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为深入探讨贵州道真新民铝土矿床的成矿物质来源、成矿环境及成矿地质作用，并建立成矿地质作用模型,本文对研究区地质特征及含铝岩系、底板黄龙组、韩家店组岩（矿）石的地球化学特征进行研究。研究结果表明：铝土矿Al2O3、TiO2、Ga/Al2O3含量与韩家店组泥页岩非常接近，含铝岩系稀土元素总量、配分曲线及δEu与韩家店组泥页岩最为接近，Zr-Cr-Ga三角图解显示该矿床含铝岩系与韩家店泥页岩分布位置接近，均落于中性或泥质母岩区；含铝岩系MnO/TiO2比值低，Ga含量高，Sr/Ba值低，显示矿床形成于陆相沉积环境，V/Zr值显示矿床具有海相沉积特征；含铝岩系具Ce正异常，Th/U值介于2～7之间，Be含量低，表明研究区铝土矿经历了风化作用、沉积作用；研究区铝土矿中的一水铝石是由三水铝石演化而成，经历了成岩后生压实脱水作用；通过研究区地表矿石与深部矿石主要化学成分对比，说明铝土矿经历后期表生淋滤作用。综合矿床地质地球化学特征，认为新民铝土矿成矿物质来源于下伏韩家店组泥页岩；成矿环境为陆相河湖环境，其沉积时曾有海水侵入；母岩演化为铝土矿的过程经历风化作用、搬运沉积作用、成岩后生作用、后期表生作用等一系列成矿地质作用。 相似文献
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贵州务川一正安一道真（务一正一道）铝土矿属于古风化壳沉积型铝土矿床,是黔中一渝南铝土矿成矿带的重要组成部分。铝土矿产于中下志留系韩家店组（S1-2hj）泥页岩或上石炭统黄龙组（C2h）灰岩的侵蚀面上,含矿层位为中二叠统梁山组（P21）。根据元素地球化学特征及相关分析表明,Ti、zr、Nb、cr、Th、Ga、Hf、Ta及V在铝土矿矿化过程中均为不活动元素。特别是Ti在铝土矿矿化过程中性质最稳定,故可对其用于质量平衡的计算。铝土矿化过程中一些元素的质量变化可以通过不活动元素在铝土矿（岩）和中下志留系韩家店组（s1-2。hj）泥页岩中的含量变化来估算。计算结果显示,大多数活动元素从铝土矿体系中移走,部分Si、Mg、K、Fe以及少量的弱活动性AJ向下渗透,并沉淀为伊利石（绢云母、绿泥石）、赤铁矿和石英或非晶体硅。通过系统研究和质量平衡计算,可初步确定SI1-2hj泥页岩为务一正一道铝土矿主要的成矿原岩。 相似文献
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贵州务正道地区铝土矿床稀土元素组成及地质意义 总被引：2，自引：0，他引：2
稀土元素(REE)是一组具有相同地球化学性质和特殊地球化学属性的指示性元素。务正道地区主要矿床稀土元素组成显示出,矿层和下伏志留系韩家店组地层稀土元素总量、配分模式基本一致,相关性较好,揭示铝土矿成矿物源与下伏志留系韩家店组有成因联系;矿层和韩家店组LREE/HREE均大于1,轻稀土富集较强烈,而重稀土不同程度亏损;(La/Ce)N平均0.87,总体较低;δCe平均1.22,为弱-中等比值,表明铝土矿物源主要来自陆源,沉积环境主要为陆相沉积,局部为海相沉积;主要层位(La/Sm)N>(Gd/Yb)N,说明轻重稀土元素分异较好;稀土元素富集对岩性有选择性,在矿层及富含绿泥岩、粉砂质页岩的志留系韩家店组地层中强烈富集,在石炭系黄龙组白云质灰岩及二叠系栖霞组灰岩中贫化。 相似文献
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三论贵州之铝土矿——贵州北部铝土矿成矿时代、物质来源及成矿模式 总被引：4，自引：1，他引：4
大量地层、古生物资料表明,道真、正安、务川及川南一带铝土矿的成矿时代属晚石炭世。地质和地球化学研究结果认为,铝土矿的成矿物质来源于下志留统韩家店群的水云母泥、页岩。成矿模式反映了铝土矿大致于晚泥盆世晚期至早石炭世早期红土化、晚石炭世搬运—沉积以及后来的成岩—后生作用和表生作用等阶段的演化历程。 相似文献
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贵州务川瓦厂坪铝土矿床地球化学特征 总被引：8，自引：0，他引：8
务川瓦厂坪铝土矿床是近年探明的大型矿床,332+333资源量4397万吨.地球化学研究显示,矿床中Al_2O_3与TiO_2含量成正相关关系,与SiO_2含量成负相关关系;硫同位素组成属于沉积岩范畴,总体显示出变化范围大(-29.20‰～+12.40‰),反映出复杂的成矿环境和轻重硫同位素的多次分离;不同岩、矿石的稀土总量(∑REE)含量变化大,LREE/HREE均大于1,显示轻稀土较富集;铝土矿层中,土状铝土矿稀土元素含量相对高,致密块状铝土矿含量相对低,稀土元素含量与矿石质量总体呈正相关关系.铝土矿层及志留系韩家店组的稀土总量含量较接近.矿床成因属古风化壳沉积型. 相似文献
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黔北务川瓦厂坪铝土矿床元素迁移规律研究 总被引：6，自引：0，他引：6
黔北务正道地区铝土矿矿床属古风化壳沉积型,成矿母岩具多源性,但主要来源于下覆的中下志留统韩家店组。本文依据Grant提出的质量平衡方程和图解法,对瓦厂坪矿床在成矿过程中元素迁移的富集、贫化（亏损）规律进行了定量研究。结果表明,主要成矿母岩韩家店组砂、页岩一中间产物铝土质页岩、粘土岩是主要元素A12O3、TiO2显著富集... 相似文献
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重庆大佛岩铝土矿床位于渝南黔北成矿带内.铝土矿含矿岩系分布在二叠系栖霞组灰岩或二叠系梁山组炭质页岩之下、志留系韩家店组粉砂质页岩或石炭系黄龙组灰岩之上,为一套含铝黏土岩组合,矿体一般在含矿岩系中部,平面上连续分布;矿石以土状和致密状铝土矿为主,含少量砾屑状和土豆状铝土矿;矿石矿物主要由硬水铝石组成,次为高岭石.通过对含矿岩系微量以及稀土元素的分析,认为重庆大佛岩铝土矿床主要是在弱酸性、氧化环境中形成的具陆相沉积特点的铝土矿床,铝土矿物源主要来自陆源;从含矿岩系中稀土元素与基底页岩中稀土元素相关系数、稀土元素配分模式曲线来看,成矿物质来源主要为下伏志留系韩家店组粉砂质页岩.大佛岩铝土矿床不仅具丰富的铝土矿资源,同时伴生有REO(rare earth oxides)、Ga、Sc、Li以及V等多种有益元素.铝土矿中伴生Ga、V等的综合利用可同主元素铝的利用结合起来,但REO、Sc、Li等因受到多方制约,目前尚无综合开发利用的可行性.因此在开发铝土矿的同时,开展伴生元素综合利用研究具有重要意义. 相似文献
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论述了黔中—川南铝土矿成矿带内早石炭世和晚石炭世铝土矿及其下伏地层的主要化学成分、稀散元素、稀土元素的地球化学特征,进而探讨了铝土矿的成矿母岩———下寒武统、下奥陶统和下志留统的泥、页岩及碳酸盐岩的成矿意义。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
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岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献