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1.
塔里木盆地哈拉哈塘凹陷天然气地球化学特征   总被引:2,自引:0,他引:2  
哈拉哈塘凹陷位于塔里木盆地塔北隆起中部,具有良好的石油地质条件,是近期油气勘探的重点区带。天然气地球化学特征研究表明,该区天然气干燥系数较低,表现出典型湿气的特征,普遍含有微量的H2S;烷烃气δ13C1和δ13C2值分别为-50.5‰~-42.6‰和-40.2‰~-35.5‰,δD1值介于-262‰~-156‰之间,碳氢同位素系列表现出典型正序特征; C7轻烃组成具有正庚烷优势分布, C5~7轻烃组成以正构和异构烷烃为主。哈拉哈塘凹陷及周缘奥陶系天然气均为海相油型气,既有干酪根裂解气,也有原油裂解气,其中哈拉哈塘天然气中混入了相当比例的原油裂解初期形成的湿气,主要来自于南部阿满过渡带地区的中上奥陶统烃源岩,天然气中具有高δ13C值特征的CO2主要来自碳酸盐岩储层在酸性地层水作用下发生的溶蚀, H2S主要源自含硫化合物的热裂解。其中天然气发生的同位素部分倒转主要源自原油伴生气与原油裂解气的混合。  相似文献   

2.
The origin and genetic types of natural gas in the Sichuan Basin are still disputed. To classify the origin and genetic types in different areas, the paper analyzes the carbon isotopic composition of gases and geologic features in the Sichuan Basin. The results showed that the gas sourced from terrestrial layers is typically characterized by terrestrial origin and was mainly accumulated nearby to form reservoir. The carbon isotopic composition of gas showed a normal combination sequence distribution, suggesting that natural gas in continental strata is not affected by secondary alteration or that this deformation is very weak. The gas source is singular, and only gas from the southern and northern Sichuan Basin shows the characteristic of mixed sources. However, marine gas presents the characteristics of an oil-formed gas. The carbon isotopic composition of natural gas in the western and central part of the basin mostly distributes in a normal combination sequence, and few of them showed an inversion, indicating that the gas perhaps had not experienced secondary alteration. The carbon isotopic composition of marine-origin gas in the southern, northern and eastern Sichuan Basin displays a completely different distribution pattern, which is probably caused by different mixing ratio of gas with multi-source and multi-period.  相似文献   

3.
Bongor盆地位于乍得境内的中非剪切带西北部,是中新生代重要的含油气盆地之一。笔者从Bongor盆地天然气组分组成及组分碳、氢同位素分析入手,综合运用常规有机地球化学分析方法,探讨了Bongor盆地不同构造单元天然气的成因及成熟度差异。分析认为,Bongor盆地天然气化学组成主要由烃类气体、非烃类气体和微量稀有气体组成,其中烃类气体属于生物热催化过渡带气、原油伴生气和凝析油伴生气等有机成因气,非烃气体主要包括无机成因的氮气、二氧化碳和氢气等。在天然气成因研究的基础上,笔者还开展了Bongor盆地烃类气体的组成及来源分析,包括气气对比和气源对比,研究认为,不同构造单元的烃类气体虽然组成相同,但相对含量略有差异,表明不同构造单元的天然气具有相似的母质来源:M组和P组的暗色泥页岩;但也不排除K组暗色泥页岩的生烃贡献。不同构造单元天然气烃类气体的成熟度差异较大,这是由于天然气源自不同层位烃源岩或同一层位烃源岩在不同演化阶段的生烃产物。  相似文献   

4.
The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin.  相似文献   

5.
川西坳陷南段天然气来源与碳同位素地球化学研究   总被引:6,自引:0,他引:6       下载免费PDF全文
川西坳陷南段是四川盆地主要的天然气产区之一。前人对该区天然气的来源有多种见解。为了更清楚地认识此地区天然气的来源与运移,本文分析了平落坝、大兴西和白马庙气田16件天然气样品的C1-C4烃及CO2组份的碳同位素组成。所获得的同位素数据结合化学成份和地质资料表明,3个气田的烃类完全是热解成因的,都来源于气田下面的上三叠统烃源岩。这些气田的甲、乙烷碳同位素组成随深度呈不同规律的变化,这些变化归因于烃源岩生烃的热解过程和烃类运移的动力学过程。平落坝气田中侏罗统气藏的烃类大部份形成于烃源岩低成熟和成熟的早期阶段并受到晚期成熟气体的不断补给。平落坝和大兴西气田多数气藏的烃类被认为是从源区垂直向上运移通过上伏地层而进入气藏的,白马庙气田的烃类被认为是沿断裂通道向上侏罗统气藏聚集的。平落坝和大兴西气田的δ^13Cco2值有很宽的分布范围(-10.7‰~-0.7‰),这表明气田的CO2由来自基底的海洋碳酸盐岩无机碳成份和沉积地层的有机碳成份混合而成。这些气田的[He/CH4]-[N2/CH4]值之间和δ^13Cco2-δ^13Cc1值之间的相关性表明,非烃气体在进入气藏前已同烃类很好地混合,并被CH4为主流相的气流携带着向气藏运移。  相似文献   

