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1.
江西香炉山矽卡岩型白钨矿矿床成因与流体特征   总被引:3,自引:1,他引:2  
熊欣  徐文艺  文春华 《矿床地质》2015,34(5):1046-1056
香炉山白钨矿矿床位于江西修水县城西北35 km处,是一座超大型白钨矿矿床。文章通过对该矿床蚀变矿化特征的研究,表明香炉山白钨矿矿床的矿化类型主要为矽卡岩型,其次为蚀变岩型(云英岩化型)。根据产状和岩相学特征进一步可将矿床的矿化过程划分为3个阶段:①矽卡岩化阶段;②白钨矿-白云母-石英阶段;③石英-硫化物阶段。流体包裹体测温结果显示,矽卡岩化阶段均一温度为354~518℃,峰值为465℃,ω(NaCl_(eq))为6.88%~13.4%;白钨矿-白云母-石英阶段均一温度为225~408℃,峰值为340℃,ω(NaCl_(eq))为2.41%~12.28%;石英-硫化物阶段均一温度为185~344℃,峰值为280℃,ω(NaCl_(eq))为2.41%~11.58%。该矿床的成矿流体为典型的中-高温、中低盐度流体体系。流体中富含F、P、H_2O等挥发分对成矿的运移和富集起到一定的作用,而CO_2对钨的迁移作用不大。流体包裹体岩相学及测温结果揭示了流体在矽卡岩阶段经历沸腾或不混溶过程,含F、低盐度、成矿流体呈酸性,有利于钨矿的沉淀,这些是含矿流体内钨迁移与成矿的重要因素。  相似文献   

2.
陕西大西沟喷流沉积型菱铁矿矿床地质特征及矿床成因   总被引:1,自引:0,他引:1  
陕西大西沟铁矿床位于秦岭造山带山-柞盆地西北部,与银洞子大型银铅矿床毗邻。矿体主要赋存在泥盆系青石垭组中上段,容矿岩石为一套海相复理石碎屑岩和碳酸盐岩建造。矿床的金属矿物主要有菱铁矿、磁铁矿、黄铁矿,其次为黄铜矿、磁黄铁矿等;非金属矿物主要是重晶石、石英、铁白云石,其次为方解石、绢云母、绿泥石、黑云母、斜长石、钠长石、堇青石等,局部地段由于表生氧化和次生富集作用而形成针铁矿、赤铁矿、蓝辉铜矿等。与矿化有关的围岩蚀变较弱,主要有硅化、绢云母化、绿泥石化和碳酸盐化。基于野外地质观察、矿物共生组合和矿石结构构造的系统研究,将大西沟铁矿床的形成划分为3期6阶段,分别是:①喷流沉积期:硅质岩-黄铁矿-菱铁矿阶段(Ⅰ)、重晶石-磁铁矿阶段(Ⅱ);②热液改造期:堇青石-黄铁矿-磁铁矿阶段(Ⅲ)、石英-碳酸盐阶段(Ⅳ)、碳酸盐-硫化物-磁铁矿阶段(Ⅴ);③表生氧化期(Ⅵ)。流体包裹体显微测温结果表明,喷流沉积期Ⅰ阶段菱铁矿完全均一温度和盐度w(NaCl_(eq))峰值区间分别为230~270℃和13%~14.5%,Ⅱ阶段重晶石中流体包裹体的完全均一温度和盐度w(NaCl_(eq))峰值区间分别为220~290℃和9%~13%;热液改造期Ⅳ阶段菱铁矿和石英中气液两相包裹体均一温度峰值区间为240~300℃,盐度w(NaCl_(eq))为2.6%~15.7%;热液改造期Ⅴ阶段菱铁矿与石英中流体包裹体,除大量气液两相包裹体外,还发育有含子矿物多相包裹体,其中,气液两相包裹体均一温度峰值区间为290~340℃,盐度w(NaCl_(eq))为5.1%~13.4%,含子矿物多相包裹体均一温度峰值区间为380~440℃,盐度w(NaCl_(eq))为40.6%~59.7%。含子晶流体包裹体可能是流体不混溶或/和高盐度流体加入的反映。矿区内不同产状碳酸盐矿物的C、O同位素组成比较均一,δ~(13)C_(PDB)值集中在-3.58‰~-1.15‰之间,δ~(18)O_(SMOW)值为21.22‰~21.82‰,均表现出海相碳酸盐或海底喷流热液溶解海相碳酸盐的特征。大西沟矿床的地质、矿化和流体特征与海底热液喷流沉积型矿床一致,可能属于典型的喷流沉积型菱铁矿床,但后期受到秦岭造山作用的影响及热液叠加改造并形成磁铁矿和少量硫化物。大西沟菱铁矿矿床与邻近的银洞子铅锌矿组成一个较完整的喷流沉积成矿系统,两者可能分别代表了喷流沉积的边缘相和中心相。  相似文献   

