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1.
杨智荔  张晓晖  袁玲玲 《岩石学报》2021,37(4):1061-1081
高硅(SiO_2 70%)花岗岩不仅是指示大陆地壳成熟度的重要标志,而且蕴含大陆地壳分异机制和稀有金属元素运移行为的关键信息。跨越辽宁-内蒙古两地分布的白音花岩基是沿华北克拉通与中亚造山带边界断裂带侵位的重要的中生代高硅花岗岩,但其形成时代和岩石地球化学特征一直缺乏系统刻画。本次离子探针(SIMS)锆石U-Pb测年指示该花岗岩岩基于晚侏罗世(162~161Ma)侵位。岩体SiO_2含量介于75.7%~77.3%;钙碱性、贫铁镁、弱过铝;富集Th与U,亏损Ba与Sr;稀土元素总量较低(∑REE=40.2×10-6~117×10~(-6)),Eu负异常明显; Zr/Hf和Nb/Ta分异显著;这些特征契合高分异I型花岗岩的典型元素地球化学行为。同时,白音花花岗岩具有低负的ε_(Nd)(t)值(-3.5~-2.6)以及低正的锆石ε_(Hf)(t)值(+0.1~+5.9)。元素与同位素地球化学示踪指示白音花花岗岩可能源自由中亚造山带型新生安山质地壳与少量古老地壳组成的复合源区,其部分熔融生成的原始酸性岩浆经历结晶分异形成高硅花岗岩。作为记录华北克拉通/中亚造山带边界断裂带晚侏罗世走滑/伸展活动的非造山型钉合岩体,白音花高硅花岗岩见证了蒙古-华北板块有别于早白垩世大规模上地壳伸展构造的中晚侏罗世区域弥散状中下地壳伸展行为。中晚侏罗世和早白垩世两段式地壳伸展轨迹不仅契合蒙古-鄂霍茨克构造域造山后重力垮塌过程,而且是促使新晋蒙古-华北板块大陆地壳垂向分异-成熟的高效途径。  相似文献   

2.
满洲里南部中生代花岗岩的锆石U--Pb年龄及Hf同位素特征   总被引:4,自引:0,他引:4  
满洲里南部地区花岗岩主要由碱长花岗岩、正长花岗岩、二长花岗岩及花岗斑岩组成。采用LA--ICP--MS技术,对满洲里南部花岗岩进行的锆石U--Pb年龄测定表明,该区中生代花岗岩浆活动分为3期:中—晚三叠世(208~239 Ma)、早侏罗世(179~185 Ma)和晚侏罗世—早白垩世(137~151 Ma),与整个大兴安岭中生代花岗岩的年代学格架基本一致,与东部的张广才岭—小兴安岭地区中生代岩浆活动时代也可以对比。锆石LA--MC--ICP--MS Hf同位素研究显示,本区中生代花岗岩的锆石εHf(t)多数为+0.7~+9.5,二阶段模式年龄为0.6~1.2 Ga,表明花岗岩浆主要源于中—新元古代增生的地壳物质。结合额尔古纳地块其他花岗岩的锆石Hf同位素资料,认为额尔古纳地块在中—新元古代时期曾发生一次重要的地壳增生事件,与兴安地块的地壳增生时间为新元古代—显生宙的特点不同。  相似文献   

3.
冀西北张家口地区晚中生代发生了大规模的中酸性岩浆活动,通过精确的锆石 U-Pb 年代学研究,获得东坪金矿东侧北栅子碱性花岗岩的侵位年龄为(130.5±1.5) Ma,其周围出露的张家口组粗面质火山岩的喷发年龄为(127.8±3.9) Ma,为早白垩世同期岩浆作用的产物.这些岩浆岩总体属于高钾钙碱性-钾玄质系列,富碱,低 Mg#(30~43);微量元素组成上具有大离子亲石元素(LILE)、轻稀土元素(LREE)相对富集(ΣLREE/ΣHREE =14.1~23.0,(La/Yb)N =20.8~42.2), Eu 弱负异常(δEu =0.62~0.97),高场强元素(Nb、Ta、Ti和 P)不同程度亏损的地球化学特征,显示出同源岩浆演化的趋势.火山岩和花岗岩(87Sr/86Sr)i 平均值分别为0.7075和0.7078,全岩εNd(t)和锆石εHf(t)值差别明显,火山岩εNd(t)=–15.9~–13.6,εHf(t)=–18.7~–13.5,而花岗岩εNd(t)及εHf(t)则显著低于火山岩,分别为–16.8~–15.9和–24.7~–18.4.地球化学以及同位素特征表明它们是经历过强烈改造的前寒武纪下地壳与中生代底侵形成的玄武质下地壳部分熔融的产物,花岗岩岩浆主要源于经历过强烈改造的前寒武纪下地壳部分熔融,而张家口组粗面质火山岩的源区可能含有相对较多的年轻地幔物质,两者可能存在源区混合作用.北栅子碱性长石花岗岩和大面积张家口组火山岩的喷发,反映了该地区在早白垩世构造体制从挤压-伸展的转折,这种构造体制转变可能与早白垩世燕山构造带开始垮塌以及岩石圈强烈伸展减薄有关  相似文献   

