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1.
张宏飞  骆庭川 《现代地质》1994,8(4):453-458
扬子克拉通北缘的铁船山岩体形成于新元古代,其岩石类型为霓石-钠铁门石花岗岩,岩石富碱质、St、Fe、REE和高场强元素,而贫Al、Ca、Mg、Sr、Ba、Co、Ni等组分,δEu=0.20,A/KNC=0.85,K2O+Na2O/Al2O3=1.09,A·R=9.28,岩石属典型的A型花岗岩,Nd、Sr和O同位素示踪反映其成岩物质来自于壳幔混合源区。根据区域地质背景的综合分析,岩体形成于活动陆缘的张裂构造环境,属活动板块边缘拉张型花岗岩。  相似文献   

2.
嵩山A型花岗岩的地质地球化学特征和构造环境   总被引:8,自引:0,他引:8  
薛良伟  尉向东 《岩石学报》1996,12(1):137-144
从岩石学、岩石化学、微量元素、REE等方面讨论了嵩山古元古代钾长花岗岩体的地质地球化学特征,结果表明这些岩体属于A型花岗岩,其SiO2、K2O、K2O/Na2O、F、Ga、Hf、Rb、Y、Co、Ga/Al、REE高,Al2O3、MgO、CaO、Na2O、Ba、Sr、V、Th低,Eu为0.15~0.27,A/CNKM<1.10,这些岩体是与古元古代熊耳群火山岩相伴生的钾质侵入岩,两者均形成于非造山的大陆裂谷环境,表明华北陆台南缘在古元古代晚期处于拉张的非造山构造环境。  相似文献   

3.
苏北牛山片麻状A型花岗岩及其成因   总被引:5,自引:3,他引:2  
苏北牛山片麻状花岗岩形成于震旦期,富含碱性长石,普遍含有碱性镁铁矿物,具有高硅、富碱、低铝、贫水,富含Nb、Zr、Y、Ga、REE及Eu明显亏损等特征,为A型花岗岩。其Y/Nb、Yb/Ta、Ce/Nb等比值较高,Ga×104/Al和碱度较低,属A2亚型花岗岩。它是苏胶造山带在晋宁期碰撞造山后的拉张环境下,由地幔热流上涌,致使下地壳岩石部分熔融,产生的岩浆于中地壳侵位而形成。  相似文献   

4.
晋南中条山北峪奥长花岗岩的岩石地球化学   总被引:3,自引:0,他引:3  
野外工作发现,北峪奥长花岗岩侵入于绛县群变富钾流纹岩之中,结合其2107±59Ma的全岩Rb-Sr等时线年龄,应为早元古代岩浆侵入的产物。北峪岩体具高的Al2O3含量和高的δ^18OSMOW(‰)比值,表明为铝过饱和的S型花岗岩。其高的Al2O3含量和低的Yb含量及强烈分异的稀土图谱,表明形成于大陆环境。在LILE元素特点上,北峪奥长花岗岩亏损U,Th,K,Rb,具低的Rb/Sr比值和高的K/Rb  相似文献   

5.
云南洱海东部新生代岩浆岩岩石化学   总被引:12,自引:1,他引:12  
谢应雯  张玉泉 《岩石学报》1995,11(4):423-433
洱海东部新生代岩浆岩K-Ar年龄范围为29~37Ma,属于第三纪。岩石有超基性、基性、中性和酸性碱性岩。岩石化学成分富碱(Na2O+K2O=6.7~9.0%),钾销比值高(K2O/Na2O>l),钛(TiO2=0.49%)和铁(FeO=5.88%)富集度较低,氧化程度高(Fe2O3/FeO=0.6~4.6)等,属于典型的钾玄岩系列,有别于拉斑玄武岩系列、钙碱性系列和碱性玄武岩系列岩石。形成于陆内裂谷构造环境,其物质来源于交代的钾质富集型软流圈地幔源区。  相似文献   

