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1.
新疆贝勒库都克A型花岗岩锆石U-Pb年龄、地球化学及锡成矿 总被引：1，自引：0，他引：1
新疆东准噶尔卡拉麦里地区是一个重要的锡成矿带,分布有多种类型花岗岩。贝勒库都克岩体位于锡成矿带中部,由黑云母正长花岗岩和黑云母二长花岗岩组成。本文通过精确的LA-ICP-MS锆石U-Pb测年获得贝勒库都克含锡黑云母正长花岗岩年龄为283±2Ma,MSWD=0.14(95%置信度),时代属于早二叠世,这与东准噶尔后碰撞深成岩浆活动的范围(330~265Ma)相吻合。岩石地球化学研究表明,贝勒库都克岩体富硅(SiO2=75.25%~76.67%),低铝(Al2O3=11.91%~12.86%),贫镁(MgO=0.02%~0.18%)和钙(CaO=0.39%~0.89%),富碱(Na2O+K2O=8.08%~8.97%),K2O>Na2O,NK/A=0.86~0.95(平均0.92),A/NCK=0.97~1.02,富集Rb、K等大离子亲石元素及Zr、Hf等高场强元素,Ba,Nb,Sr强烈亏损,δEu=0.01~0.11,其FeOt/MgO(12.71~84.51,平均34.55)和10000Ga/A1(2.97~4.20)值大,HFSE元素(Zr+Nb+Ce+Y=191.8×10-6~353.3×10-6)含量高,明显不同于典型的I型和S型花岗岩,基本属于典型的铝质A型花岗岩。年代学和地球化学综合研究表明,贝勒库都克铝质A型花岗岩是壳幔混合成因,是准噶尔地区后碰撞幔源岩浆底侵作用导致大陆地壳垂向生长过程的记录者。贝勒库都克铝质A型花岗岩Sn的含量高(6.0×10-6~19.5×10-6,个别为80.0×10-6),铝质A型花岗岩是成矿热液的直接母体,而富Sn的流体相最终形成了贝勒库都克锡矿床,锡矿与铝质A型花岗岩是同期地质事件的产物。 相似文献
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北阿尔金构造带红柳沟钾长花岗岩地球化学特征、LA-ICP-MS锆石U-Pb定年和Hf同位素组成 总被引：11，自引：1，他引：10
出露于阿尔金构造带北缘红柳沟-拉配泉混杂岩带西段的红柳沟钾长花岗岩, SiO2>69.0%, Al2O3>13.0%,(K2O+Na2O)>7.0%, K2O/Na2O>1, A/CNK介于1.04~1.08之间, 属高钾钙碱性系列的弱过铝质岩石。该岩石富集大离子亲石元素(LILE), 亏损Nb、Ta、Sr、P、Ti等高场强元素(HFSE);∑REE偏低(128.47×10-6~150.67×10-6), Eu负异常中等(δEu=0.59~0.67), LREE相对富集, 轻重稀土元素分馏明显, 其Nb/Ta、Zr/Hf比值接近上地壳, 锆石具有负的εHf(t)值(-7.13~-5.12),两阶段Hf模式年龄(TDM2)变化范围为1786~1912Ma, 反映其源区物质主要来源于古老地壳。源岩判别图解和Al2O3/TiO2<100指示其为中上地壳变质砂屑质沉积岩部分熔融的产物。LA-ICP-MS锆石U-Pb年龄为500.3Ma±1.2Ma, 结合锆石CL图像具有岩浆环带特征和Th/U>0.4, 推断该年龄为花岗岩的形成年龄。综合区域地质背景, 认为该岩石形成于与洋壳俯冲作用有关的陆缘火山弧环境。 相似文献
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老挝是东南亚地区多金属矿产的重要产地, 本文首次依据老挝全境1:100万地球化学填图数据, 初步研究了老挝铜地球化学地球化学背景和空间分布特征, 圈定了老挝地球化学异常, 主要取得了如下结论: 1)老挝水系沉积物铜含量分布范围在1.20×10–6～459.00×10–6, 平均值21.96×10–6, 背景值16.50×10–6, 不同构造单元中铜含量而言, 长山地块和各类缝合带上的铜元素平均值和中位值显著大于其他构造单元; 2)老挝铜的地球化学图显示, 其铜元素分布不均, 总体上表现为北部较高, 南部较低的格局; 3)用含量累计频率85%(33.1×10–6)为异常下限, 全老挝境内圈定铜元素地球化学异常13处, 其中4处达地球化学省规模(>1000 km2), 为老挝铜矿成矿远景区划分和勘查提供了基础性资料。 相似文献
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湖北省随州花山蛇绿混杂岩Sm—Nd、Rb—Sr同位素年代研究 总被引：2，自引：0，他引：2
