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1.
王剑锋 《中国地球化学学报》1991,10(3):277-287
Based on the data of 64 samples ,the REE geochemical characteristics of volcanic rocks in northern Zhejiang and eastern Jiangxi provinces are discussed in this paper.The REE distribution patterns in acid and intermediate-acid volcanic rocks in these areas display some similarities,as indicated by rightward-inclined V-shaped curves with negative Eu anomalies,which are parallel to earch other.In addi-tion,their REE parameters(ΣREE,ΣLREE/ΣHREE,δEu,Ce/Yb,La/Sm,La/Yb,etc)also va-ry over a narrow range with small deviations.HREE are particularly concentrated in the volcanic rocks as-sociated with uranium mineralization.The initial ^87Sr/^86Sr ratio in the volcanic rocks is about 0.7056-0.7139.All these features in conjunction with strontium isotopic data indicate that the rock-forming materials come from the sialic crust.The REE distribution patterns and REE geochemical parameters of the volcanic rocks ,as well as La/Sm-La and Ce/Yb-Eu/Yb diagrams may be applied to the sources of rock-forming and ore-forming materials. 相似文献
2.
The total rare-earth element values(ΣREE)of loess in the Xinjiang region vary over a range of 128-200 ppm ,with an average of 153ppm .The average REE content of loess lies between the earth‘s crust (155ppm) and sedimentary rocks(151ppm).The Xinjiang loess,with the REE distribu-tion patterns characterized by negative slopes ,is rich in the Ce-family elements, and has a distribu-tion pattern characteristic of sedimentary rocks.The North Xinjiang loess is relatively depleted in Tb,but rich in Yb and Lu.The South Xinjiang loess is relatively rich in light rare-earth elements.This is full proof that the Xinjiang loess comes partly from weathered materials(clay rock,sandstone)in the region studied.The REE distribution patterns in the Xinjiang loess are similar to those in the precipitated dust and Aeolian sand,indicating the same material source.The REE distribution pat-terns in the Xinjiang loess are also similar to those in loess from the middle Yellow River Valley,China and Taskent,the former USSR.This implies that loesses of the three locations(Xinjiang,the mid-dle Yellow River Valley and Taskent) come from a common material source.But the REE patterns in the Xinjiang loess are different from those in wall rocks (volcanic rock,K-bearing volcanic rock).Generally ,LREE/HREE,Eu/Eu* and Ce/Ce* ratios reflect the features of parent materials of loess,indicating that the parent rocks were probably in the early stage of alkaline weathering and the weathered materials existed in an oxidation environment with basic mediums under arid-climatic conditions before transport.As a result,the migration ability of the REE is weak. 相似文献
3.
吴素珍 《中国地球化学学报》1989,8(1):72-83
The metasedimentary-volcanic series of the Wutai and Hutuo groups experienced regional metamorphism and thus turned into moderate-to low-grade metamorphic rocks.REE abundances and REE distribution patterns in the Shizui and Taihuai Subgroup metasedimentary-volcanic rocks are typical of the Archean,whereas the Gaofan Subgroup and the Hutuo Group show post-Archean REE geochemical char-acteristics.Five types of REE distribution pattern are distinguished:(1)rightward inclined smooth curves with little REE anomaly(Eu/Eu*=0.73-0.95) and heavy REE depletion (e.g.the Late Archean metasedimentary rocks);(2)rightward inclined V-shaped curves with sharp Eu anoma-ly (Eu/Eu*=0.48-0.76) and slightly higher ∑REE (e.g.the post-Archean metasedimentary rocks);(3) rightward inclined steep curves with negative Eu anomaly(Eu/Eu*=0.73-0.76) and the lowest ∑REE (e.g.the post-Archean dolomites);(4)rightward inclined,nearly smooth curves with both positive Eu anomaly and unremarkable positive Eu anomaly(Eu/Eu*=0.95-1.25)(e.g.the meta-basic volcanic rocks);and (5) rightward inclined curves with Eu anomaly(Eu/Eu*=1.09-1.19)and heavy REE depletion(e.g.the meta-acid volcanic rocks).Strata of the two groups are considered to have been formed in an island-arc belt-an instable continental petrogenetic environment. 相似文献
4.
