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1.
出露于阿尔金造山带帕夏拉依档沟一带的帕夏拉依档岩体主要岩性为二长花岗岩、偶含斑黑云母二长花岗岩和正长花岗岩。二长花岗岩LA-ICP-MS锆石U-Pb测年结果显示其形成年龄460.1±3.9Ma,表明帕夏拉依档岩体形成于中—晚奥陶世。地球化学结果显示,常量元素具有富硅(Si O2=72.08%~72.27%)、富铝(Al2O3=14.10%~14.79%,A/CNK=1.06~1.18)、富钾(K2O=5.55%~6.33%,K2O/Na2O=1.95~2.21),低钛(Ti O2=0.19%~0.23%)、贫铁(TFe O=1.48%~1.79%)、贫镁(Mg O=0.22%~0.28%)的特点,为弱过铝质花岗岩系列,具典型的高钾钙碱性特征。稀土元素总量较高(165.58×10-6~229.86×10-6),轻稀土元素相对富集、重稀土元素亏损,有右倾型特征和明显的负Eu异常(δEu=0.11~0.17)。Ba、Sr、Ti等具负异常,Rb、Th、U、K等大离子亲石元素具正异常,Rb/Sr比值高(9.05~12.57),显示S型花岗岩特征。结合原岩判别图解,推断其源区物质主要来源于上地壳变泥质沉积岩类。结合区域资料,认为帕夏拉依档岩体形成于挤压体制向拉张体制转换的构造环境,属后碰撞花岗岩类,表明在中—晚奥陶世阿中地块和和柴达木地块间阿尔金造山带已由挤压碰撞阶段转为伸展后碰撞阶段。  相似文献   

2.
浙东地区岩浆岩广泛分布,受区域构造控制较明显,总体沿北东向余姚-丽水断裂带分布。本文对东园花岗岩体开展了详细的年代学和岩石地球化学研究。东园岩体主要由二长花岗岩、石英二长岩和少量花岗岩组成,主岩体二长花岗岩的LA-ICP-MS锆石U-Pb年龄为235.6±0.7 Ma(MSWD=0.97,2σ),花岗岩为238.1±0.8 Ma(MSWD=1.3,2σ),均属中三叠世产物。二长花岗岩和石英二长岩为准铝质-弱过铝质的钙碱性花岗岩,具高硅(62.94%~75.29%)、富碱(Na_2O+K_2O=8.17%~9.34%)且富钾(K_2O=4.54%~5.63%)的特征,轻重稀土分馏明显,具有较强的Eu正异常(δEu=0.94~2.43),明显亏损高场强元素(HFSE)Nb、P、Ti,而相对富集Th、Hf,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb,相对贫Ba。岩体属高(-中等)分异I型花岗岩,岩浆来源于具弧属性的加厚地壳部分熔融,形成于同碰撞向后碰撞阶段转变的大地构造环境,可能与太平洋板块向华南板块俯冲作用事件有关。  相似文献   

3.
西准噶尔乃至整个北疆地区广泛发育晚古生代后碰撞花岗岩类。接特布调岩体作为一个典型的代表, 岩石类型主要有中粗粒二长花岗岩和正长花岗岩, 是认识西准噶尔花岗岩岩石成因及构造-岩浆演化的关键。本文对接特布调岩体进行高精度锆石LA-ICP-MS U-Pb测年, 获得二长花岗岩和正长花岗岩的加权平均206Pb/238U年龄分别为(287±9) Ma(n=10, MSWD=0.92)和(278±3) Ma(n=14, MSWD=0.43), 确定其形成于早二叠世, 属于300 Ma前后准噶尔周边地区后碰撞岩浆活动的产物。岩石地球化学研究表明, 前人认为的接特布调I型花岗岩应归属于A型花岗岩。正长花岗岩具有高硅(SiO2: 76.11%~76.82%), 富碱(Na2O+K2O: 8.47%~8.49%), 低钛(TiO2: 0.04%~0.05%), 贫钙(CaO: 0.36%~0.42%)的特征。二长花岗岩与其类似, 高硅(SiO2: 68.35%~71.80%), 富碱(Na2O+K2O: 6.80%~7.86%), 低钛和钙(TiO2: 0.29%~0.82%, CaO: 1.76%~2.87%), 均属于准铝质或弱过铝质(ACNK: 0.98~1.09)高钾钙碱性系列。正长花岗岩相对于二长花岗岩具有相对较低的稀土元素总量(ΣREE)(分别为23.8×10-6~49.3×10-6, 95.23×10-6~222.2×10-6), 并具有明显的负Eu异常(Eu/Eu*分别为0.01~0.02, 0.57~0.72), 另外, 正长花岗岩相对二长花岗岩明显地富集大离子亲石元素(Rb、Th、K)及高场强元素(Zr、Hf、Nb), 而强烈亏损Ba、Sr、Eu、Ti等, 具有较高的10000Ga/Al比值(>2.44)。依据微量元素比值及相关判别图, 可将接特布调花岗岩体进一步细分为A1型和A2型。接特布调岩体就位于后碰撞环境, 来源于由年轻的地幔来源物质组成的下地壳。在后碰撞岩浆活动的初期, 年轻的下地壳部分熔融形成具有岛弧印迹的A2型二长花岗岩岩浆, 随着岩石圈进一步伸展, 可能在局部出现类似裂谷的环境, 即形成显示裂谷特征的A1型正长花岗岩岩浆。  相似文献   