对湖北省随州地区组成花山蛇绿混杂岩的杨家棚MORB型火山岩、小阜岛弧型火山岩进行了Sm-Nd、Rb-Sr同位素分析。由杨家棚地区火山岩样品得出的全岩Sm-Nd等时线年龄为1736±37(2σ)Ma,I_(Nd)=0.510582±42(2σ),ε_(Nd)(t)=+3.7;由小阜火山岩样品得出的全岩Sm-Nd等时线年龄为1197±170(2σ) Ma,I_(Nd)=0.51125±18(2σ),ε_(Nd)(t)=+3.1;小阜火山岩样品全岩Rb-Sr等时线年龄为737±31(2σ)Ma,I_(sr)=0.7052±13(2σ)。这些结果表明花山洋盆的形成时间可能为中元古代,而非古生代;737Ma指示了其后期的变质年龄。 相似文献
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海南晨星安山质火山岩地球化学、年代学特征及其构造意义 总被引：2，自引：0，他引：2
海南晨星地区发育一套变安山质火山岩,呈透镜状或层状夹于晚古生代变沉积地层中。该安山质火山岩SiO2含量为52.87%～65.27%;富Al2O3(15.59%～21.55%),具有较高的稀土元素丰度(ΣREE=166.80×10-6～246.21×10-6),平均204.39×10-6,(La/Yb)N=5.78～7.47,(Gd/Yb)N=1.24～1.58;大离子亲石元素富集、高场强元素Nb-Ta和Ti-P亏损明显,Eu弱负异常(δEu=0.72～0.90);在Nb/Y-(Zr/TiO2)×10-4和La/Yb-Sc/Ni图解上落入安山质大陆岛弧型火山岩区。火山岩样品10HN13B的LA-ICP-MS锆石U-Pb年代学测试表明,该安山质火山岩形成年龄为345±4Ma,表明在早石炭世晚期(～345Ma)在海南中部存在有安山质弧岩浆作用。该年龄的获得表明晨星地区夹持该安山质火山岩的原下二叠统峨查组很可能为一套石炭-二叠纪海相火山-碎屑沉积建造,或需要进一步解体。 相似文献
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巴斯克花岗闪长岩位于野马泉岛弧内,本文综合野外地质、岩相学、地球化学以及锆石U-Pb年代学等多学科手段,进而为该地区晚石炭世时期构造背景提供岩浆岩约束。岩石地球化学研究表明,岩体主量元素具有高硅、准铝—弱过铝质、钙碱性的I型花岗岩特征;岩石样品稀土元素总量在83.79×10-6至 125.67×10-6之间,且轻/重稀土之间的比值介于5.32至8.63之间(平均值为7.1),指示轻稀土较重稀土富集。Eu 元素轻度负异常 (δEu=0.69~0.89)。样品富集大离子亲石元素(如K、Rb、Ba),且亏损高场强元素(HFSE,如Nb、Ta和Ti)及P, Nb、Ta负异常明显。岩体锆石206U/238Pb加权平均年龄为301.3±2.5 Ma (MSWD=0.33)和310.7±3.6 Ma (MSWD=0.75),表明岩体形成时代为晚石炭世。综合区域地质特征、岩石地球化学和岩浆源区特征,表明东准噶尔地区晚石炭世(310~301 Ma)处于造山带碰撞后的陆壳伸展构造体制,且岩浆具有壳幔混合和分批熔融、增量生长的特征。 相似文献
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中天山白石头泉岩体年代学、岩石成因及构造意义 总被引：2，自引：2，他引：0
白石头泉岩体位于中天山北缘边界断裂(沙泉子断裂)南侧。该岩体从下至上可分为五个连续过渡的岩相带,即淡色花岗岩(a带),含天河石花岗岩(b带),天河石花岗岩(c带),含黄玉天河石花岗岩(d带)以及黄玉钠长花岗岩(e带),其中,b、c、d和e带均为a带分异的产物。白石头泉岩体的LA-ICP-MS锆石U-Pb定年结果表明,该岩体侵位于早二叠世早期(295.6±1.3Ma),并于印支期(~214Ma)经历了一次热事件的改造。淡色花岗岩在主量元素上富硅(SiO2= 74.93%~76.18%)、富碱(K2O + Na2O=8.07%~8.80%)、富钠(K2O / Na2O=0.82~0.89),贫钙、镁,而在微量元素上富Rb、F和Ga(Al/Ga比值为2217~3134),贫Ba、Sr和Eu并具强烈的铕负异常(δEu=0.0020~0.0091),反映出其源区为富含白云母的片岩(或片麻岩),成岩压力较低,温度大于860℃。结合区域地质特征,作者等认为白石头泉岩体形成于相对拉张的构造背景,是中-上地壳源岩经历高温贫水熔融的产物,其形成与幔源岩浆内侵作用有关。 相似文献