6.
The Lunnan Lower Uplift in the Tarim Basin, NW China contains a composite petroleum system with mainly biodegraded heavy oil in the west, normal oil in the center and gas condensate in the east. Twenty-three gas samples and 37 oil samples taken from three major hydrocarbon bearing intervals in the Lunnan lower bulge were analyzed for their stable carbon isotopes and molecular biomarkers. On the basis of their isotopic compositions, biomarkers, especially diamondoids, and integrating the physical properties of the hydrocarbons including densities, GOR and PVT relationships, it has been concluded that the recently discovered deep (6500 m) eastern Lungu giant Ordovician gas condensate pool with an estimated reserve of 723 million bbl oil equivalent is a secondary hydrocarbon accumulation derived from the mixing of an early formed oil and a late formed gas. The extremely dry gases with a gas dryness of >0.98 were derived from thermal cracking of crude oils and charged to an existing oil reservoir causing extensive gas washing and secondary alteration. Compared with most of the hydrocarbons in the Lunnan area, the gas from the eastern Lungu gas condensate pool has a heavier carbon isotopic composition, higher dryness and a higher maturity level. The unique physical, chemical and isotopic compositions of the gas condensate are believed to be a direct result of gas flushing of an early formed eastern Lungu oil pool by a late formed dry gas from oil cracking. The eastern Lungu gas condensate pool is presently characterized by containing “dry gas, heavy oil, abundant aromatics and high wax”.  相似文献   

7.
塔里木盆地北部奥陶系油气相态及其成因分析   总被引:8,自引:3,他引:5  
塔里木盆地北部地区奥陶系是最重要的勘探层系,油气资源丰富;同时油气相态复杂多样,既有凝析气藏、正常油藏,也有稠油油藏、沥青等。通过对油气藏形成演化与保存过程的系统分析,结合油气地球化学和流体包裹体等分析数据,发现油气相态的多样性与油气多期次充注与次生蚀变作用有关。提出塔北隆起的东部奥陶系存在三期油气充注过程,分别发生在加里东运动晚期-海西早期、海西运动晚期、喜马拉雅运动晚期,原油主要来源于中、上奥陶统烃源岩,天然气主要来自与寒武系烃源岩有关的液态烃的裂解;塔北隆起的中西部奥陶系的油气充注主要发生在海西运动晚期。塔北奥陶系油藏形成以后,经历了三期明显的调整改造过程:海西早期构造抬升导致志留-泥盆系遭受剥蚀,东部源自寒武系油气的古油藏遭受破坏,形成沥青;三叠系沉积前的晚海西运动,使得奥陶系生源的油藏大范围遭受降解稠化;晚喜山期,来自于满加尔坳陷的天然气自东向西充注,致使隆起东部早期形成的油藏发生强烈的气侵改造,形成次生凝析气藏。而中西部奥陶系油藏在三叠系沉积前遭受降解稠化后,一直处于沉降深埋过程,油藏得到有效保存;由于成藏时间较早,轻质组分散失较多,气油比极低,油质较稠。研究认为,油气相态的多样性主要受晚海西期构造运动的抬升造成的生物降解作用和喜马拉雅晚期构造运动造成的天然气自东向西大规模充注对油藏进行气洗改造两大过程的控制。  相似文献   

8.
王杰  顾忆  饶丹  楼章华 《地球化学》2007,36(6):549-558
塔河油田奥陶系天然气主要以烃类气体为主,甲烷占绝对优势,绝大部分天然气重烃含量较高,非烃气体以N2和CO2为主,含有一定量的H2S.塔河奥陶系天然气具有相同母质来源,为不同成熟度油型气的复合,二氧化碳气体为碳酸盐岩热变质作用产生.塔河奥陶系天然气的生成具有多阶连续的特征,既有反映成熟阶段的正常原油伴生气和较高成熟阶段的凝析油伴生气,又有反映高过成熟阶段的高温裂解气.主体区奥陶系天然气具有两期充注、两期混合的特征.早期充注的为典型原油伴生气,充注方向为从东南向西北,从东向西;晚期充注的为高温裂解气,充注方向为从东向西.还对两期主要天然气充注的范围进行了初步厘定.  相似文献   

