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沉积物中的重金属属于持久性污染物,具有富集性、难降解性和毒性,长时间累积会对生态环境和人体健康造成威胁。为研究珍珠湾红树林湿地表层沉积物中的重金属含量分布特征及质量现状,2021年9月在珍珠湾红树林分布区采集13件表层沉积物样品,分析测试重金属含量。结果表明: 与国内其他红树林湿地相比,珍珠湾红树林湿地表层沉积物中的重金属含量处于相对较低水平; 地累积指数法显示大部分表层沉积物样品无重金属污染,仅有2个站位受到Cd和Hg的轻微污染,潜在生态风险指数法表明湾内各站位均为低生态风险; 相关性分析和主成分分析表明,Cd主要受江平江输入和珍珠湾东南部海水养殖的影响,其他元素主要为自然背景的岩石风化沉积,利用主成分-多元线性回归模型对重金属的来源进行解析认为,表明江平江输入的重金属贡献率为57%,海水养殖影响的重金属贡献率为43%。综上所述,珍珠湾红树林湿地整体生态状况良好,但仍需重点关注Cd的输入。 相似文献
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厦门西港沉积环境变化及重金属的污染累积 总被引：1，自引：0，他引：1
通过测定柱状沉积物中的重金属、有机碳和硫化物含量, 结合沉积物粒度分析及现代沉积速率, 重现了厦门西港近70a的沉积环境变化及重金属的污染历史, 探讨了沉积环境对重金属累积过程的影响.结果表明, 厦门西港污染指示元素为Cu, Zn, Pb, As, 富集程度依次为As > Cu > Zn > Pb, 元素Cr, Cd和Hg在研究海域内没有富集现象.综观70a来, 厦门西港沉积物组成变化较大, 沉积环境变化明显, 重金属含量的垂向变化特征与当时的水动力、沉积环境变化紧密相关.研究表明, 沉积物来源越稳定, 沉积物粒径越小, 分选性越好, 则沉积物中重金属含量越高; 同时, 各层位的绝大部分重金属与有机碳和硫化物呈显著正相关关系. 相似文献
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因重金属难以被生物降解,易形成毒害环境因子,沉积物中的重金属污染演变是工业化以来全球共同面临的生态环境问题。为揭示福建三都澳地区人类活动与重金属沉积的关系,对采集自三都澳海域的6根岩心柱进行了系统的粒度分析、210Pb测年以及重金属元素测试。研究结果表明：（1）近百年来,三都澳海域沉积物重金属含量呈现显著增加趋势,顶部比底部增加1.01~2.8倍,并表现出3个明显演变阶段：1900-1950年,沉积物中的重金属含量相对稳定;1950-2000年,重金属含量开始缓慢增加;2000年以来,远岸区重金属含量急剧增加。这种变化趋势与人口、经济发展密切相关。（2）三都澳近岸区沉积物重金属含量总体大于远岸区,自2000年以来,近岸区和远岸区沉积物重金属含量的演变趋势呈现差异性,表现为近岸区重金属含量有所降低,远岸区重金属含量急剧升高,这种时空差异与沉积物粒度变化及地区产业分布有密切关系。（3）重金属对三都澳海洋生态环境影响较大,在湾内渔业养殖强度越来越高的背景之下,应对近期以来湾内重金属含量的快速升高给予足够重视,提高保护和修复治理力度,避免海洋生态破坏。 相似文献
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Spatial distribution of heavy metals in surficial sediments from Guanabara Bay: Rio de Janeiro, Brazil 总被引：1，自引：0，他引：1
José Antônio Baptista Neto Franz Xaver Gingele Thomas Leipe Isa Brehme 《Environmental Geology》2006,49(7):1051-1063
Ninety-two surface sediment samples were collected in Guanabara Bay, one of the most prominent urban bays in SE Brazil, to
investigate the spatial distribution of anthropogenic pollutants. The concentrations of heavy metals, organic carbon and particle
size were examined in all samples. Large spatial variations of heavy metals and particle size were observed. The highest concentrations
of heavy metals were found in the muddy sediments from the north western region of the bay near the main outlets of the most
polluted rivers, municipal waste drainage systems and one of the major oil refineries. Another anomalous concentration of
metals was found adjacent to Rio de Janeiro Harbour. The heavy metal concentrations decrease to the northeast, due to intact
rivers and the mangrove systems in this area, and to the south where the sand fraction and open-marine processes dominate.