3.
乐红铅锌矿床是扬子地块西南缘滇东北铅锌(银)多金属矿集区中的典型代表之一。通过对该矿床不同成矿阶段闪锌矿、石英、重晶石和方解石中流体包裹体岩相学、显微测温学和显微激光拉曼探针等测试,阐述了该矿床成矿流体性质和演化特征,并探讨了其成矿过程。研究发现,该矿床流体包裹体主要包括4类:Ⅰ类气相、Ⅱ类水溶液相(由Ⅱa型-富液相气液两相、Ⅱb型-富气相气液两相、Ⅱc型纯液相组成)、Ⅲ类含CO_2三相(V_(CO_2)+L_(CO)+L_(HO))及Ⅳ类含子矿物(L+V+S)包裹体。结果显示,重晶石阶段的均一温度为240.3~319.3℃,w(NaCl_(eq))为2.24~2%~1~20.73%,表现出中高温-中低盐度流体性质;白云石-黄铁矿-石英阶段具有中-高温(219.8~310.1℃),中盐度(w(NaCl_(eq))为7.02%~17.61%)特征;闪锌矿-方铅矿-黄铁矿阶段,包括S1闪锌矿具有中温(217.8~292.2℃)-中盐度(w(NaCl_(eq))为8.81%~16.71%)性质;S2闪锌矿具有中低温(180.2~241.3℃)-中盐度(w(NaCl_(eq))为7.73%~18.47%)性质;S3闪锌矿具有中低温(140.4~227.4℃)-中低等盐度(w(NaCl_(eq))为0.35%~19.21%)的流体性质,通过该阶段中含CO_2三相包裹体测试,估算成矿压力和成矿深度分别为45~74.9 MPa(平均58.2 MPa)、1.7~2.8 km。方解石阶段均一温度为165.3℃,中等盐度,w(NaCl_(eq))为11.28%,表现出低温-中等盐度的特征。不同成矿阶段的包裹体温度大致反映了该矿床成矿流体从早阶段至晚阶段,呈现中高温、中低盐度→中温、中等盐度→中低温、中低盐度的演化过程;早期高温-低盐度深部流体在热动力和构造应力驱动下大规模运移,受断裂构造影响发生减压沸腾作用,同时与大气降水发生混合,成矿流体物化性质陡变引起铅锌硫化物等的沉淀,并最终形成矿床。该研究为揭示矿床流体性质、演化及矿床成因提供了证据,深化了"构造-流体‘贯入’成矿"模型,亦对深化矿床成矿机制与指导找矿预测具有重要意义。  相似文献   