4.
蓝田和牧护关岩体位于东秦岭造山带西端,两者以洛南-栾川断裂为界。前者主要岩性为巨斑状二长花岗岩和中细粒二长花岗岩,而后者主要由二长花岗岩、花岗闪长岩和黑云母花岗岩组成。选自两岩体的锆石韵律震荡环带发育,Th/U大于0.1,属于岩浆成因锆石,其SIMS U-Pb年龄分别为147±2 Ma和149±1 Ma,均形成于晚侏罗世。蓝田和牧护关岩体锆石εHf(t)值分别集中于-16.9~-7.2和-9.3~-6.8,二阶段Hf模式年龄集中范围分别为1.7~2.3 Ga和1.6~1.8 Ga,指示它们的岩浆来源可能主要为新生的早-中元古代地壳物质。岩石地球化学进一步指示二者形成经历了古老地壳熔融、围岩混染、岩浆混合和结晶分异等复杂演化过程。综合研究表明,东秦岭地区约150 Ma的岩浆作用代表了该区晚侏罗世-早白垩世岩石圈伸展作用,其动力学背景很可能与晚中生代古太平洋板块向东亚大陆边缘俯冲有关。  相似文献   

5.
采用原位锆石U-Pb定年和岩石学、地球化学综合等方法研究大别山及邻区岩浆岩的形成时代,结果表明:大别山中生代岩浆活动启动于晚侏罗世,大规模爆发于早白垩世。大别山南部的张榜花岗岩侵入体锆石LA-ICP MS年龄为150.3Ma±2.0Ma,是目前发现的大别山最早的中生代岩浆活动记录,比早白垩世岩浆活动的峰期(~130Ma)早约20Ma,标志着大别山晚中生代巨量岩浆活动的启动。锆石的LA-MC-ICP MS Hf同位素结果计算的εHf(t)为-29左右,二阶段模式年龄大约为3.05Ga,表明岩浆源区为与扬子陆核类似的大别山早前寒武纪变质基底,新生地幔物质贡献极少。年代学资料和地球化学指标的统计表明,长江中下游成矿带与大别山地区晚中生代岩浆活动在时间上是同步的,但二者岩浆性质和成因机制不同。大别山130Ma的拆沉物质主要为古老地壳物质,地壳加厚是陆陆碰撞的结果,幔源岩浆上涌出现在拆沉事件之后;长江中下游地区于150Ma因幔源岩浆底侵而使下地壳强烈加厚,引发了该下地壳于130Ma的拆沉作用,幔源岩浆的上涌贯穿整个过程。  相似文献   

6.
近年来对青藏高原中拉萨地块西部中生代岩浆作用的源区、成因和演化等问题的研究较少。本文针对中拉萨地块西部噶尔县左左乡两个中酸性岩体进行了岩石学、锆石U-Pb年代学、微量元素和锆石Hf同位素,以及主量元素和微量元素地球化学研究。左左乡北侧岩体寄主花岗闪长岩和闪长质包体获得同期(163Ma和160Ma)的年龄,属于晚侏罗世;南侧岩体花岗岩年龄为142~147Ma,属于早白垩世。北侧与南侧的中酸性岩石均属于准铝质-弱过铝质高钾钙碱性I型花岗岩,富集大离子亲石元素和轻稀土元素,亏损高场强元素。晚侏罗世岩体寄主岩具有较为富集的锆石Hf同位素成分(ε_(Hf)(t)=-16.8~-13.6),可能来源于古老下地壳的部分熔融;包体具有相似的Hf同位素成分(ε_(Hf)(t)=-15.7~-13.6),结合晚侏罗世寄主岩与包体较高的MgO(4.13%~6.90%)、Cr(146×10~(-6)~370×10~(-6))和Ni(31×10~(-6)~113×10~(-6))含量,说明包体代表的中基性岩浆可能源于古老富集地幔的熔融,并且在晚侏罗世寄主花岗闪长岩与闪长质包体所代表的两种岩浆间发生过充分的岩浆混合作用。南侧早白垩世花岗岩具有较负且变化范围大的ε_(Hf)(t)值(-8.2~-4.8和-3.8~+0.2),指示早白垩世岩浆活动中有更多亏损地幔物质或新生地壳物质的加入,并且亏损地幔物质或新生地壳物质与拉萨地块古老地壳物质熔融形成的酸性岩浆发生了岩浆混合,经历岩浆混合后中酸性岩浆又发生了角闪石、长石的分离结晶,最终形成南侧早白垩世岩体的一系列中酸性岩石。研究区早白垩世亏损地幔物质或新生地壳物质的增多可能与南向俯冲的班公湖-怒江板片的回转有关。  相似文献   

