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1.
洪涛  游军  吴楚  徐兴旺 《岩石学报》2015,31(9):2583-2596
扬子板块西缘滇西地区是否存在古老基底一直存在争议。本文对滇西桃花地区花岗斑岩进行了岩石学、地球化学和锆石SHRIMP U-Pb年代学研究。形成于晚造山-后碰撞背景的桃花花岗斑岩具岛弧花岗岩地球化学特征,其成因可能与:1)俯冲拆离的洋壳俯冲拆离的洋壳或富集地幔重熔作用;2)加厚的地壳部分熔融。花岗斑岩中的继承锆石有两种类型:一类是发育具有密集振荡环带的岩浆锆石;另一类是次浑圆状锆石。测年结果显示,花岗斑岩的岩浆锆石年龄为36.35±0.35Ma,环带发育的继承锆石年龄介于167~891Ma之间;而次浑圆状继承锆石可以分为两组,其207Pb/206Pb加权平均年龄分别为1851±22Ma与2499±32Ma。新的锆石测年结果表明着滇西桃花地区不仅存在古金沙江洋东向俯冲形成的晚古生代弧岩浆记录,还发现新元古代岩浆活动信息,及早古元古代和新太古代的锆石记录。推测1.8Ga与2.5Ga锆石可能是捕获自地壳或围岩(石鼓片岩),表明滇西地区可能存在古老基底。  相似文献   

2.
赵苗  杨竹森  张洪瑞 《地球科学》2019,44(6):2187-2196
伊朗乌尔米耶-达克塔尔弧岩浆带(Urumieh-Dokhtar magmatic arc,UDMA)是特提斯域最重要的斑岩铜矿省,发育大量中新世大型超-大型斑岩铜矿床;同时,该带也发育大量同时代无矿岩体,但控制岩体成矿潜力的关键因素尚不清楚.为此,选择该带中段、成矿及无矿岩体同时发育的大理矿区,针对成矿及无矿岩体开展了系统的锆石岩相学、年代学、微量元素地球化学及Hf同位素地球化学对比.结果显示,无矿闪长岩(锆石U-Pb年龄:17.4±0.3 Ma)比成矿石英闪长斑岩(锆石U-Pb年龄:15.6±0.1 Ma)形成略早,但近乎同期;闪长岩εHf(t)值变化介于+2^+4,石英闪长斑岩εHf(t)值变化介于+2^+5,两者具有类似的Hf同位素组成;闪长岩中锆石常含老的继承核(172~920 Ma),石英闪长斑岩则不发育继承锆石;闪长岩及石英闪长斑岩中的中新世锆石具有类似的稀土配分模式,且Eu负异常不明显,而闪长岩中的锆石继承核则显示出明显的Eu负异常,配分模式与中新世锆石不同.基于上述结果,我们提出大理矿区的两套中新世岩体具有相同的岩浆源区,但经历了不同的地壳演化过程,成矿的石英闪长斑岩浆形成后,与古老地壳没有明显交互,而无矿的闪长岩浆,在上升过程中与地壳物质、特别是古老还原性物质发生了交互,交互过程中岩浆氧逸度降低,是该套岩浆不成矿的主要原因.进而我们提出UDMA带中段斑岩成矿与否不仅与前人所认为的受岩浆源区控制,也与岩浆演化过程密不可分.  相似文献   

3.
对金沙江缝合带东侧雪鸡坪同碰撞石英闪长玢岩进行了岩石学、岩石化学、稀土元素、锆石SHRIMPU-Pb定年等研究,石英闪长玢岩锆石SHRIMPU-Pb年龄为215Ma。结合前人的资料,认为金沙江洋盆闭合、板块碰撞的时间应为266Ma,碰撞阶段的年龄范围为266~215Ma。对无老核的岩浆型锆石的形成条件、结构简单的典型纯岩浆型锆石定年的测试点数量等方面也进行了讨论。  相似文献   

4.
滇西北中甸松诺含矿斑岩的锆石SHRIMP U-Pb年龄及地质意义   总被引:9,自引:1,他引:8  
位于义敦岛弧南端的中甸岛弧中广泛发育印支期斑岩及斑岩型和矽卡岩型铜矿床。松诺(或称松诺力赞)复式岩体位于东斑岩带中部,由石英闪长玢岩、黑云石英二长斑岩、闪长玢岩和含矿石英二长斑岩组成,其南部为普朗超大型斑岩铜矿床,北部为地苏嘎铜矿点。本文对含矿石英二长斑岩进行了岩相学和锆石SHRIMPU-Pb定年研究,结果表明所有锆石颗粒自形较好且均发育规则的韵律环带,Th含量为180~854μg/g,U含量为270~709μg/g,Th/U比值为0.77~1.24,为典型岩浆成因锆石。获得了含矿石英二长斑岩的侵位年龄为220.9±3.5Ma(n=9,MSWD=1.6),这与中甸岛弧洋壳俯冲造山作用的时限(210~235Ma)相吻合。  相似文献   