4.
江西武山铜矿床是长江中下游多金属成矿带内重要的矽卡岩型矿床之一。文章对该矿床中的流体包裹体进行了详细研究,重点分析了成矿流体的演化过程及其成矿意义。根据野外地质产状和室内岩相学特征,将武山矽卡岩型铜矿床热液成矿过程分为气成-高温热液期和热液期,前者包括矽卡岩阶段和磁铁矿阶段,后者包括石英-硫化物阶段和碳酸盐阶段。其中,石英-硫化物阶段是该铜矿形成的主要阶段,可进一步细分为辉钼矿-石英和黄铁矿-黄铜矿-石英2个阶段。岩相学观察显示,包裹体类型有Ⅰ型含子矿物包裹体(L+V+S)、Ⅱ型气液两相包裹体(L+Ⅴ)和Ⅲ型气相包裹体(Ⅴ)。气成-高温热液期的石榴子石中流体包裹体数量不多,但Ⅰ型、Ⅱ型和Ⅲ型包裹体都有;而热液期的石英与方解石中流体包裹体数量众多,以Ⅱ型包裹体为主。从早期矽卡岩阶段至碳酸盐阶段,成矿热液经历了从高温(378~518℃)、高盐度[ω(NaCl_(eq))介于17.3%~45.1%)向低温(113~250℃)、低盐度[ω(NaCl_(eq))介于3.4%~11.9%]的持续演化。热液演化过程中发生了流体沸腾作用和岩浆热液与大气降水的混合作用。其中,矽卡岩阶段的水-岩作用、沸腾作用与矽卡岩的形成密切相关,而成矿阶段的沸腾作用与混合作用可能是铜矿床形成的重要机制。H、O同位素研究表明,各成矿阶段的成矿流体以岩浆水为主,但随着成矿作用的进行,大气降水在成矿流体中的体积质量逐渐增大。  相似文献   

5.
八大关斑岩型Cu-Mo矿床是我国内蒙大兴安岭成矿带北段典型的斑岩型Cu-Mo矿床之一,矿体主要产出在成矿斑岩体与围岩的内外接触带。通过详细的岩相学和矿相学观察,矿床可以划分出5个成矿阶段,即钾长石阶段→辉钼矿-石英阶段→磁铁矿-黄铁矿(黄铜矿)石英阶段→铜(铅锌)石英阶段→石英-绿泥石±碳酸盐阶段。矿床内石英中的流体包裹体类型有富气相包裹体、富液相包裹体、含子矿物的多相包裹体和含CO_2的三相包裹体,但石英-绿泥石阶段石英中明显缺乏后两类包裹体。显微测温和激光拉曼结果显示,石英斑晶中代表早期成矿流体的均一温度为460~572℃,盐度ω(NaCl_(eq))高达59.76%,子矿物有石盐和代表氧化环境的硬石膏,气相成分富含CO_2,液相成分以H_2O为主,富含CO_3~(2-)。辉钼矿-石英阶段流体包裹体的均一温度为320~440℃,盐度ω(NaCl_(eq))为0.83%~63.13%,子矿物有石盐、赤铁矿和未知硫化物,可见富气相、富液相和含CO_2或子矿物的多相包裹体共存,且其具有相近的均一温度,但盐度相差悬殊,指示成矿流体曾发生过沸腾作用;而铜(铅锌)-石英阶段的均一温度为260~340℃,盐度ω(NaCl_(eq))为0.42%~37.40%,子矿物有石盐和硬石膏,气液相成分以H_2O为主,富含CO_3~(2-)。与辉钼矿-石英阶段相比,该阶段成矿流体的温度变化尤为显著。石英-绿泥石阶段中流体包裹体的均一温度为237~306℃,盐度ω(NaCl_(eq))则低于10.86%,无子晶,贫CO_2。综合O、H同位素,初始成矿流体属于中高温、高盐度、高氧逸度和富CO_2的岩浆热液;随着成矿过程的进行,大气水的混合比例越来越高,成矿流体逐渐演化为岩浆热液和大气水的混合热液;晚阶段成矿流体主要以大气水为主。通过系统的流体包裹体研究,我们认为矿床的成矿物质是由同一流体带入成矿热液系统,但其沉淀机制却发生了解耦,即辉钼矿的沉淀主要与减压沸腾作用有关,而铜(铅锌)硫化物的沉淀主要与温度降低有关。  相似文献   