7.
大兴安岭中部中生代花岗岩成因和构造背景的确定对讨论该地区及东北地区中生代构造-岩浆演化具有重要意义。乌兰浩特地区中生代花岗岩详细的岩石地球化学及Hf、Nd同位素的研究表明:研究区中晚三叠世查干岩体是A2型花岗岩;早中侏罗世景阳岩体为I型花岗岩,而大石寨岩体是具有特殊稀土元素四分组效应的花岗岩;早白垩世花岗岩体可根据其Sr含量划分为高Sr和低Sr两类,它们具有相同或相似的源岩组成,但其起源深度不同。其中高Sr型花岗岩类似于C型埃达克质花岗岩,起源于压力较高的下地壳,而低Sr型及永和屯花岗岩则是起源于压力较低的中地壳的高分异Ⅰ型花岗岩。全岩Nd和锆石Hf同位素特征及前人的研究结果显示,乌兰浩特地区花岗岩类岩石的源区主要为显生宙新增生的年轻地壳物质,并有老的地壳物质的贡献,并且随着花岗岩侵位时间的逐渐变新,锆石的εHf(t)值逐渐减小,认为地幔上涌导致岩浆底侵以及老地壳物质的折返是造成下地壳源岩组成复杂的原因。  相似文献   

8.
对内蒙赤峰楼子店拆离断层带下盘前人划为前寒武纪岩石的糜棱状花岗质岩石中锆石进行了U-Pb年龄测定和Hf同位素测试,结果显示其时代为晚古生代至中生代。楼子店扎兰营子片麻状花岗岩的锆石206Pb/238U年龄为253.6±1.2Ma,锆石εHf(t)值为-8.6~-14.6,锆石Hf同位素地壳模式年龄为1.8~2.2Ga;朝阳沟糜棱岩化片麻状花岗岩的锆石206Pb/238U年龄为150.43±0.79Ma,锆石εHf(t)值为-5.6~-14.9,锆石Hf同位素地壳模式年龄为1.6~2.1Ga;莫里海沟片麻状闪长岩的锆石206Pb/238U年龄为127.6±3.1Ma,锆石εHf(t)值为-5.1~-13.9,锆石Hf同位素地壳模式年龄为1.5~2.1Ga。不同岩性、不同形成年龄的3个样品的εHf(t)值主要为负值,说明这些岩石主要来自地壳岩石的部分熔融。2.2~1.5Ga的锆石Hf同位素两阶段模式年龄表明它们可能主要来源于华北克拉通下地壳物质的部分熔融。结合该区已经获得的锆石U-Pb年龄,将该区古生代至中生代花岗质岩浆作用划分为4个时期:早石炭世(327Ma)、二叠纪(285~252Ma)、中三叠世—早侏罗世(241~184Ma)、中侏罗世—早白垩世(163~125Ma)。早石炭世喇嘛洞混合花岗岩的产出对应于古亚洲洋古生代向南俯冲于华北板块的时期,二叠纪花岗岩是古亚洲洋最后闭合、蒙古弧与华北陆块北缘拼合与伸展有关的岩浆活动的产物,大面积的中三叠世—早侏罗世的花岗岩是西伯利亚与华北陆块碰撞后地壳伸展的记录,中侏罗世—早白垩世(163~125Ma)岩浆活动则发育在伸展构造背景中,与岩石圈减薄存在密切的成因联系。这些新年龄资料将为华北陆块北缘古生代—中生代的地质构造演化提供重要的年代学制约。  相似文献   

9.
李舢  王涛  童英  王彦斌  洪大卫  欧阳志侠 《岩石学报》2011,27(10):3055-3070
LA-ICP-MS锆石U-Pb定年结果表明,北山柳园地区辉铜山钾长花岗岩的形成年龄为397±3Ma (MSWD=1.1).地球化学特征显示为高钾钙碱性的高分异Ⅰ型花岗岩到A型花岗岩过渡的特征.其全岩εNd(t)值为-1.3~ +1.2,Nd模式年龄(tDM)为960 ~ 1530Ma;锆石εHf(t)值为-1.0~ +5.8,两阶段Hf模式年龄(tDM2)为1024~1455Ma.地质背景、地球化学和同位素综合分析显示,辉铜山岩体为造山后伸展拉张背景下,幔源岩浆底侵导致上覆年轻地壳(可能为洋壳、岛弧建造或增生楔物质)部分熔融形成的钙碱性花岗闪长质岩浆经进一步演化及结晶分异形成.北山南带地区早-中泥盆世花岗岩显示出高分异钙碱性Ⅰ型花岗岩、I-A型花岗岩和A型花岗岩的组合特征.因此,在397Ma左右,北山地区古生代岩浆已经从Ⅰ型或S型转化为I-A型特征,构造环境转化为后造山或同造山晚期的伸展环境.  相似文献   