V. E. Strikha 《Geochemistry International》2006,44(8):791-807
Geochemical and isotopic data were used for a comparative analysis of Late Mesozoic (150–120 Ma) granitoids in various geological
structures of the upper Amur area. The granitoids are metaluminous high-potassic I-type rocks of the magnetite series. They
have variable alkalinity and consist of the monzonite-granite and granosyenite-granite associations. The monzonite-granite
association consists of calc-alkaline granitoids of normal alkalinity belonging to the Umlekan-Ogodzhinskaya volcanic-plutonic
zone and the Tynda-Bakaran Complex of the Stanovoy terrane. The rocks are characterized by negative anomalies of U, Ta, Nd,
Hf, and Ti (in patterns normalized to the primitive mantle), with Eu anomalies pronounced weakly in the granodiorites and
quartz and monzodiorites and more clearly in the granites: Eu/Eu* = 0.37–0.95, and (La/Yb)n = 7–24, Tbn/Ybn = 1.4–3.2. The granosyenite-granite association comprises of moderately alkaline rocks, which are subdivided into three groups
according to their geochemistry. The first group consists of phase-I granosyenites of the Uskalinskii Massif of the Umlekan-Ogodzhinskaya
zone with the highest concentrations of Sc, V, Cr, Co, Ni, Cu, Cs, Rb, Sr, Y, Zr, Yb, and Th; negative anomalies at Ba, Ta,
Sr, and Hf; Eu/Eu* = 0.50–0.58, (La/Yb)n = 15–16, and Tbn/Ybn = 1.8. The second group comprises of moderately alkaline granitoids of the Umlekan-Ogodzhinskaya zone and the Khaiktinskii
Complex of the Baikal-Vitim superterrane. Geochemically, the granitoids of this group are generally similar to the monzodiorite-granite
association and differ from it in having lower concentrations of REE and Y, Eu/Eu* = 6.2–1.0, (La/Yb)n = 28–63, and Tbn/Ybn = 2.1–4.5. The third group consists of granitoids of the Chubachinskii Complex of the Stanovoi terrane, which typically show
negative Cs, Rb, Th, U, Ta, Hf, and Ti anomalies; the lowest concentrations of V, Cr, Co, and Ni; and the highest contents
of Sr. The granosyenites of the first phase display clearly pronounced negative Eu anomalies (Eu/Eu* = 0.53–0.68), (La/Yb)n = 7–24, and Tbn/Ybn = 0.8–2.0. The granitoids of the second phase have (La/Yb)n = 51–84, no Eu anomalies, or very weak Eu anomalies (Eu/Eu* = 0.97–1.23). The silica-oversaturated leucogranites of the third
phase are characterized by elevated concentrations of REE, clearly pronounced Eu anomalies (Eu/Eu* = 0.48), and flat REE patterns
(Tbn/Ybn = 1.3). The diversity of the granitoids is demonstrated to have been caused largely by the composition of the Precambrian
source, which was isotopically heterogeneous. The rocks of the monzodiorite-granite association and first-group granosyenites
of the granosyenite-granite association of the Tynda-Bakaran Complex were supposedly derived from garnet-bearing biotite amphibolites.
In contrast to these rocks, the source of the second-group granites of the granosyenite-granite association was of mixed amphibolite-metagraywacke
composition. The third-group of granitoids were melted out of Early Proterozoic crustal feldspar-rich granulites of variable
basicity, with minor amounts of Archean crustal material. The granitoids were emplaced in a collisional environment, perhaps,
during the collision of the Amur superterrane and Siberian craton. This makes it possible to consider these rocks as components
of a single continental volcanic-plutonic belt.
Original Russian Text ? V.E. Strikha, 2006, published in Geokhimiya, 2006, No. 8, pp. 855–872. 相似文献
5.