4.
浙江北部地区位于扬子及华夏两大板块相交接的江绍断裂带的北段,出露的新元古代花岗岩有石角、平水、桃红和西裘等岩体,年龄位于814Ma~932Ma之间。本文获得的该时期含白云母花岗岩锆石LA-ICP-MS U-Pb年龄为960.1Ma±6.5Ma,为新元古代早期岩浆活动产物。地球化学特征显示其SiO2质量分数普遍较高,变化于72.89%~74.82%、w(CaO)为0.24%~1.44%、全碱含量较高(7.46%~8.50%)且K2O质量分数普遍高于Na2O(w(Na2O)为2.08%~4.41%、w(K2O)为3.22%~6.00%之间),A/CNK为0.98~1.34,为偏铝质到过铝质系列;富集K,Rb,Ba等大离子亲石元素(LILE)和轻稀土元素(LREE/HREE=12.02~16.10),轻重稀土分馏明显((La/Yb)N=11.02~24.16),具中等至弱的Eu负异常(δEu=0.21~0.85),而Nb,Ta,Ti等高场强元素(HFSE)则相对亏损。以上特征均表明浙北绍兴地区新元古代早期花岗岩类可能源于过铝质熔体,局部富集白云母晶簇的岩相学特征也表明岩石类型类似于富云母的过铝质花岗岩类(CPG),物质来源可能为富云母的变泥质沉积岩的部分熔融,形成环境更可能为同碰撞及后碰撞环境,与陆壳碰撞加厚导致的剪切重熔有关。  相似文献   

5.
与锡矿有关的花岗岩成因一直是地学界关注的焦点。来利山花岗岩位于云南省腾冲—梁河地区(花岗岩带上),构造上属于腾梁花岗岩带。该花岗岩带总体呈北北东向带状展布,构成冈底斯的南延部分。来利山岩体主要由似斑状黑云母二长花岗岩和中粗粒黑云母正长花岗岩组成。本次工作在前人研究的基础上对来利山花岗岩进行了岩石学、地球化学和年代学研究,获得二长花岗岩(14L-4)锆石LA-ICP-MS U-Pb年龄为(52.34±0.68)Ma(MSWD=1.4,n=26)。地球化学数据显示二长花岗岩相对富铝(Al2O3=14.70%~15.27%)、碱(K2O+Na2O=8.07%~8.50%)、钙(Ca O=1.64%~2.56%)、REE、Ba。铝饱和度(A/CNK)为0.97~1.12,平均为1.04,属偏铝质到弱过铝质岩石。正长花岗岩相对富硅(Si O2=74.57%~76.69%)、Rb,强烈亏损Ba、Sr、P、Ti、Eu,铝饱和度(A/CNK)为1.05~1.18,平均为1.09,属弱过铝质岩石。两类花岗岩系同源岩浆于不同阶段侵位形成,二者在矿物学、地球化学、年代学等方面表现出良好的演化关系,均显示S型花岗岩的特征。其形成与印度大陆和亚洲大陆碰撞过程中地壳物质部分熔融有关。  相似文献   

6.
罗伟 《地质与勘探》2016,52(2):261-270
碧罗雪山花岗岩体位于三江成矿带中段的左贡岩浆弧带内,由花岗闪长岩、二长花岗岩、钾长花岗岩和少量暗色包体组成。花岗岩类SiO_2含量67.10%~74.67%,富钾(K_2O/Na_2O=1.32~2.67)和低CaO(0.83%~2.6%),铝过饱和指数A/CNK=1.07~1.26,标准矿物中出现刚玉(1.06~3.38)。以上特征表明,该岩体为强过铝质高钾钙碱性S型花岗岩。稀土元素配分曲线呈右倾型,具弱至中等负Eu异常(δEu=0.38~0.97),相对亏损Nb、Ta、P、Ti等高场强元素,富集Cs、Rb、Th、U、K等大离子亲石元素。研究表明花岗岩为富含长石的砂屑岩部分熔融形成,形成于挤压环境向伸展环境转换的后碰撞阶段,为临沧花岗岩基的北延部分。  相似文献   

