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1.
勐库地区新近发现的退变质榴辉岩中晚期退变质作用形成的闪石类矿物十分丰富,其携带了大量晚期退变质过程中的岩石成因信息。本文通过系统的矿物学研究,鉴定出了3期10种闪石类矿物,其中以镁钙闪石、镁角闪石、铁镁钙闪石、铁韭闪石、透闪石、阳起石等钙质闪石类为主,有少量冻蓝闪石、蓝透闪石等钠-钙闪石类。研究发现,随着退变质过程中时间的推移,角闪石的形成环境逐渐由还原环境向弱氧化环境、氧化环境演变。根据角闪石电子探针成分测试结果计算了相应的温度、压力条件。结合岩相学的资料,将退变质过程分为3期:(1)第1期早阶段为近等温降压过程(p=0.56~0.75 GPa,t=642~709℃),主要形成铁韭闪石、铁镁钙闪石、镁钙闪石;晚阶段为等温降压过程(p=0.39~0.56 GPa,t=619~642℃),主要形成镁钙闪石及少量镁绿钙闪石、铁韭闪石;(2)第2期为降温降压过程(p=0.23~0.42 GPa,t=460~610℃),主要形成镁角闪石、冻蓝闪石及铁角闪石;(3)第3期为近等温降压过程(p=0.09~0.31 GPa,t=350~420℃),主要形成透闪石、阳起石、蓝透闪石等。闪石类的成分变化反映了退变质榴辉岩从地壳底部的角闪石榴辉岩-高压麻粒岩相温压环境向中上地壳角闪岩相、绿片岩相温压环境的渐次退变质作用过程。这与昌宁-孟连构造带上印支期的碰撞造山作用、燕山期的区域性地壳伸展、喜马拉雅期的陆内造山运动具有较好的对应关系。  相似文献   

2.
系统论述了扩张脊之下的洋壳增生模式、辉长岩地球化学特征及其对岩浆源区及岩浆过程的反映,总结了辉长岩在洋底环境和俯冲带中的变质作用及微量元素地球化学行为,并探讨了蛇绿混杂岩带中辉长岩的特点。对典型蛇绿岩的研究表明,在席状岩墙根部区域存在熔体透镜,来自地幔的岩浆在此贮存、分异。蛇绿岩中不同层位辉长岩的成分差异及结构、构造特点反映了该分异过程。辉长岩以及辉长岩中单斜辉石的地球化学特征可以反演岩浆的源区特征和岩浆分异、混合过程。辉长岩发生的洋底变质包括与洋脊附近热液对流相关的绿片岩相-麻粒岩相变质作用和与超镁铁岩蛇纹石化相关的异剥钙榴岩化作用。辉长岩在变质过程中不相容元素的活动性与温度、流体性质以及构造作用密切相关。  相似文献   

3.
太行山北段王安镇岩基超镁铁质岩中角闪石成因意义   总被引:1,自引:0,他引:1  
太行山北段中生代岩基中发育有基性-超基性岩体。本文以太行山北段王安镇岩基中的窑沟岩体为研究对象,对橄榄辉石角闪石岩中角闪石的矿物学特征以及形成条件进行初步研究,探讨其成因意义。结果表明,窑沟岩体橄榄辉石角闪石岩中的角闪石属于岩浆成因,并且角闪石环带发育,核部呈棕色,边缘为绿色,两者具有共同的特征,其(Ca+Na)B≥1.00,NaB0.50,均属于钙质角闪石。它们的Si/(Si+Ti+A1)值的范围为0.704 2~0.788 5,属幔源角闪石。Na、K、Ti、Al和Fe3+的相对含量存在差异,其棕色部分为镁绿钙闪石,绿色部分为镁绿钙闪石质普通角闪石以及浅闪石质普通角闪石。角闪石的环带特征反映出同一期岩浆结晶的不同阶段,体现出压力和温度等生成条件的变化。角闪石环带中核部的镁绿钙闪石结晶时温度和压力较高,深度较大,属于下地壳环境;而边缘角闪石在较低压地壳环境生成。角闪石所体现的岩浆来源于上地幔,并且在燕山运动前期的晚三叠世开始集聚,先其周围的中酸性岩体侵位,暗示在晚三叠世华北克拉通岩石圈就已发生部分熔融和华北克拉通破坏的开始。  相似文献   