勐满金矿床位于云南省勐海县境内,地处临沧-景洪褶皱束之临沧-澜沧复背斜南部,截至2005年探明金矿资源量17t,主矿体属于地表红土型氧化矿,平均品位为0.60×10-6。文章基于对勐满金矿床矿区内新元古界曼来组片岩和中侏罗统花开左组碎屑岩及矿区外围东部的临沧花岗岩的LA-ICP-MS锆石U-Pb年龄测定,探讨了曼来组片岩和花开左组碎屑岩地层的物质来源,追溯母岩的物质源区,并结合矿区普遍发育的硅化岩和硅质脉体的地球化学特征,分析了金成矿的物质来源。勐满金矿床曼来组中主要碎屑锆石年龄为(957.0±9.8)Ma,属新元古代早青白口纪;中侏罗系花开左组主要碎屑锆石年龄为(224.2±2.8)Ma,与临沧花岗岩基中2件黑云母二长花岗岩的年龄(分别为(228.7±2.8)Ma和(229.4±2.0)Ma)一致,表明花开左组地层的物质来源可能与临沧花岗岩有关。微量元素测试结果显示,矿区硅化岩与硅质脉体具有相似的稀土元素配分模式与微量元素组成,均表现为富集U、Th、Pb等大离子亲石元素,亏损Zr、Hf、Nb、Ta等高场强元素,轻稀土元素明显富集,重稀土元素亏损,中-弱的Eu负异常,Ce异常不明显,与矿区围岩及临沧花岗岩体南部的黑云母花岗岩具有相似的变化趋势。硅化岩稀土元素总量为42.3×10-6~311.0×10-6,平均为131.8×10-6;硅质脉体稀土元素总量为5.0×10-6~280×10-6,平均为56.8×10-6,显示硅化岩相对于硅质脉体具有更高的稀土元素总量。硅质脉体((La/Yb)N为4.3~133.4,平均36.7)相对于硅化岩((La/Yb)N为2.1~26,平均为8.5)具有更高的轻、重稀土元素分馏特征。硅化岩的地球化学特征变化介于围岩与硅质脉之间,表明硅化岩既继承了围岩特征,又有经热泉活动改造的痕迹。综合锆石年代学结果与沉积物源分析,认为矿区花开左组砂岩主要为临沧岩体经受风化搬运沉积的产物,曼来组向花开左组提供金的量不足以形成花开左组中的碎屑岩型矿体,热泉活动产生的流体是金成矿的另一重要物质来源,同时是导致金后期富集的重要因素。据此推断,花开左组是赋矿层位,而并非矿源层。结合低硫型矿床标志性矿物冰长石的出现,提出勐满金矿属于典型的与热泉活动有关的低硫型浅成低温热液金矿。 相似文献
6.
R. K. Bikramaditya Singh 《Journal of the Geological Society of India》2010,75(4):618-631
Low to medium grade crystalline rocks locally known as Bomdila Group extensively covers the Lesser Himalayan region in Western
Arunachal Himalaya. This Group consists dominantly of mylonitic gneisses of granitic composition of Palaeoproterozoic age,
named as Bomdila mylonitic gneiss (BMG) and a small body of hornblende bearing granite of Mesoproterozoic age known as Salari
granite (SG). The BMG is affinity to peraluminous (A/CNK > 1.1) with high content of SiO2, K2O/Na2O ratio, normative corundum, high ratio of FeOt/MgO in biotite (3.21–5.11) that shows characteristics of S-type granite whereas SG has granodiorite composition with high
Na2O, low K2O, presence of hornblende, normative diopside, low A/CNK ratio (<1.1) and low FeOt/MgO ratio in biotite (1.58–1.60) indicates metaluminous I-type granite affinity. The SG has more fractionated nature of REE
[(Ce/Yb)N = 9.06–18.53] and minor negative Eu anomalies [EuN/Eu* = 0.69–0.94] as compared to BMG which has less fractionation of REE [(Ce/Yb)N = 5.95–9.16] and strong negative Eu anomalies [EuN/Eu* = 0.37–0.43]. Geochemical and petrological studies suggest that the SG and BMG are not genetically related; SG appears
to have derived from igneous source whereas the BMG have been derived from sedimentary source, however these granitoids might
have produced during the same thermal event. 相似文献
7.
Geochemical Characteristics of Cenozoic Basaltic High-K Volcanic Rocks from Maguan Area, Eastern Tibet 总被引：3，自引：0，他引：3
The major element, trace element and Nd-Sr isotopic composition of Cenozoic basaltic volcanic rocks from the Maguan area, eastern Tibet, indicates that the volcanic rocks are enriched in alkalis, especially K (K2O up to 3.81%) and depleted in Ti (TiO2 = 1.27%-2.00%). These rocks may be classified as two groups, based on their Mg# numbers: one may represent primary magma (Mg# numbers from 68 to 69), and the other, the evolved magma(Mg# numbers from 49 to 57). Their REE contents are very high (∑REE = 155.06-239.04μg/g). Their REE distribution patterns are of the right-inclined type, characterized by LREE enrichment [(La/Yb)N =12.0-19.2], no Ce anomaly (Ce/Ce*=1.0), and weak negative Eu anomaly (Eu/Eu*=0.9). The rocks are highly enriched in Rb, Sr and Ba (59.5-93.8μg/g, 732-999 μg/g, and 450-632 g/g, respectively), high in U and Th (1.59-2.31μg/g and 4.73-8.16 μg/g, respectively), and high in Nb, Ta, Zr and Hf (70-118 μg/g,3.72-5.93 μg/g, 215-381 μg/g, and 5.47-9.03 μg/g, respectively). In the primitive mantle-normalized incompatible element spidergram, Nb, Ta, Zr, Hf and P show positive anomalies, whereas Ba, Ti and Y show negative anomalies. The 87Sr/86Sr ratios range from 0. 704029 to 0.704761; 143Nd/144Nd from 0. 512769 to 0. 512949; and εNd from 2.6 to 6.1. These geochemical features might suggest that the potential source of the basaltic high-K volcanic rocks in the Maguan area is similar to the OIB-source mantle of Hawaii and Kergeulen volcanic rocks. 相似文献
8.
