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1.
越南西北部Posen花岗岩锆石U-Pb年龄和Hf同位素组成特征 总被引：2，自引：2，他引：0
HIEU PhamTrung 陈福坤 祝禧艳 王伟 NGUYEN ThiBichThuy BUI MinhTam NGUYEN QuangLuat 《岩石学报》2009,25(12):3141-3152
本文报道出露于越南西北部的Posen花岗岩岩体锆石U-Pb年龄和Hf同位素组成特征,讨论岩石成因和该地区新元古代岩浆作用的大地构造意义.分析3个花岗岩样品获得723Ma至760Ma的锆石U-Pb年龄,表明花岗岩形成于新元古代.该花岗岩的锆石Hf同位素组成有较大的变化范围,ε_(Hf)(t)值变化范围为-16.1至+3.4,单阶段Hf模式年龄为1186～1945Ma,暗示Posen花岗岩有着复杂的源区物源组成.在误差范围内,锆石两阶段Hf同位素模式年龄值主要集中在2.0～2.1Ga,与两阶段Nd同位素模式年龄值2.1～2.2Ga一致,说明花岗岩体主要由古元古代地壳物质部分熔融形成的.部分锆石颗粒具有正ε_(Hf)(t)值,可能指示花岗岩岩浆形成过程中存在壳-幔混合相互作用.在越南西北部发育新元古代岩浆作用可能与扬子板块广泛发育的、伴随Rodinia超大陆裂解过程的岩浆活动存在成因的联系,也揭示越南西北部地体可能与扬子板块具有亲缘关系,因此,可以推断马江断裂带应该代表印支板块和华南板块之间的古特提斯缝合带在越南西北部的延伸. 相似文献
2.
《西北地质》2020,(1)
大红柳滩岩体位于西昆仑造山带东段,主要由黑云母二长花岗岩、二长花岗岩及二云母花岗岩组成。笔者对大红柳滩岩体东南部的黑云母二长花岗岩进行了锆石LA-ICP-MS U-Pb定年,测得黑云母二长花岗岩的侵位年龄分别为(214±1.8)Ma,说明大红柳滩岩体为印支晚期岩浆活动的产物。大红柳滩岩体具有高δ~7Li(0.76‰～3.25‰)和低Li(5.04×10-6～52.22×10~(-6))同位素地球化学特征;黑云母二长花岗岩样品的锆石ε_(Hf)(t)值介于-1.86～2.16,二阶段模式年龄为1113～1 368Ma;在ε_(Hf)(t)-锆石U-Pb年龄图解中,所有数据点均落在球粒陨石演化线附近。综合研究表明,大红柳滩岩体的原始岩浆是由地幔与中元古代地壳2个单元形成的混合岩浆。 相似文献
3.
蚌埠隆起区中生代花岗岩的岩石成因：锆石Hf同位素的证据 总被引：3，自引：5，他引：3
对蚌埠隆起区中生代不同时期的花岗岩中6个岩体的锆石LA-MC-ICP MS原位Hf同位素的研究,据此限定它们的岩浆源区和重建华北克拉通东南部的构造格架。结果表明,中生代不同时期的花岗岩中岩浆锆石的初始Hf同位素组成(ε_(Hf)(t))可以分成两组:第一组的女山(130Ma)和西庐山花岗岩(130Ma)的ε_(Hf)(t)值分别为-18.4和-16.1;第二组的曹山(110Ma)、锥山二长花岗岩(110Ma)和蚂蚁山花岗岩(110Ma)以及淮光花岗闪长岩(130Ma)的ε_(Hf)(t)值分别为-22.3、-23.1和-21.1以及-28.1,这些岩浆锆石低的ε_(Hf)(t)值表明它们可能来源于古老的大陆下地壳。女山和西庐山岩体中早古生代—新元古代继承锆石具有低的ε_(Hf)(t)值(-2.3～-7.7)和1.52Ga～1.79Ga的Hf同位素两阶段模式年龄,表明它们的岩浆源区主要以扬子克拉通下地壳物质为主。曹山、锥山和蚂蚁山以及淮光岩体中岩浆锆石的Hf同位素两阶段模式年龄为1.89Ga～2.58Ga,结合淮光岩体中古元古代继承锆石和3400Ma捕获锆石中低的ε_(Hf)(t)值(-5.7～-6.8,-0.6、-0.9)和古老的Hf同位素两阶段模式年龄(2.44Ga～2.80Ga,3.7Ga),表明它们主要来源于华北克拉通下地壳物质的部分熔融。淮光和女山岩体中古元古代—新太古宙继承锆石中正的ε_(Hf)(t)值(0.3～6.7)以及高的ε_(Hf)(t)值(16.9～21.7)的存在,暗示形成这些古老继承锆石的初始物质中有幔源物质的涉入。蚌埠隆起区深部地壳中扬子克拉通基底物质的存在暗示扬子克拉通可能沿着郯庐断裂带向西或北西方向俯冲于华北克拉通之下。 相似文献
4.