4.
雅鲁藏布蛇绿混杂带在南迦巴瓦峰地区呈弧形连续分布,主要岩石类型有石英岩和云母石英片岩、绿片岩、斜长角闪岩、变质辉长岩、变余辉绿岩等。主要造岩矿物中,角闪石属富镁的镁角闪石、镁闪石、韭闪角闪石、浅闪角闪石等;单斜辉石为富镁的类型,成分相当于透辉石;橄榄石为典型的镁橄榄石;斜长石在角闪岩类中为中长石,是变质成因的。利用地质温压计估算出的变质温压条件分别为:t=500~650℃,P=0.75~0.8GPa,相当于角闪岩相变质作用,发生在47~47Ma左右。晚期经历了低温、高压变质作用,形成高压型的多硅白云母,时代为27~20Ma,与该区结合带边界阿尼桥断层和米林.鲁朗断层发生强烈走滑有关。地壳加速隆升、剥蚀时期形成的多硅白云母为中、低压型。  相似文献   

5.
赣东北高压变质岩的岩石类型、矿物组成与变质过程   总被引:6,自引:1,他引:6  
赣东北高压变质岩包括含硬玉霓辉石钠长角闪片岩、含硬玉霓辉石石英钠长石岩、含霓辉石角闪石英钠长石岩、含霓辉石钠长角闪片岩、蓝透闪石石英钠长石岩、镁钠闪石石英钠长石岩等岩石类型,主要组成脏矿物为硬玉、霓辉石、镁钠闪石、蓝透闪石、镁角闪石、阳起石、石英、钠长石、金红石和榍石。研究表明,高压变质峰期后经历了近等温降压退变质过程。  相似文献   

6.
蛇纹岩、异剥钙榴岩和蛇绿碳酸岩是蛇绿岩套中超基性单元特有的3类岩石组合,该套岩石组合的形成过程复杂,经历了从地幔岩浆结晶分异、洋脊变质作用改造和俯冲-仰冲构造过程,记录了从地幔岩浆侵位到造山带形成、演化的全程信息。蛇纹岩由方辉橄榄岩、二辉橄榄岩和纯橄岩通过水化和氧化过程而形成;异剥钙榴岩由含水石榴石、符山石、绿帘石族矿物、透辉石和绿泥石等含水和含钙的硅酸盐矿物组成,是由基性岩经历钙交代和水化作用而形成;蛇绿碳酸岩则由高度破碎变形的蛇纹岩角砾和碳酸岩基质(方解石、白云石或菱镁矿)共同组成,碳酸钙主要来自海水参与蛇纹岩化过程产生的富钙热液。阿尔卑斯西部的Zermatt-Saas蛇绿岩体中这3种岩石的组合研究表明:蛇纹岩化过程发生在大洋变质时期,超基性岩体在海水的作用下形成蛇纹岩。蛇纹岩化过程中释放出主要来自斜方辉石和单斜辉石的钙,与水共同作用交代超基性岩体中的基性岩脉,从而形成异剥钙榴岩。蛇绿碳酸岩形成于俯冲变质之前或俯冲变质的早期。这3类岩石一经形成,都经历了其后的叠加变质作用,进而表明Zermatt-Saas蛇绿岩经历了大洋变质、与俯冲、折返和抬升有关的高压变质和区域变质、绿片岩相变质和晚期热液变质作用的pT轨迹演化,代表着西阿尔卑斯从洋脊变质作用到俯?  相似文献   

7.
"罗田穹隆"中的下地壳俯冲成因榴辉岩及其地质意义   总被引:12,自引:0,他引:12  
在“罗田穹隆”中发现了下地壳俯冲成因榴辉岩.榴辉岩呈透镜状或板状产于含石榴子石条带状片麻岩中.新鲜的榴辉岩主要由石榴子石、绿辉石、金红石等组成.含少量退变质的角闪石、斜长石、紫苏辉石、透辉石、(钛)磁铁矿和石英等.研究区榴辉岩以保留早期麻粒岩相变质矿物残留体以及经受晚期麻粒岩相和角闪岩相退变为特征.指示它们由扬子镁铁质下地壳麻粒岩相岩石俯冲到深部发生变质并形成榴辉岩.然后折返至下地壳发生麻粒岩相退变,由于麻粒岩相退变质阶段仅以后成合晶形式出现.因而它们可能在下地壳停留时间不长.就又进一步被构造抬升至中上地壳而发生角闪岩相退变.大别山造山带乃至扬子板块北缘现今缺乏厚层镁铁质下地壳.它们也很少出露地表.推测这些俯冲的镁铁质下地壳可能已拆离再循环进人地幔.从而为“罗田穹隆”的形成和演化以及大别山高压-超高压岩石的形成与折返机制等研究提供了关键性的岩石学证据。  相似文献   