河南舞阳地区赵案庄铁矿床成矿时代及地质意义——中国最古老的岩浆型铁矿床 总被引：1，自引：0，他引：1
河南舞阳地区赵案庄铁矿床是产于超基性岩中的隐伏矿床。超基性岩侵位于新太古界太华群赵案庄组透辉斜长角闪片麻岩中。矿体呈似层状,具有多层。矿石成分较复杂,主要矿物为磁铁矿、蛇纹石、氟磷灰石等。矿床规模为中等,其成因是与超基性岩有关的岩浆晚期磷灰石-磁铁矿矿床。在磷灰蛇纹磁铁矿石中选出的锆石样品为变质锆石,利用激光烧蚀多接收器电感耦合等离子体质谱仪(LA-MC-ICPMS)进行微区原位U_Pb同位素测年,获得不一致线的上交点年龄为(1943±5)Ma(MSWD=2.3)。同时对锆石阴极发光(CL)图像研究,表明该年龄代表锆石遭受强烈变质作用的年龄,可以限定矿体形成时代的上限,即矿体形成时代不晚于1943 Ma。超基性岩浆演化晚期,岩浆充填构造裂隙呈透辉石岩脉产出。透辉石脉与矿体同期并且穿切铁山庙组BIF型铁山铁矿。铁山庙组形成时代在2300~2500 Ma之间。透辉石岩脉形成时代不早于该组年龄,可作为赵案庄铁矿床形成时代的下限。赵案庄铁矿床的形成时代为1943~2300 Ma,为古元古代,这是中国目前发现的最古老的岩浆型铁矿床。该成矿地质时代反映了在华北陆块东南缘曾发生过一次地壳扩张和裂陷活动及华北克拉通裂解事件。 相似文献
9.
Preliminary studies have shown that REE geochemical characteristics are useful criteria to discriminate the two types of granitic
rocks in Jiangxi Province. They are also of significant indication of metallization.
The principal REE geochemical indices are ΣREE, ΣCe/ΣY andδEu, as well as REE distribution pattern. Each of the two types of granitic rocks has a metallogenic evolutionary series of
its own with a successive decrease inδEu.
The application of REE geochemistry in the study of petrogenesis and ore genesis has been receiving increasing attention.
As will be shown in this paper, REE geochemical characteristics, especially ΣREE, ΣCe/ΣY,δEu and REE distribution pattern, are efficient indicators for distinguishing between the two series of granitic rocks in Jiangxi,
and thus enable us to have a better understanding of the ore-forming processes in this region. 相似文献
10.
The metamorphic belt in central Jiangxi, located in the compound terrain within the Cathaysia, Yangtze Block and Caledonian fold zone of South China, is composed dominantly of meta-argillo-arenaceous rocks, with minor amphibolite. These rocks underwent amphibolite-facies metamorphism. The meta-argillo-arenaceous rocks show large variations in major element composition, but have similar REE patterns and trace element composition, incompatible element and LIE enrichments [ high Th/Sc (0.57-3.59) , La/Sc ( 1.46 - 12.4), La/Yb (5.84 - 19.0) ] and variable Th/U ratios, with ∑REE = 129-296μg/g, δEu =0.51 -0.86, and (La/Yb)N = 3.95 -12.9. The Nd isotopic model ages tDM of these rocks vary from 1597 to 2124 Ma. Their 143 Nd/144 Nd values are low [εNd (0) = - 11.4 to -- 15.8]. Some conclusions have been drawn as follows: (1) The metamorphic rocks in central Jiangxi Province are likely formed in a tectonic environment at the passive continental margin of the Cathaysia massif. (2) The metamorphosed argillo-arenaceous rocks are composed dominantly of upper crustal-source rocks (Al- and Krich granitic or/and sedimentary rocks of Early Proterozoic), which experienced good sorting, slow deposition and more intense chemical weathering. (3) According to the whole-rock Sm-Nd isochron ages (1113±49 to 1199 ± 26 Ma) of plagioclase-amphibole (schist) and Nd isotopic model age tDM ( 1597 - 2124Ma) of meta-argillo-arenaceous rocks, the metamorphic belt in central Jiangxi Province was formed during the Middle Proterozoic ( 1100 - 1600 Ma). 相似文献
11.