6.
江西香炉山矽卡岩型钨矿床流体包裹体研究   总被引:13,自引:5,他引:8  
从江西西北部至安徽南部发育一条显著的斑岩-矽卡岩型钨成矿带,香炉山是其中一典型的矽卡岩钨矿床。矿床具有明显的矿化分带特征,由近接触带矽卡岩和云英岩矿体和远接触带脉状石英-硫化物-白钨矿和透镜状矿体组成。通过对不同蚀变带上矿石矿物和脉石矿物的流体包裹体显微测温分析表明:矽卡岩中的流体包裹体的均一温度范围在209~383℃,脉状石英-白钨矿和石英-硫化物-白钨矿中流体包裹体的均一温度范围分别为163~278℃和204~284℃,晚期方解石脉的温度最低为143~235℃;矽卡岩中的流体包裹体的盐度范围在0.35%~5.26%NaCleqv,脉状石英-白钨矿和石英-硫化物-白钨矿中流体包裹体的盐度范围分别为0.35%~5.86%NaCleqv和0.70%~9.21%NaCleqv,晚期方解石脉的盐度为0.35%~2.07%NaCleqv。激光拉曼探针测试表明,矽卡岩、石英-白钨矿脉和石英-硫化物-白钨矿脉中流体包裹体组分主要为H2O,还含有一定量CH4和少量的N2。从早期到晚期成矿阶段表现为一个降温的过程,指明了钨成矿温度较宽泛;钨在流体中可能以钨酸的形式运移,与围岩反应时,温度降低和碱性升高,促使白钨矿沉淀成矿。早期到晚期成矿流体温度和物质组成发生变化是成矿发生分带的重要原因。  相似文献   

7.
崤山金矿床位于华北克拉通南缘的豫西地区,矿体大多呈脉状产于断裂带内。成矿期可以划分为3个阶段:(1)石英-黄铁矿阶段;(2)石英-多金属硫化物阶段;(3)石英-碳酸盐阶段。成矿期石英中发育气液两相水溶液包裹体(WL型)和H_2O-CO_2包裹体(C型)。石英-黄铁矿阶段发育WL型和C型包裹体,它们的均一温度为300~393℃,盐度w(NaCl_(eq))为1.6%~11.0%,密度介于0.57~0.82 g/cm~3;石英-多金属硫化物阶段亦发育WL型和C型包裹体,它们的均一温度为261~298℃,盐度w(NaCl_(eq))为1.1%~11.8%,密度介于0.74~0.89 g/cm~3;石英-碳酸盐阶段仅见WL型包裹体,其均一温度为193~258℃,盐度w(NaCl_(eq))介于2.2%~12.7%,密度为0.87~0.97g/cm~3。成矿流体具有中高温、中低盐度、低密度等特征,属于H_2O-NaCl±CO_2体系。崤山金矿石英的δ~(18)OH_2O值介于0.7‰~4.5‰之间,δDV-SMOW值介于-47.8‰~-69.5‰之间。H-O同位素结果表明成矿流体主要来源于岩浆水。矿石硫化物的δ_(34)SV-CDT值为0.7‰~3.9‰,206Pb/204Pb值为17.391~17.728,~(207)Pb/~(204)Pb值为15.420~15.577,~(207)Pb/~(204)Pb值为37.420~37.923。S-Pb同位素结果表明成矿物质主要来源于花岗质岩浆。崤山金矿为中温热液脉型金矿,流体相分离和温度的降低是导致矿质沉淀的主要机制。  相似文献   