The geochemical normalization of metal data to Li or Al has also demonstrated that the anthropogenic input of heavy metals
have altered the natural sediment heavy metal distribution. 相似文献
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城市地表沉积物已成为城市环境污染的重要组成部分,是城市环境中各种污染物的"源"和"汇",通过研究城市地表沉积物的物化及矿物学特征对城市环境质量的监测具有良好的指示作用。本文在成都市中心城区不同区域采集40件地表沉积物样品,利用激光粒度分析仪、扫描电镜能谱和X射线衍射等技术分析研究了地表沉积物的粒径分布特征、重金属分布特征、矿物组成特征及微区形貌特征。结果表明:地表沉积物粒径的质量和体积分布特征具有较高一致性,均以中细颗粒物为主,其中小于0. 3mm的地表沉积物占总质量或体积的70%以上,小于0. 125mm的地表沉积物占总质量或体积的40%左右; Cu、Pb、Zn、As、Hg、Cr、Cd、Ni等重金属随着沉积物粒径的减小而呈明显增加的趋势,主要存在于小于0. 125mm粒径的沉积物中,同时在成都市中心城区各方位区域和各环路区域的分布上存在一定的差异; Si、Ca、K、Na等造岩元素在不同粒径级别沉积物中都大量存在;地表沉积物矿物组成主要是石英、长石类、方解石等,且各类矿物在不同粒径级别沉积物中所占含量大致相当,但细粒径矿物表现出胶体行为,极易吸附各种微量重金属。研究认为,城市地表沉积物的粒径分布特征和矿物组成特征是影响重金属在沉积物中分布的内在因素,而人类活动是决定地表沉积物重金属污染程度的关键因素。 相似文献
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Surficial sediment samples were collected at 47 stations in Little Traverse Bay, Lake Michigan, to determine the geochemical
associations between certain rare earth elements (REE's) and trace metals. Each sample was analyzed for carbonate carbon,
organic carbon, grain size, and the elements Al, Ca, Ce, Co, Cr, Eu, Fe, Hf, La, and Mn. Two distinct Ce subpopulatins were
identified by graphical analysis, and an R-mode factor analysis was applied to data from the “enriched” Ce subpopulation (18
samples). Results show that the REE's and trace metals are primarily enriched in the authigenic phase of these sediments.
Partial correlation analyses indicate that the REE's are primarily associated with hydrous Fe oxides relative to organic matter
in this phase. The ratio of Ce/La concentrations increased markedly from the bay margins to the central trough of the bay,
indicating that Ce, similar to Fe, exhibits a variable oxidation state in the authigenic phase of nearshore fine-grained sediments.
The results of the present study suggest that the REE's and trace metals behave coherently in the authigenic phase of recent
lacustrine sediments, and the REE's may be useful as geochemical tracers to differentiate between trace metal enrichments
in surface sediments as a result of diagenesis and pollution loadings. 相似文献
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Distribution and speciation of heavy metals and their sources in Kumho River sediment,Korea 总被引：1，自引：1，他引：0
The interaction between heavy metals and river sediment is very important because river sediment is the sink for heavy metals
introduced into a river and it can be a potential source of pollutants when environmental conditions change. The Kumho River,
the main tributaries of the Nakdong River in Korea, can be one of the interesting research targets in this respect, because
it runs through different geologic terrains with different land use characteristics in spite of its short length. Various
approaches were used, including mineralogical, geochemical, and statistical analyses to investigate the distribution and behavior
of heavy metals in the sediments and their sources. The effect of geological factor on the distribution of these metals was
also studied. No noticeable changes in the species or relative amounts of minerals were observed by quantitative X-ray diffraction
in the sediments at different stations along the river. Only illite showed a significant correlation with concentrations of
heavy metals in the sediments. Based on an average heavy metal concentration (the average concentrations of Cd, Co, Cr, Cu,
Ni, Pb, and Zn were 1.67, 20.9, 99.7, 125, 97.6, 149, 298 ppm, respectively), the sediments of the Kumho River were classified
as heavily polluted according to EPA guidelines. The concentrations of heavy metals in the sediments were as follows: Zn > Pb > Cu > Ni > Cr > Co > Cd.