The Tanami Region, a poorly exposed, mostly Paleoproterozoic province within the North Australian Craton, hosts a number of
significant gold deposits in diverse settings. Rare exposures of 2,520–2,500 Ma amphibolite facies Archean gneiss and metasedimentary
rocks form basement to the thick overlying metasedimentary succession of the 1,880–1,830 Ma Tanami Group. The basal unit of
the Tanami Group is the Dead Bullock Formation, a fining-upward deep-water succession dominated by siltstone, carbonaceous
siltstone, iron-rich siltstone and mafic sills. Carbonaceous- and iron-rich lithologies in the upper Dead Bullock Formation
represent important hosts for gold mineralization. The conformably overlying Killi Killi Formation represents turbiditic sedimentary
rocks that are correlated with the widespread Lander Rock beds of the Arunta Region. Sedimentation of the Tanami Group was
terminated by regional deformation and greenschist to amphibolite facies metamorphism during the Tanami Event (D1/M1), at around 1,830 Ma. The Tanami Group is unconformably overlain by rhyolite, siliciclastic sedimentary rocks, and felsic
ignimbrite of the Ware Group that were deposited at about 1,825–1,810 Ma. Subsequent ESE–WNW to SE–NW directed shortening
(D2), followed by NE–SW to E–W directed shortening (D3), has resulted in open NE F2- and NW F3-trending folds in both the Tanami and Ware Groups. Voluminous granitoids, dominated by I-type, biotite granodiorite, and
monzogranite were intruded in the interval 1,825–1,790 Ma and have been subdivided using geochemical criteria into the Birthday,
Frederick, and Grimwade Suites. Basalt and immature sedimentary rocks of the Mount Charles Formation are restricted in extent
to the Tanami mine corridor, and are interpreted to reflect a continental rift succession that was deposited around 1,800 Ma,
with an early Archean sedimentary provenance. Steep S to SE dipping F4-fold structures of Tanami and Ware Group metasedimentary rocks, many spatially associated with 1,825–1,790 Ma granitoid intrusions,
indicate a period of SSE-directed regional shortening (D4) syn-to-post the regional granitoid intrusive phase. A network of N to NW striking faults, several of which are interpreted
as oblique thrusts with a component of left lateral movement, indicates a period of D5 convergence during WSW–ENE to E–W directed shortening. The Tanami mine corridor fault system comprises a network of N, NE
to ENE striking D5 faults that merge with N to NW striking faults and probably accommodated movement between granite core domains. D5 faulting is associated with the main phase of gold mineralization in suitable structural–lithological traps. The Paleoproterozoic
basement of the Tanami Region is unconformably overlain by quartz sandstone, lithic arenite, and conglomerate of the Pargee
Sandstone. Pargee Sandstone may represent syn-tectonic sedimentation related to the 1,730 Ma Strangways Orogeny, and is unconformably
overlain by the late Paleoproterozoic platform cover succession of the Birrindudu Group. The Paleoproterozoic basement and
cover sequences have subsequently undergone several episodes of faulting, collectively termed D6+. The Paleoproterozoic evolution of the Tanami Region is interpreted to have occurred in an intracratonic setting, but was
fundamentally influenced by tectonic events in the adjacent Halls Creek Orogen (1,835–1,805 Ma Halls Creek Orogeny) and Arunta
Region (1,815–1,800 Ma Stafford Event). The boundaries between the Tanami Region and Kimberley Region to the northwest and
the Arunta Region to the southeast are transitional, and are largely defined by the presence or absence of identifiable Dead
Bullock Formation. 相似文献
12.