8.
新疆阿尔泰南缘乌吐布拉克铁矿成矿机制研究   总被引:4,自引:2,他引:2  
乌吐布拉克中型铁矿床赋存于上志留统-下泥盆统康布铁堡组变质火山-沉积岩系中,矿体呈似层状、透镜状,矿体及其周围发育大量矽卡岩矿物组合。早期矽卡岩阶段包裹体均一温度为256~534℃,盐度为11.90%~>73.96%NaCleqv,密度为0.56~0.96g/cm3,表明成矿流体为高-中温、高-中盐度、高-中密度的NaCl-H2O体系;退化蚀变阶段包裹体均一温度为188~313℃,盐度为12.30%~>39.76%NaCleqv,密度为0.83~1.05g/cm3,表明成矿流体为中温、中-低盐度、高-中密度的NaCl-H2O体系。石英-硫化物-碳酸盐阶段包裹体均一温度为162~320℃,盐度为2.90%~15.57%NaCleqv,密度为0.70~1.02g/cm3,成矿流体为NaCl-H2O-CO2±CH4或N2型流体。石榴子石氢氧同位素表明早期矽卡岩阶段成矿流体主要来源于岩浆水,石英及方解石的氢氧同位素暗示石英-硫化物-碳酸盐阶段存在低温、低盐度的大气降水的加入。方解石的碳、氧同位素表明流体中碳主要来自深部岩浆。硫化物硫同位素表明硫来源于岩浆硫。成矿机制可能为早三叠世岩浆热液交代上志留-下泥盆统康布铁堡组火山岩形成矽卡岩矿物,在矽卡岩退化蚀变过程中形成铁矿体。  相似文献   

9.
唐一昂 《地质与勘探》2017,53(2):217-226
梅子冲铅锌钨多金属矿床位于广东省韶关市一六矿区。野外调查和室内显微镜鉴定表明,梅子冲矿床成矿作用分为两期五阶段,第一期为矽卡岩期,可以分为早期矽卡岩阶段(A1)、晚期矽卡岩阶段(A2)和钾长石白钨矿阶段(A3);第二期为热液期,可以分为石英硫化物阶段(B1)和石英碳酸盐阶段(B2)。矿体的石英和白钨矿中含有富液相的气液两相流体包裹体,地质特征结合包裹体测温资料表明,成矿温度介于207℃~449℃,盐度为1.16%~12.4%,反映矿床形成于中-高温环境。成矿流体特征及成矿温度的演化表明,A1+A2至A3阶段的流体混合作用可能导致了白钨矿的形成,A3至B1阶段的流体混合作用可能促进了铅锌矿的形成。  相似文献   

10.
滇东南南秧田矽卡岩型钨矿床成矿演化   总被引:3,自引:1,他引:2  
南秧田矽卡岩型白钨矿床是滇东南老君山钨锡多金属成矿区的重要组成部分之一。该矿床由多个白钨矿体组成,以层状、似层状矽卡岩型矿石为主,矽卡岩矿物组合以透辉石+钙铁辉石+钙铝榴石+角闪石+绿帘石为主。南秧田钨矿床的形成经历了矽卡岩阶段,石英-白钨矿阶段和方解石阶段,通过对不同阶段矿石矿物和脉石矿物的流体包裹体显微测温分析表明:矽卡岩中的流体包裹体的均一温度范围为221~423℃,石英-白钨矿的均一温度为177~260℃,晚期方解石脉的温度最低,为173~227℃。矽卡岩中的流体包裹体的盐度w(Na Cleq)为0.18%~16.34%,石英-白钨矿的盐度w(Na Cleq)为0.35%~7.17%,晚期方解石脉的盐度w(Na Cleq)为0.35%~2.24%。激光拉曼探针测试表明,3个阶段的流体包裹体组分主要为H2O,还有少量的N2,只有在石英-白钨矿阶段的流体包裹体组分除了H2O以外,还有少量的CH4。矿床从早期到晚期成矿阶段表现为一个降温的过程,说明钨成矿温度较宽泛。成矿期含矿矽卡岩的δ13CPDB值为-5.7‰~-6.9‰,δ18OSMOW值为5.8‰~9.1‰,表明成矿流体主要是岩浆水,其次为含有机质的碳酸盐岩地层和大气降水,反映出典型岩浆热液交代作用的特征。  相似文献   

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This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

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最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

15.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).  相似文献   

16.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

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