它们出露在华北陆块北缘的构造单元内,侵位于中高级变质基底岩石红旗营子群中.锆石LA-ICP-MS定年结果表明,海流图花岗岩岩体记录了两期岩浆作用,即299±3Ma和254±11Ma;镇宁堡片麻状二长花岗岩和白花沟片麻状黑云母石英二长闪长岩分别形成于287±1Ma和252±3Ma.这些晚古生代花岗岩类岩石具有较低的初始~(87)Sr/~(86)Sr值(0.7062～0.7076)、低的ε_(Nd)(t)值(-18.1至-9.6)和古老的Nd亏损地幔模式年龄(2.49～1.87Ga).其锆石的ε~(Hf)(t)值变化在-13.2至-7.4之间,Hf平均地壳模式年龄值(T_(DM)~C)在2.15Ga至1.79Ga之间.锆石Hf同位素特征与全岩Nd同位素特征指示古老的华北陆块地壳物质是花岗岩浆的主要物源.在形成时代和地球化学特征上,崇礼-赤城地区晚古生代花岗岩与出露在东部丰宁-承德地区的花岗岩类岩石既有相似性,又有不同之处,可能代表华北陆块北缘不同构造背景下岩浆作用的产物. 相似文献
8.
安徽省金寨县沙坪沟钼矿含矿岩体锆石U-Pb年龄和Hf同位素特征及其地质意义 总被引：9，自引：3，他引：6
安徽省金寨县沙坪沟斑岩型钼矿位于大别山东段,钼矿化与石英正长斑岩和爆破角砾岩紧密相关.石英正长斑岩和爆破角砾岩LA-ICP-MS锆石U-Pb年龄分别为116.1±2.2Ma和112.9±1.2Ma,侵位于早白垩世.两类岩石都显示出高钾、富碱、富铝的特点,属过铝质A型花岗岩,具有较高浓度的大离子亲石元素和相对低含量的高场强元素以及较低的HREE和Y、Yb含量,暗示其源于石榴石作为残留相的较深层次的下地壳物质部分熔融.石英正长斑岩εHf(t)变化于-14.4～-12.4,分布于亏损地幔演化线之下,tDM2变化于1598～1707Ma,指示岩浆源于古老下地壳物质的部分熔融,古老下地壳可能由宽坪群(1.85～1.4Ga)组成;爆破角砾岩εHf(t)为-10.1～-2.7,tDM2为1097～ 1486Ma,指示物源区比斑岩更年轻,可能来自宽坪群与地幔物质的混合.以上表明,从石英正长斑岩到爆破角砾岩,成岩岩浆来源变深,由地壳为主演变为壳幔混合,形成于碰撞造山加厚地壳的减薄过程;在大地构造上,能够作为源区的地层单元皆分布于矿区以北,因此我们认为在中生代碰撞造山过程中,华北大陆板块向南俯冲到大别山之下. 相似文献
9.
10.
华北克拉通五台群LA-ICP-MS锆石U-Pb年龄和Hf同位素特征 总被引：2，自引：0，他引：2
通过对五台群石咀亚群金刚库组4个典型样品的LA-ICP-MS锆石U-Pb年龄和Hf同位素研究,对五台群的形成时代及华北克拉通新太古代—古元古代期间的地壳演化进行了探讨。锆石U-Pb同位素测定结果表明,侵入金刚库组中的片麻状花岗岩锆石的U-Pb年龄为2548Ma,因此五台群的上限年龄约为2.5Ga;金刚库组黑云母石英片岩和片麻状石英闪长岩的原岩锆石U-Pb年龄分别为2663Ma和2636Ma,因此五台群的下限年龄约为2.7Ga。五台群的地质年龄为2.5~2.7Ga,属于新太古代。锆石Hf同位素研究结果表明,黑云母石英片岩和片麻状石英闪长岩的二阶段Hf模式年龄(tDM2)均为2.8Ga左右,指示2.8Ga左右是五台山区乃至整个华北克拉通地壳生长的重要时期;片麻状花岗岩tDM2平均为2.57Ga,与锆石结晶年龄非常接近,表明2.5Ga左右也是华北克拉通地壳的主要增生期。地壳的增长是幕式的,2.8Ga和2.5Ga都是华北克拉通地壳生长时期。 相似文献
11.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world. 相似文献
12.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
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14.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
15.
I. Bejarano-Ramirez Jose M. Jurado R. Muñiz-Valencia Á. Alcázar Silvia G. Ceballos-Magaña A. Olivos-Ortiz O. Rangel 《International Journal of Environmental Science and Technology》2017,14(6):1333-1342
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments). 相似文献
16.
《Geoforum》2017
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South. 相似文献
17.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability. 相似文献
18.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
19.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification
(e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes
of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application
inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen
constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter
are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system,
our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro
and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically
applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect
to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics
can be extracted from the new statistics; however, substantial additional information is also available. From the practical
point of view, E-classification is substantially faster than the Zingg method. 相似文献
20.
Pools,riffles, and channelization 总被引：2，自引：0，他引：2
Edward A. Keller 《Environmental Geology》1978,2(2):119-127
The addition of regularly spaced deeps (pools) and shallows (riffles) that provide a variety of flow conditions, areal sorting
of stream-bed material, cover for wildlife, and a positive aesthetic experience, may be desirable in many channel projects.
Such designs will reduce adverse environmental impacts of stream channel modifications.
Analysis of variance for pool-to-pool spacing data suggests that there is no significant difference with respect to channel
width between pools that form in natural streams and those in streams affected by a variety of human uses. Short of channelization,
which changes the channel width, pools and riffles, within limits, are not particularly sensitive to environmental stress.
Experiments in Gum Branch near Charlotte, North Carolina, support the hypothesis that channel form and process evolve in harmony
and that manipulation of cross-channel morphology can influence the development of desired channel processes. Planned manipulation
of its channel form induced Gum Branch to develop as desired. Morphologic stability consisting of incipient point bars, pools,
and riffles was maintained over a period of high magnitude flood events, only to be degraded later by a wave of sediment derived
from upstream construction and stream-bank failures. Thus, environmentally desirable channel morphology in urban streams cannot
remain stable if changes in the sediment load or storm-water runoff exceed the limits of the stream's ability to make internal
adjustments while maintaining morphologic stability. 相似文献