This paper aims to discuss the depositional settings and provenances for the Jurassic in Jiyuan basin, North China, based on the rare earth element (REE) and trace element features of 16 Jurassic argillaceous rock samples from the Anyao, Yangshuzhuang and Ma’ao Formations, respectively. Generally, geochemical analysis results show that chondrite-normalised REE distribution patterns of all the three formations are characterised by light-REE (LREE) enrichment, moderately negative Eu anomalies, slightly negative Ce anomalies, and strong fractionation between LREE and heavy-REE (HREE). Trace element proxies V/(V + Ni), Ce anom index, Ce/La, Sr/Ba, and Sr/Cu indicate a weak oxidation–reduction environment, progressively decreasing reducibility and water depth from the bottom up during Jurassic in Jiyuan basin. Palaeoclimate varied from humid in the Early Jurassic to arid in the Middle Jurassic, corresponding with the variations of palaeoredox and palaeosalinity. The provenances of Jurassic rocks in Jiyuan basin are mainly from felsic sources related to active continental margin and continental island arc. The Early–Middle Jurassic (Anyao and Yangshuzhuang Formations) provenances are mainly derived from North Qinling and partially from the eroded recycled felsic sedimentary covers of Taihang Mountain. In the late stage of Middle Jurassic (Ma’ao Formation), Taihang Mountain has been the primary source to Jiyuan basin. We conclude that the Jurassic rocks of Jiyuan basin reveal the progressive uplift and denudation processes of the Taihang Mountain. 相似文献
13.
Adel A. A. Abdel Wahed Khaled G. Ali Magdy M. A. Khalil Ahmed E. Abdel Gawad 《Arabian Journal of Geosciences》2012,5(1):29-44
The Dokhan volcanics are represented by a thick stratified lava flows succession of basalt, andesite, imperial porphyry, dacite,
rhyodacite, rhyolite, ignimbrites, and tuffs. These lavas are interbanded with their pyroclastics in some places including
banded ash flow tuffs, lithic tuffs, crystal lapilli tuffs, and agglomerates. They are typical calc–alkaline and developed
within volcanic arc environment. All rocks show moderate enrichment of most large ion lithophile elements relative to high
field strength elements (HFSE). The incompatible trace elements increase from basalt through andesite to rhyolite. The felsic
volcanics are characterized by moderate total rare earth elements (REE) contents (162 to 392 ppm), less fractionated patterns
{(Ce/Yb)N = (1.24 to 10.93)}, and large negative Eu anomaly {(Eu/Eu*) = (0.15 to 0.92)}. The mafic volcanics have the lowest REE contents
(61 to 192 ppm) and are relatively steep {(Ce/Yb)N = (3.2 to 8.5)}, with no negative Eu anomalies {(Eu/Eu*) = (0.88 to 1)}. The rhyolite displays larger negative Eu anomaly
(Eu/Eu* = 0.28) than those of other varieties, indicating that the plagioclase was an early major fractionating phase. The
mineralogical and chemical variations within volcanics are consistent with their evolution by fractional crystallization of
plagioclase and clinopyroxene. 相似文献
14.
Characteristics of magmatic rocks and tectonic setting of Mazhuangshan area, East Tianshan, China 总被引：1，自引：1，他引：0
The Mazhuangshan area lies in northeast to Aqikekuduke,where are distributed in-termediate-acid rocks,which were formed in the Middle-Late Carboniferous epoch.The magmatic rocks are peraluminous and belong to calcareous series.All values of ACNK(1.03-2.12),ANK(1.67-2.93),SI(4.1-33),δ(0.71-4.82),La/∑REE(0.09-0.26) ∑LREE/∑HREE(1.76-11.01),(La/Sm)N(1.60-6.35),(Sm/Nd)N(0.33-0.58),(La/Yb)N(4.7-12.1),LaN/Lux(5.9-11.8),(Ce/Yb)N(3.14-6.64),δEu(0.38-1.06),RbN/SrN(41-120)and Sr(0.02-0.2)demonstrate they vary with D_I(45-90).S-B diagram also shows that the lithophile elements are abundant in acidic magmatic rocks,Moreover,it is concluded that the primitive magma originated from a subduction zone at the continental edge,and underwent fractional crystallization and contamination,then generated the magmatic rocks,The multi-cation index(R:3055-3993,R2:286-438) shows that the primitive magma originated from the mantle,All these conclusions are beneficial for exploring gold deposits in the area. 相似文献
15.
The accessory minerals apatite and sphene are the main carriers of REE in alkaline rocks.Their chondrite-normalized REE patterns decline sharply to the right as those of the host rocks,In the patterns an obvious negative Eu anomaly and a positive Ce anomaly can be seen in apatite and sphene,respectively.Zircon from alkaline rocks is different in REE pattern,I,e,. a nearly symmetric“V“-shaped pattern with a maximum negative Eu anomaly.Compared with the equivalents from granites,apatite,sphene and zircon from alkaline rocks are all characterized by higher (La/Yb)N ratio and less Eu depletion,As to the relative contents of REE in minerals,apatite,sphene and zircon are enriched in LREE,MREE and HREE respectively,depending on their crystallochemical properties. 相似文献
16.