10.
目前对于华北克拉通东部晚中生代花岗质岩石的成因仍存在地幔柱、加厚/拆沉下地壳部分熔融、俯冲板片脱水导致地壳熔融等不同认识。辽西兴城地区晚中生代花岗质岩石主要由二长花岗岩、石英闪长岩、花岗斑岩和石英正长岩组成,岩浆成因锆石U-Pb同位素定年结果显示岩浆活动主要发生于晚侏罗世(156Ma)、早白垩世早期(139Ma)、早白垩世中期(130~125Ma)。岩石地球化学测试分析结果显示岩石属于高钾钙碱性系列且具有富集K、Pb等大离子亲石元素而相对亏损Nb、Ta、Ti等高场强元素等活动陆缘岩浆岩特点,表明辽西地区晚中生代岩浆活动的发生与俯冲作用有关。晚侏罗世-早白垩世早期(156~139Ma)花岗质岩石地球化学特征与I型花岗岩类似,同时具有富集的Hf同位素组成(εHf(t)=-22.70~-18.66)和古老的Hf同位素二阶段模式年龄(tDM2=2387~2767Ma),其初始岩浆可能来源于古老中上地壳的部分熔融;形成于130Ma的花岗质岩石同样具有与I型花岗岩相类似的岩石地球化学特征,但其Hf同位素组成突变为亏损(εHf(t)=+3.64~+6.22、tDM1=537~969Ma),其初始岩浆起源于新元古代新生地壳物质的部分熔融并混入少量亏损地幔物质组分;形成于125Ma的花岗质岩石为碱性A型花岗岩,岩石地球化学特征与其他岩石有所不同,具有负的εHf(t)值(-17.30~-11.56)和相对古老的Hf同位素二阶段年龄(tDM2=1917~2278Ma),初始岩浆可能起源于较为古老的中下地壳部分熔融并有幔源物质的参与。华北克拉通东部形成于160~139Ma的花岗质岩石具有I型、高钾钙碱性、与埃达克质岩石类似的高Sr/Y、低Y含量特征和富集的Hf同位素组成,而形成于130~120Ma的花岗质岩石具有A型、碱性、与典型岛弧岩浆岩类似的岩石地球化学特征和相对亏损的Hf同位素组成,同时晚中生代岩浆活动具有向洋年轻化的特点,表明华北克拉通东部156~139Ma期间可能受到古太平洋板块的持续俯冲作用,而139~130Ma古太平洋俯冲板片开始回撤,130~125Ma进入古太平洋俯冲板片持续回撤导致的强烈区域伸展作用阶段。古太平洋俯冲板片脱水交代岩石圈地幔并形成幔源岩浆,幔源岩浆不断底侵作用于古老/新生地壳使其发生部分熔融为花岗质岩石提供岩浆来源。  相似文献   

11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

13.
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South.  相似文献   

14.
15.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

16.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability.  相似文献   

17.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

18.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification (e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system, our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics can be extracted from the new statistics; however, substantial additional information is also available. From the practical point of view, E-classification is substantially faster than the Zingg method.  相似文献   

19.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引:25,自引:2,他引:25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

20.
Pools,riffles, and channelization   总被引:2,自引:0,他引:2  
The addition of regularly spaced deeps (pools) and shallows (riffles) that provide a variety of flow conditions, areal sorting of stream-bed material, cover for wildlife, and a positive aesthetic experience, may be desirable in many channel projects. Such designs will reduce adverse environmental impacts of stream channel modifications. Analysis of variance for pool-to-pool spacing data suggests that there is no significant difference with respect to channel width between pools that form in natural streams and those in streams affected by a variety of human uses. Short of channelization, which changes the channel width, pools and riffles, within limits, are not particularly sensitive to environmental stress. Experiments in Gum Branch near Charlotte, North Carolina, support the hypothesis that channel form and process evolve in harmony and that manipulation of cross-channel morphology can influence the development of desired channel processes. Planned manipulation of its channel form induced Gum Branch to develop as desired. Morphologic stability consisting of incipient point bars, pools, and riffles was maintained over a period of high magnitude flood events, only to be degraded later by a wave of sediment derived from upstream construction and stream-bank failures. Thus, environmentally desirable channel morphology in urban streams cannot remain stable if changes in the sediment load or storm-water runoff exceed the limits of the stream's ability to make internal adjustments while maintaining morphologic stability.  相似文献   

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