9.
肖中尧  卢玉红  吴懿  赵福元  钱玲  金英爱 《地质科学》2005,40(2):262-273,283
满东1气藏的发现是塔里木盆地东部地区油气勘探获得新突破的重要标志。本文充分利用目前所获得的大量地质和地球化学资料,从天然气的组份特征、成因类型、成熟度和气源对比等方面对该井天然气的成因进行了分析,认为满东1井天然气属于海相腐泥型天然气,来源于寒武系-下奥陶统海相过成熟烃源岩,烃类气体组成具有油裂解气的特征。海相泥质烃源岩中氨基粘土矿物在过成熟阶段分解并氧化,形成大量的氮气,导致满东1气藏高含氮气。包裹体和埋藏史研究结果表明满东1气藏成藏过程复杂,主要成藏期为燕山喜马拉雅期。  相似文献   

10.
鄂尔多斯盆地海相碳酸盐岩层系天然气成藏研究   总被引:7,自引:0,他引:7  
鄂尔多斯盆地两套优质烃源岩,即上奥陶统背锅山组泥灰岩和中奥陶统平凉组中下部页岩,是海相碳酸盐岩层系古油藏原油和现今靖边气田油型气的主要来源。两套优质烃源岩主要分布在盆地的西部和西南部,呈"L"型展布,盆地内部缺失;它们累计厚度约50~350m。平凉泥岩TOC介于0.5%~1.2%,平均0.9%,厚度20~50m,而灰岩TOC主要分布在0.2%~0.4%区间,平均0.3%。背锅山组泥岩有机碳相对较高,TOC介于0.22%~3.3%,平均为0.93%。三叠纪末期,两套优质烃源岩生成的大量液态烃类进入中央古隆起控制的斜坡部位,形成古油藏;侏罗纪-早白垩世,地层持续加深和地温梯度升高,烃源岩热演化程度达到高-过成熟阶段,古油藏温度超过180℃,原油开始热裂解生成天然气。油气的热裂解导致气藏压力不断增大,驱使部分气体进一步扩散运移。晚白垩世燕山运动IV幕,盆地东部大规模持续挤压抬升导致了原有油气藏经历了西高东低转变为东高西低的构造反转,形成构造枢纽。中央隆起带聚集油气的优势被改造,裂解形成的天然气向东或东北方向运移。但是运移过程中,东部盐岩、膏盐、致密碳酸盐岩侧向封堵。在靖边气田中心部位,由于奥陶系顶部缺失石炭系铁铝土岩封盖,使得部分石炭-二叠系生成的天然气沿着不整合面进入风化壳,形成从奥陶系来源的原油裂解气与石炭-二叠系生成的煤型气相混合。  相似文献   

11.
The molecular compositions and stable carbon and hydrogen isotopic compositions of natural gas from the Xinchang gas field in the Sichuan Basin were investigated to determine the genetic types. The natural gas is mainly composed of methane (88.99%–98.01%), and the dryness coefficient varies between 0.908 and 0.997. The gas generally displays positive alkane carbon and hydrogen isotopic series. The geochemical characteristics and gas-source correlation indicate that the gases stored in the 5~(th) member of the Upper Triassic Xujiahe Formation are coal-type gases which are derived from source rocks in the stratum itself. The gases reservoired in the 4~(th) member of the Xujiahe Formation and Jurassic strata in the Xinchang gas field are also coal-type gases that are derived from source rocks in the 3~(rd) and 4~(th) members of the Xujiahe Formation. The gases reservoired in the 2~(nd) member of the Upper Triassic Xujiahe Formation are mainly coal-type gases with small amounts of oil-type gas that is derived from source rocks in the stratum itself. This is accompanied by a small amount of contribution brought by source rocks in the Upper Triassic Ma'antang and Xiaotangzi formations. The gases reservoired in the 4~(th) member of the Middle Triassic Leikoupo Formation are oil-type gases and are believed to be derived from the secondary cracking of oil which is most likely to be generated from the Upper Permian source rocks.  相似文献   