N. B. Kuznetsov S. Yu. Orlov E. L. Miller A. V. Shazillo A. V. Dronov A. A. Soboleva O. V. Udoratina G. Gehrels 《Doklady Earth Sciences》2011,438(2):759-765
The first results of U/Pb isotopic dating (LA ICP MS) of detrital zircons from sands from the Middle Cambrian Sablinka Formation,
Upper Cambrian Ladoga Formation, Low Ordovician Tosna Formation, and calcareous sands from Syas’ Formation (Sargaevskii horizon
of the Upper Frasnian) from Baltica-Ladoga Glint (BLG) of the Southern Ladoga area are presented. The obtained ages of detrital
zircons span the intervals 492.7 ± 5.1-3196.4 ± 5.1 Ma (Sablino Formation); 577.9 ± 7–2972.6 ± 13.4 Ma (Ladoga Formation);
509.4 ± 8.5–3247.6 ± 10.1 Ma (Tosna Formation); 451.1 ± 14.7–2442.2 ± 6.9 Ma (Syas’ Formation). A comparison of the obtained
isotopic ages of detrital zircons to ages of crystalline complexes composing the Kola-Karelian, Svecofennian, and Sveconorwegian
domains of Baltic Shield and Pre-Uralian-Timanian structures of Subpolar and Polar Urals and basement of Pechora Basin was
carried out. It is proposed that the Middle Paleozoic sedimentary basin accumulated Upper Frasnian rocks of Syas’ Formation.
The basin ranged northward from the present-day BLG and occupied the eastern part of the Baltic Shield. 相似文献
17.
John K. Zachariah V. Rajamani Gilbert N. Hanson 《Contributions to Mineralogy and Petrology》1997,129(1):87-104
The N–S trending, 2–4 km wide Ramagiri schist belt is made up of three blocks dominated by metavolcanic rocks, separated
and surrounded by granitic rocks of distinct characteristics. The metavolcanic rocks are tholeiitic in composition and are
very similar in their major element composition as well as in their abundances of some trace elements. However, the rare earth
elements (REE) require distinct sources. The rocks of the amphibolite facies eastern block have LREE depleted REE patterns
([Ce/Yb] = 0.7–0.9), requiring derivation from depleted mantle-like sources. The greenschist facies metatholeiitic rocks of
the central block have LREE enriched REE patterns ([Ce/Yb] = 3–6), reflecting the nature of their source(s). The Nd isotopic
data require that the LREE enriched nature could not have been attained significantly prior to its melting. The fine-grained,
upper greenschist facies metatholeiites of the western block have flat to slightly LREE depleted patterns ([Ce/Yb] = 0.8–0.95).
Minor fractional crystallization of rock forming minerals may relate a few samples to each other among samples from each of
the three blocks. Different extents of partial melting of distinct mantle sources have played a dominant role in the generation
of the parent magmas to the central versus eastern and western block metatholeiites.
The geochemical data suggest that the mantle sources were non-lherzolitic, and that these sources may have seen previous episodes
of melt addition and extraction prior to melting that gave rise to the parent melts to the rocks ∼2750 Ma ago. The REE data
indicate that while the sources of the eastern and western block rocks were similar to depleted mantle (ɛNd(
i
) about +2), the source of the central block rocks (ɛNd(
i
) about +3.5) were enriched in large ion lithophile element (LILE)-rich fluids/melts probably derived from subducting oceanic
crust. This and other trace element signatures point to magma extraction in tectonic settings similar to modern island arcs.
Subsequent to magma emplacement and crystallization, all the three suites of rocks were affected by interaction with low-temperature,
crustal derived fluids (ɛNd 2750Ma of about −8 to −12), probably during the accretion of the three blocks of the belt in the present form. The inferred source
characteristics, tectonic setting of magma generation and the crustal fluid processes seem to suggest that Phanerozoic-style
tectonic processes may have been important in the generation of Archean crust in the Dharwar craton.
Received: 31 July 1995 / Accepted: 12 May 1997 相似文献
18.