5.
东准噶尔琼河坝桑德乌兰斑岩铜钼矿区含矿花岗斑岩透长石、石英斑晶粒内破裂构造发育,锆石普遍发育具核内破裂构造或碎裂状的核。破碎的锆石核与透长石、石英斑晶可能形成于深部岩浆房。锆石U-Pb定年结果显示,破碎变形的锆石核年龄为442.2±3.5Ma,锆石环带的年龄为412.7±3.3Ma,前者代表破碎变形锆石的形成时间,后者代表斑岩侵位与结晶的时间。Hf同位素结果显示,破碎的有核锆石与其外环带具一致的εHf(t)初始值与tDM2模式年龄,它们可能为同一岩浆或成因相同的岩浆不同阶段结晶的产物。这意味着琼河坝地区在早古生代(至少在442Ma)就开始有弧岩浆活动。幔源特征的εHf(t)值(10.3~15.1)与较老的模式年龄(tDM2=469~761Ma)显示形成研究区花岗斑岩的岩浆可能源于晚元古代-奥陶纪玄武质地壳的部分熔融。  相似文献   

6.
江家等系列花岗闪长斑岩是皖南祁门县东源钨钼矿区含矿岩体的组成部分,位于东源花岗闪长岩的西侧。对江家和方村花岗闪长斑岩进行的SHRIMP锆石U-Pb测年结果表明,江家、方村花岗闪长斑岩的结晶年龄为149~152Ma,与富钨的东源花岗闪长岩相近。岩石地球化学和锆石Hf同位素分析显示,江家等系列花岗闪长斑岩源区具有复杂的多成分端元,其中老锆石核的正εHf值反映了成岩岩浆对晋宁期岩浆岩的继承,震荡岩浆环带的负εHf值(-39.5~-2.86)指示源区的主要成分为古老的地壳物质,有少量地幔物质的混染。全岩锆石饱和温度(737~913°C)显示岩浆组成中有幔源物质的贡献。  相似文献   

7.
江家等系列花岗闪长斑岩是皖南祁门县东源钨钼矿区含矿岩体的组成部分,位于东源花岗闪长岩的西侧。对江家和方村花岗闪长斑岩进行的SHRIMP锆石U-Pb测年结果表明,江家、方村花岗闪长斑岩的结晶年龄为149~152Ma,与富钨的东源花岗闪长岩相近。岩石地球化学和锆石Hf同位素分析显示,江家等系列花岗闪长斑岩源区具有复杂的多成分端元,其中老锆石核的正εHf值反映了成岩岩浆对晋宁期岩浆岩的继承,震荡岩浆环带的负εHf值(-39.5~-2.86)指示源区的主要成分为古老的地壳物质,有少量地幔物质的混染。全岩锆石饱和温度(737~913°C)显示岩浆组成中有幔源物质的贡献。  相似文献   

8.
湘中锡矿山矿区煌斑岩中捕获锆石U-Pb定年及其地质意义   总被引:1,自引:0,他引:1  
利用LA-ICP-MS技术,对湘中锡矿山煌斑岩中的锆石进行U-Pb同位素定年。研究表明,该煌斑岩中的锆石呈半自形或半浑圆状,为捕获锆石。锆石阴极发光图像显示有典型的振荡环带和韵律结构,部分还可见扇形分带,其形貌和地球化学特征均显示为岩浆成因。锆石U-Pb同位素年龄主要集中在830 Ma和800 Ma附近,少量为~730 Ma,与江南古陆前寒武纪浅变质岩的年龄十分吻合,揭示湘中盆地深部确实存在新元古界基底,这为示踪湘中锑矿的成矿物质来源和判别湘中地区大地构造环境提供了新的依据。锡矿山煌斑岩形成于一种拉张伸展的构造环境中,其侵位深度为5 km以上。  相似文献   

9.
对乌拉特中旗德尔斯地区黑云母二长花岗岩岩相学、锆石SHRIMP U-Pb年代学和岩石地球化学进行了研究,并讨论了岩石成因及研究区晚海西期构造演化。黑云母二长花岗岩发育两期:早期为中粗粒斑状黑云母二长花岗岩,晚期为中细粒黑云二长花岗岩。岩石中的锆石大部分具核-边结构:边部震荡环带发育,Th/U值为0.16~0.50,反映了岩浆成因;核部呈浑圆状,多数具岩浆环带,个别弱分带-无分带,Th/U值为0.06~0.44,表明核部大部分属岩浆型残留锆石,个别为变质型残留锆石。测年结果显示:边部锆石加权平均年龄为早、中二叠世((279±3) Ma、(266±3) Ma),代表黑云母二长花岗岩形成时代;核部残留锆石加权平均年龄为(1 972±63) Ma 、(1 962±43) Ma,代表源岩的形成时代。岩石属于亚碱性系列,REE配分形式呈右倾型,LREE/HREE为5.86~22.81,明显亏损高场强元素Nb,富集大离子亲石元素Rb、Ba,显示活动大陆边缘火成岩的地球化学特征。黑云母二长花岗岩地球化学属性反映了早、中二叠世古亚洲洋向华北板块北缘的俯冲作用及古亚洲洋消亡的演化历史。  相似文献   

10.
采用高精度离子探针(SHRIMP)测年方法对西藏念青唐古拉山英云闪长质和石英闪长质正片麻岩中锆石的成因和形成时代进行了研究。在阴极发光图像中,片麻岩中的锆石具有较好的晶形,并显示出清晰的岩浆锆石韵律环带结构。离子探针分析表明,片麻岩中的锆石具有高的Th/U比值。对2颗片麻岩中的锆石进行了离子探针U-Pb测年,测得英云闪长质和石英闪长质片麻岩中的锆石206Pb/238U结晶年龄分别为58.5Ma±0.7Ma和63.5Ma±0.8Ma。这一结果意味着念青唐古拉山正片麻岩形成于安第斯型的冈底斯岩浆作用期间。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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