12.
Oil and gas exploration in eastern Tarim Basin, NW China has been successful in recent years, with several commercial gas accumulations being discovered in a thermally mature to over-mature region. The Yingnan2 (YN2) gas field, situated in the Yingnan structure of the Yingjisu Depression, produces gases that are relatively enriched in nitrogen and C2+ alkanes. The δ13C1 (−38.6‰ to −36.2‰) and δ13C2 values (−30.9‰ to −34.7‰) of these gases are characteristic of marine sourced gases with relatively high maturity levels. The distributions of biomarkers in the associated condensates suggest close affinities with the Cambrian–Lower Ordovician source rocks which, in the Yingjisu Sag, are currently over-mature (with 3–4%Ro). Burial and thermal maturity modeling results indicate that paleo-temperatures of the Cambrian–Lower Ordovician source rocks had increased from 90 to 210 °C during the late Caledonian orogeny (458–438 Ma), due to rapid subsidence and sediment loading. By the end of Ordovician, hydrocarbon potential in these source rocks had been largely exhausted. The homogenization temperatures of hydrocarbon fluid inclusions identified from the Jurassic reservoirs of the YN2 gas field suggest a hydrocarbon emplacement time as recent as about 10 Ma, when the maturity levels of Middle–Lower Jurassic source rocks in the study area were too low (<0.7%Ro) to form a large quantity of oil and gas. The presence of abundant diamondoid hydrocarbons in the associated condensates and the relatively heavy isotopic values of the oils indicate that the gases were derived from thermal cracking of early-formed oils. Estimation from the stable carbon isotope ratios of gaseous alkanes suggests that the gases may have been formed at temperatures well above 190 °C. Thus, the oil and gas accumulation history in the study area can be reconstructed as follows: (1) during the late Caledonian orogeny, the Cambrian–Lower Ordovician marine source rocks had gone through the peak oil, wet gas and dry gas generation stages, with the generated oil and gas migrating upwards along faults and fractures to form early oil and gas accumulations in the Middle–Upper Ordovician and Silurian sandstone reservoirs; (2) since the late Yanshanian orogeny, the early oil accumulations have been buried deeper and oil has undergone thermal cracking to form gas; (3) during the late Himalayan orogeny, the seals for the deep reservoirs were breached; and the gas and condensates migrated upward and eventually accumulating in the relatively shallow Jurassic reservoirs.  相似文献   

13.
鄂尔多斯盆地中部气田天然气混源的地球化学标志与评价   总被引:4,自引:1,他引:4  
鄂尔多斯盆地中部气田奥陶系风化壳天然气藏的气源问题是迄今尚有争议的重要问题。在前人大量研究的基础上,系统研究了该气田天然气混源的地球化学特征与标志,并利用多指标综合评价了气藏的气源。研究结果表明,鄂尔多斯盆地中部气田奥陶系风化壳天然气具有高一过成熟干气的组分和同位素特征。天然气的来源比较复杂,既有以石炭一二叠系来源为主的煤成气,又有以下古生界来源为主的油型气。该气田东部区块的天然气主要为煤成气,中部气田北部、西部及南部区块的天然气主要为油型气。  相似文献   

14.
塔里木盆地原油的成因研究   总被引:9,自引:0,他引:9  
段毅  惠荣耀 《甘肃地质》1997,6(1):67-73
对塔里木盆地原油和生油岩饱和烃进行GC-C-MS和GC-MS分析,利用单个正构烷烃碳同位素组成和三环萜烷分布特征进行油源对比,研究了塔里木盆地原油的油源问题;根据寒武—奥陶系富含菌藻有机质生油岩饱和烃色谱分析结果,对塔里木盆地海相原油含蜡较高的成因进行了探讨  相似文献   

15.
Research on the molecular fossil characteristics of heavy oil from Well Tadong-2 is of great importance to constrain the source of marine crude oils in the Tarim Basin, Xinjiang, China. The authors synthetically applied the isotope mass spectrograph, chromatography and chromatography-mass spectrography to the studies of molecular fossil characteristics of heavy oil from Well Tadong-2 in the Tarim Basin, and the results obtained revealed that heavy oil from Well Tadong-2 is characterized by high gammacerane, high C28 sterane, low rearranged sterane and high C27-triaromatic steroid, these characteristics are similar to those of Cambrian-Lower Ordovician source rocks, demonstrating that Cambrian crude oils came from Cambrian-Lower Ordovician source rocks; condensed compounds (fluoranthene, pyrene, benzo[a]anthracene, bow, benzo fluoranthene, benzopyrene) of high abundance were detected in heavy oil from Well Tadong-2, and the carbon isotopic values of whole oil are evidently heavy, all the above characteristics revealed that hydrocarbons in the crude oils became densified in response to thermal alteration.  相似文献   