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阜平群下部太古代变质岩石的REE、Rb-Sr和Sm-Nd年龄及其意义 总被引：16，自引：0，他引：16
对采自阜平群下部16个变质岩石样品进行了Sm-Nd年龄测定,部分样品还进行了Rb-Sr年龄测定和REE分析。Sm-Nd同位素结果形成两条等时线。一条等时线具有年龄为:2790±171(2σ)Ma,I_(Nd)=0.50917±16(2σ),ε_(Nd)(t)=±1.6;另一条等时线,t=1949±84(2σ)Ma,I_(Nd)=0.50986±5(2σ),ε_(Nd)(t)=-5.0±1.0。Rb-Sr同位素数据分散,参考等时线年龄为2070Ma。 相似文献
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新疆西准噶尔接特布调A型花岗岩年代学、地球化学及岩石成因 总被引：3，自引：0，他引：3
西准噶尔乃至整个北疆地区广泛发育晚古生代后碰撞花岗岩类。接特布调岩体作为一个典型的代表, 岩石类型主要有中粗粒二长花岗岩和正长花岗岩, 是认识西准噶尔花岗岩岩石成因及构造-岩浆演化的关键。本文对接特布调岩体进行高精度锆石LA-ICP-MS U-Pb测年, 获得二长花岗岩和正长花岗岩的加权平均206Pb/238U年龄分别为(287±9) Ma(n=10, MSWD=0.92)和(278±3) Ma(n=14, MSWD=0.43), 确定其形成于早二叠世, 属于300 Ma前后准噶尔周边地区后碰撞岩浆活动的产物。岩石地球化学研究表明, 前人认为的接特布调I型花岗岩应归属于A型花岗岩。正长花岗岩具有高硅(SiO2: 76.11%~76.82%), 富碱(Na2O+K2O: 8.47%~8.49%), 低钛(TiO2: 0.04%~0.05%), 贫钙(CaO: 0.36%~0.42%)的特征。二长花岗岩与其类似, 高硅(SiO2: 68.35%~71.80%), 富碱(Na2O+K2O: 6.80%~7.86%), 低钛和钙(TiO2: 0.29%~0.82%, CaO: 1.76%~2.87%), 均属于准铝质或弱过铝质(ACNK: 0.98~1.09)高钾钙碱性系列。正长花岗岩相对于二长花岗岩具有相对较低的稀土元素总量(ΣREE)(分别为23.8×10-6~49.3×10-6, 95.23×10-6~222.2×10-6), 并具有明显的负Eu异常(Eu/Eu*分别为0.01~0.02, 0.57~0.72), 另外, 正长花岗岩相对二长花岗岩明显地富集大离子亲石元素(Rb、Th、K)及高场强元素(Zr、Hf、Nb), 而强烈亏损Ba、Sr、Eu、Ti等, 具有较高的10000Ga/Al比值(>2.44)。依据微量元素比值及相关判别图, 可将接特布调花岗岩体进一步细分为A1型和A2型。接特布调岩体就位于后碰撞环境, 来源于由年轻的地幔来源物质组成的下地壳。在后碰撞岩浆活动的初期, 年轻的下地壳部分熔融形成具有岛弧印迹的A2型二长花岗岩岩浆, 随着岩石圈进一步伸展, 可能在局部出现类似裂谷的环境, 即形成显示裂谷特征的A1型正长花岗岩岩浆。 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance. 相似文献
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Alexander E. C. Broberg J. S. Kehren A. R. Graziani M. M. Turri W. L. 《Environmental Geology》1993,22(4):353-361
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes. 相似文献
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岩石密度和超高压岩石折返速率 总被引：1，自引：3，他引：1
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。 相似文献
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滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床. 相似文献