In contrast, contamination levels based on the average I
geo (index of geoaccumulation) values were as follows: Pb > Cd > Zn > Cu > Co = Cr > Ni. The concentrations of heavy metals increased
downstream (with the exception of Cd and Pb) and were highest near the industrial area, indicating that industrial activity
is the main factor in increasing the concentrations of most heavy metals at downstream stations. Sequential extraction results,
which showed increased heavy metal fractions bound to Fe/Mn oxides at the downstream stations, confirmed anthropogenic pollution.
The toxicity of heavy metals such as Ni, Cu, and Zn, represented by the exchangeable fraction and the fraction bound to carbonate,
also increased at the downstream stations near the industrial complexes. Statistical analysis showed that Pb and Cd, the concentrations
of which were relatively high at upstream stations, were not correlated with other heavy metals, indicating other possible
sources such as mining activity. 相似文献
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Suspended and bed sediments collected from the entire region of the Godavari River basin were analyzed for Fe, Mn, Cr, Cu, Ni, and Zn. There are pronounced temporal and spatial variations in the heavy metal distributions. The concentrations of heavy metals in the suspended sediments are significantly higher than the bed sediments.Throughout the basin heavy metals are enriched in the finer fractions (<2 µm) of the bed sediments. The average heavymetal composition of the sediments is higher when compared to the average Indian river sediments. Heavy-metal concentration in the two shallow cores collected shows, to some extent, the influence of urbanization. When compared to the other tropical Indian rivers such as the Krishna, the Godavari appears to be a significant contributor of heavy metals to the Bay of Bengal. Considering the enormous sediment load of the Godavari River—170 million tons/yr, the heavy metal fluxes to the Bay of Bengal is very significant. Except for the Pranhita, other tributaries of the Godavari do not contribute significant loads of heavy metals. All the metals show high correlation among themselves and the correlation is more pronounced in suspended sediments than in the bed sediments. The heavy-metal distribution, fractionation, and its relationship with total suspended sediments and depth in various parts of the basin are discussed in detail. 相似文献
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A. Parizanganeh B.Sc. M.Sc. Ph.D. V. C. Lakhan Ph.D. F.R.G.S. C.E.I. C.E.S. H. Jalalian Ph.D. 《International Journal of Environmental Science and Technology》2007,4(3):351-358
The nearshore marine environment of the Caspian sea is a major repository for toxic metals originating from various sources. Since the persistent toxic metals pose serious health risks this research concentrated on investigating the concentrations and spatial distribution of metals in the nearshore sediments along the Iranian coast of the Caspian sea. Fourteen sampling sites were selected along the coast and approximately 400 g of surficial sediments were obtained. Samples were sieved and three grain size fractions from each sample plus fourteen bulk samples were selected for the analysis of metals. Laboratory analysis of the samples utilized the Cold Acetic protocol, followed by Inductively coupled plasma optical emission spectroscopy. The statistical techniques were used to analyze all obtained data. Linear regression analysis demonstrated that grain size of the sediments was not a major factor controlling the concentrations and spatial distributions of heavy metals. Box and Whisker plots emphasized that metal concentrations were not homogeneously distributed. Discriminant analysis was also proved to be useful in identifying geographic areas where heavy metal concentrations occur along the coast. 相似文献
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Concentration distribution and assessment of several heavy metals in sediments of west-four Pearl River Estuary 总被引：2，自引：0，他引：2
Shanshan Wang Zhimin Cao Dongzhao Lan Zhichang Zheng Guihai Li 《Environmental Geology》2008,55(5):963-975
Grain size parameters, trace metals (Co, Cu, Ni, Pb, Cr, Zn, Ba, Zr and Sr) and total organic matter (TOM) of 38 surficial
sediments and a sediment core of west-four Pearl River Estuary region were analyzed. The spacial distribution and the transportation