8.
造山带环境中的东疆型镁铁—超镁铁杂岩   总被引:8,自引:5,他引:8  
顾连兴  王金珠 《岩石学报》1994,10(4):399-356
新疆东部黄山-镜儿泉一带产有大-中型铜镍矿床的镁铁-超镁铁岩体是中石炭统弧后盆地引张环境下的热侵位产物,主要岩石类型有橄榄岩、辉橄岩、橄辉岩、二辉岩、辉长苏长岩、苏长辉长岩、辉长岩、橄长岩、辉长岩和闪长岩等;其超镁铁岩相对富铁.不具变质组构,并具橄榄石+斜方辉石+单斜辉石+角闪石±斜长石矿物组合;岩石化学以富硅、贫碱、贫铝、贫钙为特征,并具拉斑玄武岩系演化趋势。这些岩体是造山带杂岩体的一种新类型,可称为东疆型。  相似文献   

9.
胶北地块变质基底超镁铁岩的矿物岩石地球化学特征   总被引:2,自引:2,他引:0  
胶北地块变质基底的蛇纹岩、蛇纹岩化尖晶石方辉橄榄岩、尖晶石橄榄斜方辉石岩、角闪石岩自形成以后,经历了早期的高角闪岩相和晚期绿片岩相的变质作用,因而记录了三个阶段的矿物组合:早期的Opx1+Ol1+Spl1;中期的Opx2+Ol2+Spl2+Amp2和晚期的Amp3+Srp3+Mag3+Cal组合。超镁铁岩中普遍存在的角闪石,具有粒状变晶结构特征,形成于角闪岩相和绿片岩相的变质作用过程。蛇纹石没有受到应力作用的迹象,显示其形成于晚期非挤压环境的交代变质作用过程。尖晶石橄榄岩中斜方辉石的矿物化学以及尖晶石橄榄岩的高Mg O含量都表现出克拉通橄榄岩的性质。角闪石岩的稀土元素配分图解的(La/Sm)N的比值1.11~1.41,(La/Yb)N的比值0.91~1.61,超镁铁岩多元素图解显示无高场强元素异常,都表明胶北地块变质基底的超镁铁岩形成的构造背景或是裂谷环境。尖晶石矿物的Mg#0.72~0.79、Cr#0.06~0.12表明交代变质成因。方辉橄榄岩橄榄石的Fo值88.42~90.50、超镁铁质岩石全岩主元素的分散性、较大的∑REE含量变化以及Si/Al-(Mg+Fe)/Al和Mg/Ti-Fe/Ti主元素的比值图解所表现出的超镁铁岩与角闪石岩具有成因联系等,都表明胶北变质基底的超镁铁岩可能是具有堆晶成因的一套幔源岩浆系列。高MgO含量(16%~42%)表现出前寒武纪变质基底的橄榄岩地幔性质;高水含量反映出漫长地质历史时期变质作用过程。  相似文献   

10.
塔克札勒蛇绿混杂岩带的变质作用 ,具大洋水热变质、俯冲变质和区域低温动力变质作用的特征 ,其中以大洋水热变质作用为主。中志留世末洋盆扩张阶段 ,形成葡萄石、绿纤石相→低绿片岩相→角闪岩相的递增变质特征 ;早石炭世初洋壳向陆壳之下俯冲 ,俯冲变质作用不显著 ,仅见超镁铁岩具叶蛇纹石、纤维蛇纹石及绢石蚀变矿物 ;早石炭世中期塔克札勒有限洋盆开始粘连闭合 ,于晚石炭世早期褶皱造山 ,使蛇绿混杂岩带产生角闪岩相→高绿片岩相→低绿片岩相的退变质特征 ,使蛇绿岩带在辉长岩中由棕色角闪石退变为透闪石、阳起石和绿泥石、绢云母及绿帘石等变质矿物 ,是区域低温动力变质作用的产物 ,属低绿片岩相  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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20.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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