6.
苏北石桥岩群沉积环境及其大地构造意义探讨   总被引:2,自引:1,他引:1  
樊金涛 《江苏地质》2000,24(3):129-134
石桥岩群是一套浅变质的正常沉积碎屑岩,同位素地质年龄Ma。岩石富SiO2、K2O、REE,贫Al2O3、Mno、Ca、Na2O、Sr,K2O/Na2O、SiO2/AlO3比值高,铕负异常明显,表明它是伸展型断陷盆地边缘之河口浅海环境中沉积的稳定型复理式建造。它揭示苏胶造山带在晋宁期造山后的震旦纪开始裂解,是Rodina超大陆震旦纪裂解的组成部分。  相似文献   

7.
福建沿海铝质A型花岗岩的地球化学及岩石成因   总被引:78,自引:7,他引:71  
以乌山、金刚山和新村三个典型岩体为例,系统研究了福建沿海铝质A型花岗岩的地质和地球化学特征。研究结果表明,铝质A型花岗岩常含有锰铝榴石、富锰白云母等特征的富铝矿物,化学成分上相对富铝,为一套准铝到弱过铝的岩石组成,并具有贫磷、贫钛,氧化指数较低等特征。与碱性花岗岩相比,其Nb、Ta、Zr、Hf、Ga、Y和Zn等元素的含量及稀土总量和Ga/Al比值均偏低,但轻、重稀土的分馏程度(尤其是重稀土的分馏程  相似文献   

8.
王一先  包志伟 《地球化学》1999,28(4):367-373
赣东北蛇绿混杂岩带中的西湾斜长花岗岩富Al2O3和Na2O,贫K2O;Sr、Ba和Th含量高,而Rb和高场强元素含量很低;LREE富集、无Eu异常;δNd(t)值高,为5.39。(^87Sr/^86Sr)i低,为0.7027。这些特征表明西湾斜长花岗岩是大洋斜长花岗岩。在La/Sm-La图中,该斜长花岗岩与超基性岩和基性岩的分离结晶趋势不一致,所以它不是岩浆分离结晶的产物,而可能是基性岩石小比例部  相似文献   

9.
赣南寨背A型花岗岩体的地球化学特征及其构造地质意义   总被引:86,自引:9,他引:77  
陈培荣 《岩石学报》1998,14(3):289-298
赣南寨背岩体主要为黑云母钾长花岗岩,黑云母结晶晚于长石和石英,锆石群型地温测量标尺显示其结晶温度为800℃~900℃,表明寨背岩体形成于一种高温贫水的花岗质岩浆。岩石的化学成分特点为准铝质(Al2O3为12.21%~12.62%),富硅(SiO2为75.66%~76.74%),偏碱(Na2O+K2O为7.93%~8.90%),FeOT/MgO值高(59~148),CaO和MgO含量低(分别为0.10%~0.65%和0.01%~0.02%),富含REE(Eu除外,ΣREE平均为500μg/g),Y、Ga、Nb等高场强元素(HFSE)以及F,Sr和Ba较低。这些特点与本区的I型和S型花岗岩有明显差别,是一种典型的A2型花岗岩。寨背岩体Rb-Sr等时线年龄为176Ma,与辉长岩、双峰式火山岩有密切的时空关系,表明赣南地区在燕山早期即进入拉张裂解阶段。  相似文献   

10.
一个古元古代A型流纹岩   总被引:17,自引:2,他引:15  
于津海  王德滋 《地球化学》1998,27(6):549-558
山西吕梁群流纹岩是一个古元古代的弱碱性火山岩,它具有高SiO2,Na2O+K2O和Zr,Ga等高场强元素和高FeO^*/MgO,Rb/Sr和Ga/Al比值,以及低CaO,Sr和Eu/Eu^*的地球化学特征,相似于A型花岗质岩石。它形成于大陆边缘裂谷环境,化学成分及同位素特征为高εNd(t)值,低(^87Sr/^86Sr)i值,表明流纹岩的原始岩浆由下地壳晚太古代变质岩受裂谷岩浆和热流作用的影响部分  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

19.
20.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

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