16.
鄂尔多斯中部奥陶系水溶烃的分子地球化学特征   总被引:1,自引:0,他引:1  
应用GC、GC/MS分析法,系统剖析了鄂尔多斯中部奥陶系马家沟组水溶烃的分子地球化学特征,对其生物标志物组成、成熟度和成因进行了研究。研究认为,鄂尔多斯中部马家沟组水溶烃系高-过成熟阶段的烃产物,主要来源于古生界海相碳酸盐岩的贡献,并且不同井区水溶烃的有机质生源构成和成熟度等存在差异,从北(陕81井)到南(陕12井),水溶烃组成中菌藻类低等生源比例增加,反映了古生界源岩的贡献增大。  相似文献   

17.
傅碧宏 《沉积学报》1995,13(4):153-160
根据塔里木盆地西北缘中奥陶统和下志留统各组岩石的光谱特征分析,选择了TM3/1(Y)2/3(M)7/5(C)减色比值合成影像对研究区岩石地层层序进行划分和对比,划分出O12、O22、O32、S11和S21等5个影像岩石地层单元,它们与研究区的岩性组一致,但其精度高于研究区1:20万地质图。通过影像岩石地层的对比研究发现,研究区西部皮羌断裂以西在中奥陶世几乎未接受沉积,皮羌断裂以东出现了坎岭组,再往东至研究区东部,中奥陶统沉积较全;早志留世早期研究区西部沉积了海相红层,往研究区东部则相变为海相绿色地层。尤其是通过TM比值图像的分析,发现前人认为分布很局限,但具有很大生油潜力的印干组在研究区分布范围较广,并推断其沉积中心位于与研究区相邻的塔北隆起和北部坳陷一带。这为塔里木盆地油气评价和勘探提供了新的资料,并表明TM遥感数据的应用是沉积盆地油气勘探研究中的一种很有潜力技术方法。  相似文献   

18.
莺歌海盆地东方1-1气田天然气来源与运聚模式   总被引:6,自引:2,他引:4  
莺歌海盆地东方 1-1气田以其埋藏浅、天然气成份变化大、气藏位于底辟构造带等特征一直是研究的热点。长期以来对其气源、充注历史等问题存在不少疑问。该研究应用生烃动力学与碳同位素动力学方法通过对典型烃源岩的研究,建立起了烃源岩在地质条件下的生气模式与碳同位素分馏模式。结合天然气地质地球化学特征,研究认为:东方 1-1气田烃类气体主要来源于梅山组烃源岩,非烃气体来源于三亚组或更深部含钙地层;天然气藏形成相当晚,与底辟作用有关,烃类气体主要充注时间在 1.3Ma以后,CO2气体主要充注时间在 0.1Ma左右;天然气成份的非均一性主要受控于底辟断裂活动所控制的幕式充注。  相似文献   

19.
塔里木盆地石油地质研究新进展和油气勘探主攻方向   总被引:48,自引:18,他引:30  
“十五”以来,塔里木盆地石油地质攻关研究取得了多项新进展,主要表现在: 1)发现库车前陆盆地既富气也富油; 2)克拉通区下古生界碳酸盐岩油气富集受储层控制,斜坡带富油; 3)哈得逊周缘东河砂岩具有形成大型地层油气藏的地质条件; 4)塔中地区志留系发育岩性油气藏; 5)下白垩统克孜勒苏群是塔西南喀什凹陷北缘的主要目的层; 6)塔东地区原油裂解气勘探潜力颇大。近期的勘探思路是:以温宿凸起及周缘为重点,加强预探;积极评价轮南奥陶系潜山、塔中多目的层和哈得逊周缘石炭系3个有利区;准备塔西南西部、塔北西部英买力和塔东及塔东南地区3个新领域。  相似文献   

20.
塔里木盆地中-上奥陶统浊积岩物源分析及大地构造意义   总被引:3,自引:0,他引:3  
通过地表露头及钻井取心的浊积岩沉积特征观察及古流向分析、砂岩主量元素化学成分分析及地震相分析,提出塔里木盆地奥陶系陆源碎屑浊积岩主要发育于塔东地区及塘古兹巴斯坳陷的上奥陶统之中,其浊流沉积物源主要来自盆地东南侧的阿尔金岛弧、其次来自盆地西南侧的库地活动陆缘隆起;仅盆地东北缘却尔却克山地区出露的中奥陶统顶部的却尔却克组下部陆源碎屑浊积岩的物源区,主要来自其北侧的库鲁克塔格被动陆缘隆起(台地隆起剥蚀区)。综合分析认为,晚奥陶世发生于板块南缘的阿尔金岛弧及库地活动陆缘隆起与塔里木板块的碰撞挤压运动产生的大量陆源碎屑物源,导致了板块内部多个孤立碳酸盐台地的逐步消亡及板块南部浊流盆地群的形成。  相似文献   

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