7.
湘东北位于扬子板块东南缘江南造山带中段,出露的新元古代花岗岩有长三背、大围山和葛藤岭等岩体,同属于九岭岩体的一部分。湘东北新元古代花岗岩SiO2含量变化于60%~72%、CaO为0.6%~3%、Na2O为1.98%~3.72%、K2O为2.95%~4.99%之间,A/CNK>1.1,富集K、Rb、Ba等大离子亲石元素(LILE)和轻稀土元素(LREE/HREE=3.1~10.5)、Eu负异常明显(δEu=0.37~0.58),而Nb、Ta、Ti等高场强元素(HFSE)相对亏损。这些特征表明湘东北新元古代花岗岩来源于过铝质熔体,岩石类型上类似于富黑云母过铝花岗岩类(CPG),可能来源于富黑云母的变泥质沉积岩的熔融,如中元古代冷家溪群变质沉积岩等,形成于同碰撞环境,可能与陆壳加厚导致的剪切重熔有关。  相似文献   

8.
滇西腾冲—梁河地区发育古近纪二长花岗岩和钾长花岗岩,记录了印度-欧亚大陆碰撞的岩浆活动信息。二长花岗岩的锆石U-Pb年龄为51.4±0.4 Ma,其176 Hf/177 Hf值为0.282554~0.282592,εHf(t)=-6.65~-5.30,其二阶段模式年龄为1.46~1.55Ga。腾冲—梁河古近纪花岗岩以高SiO2(68.96%~78.68%)、高K2O(4.56%~6.29%)和高Al2O3(12.40%~16.42%)为特征,K2O/Na2O值为0.93~7.24,Al2O3(K2O+Na2O),A/CNK值为0.99~2.31,属于富钾钙碱性偏铝—强过铝质花岗岩;绝大多数样品具有强烈的负Eu异常(Eu/Eu*为0.19~0.51),富集Cs、Rb,亏损Sr、P、Ti、Ba、Nb、Ta,具有Pb的正异常。元素地球化学特征指示,其主要源于区域上地壳变质杂砂岩的部分熔融;结合区域地质,认为腾梁地区62~51Ma的花岗岩是对印度-欧亚大陆碰撞高峰期的岩浆响应。  相似文献   

9.
粤北竹山下岩体锆石U-Pb同位素定年及其地球化学特征   总被引:1,自引:0,他引:1  
竹山下岩体锆石SHRI MP U-Pb年龄为161.0±3.0 Ma,属燕山早期岩浆活动产物。该岩体的主要元素显示富硅(Si O2=76.05%~79.16%)、富碱(K2O+Na2O=7.77%~8.40%)、强过铝质(A/CNK=1.08~1.26)和低CaO/Na2O值(0.04~0.06)等特征。微量元素富集大离子元素而亏损Ba,Sr,Ce和Ti;LREE轻微亏损(LREE/HREE=0.82~1.09),Eu亏损明显(δEu=0.06~0.11),且具有较明显的四分组效应(TE1,3=1.07~1.24)。上述特征表明,竹山下岩体属于典型的壳源型花岗岩,是在地壳伸展-减薄的构造背景下,由泥质变质岩经过低程度部分熔融的方式而形成。  相似文献   

10.
内容提要:滇西腾冲–梁河地区发育古近纪二长花岗岩和钾长花岗岩,记录了印度–欧亚大陆碰撞的岩浆活动信息。二长花岗岩的锆石U-Pb年龄为51.4±0.4Ma,其176Hf/177Hf比值为0.282554~0.282592,εHf(t)= -6.65~-5.30,其二阶段模式年龄为1.46~1.55Ga。腾冲–梁河古近纪花岗岩以高SiO2 (68.96%~78.68%)、高K2O (4.56%~6.29%)和高Al2O3(12.40%~16.42%)为特征,K2O/Na2O比值为0.93~7.24,Al2O3>(K2O+Na2O),A/CNK值为0.99~2.31,属于富钾钙碱性偏铝–强过铝质花岗岩;绝大多数样品具有强烈的负Eu异常(Eu/Eu*为0.19~0.51),富集Cs、Rb,亏损Sr、P、Ti、Ba、Nb、Ta,具有Pb的正异常。元素地球化学特征指示,其主要源于区域上地壳变质杂砂岩的部分熔融;结合区域地质,认为腾梁地区62~51Ma的花岗岩是对印度–欧亚大陆碰撞高峰期的岩浆响应。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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20.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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