procession of the chemical element in surficial sediments were studied mainly. Multivariate statistics are used to analyses
the interrelationship of metal elements, TOM and the grain size parameters. The results demonstrated that terrigenous sediment
taken by the rivers are main sources of the trace metal elements and TOM, and the lithology of parent material is a dominating
factor controlling the trace metal composition in the surficial sediment. In addition, the hydrodynamic condition and landform
are the dominating factors controlling the large-scale distribution, while the anthropogenic input in the coastal area alters
the regional distribution of heavy metal elements Co, Cu, Ni, Pb, Cr and Zn. The enrichment factor (EF) analysis was used
for the differentiation of the metal source between anthropogenic and naturally occurring, and for the assessment of the anthropogenic
influence, the deeper layer content of heavy metals were calculated as the background values and Zr was chosen as the reference
element for Co, Cu, Ni, Pb, Cr and Zn. The result indicate prevalent enrichment of Co, Cu, Ni, Pb and Cr, and the contamination
of Pb is most obvious, further more, the peculiar high EF value sites of Zn and Pb probably suggest point source input. 相似文献
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中国海域拥有宽广的大陆架，同时还有陆坡和深海盆，有众多河流入海并输入巨量的陆源物质，沉积物记录了海陆变迁、环流变化、海平面升降、物质输送和气候变化等环境信息。沉积物的粒度特征可以反映沉积动力、物质来源和搬运距离等，可以通过沉积物粒度组成、参数及各种图解来研究沉积环境的变化。前人对中国海域表层沉积物的粒度分布特征展开了大量的研究，取得了丰富的研究成果，但这些研究多集中在某一海域或区域，缺乏对整个中国海域的表层沉积物类型的宏观系统认识。本文基于中国地质调查局“1：100万海洋区域地质调查项目”获取了中国海域4300个海底表层沉积物样品，通过沉积物粒度分析，结合前人已发表资料，对中国海域表层沉积物的沉积类型特征、物质来源和运移模式等开展了系统的研究。本文把浅海和半深海沉积物按照含砾石和不含砾石主要划分出5个和7个沉积物类型，深海沉积物主要划分了9个沉积类型，研究结果表明：中国海域表层沉积物沉积类型多样、来源复杂，主要受控于物质来源、水动力条件和地形地貌的变化，在东部海域总体呈现“大江大河-宽缓陆架-残留慢速沉积”的条带状沉积分异模式，而在南部海域呈现的是“短源性河流-多类型陆架-重力流快速沉积”的环带状沉积分异模式。本文的结果对研究中国海域沉积物的宏观分布规律提供了基础资料，对理解海洋沉积动力过程具有重要意义，同时沉积物粒度的特征对海底砂矿分布也具有指示意义。 相似文献
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Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India) 总被引：1，自引：1，他引：0
Sanjay Kumar Sundaray Binod Bihari Nayak Byeong-Gweon Lee Dinabandhu Bhatta 《Environmental Earth Sciences》2014,71(4):1893-1909
Dynamics of heavy metals in the surface sediments of Mahanadi river estuarine system were studied for three different seasons. This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO3”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system. 相似文献
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由于受湖泊动力条件和物质来源的影响,湖泊表层沉积物的各粒度组分表现出不同的空间分布特征。选择滇西北程海作为研究对象,通过测试程海表层沉积物的粒度,分析了其不同粒度组分的空间分布特征,对影响程海表层沉积物粒度空间分布的因素进行探讨。研究结果表明:程海表层沉积物的优势粒级为粉砂,各样品沉积类型为黏土质粉砂。粒度组分及其参数的空间分布特征变化差异明显,黏土组分含量呈现出由南向北逐渐增加的趋势,而粉砂、中值粒级则呈现出相反的变化趋势,表明程海沉积物粒径受盛行南风的控制与影响,表现为湖泊水动力由南向北逐渐减弱。程海表层沉积物的粒度空间分布特征表明,其表层沉积物易受盛行风的影响向北扩散,因此,应加强该地区沿岸,特别是南岸人类活动的管理,有效控制人为物质的输入,减少污染物的扩散。 相似文献
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This paper examines the surface sediments collected from Dongping Lake in China for speciation and distribution of toxic heavy metals (Cu, Pb, Ni, Cd) in different grain size fractions, and for the factors that need to be considered in potential hazard of metals to the environment. Four grain size fractions (<63, 63–78, 78–163 and 163–280 μm), divided in wet condition, and bulk samples less than 280 μm in diameter were analyzed for their distribution, density and appearance. A three-stage extraction procedure following the BCR protocol was used to chemically fractionate metals into “acid soluble”, “reducible”, “oxidizable” and “residual” fractions. Correlation analysis was used to analyze the datasets. The results showed that <63 μm grain size part constitutes the major proportion of the sediments, but its density is the smallest among the four grain size fractions. In general, the metal content curve against grain size presents “S” distribution, and the highest concentrations do not exist in <63 μm grain size. Appearance observation indicates that the adsorbed substance increases gradually along with the decreasing grain size. The dominant speciation of elements and the extent of pollution are responsible for the metal distribution in different grain size sediments. While studying bioavailability and mobilization of metals, it is advisable to take metal speciation, grain size distribution and density into consideration. 相似文献
18.