对内蒙古阿巴嘎旗甘珠音敖包地区中生代火山岩进行了锆石U-Pb测年和岩石地球化学研究,对其形成时代、岩石成因及构造背景给予制约。研究区主要发育中生代满克头鄂博组酸性火山岩和梅勒图组中性火山岩。LA-ICP-MS锆石U-Pb同位素定年结果显示,2组火山岩形成年龄分别为163.6±0.6Ma和139.6Ma±0.7Ma。岩石地球化学研究表明,满克头鄂博组酸性火山岩为碱性系列,具有高硅、富碱、低TFeO、Al_2O_3、TiO_2、MgO、CaO和Na_2O的特征,轻稀土元素富集、重稀土元素亏损、轻重稀土元素分馏明显,Eu强烈亏损,大离子亲石元素Rb、Th、K明显富集,Ba、Sr明显亏损,高场强元素Nb、Ta、P、Ti强烈亏损,具有A型花岗岩特点,形成于陆壳岩石的部分熔融。梅勒图组中性火山岩亦为碱性系列岩石,富碱、富钠、贫钾,高Al2O3、TiO2、MgO,贫CaO,LREE富集,HREE亏损,轻重稀土元素分馏明显,具微弱的负Eu异常,富集大离子亲石元素(LILEs)Rb、Ba、Th、U、K等,亏损高场强元素Nb、Ta、Ti、Y、Yb、Lu等,来源于下地壳镁铁质岩石部分熔融。结合岩石学及该地区构造背景特征,认为满克头鄂博组和梅勒图组火山岩可能形成于蒙古-鄂霍茨克的俯冲作用导致的大兴安岭西坡—冀北—辽西地区加厚陆壳坍塌或拆沉作用的伸展环境。 相似文献
19.
The Duolanasayi gold deposit, 60 km NW of Habahe County, Xinjiang Uygur Autonomous Region, is a mid-large-scale gold deposit controlled by brittle-ductile shearing, and superimposed by albitite veins and late-stage magma hydrothermal solutions. There are four types of pyrite, which are contained in the light metamorphosed rocks (limestone, siltstone), altered-mineralized rocks (chlorite-schist, altered albite-granite, mineralized phyllite), quartz veins and carbonatite veinlets. The pyrite is the most common ore mineral. The Au-barren pyrite is present mainly in a simple form and gold-bearing pyrite is present mainly in a composite form. From the top downwards, the pyrite varies in crystal form from {100} and {210} {100} to {210} {100} {111} to {100} {111}. Geochemical studies indicate that the molecular contents of pyrite range from Fe1.057S2 to Fe0.941S2. Gold positively correlates with Mn, Sr, Zn, Te, Pb, Ba and Ag. There are four groups of trace elements: Fe-Cu-Sr-Ag, Au-Te-Co, As-Pb-Zn and Mn-V-Ti-Ba-Ni-Cr in pyrite. The REE characteristics show that the total amount of REE (ΣREE) ranges from 32.35×10 -6 to 132.18×10 -6; LREE/HREE, 4.466-9.142; (La/Yb)N, 3.719-11.133; (Eu/Sm)N, 0.553-1.656; (Sm/Nd)N, 0.602-0.717; La/Yb, 6.26-18.75; δEu, 0.628-2.309; δCe, 0.308-0.816. Sulfur isotopic compositions (δ 34S=-2.46‰--7.02‰) suggest that the sulfur associated with gold mineralization was derived from the upper mantle or lower crust. 相似文献
20.
LAI Shaocong QIN Jiangfeng LI Yongfeng LIU Xin 《中国地球化学学报》2007,26(3):305-311
Neogene volcanic rocks in the Belog Co area, Qiangtang, northern Tibet, are represented by a typical intermediate-basic and intermediate alkaline rock association, with latite-trachyte as the main rock type. The results of chemical analysis are: SiO2=52%–62%, Al2O3>15%, Na2O/K2O>1 and MgO<3.30%. In addition, the volcanic rocks are LREE-enriched with LREE/HREE=10–13, (La/Yb)N=15–19, and show a weak negative Eu anomaly with δEu=0.71–0.89. The close relationship between Mg# and SiO2 and the co-variation of the magmatophile elements and ultra-magmatophile elements such as La/Sm-La and Cr-Tb indicate that this association of volcanic rocks is the product of comagmatic fractional crystallization. The rock association type and lower Sm/Yb values (Sm/Yb=3.23–3.97) imply that this association of volcanic rocks should have originated from partial melting of spinel lherzolite in the lithospheric mantle. On the other hand, the weak negative Eu anomaly and relative depletion in Nb, Ta and Ti reflect the features of terrigenous magma. So the Neogene Belog Co alkaline volcanic rocks should be the result of partial melting of the special crust-mantle transition zone on the Qinghai-Tibet Plateau. 相似文献