基于海南西部四更沙及其邻近海域185个底质的粒度数据,并结合研究区动力状况和水深地形特征,研究表层沉积物的组分和类型分布、粒度参数及其沉积环境分区。结果表明:①研究区沉积物类型多样,包括12种沉积类型,以砂质粉砂、粉砂、粉砂质砂和含砾砂为主,沉积物平均粒径变化范围较大(-0.70~7.13 φ),且大体呈现由北向南逐渐变细的分布趋势;②运用Fleming的三角图式,结合物源状况及地形地貌条件,对沉积环境进行划分,将研究区划分为四更沙岸外海滨沉积区、北黎湾中部沉积区和八所港近岸沉积区等3个沉积区;③研究区沉积物分布特征受沉积物来源和水动力及地形条件共同影响。横向分布上,西部主要受强潮流输沙影响,东部近岸则主要受波浪掀沙和搬运作用影响,表现为两侧粗,中间相对较细的特征。纵向上,四更沙岸外海滨沉积区,沉积物主要受昌化江影响,粒径粗,表现为河口沉积特征;北黎湾中部沉积区,沉积物粒径分布范围广,表现为较强的过渡区特性;八所港近岸沉积区,沉积物粒径最细,泥沙来源主要为外海带来的泥沙。 相似文献
19.
S. M. Ussenkov 《Environmental Geology》1997,32(4):274-280
The areal distribution of oil products and various trace metals have been studied in bottom surface deposits from the harbors
of Neva Bay. The data of contents were normalized to natural background concentrations. Also the size and biomass of benthos
groups were analyzed. The results show clearly that industrial discharges have elevated levels of contamination in the sediments.
Few efficient measures against environmental contamination have been taken. The sediments contain very high concentrations
of oil products and such heavy metals as Hg, Pb, Cu, and Zn. The benthic organisms most sensitive to heavy metal contamination
are Chironomidae. The dredging and dumping of the contaminated deposits can lead to secondary contamination of the Gulf of Finland and the
Baltic proper.
Received: 18 November 1996 · Accepted: 17 March 1997 相似文献
20.
强潮海湾近岸表层沉积物时空分布特征及水动力响应——以杭州湾北岸为例 总被引：5，自引：0，他引：5
沉积物粒度参数是表征其分布和输运特征的重要信息。根据2005年7月和2006年12月采集的167个表层沉积物样品以及收集到的实测水文资料,以杭州湾北岸为例,分析研究强潮海湾近岸表层沉积物的时空变异特征,同时在应用GSTA模型对沉积物进行输运趋势分析的基础上探讨该区域的泥沙来源,并通过掀沙计算分析表层沉积物对高能水动力环境的响应过程。结果表明:（1）杭州湾北岸表层沉积物普遍较细,以粉砂质粘土为主,在南汇、金山岸段存在两个砂质密集区,并且随动力条件的不同在由岸向海方向呈现出逐渐变细的粒度趋势;（2）表层沉积物粒度特征在洪、枯季亦存有差异,枯季较洪季存在普遍粗化现象;（3）GSTA模型结果显示该区域泥沙主要来源于上游岸段来沙和湾口海域来沙,此外局部区域之间的泥沙交换过程也是区域内泥沙平衡协调的重要途径;（4）潮流掀沙作用主要以南汇和奉贤水域为主,波浪掀沙作用范围基本覆盖研究区域的整个岸段,且波高为1.5 m（P=94.9%）以下的波浪掀沙作用对浅水区域的影响最为显著。 相似文献