甘肃大佛寺、金佛寺花岗岩体的锆石U-Pb年龄、Hf-O同位素和全岩地球化学特征及地质意义 总被引：2，自引：0，他引：2
走廊过渡带大佛寺花岗岩为弱过铝质(A/CNK=1.03~1.06),SiO_2(76.7%~78.9%)、全碱(Na2O+K2O=7.7%~8.3%)、Rb(303×10~(-6)~383×10~(-6))、Nb(32×10~(-6)~42×10~(-6))、重稀土(Yb~8×10~(-6))含量以及和FeOT/MgO(6.3~7.6)、Ga/Al(3×10-4)、Rb/Ba(3.0~6.2)比值较高,MgO(~0.1%)、CaO(0.5%~0.6%)含量较低,Ba、Sr、Eu、Ti强烈亏损,属A型花岗岩,其源岩可能为泥质岩。大佛寺花岗岩中锆石δ18O和εHf(t)值分别为7.8‰~8.6‰(平均8.24±0.13‰)和-4.8~-2.0,Hf同位素两阶段亏损地幔模式年龄1540~1717Ma,岩浆温度达到~820℃以上。北祁连造山带北缘金佛寺花岗岩为过铝质(A/CNK=1.0~1.1),SiO_2(65.5%~75.0%)、MgO(0.6%~2.2%)、Fe2O3(1.9%~5.2%)、TiO_2(0.3%~0.8%)含量变化较大,其主量和微量元素特征与北祁连造山带的柴达诺花岗岩相似,源岩可能包括杂砂岩和角闪岩。金佛寺花岗岩的锆石δ18O为7.4%~9.7‰(平均8.03±0.36‰),εHf(t)在-0.5~+1.9之间,Hf同位素两阶段亏损地幔模式年龄为1289~1439Ma,岩浆温度达到800~900℃。走廊过渡带大佛寺花岗岩、北祁连造山带北缘金佛寺花岗岩的锆石U-Pb SIMS年龄分别为426.1±2.8Ma、424.0±1.6Ma,不同构造单元发育同时期岩浆活动以及A型花岗岩的出现,表明在~425Ma北祁连洋盆已经闭合,北祁连造山带及邻区进入到后碰撞拉伸阶段。 相似文献
5.
冈底斯南缘变形花岗岩锆石U-Pb年龄和Hf同位素组成：新特提斯洋早侏罗世俯冲作用的证据 总被引：21，自引：17，他引：21
本文对产于冈底斯南缘一个变形花岗岩进行了主量元素、微量元素、原位锆石 LA-ICP-MS U-Pb 定年和锆石 Hf 同位素组成研究。结果表明,变形花岗岩为高硅(SiO_2=73.38%～76.06%)钙碱性岩系,K_2O/Na_2O=0.69～1.17,铝指数(A/CNK)=1.03～1.07,为弱过铝质岩石。变形花岗岩微量元素组成显示贫大离子亲石元素(e.g.Rb=47×10~(-6)～71×10~(-6))和高场强元素(e.g.Nb=1.3l×10~(-6)～3.09×10~(-6),Ta=0.23×10~(-6)～0.54×10~(-6)),具有岛弧型花岗岩的地球化学属性。变形花岗岩锆石 U-Pb 年龄为178±1Ma,该年龄代表岩浆结晶年龄。锆石 Hf 同位素组成显示ε_(Hf)(178Ma)值变化于 14.1～ 17.7,表明变形花岗岩岩浆来自初生地壳物质的部分熔融。变形花岗岩的岩石成因与新特提斯洋向欧亚板块南缘的俯冲消减作用存在联系,其岩浆结晶年龄反映了新特提斯洋发生俯冲消减的开始时代不晚于早侏罗纪,说明了新特提斯洋经历了较长时间的演化。 相似文献
6.
胶西北新城金矿床二长花岗岩岩石地球化学、锆石U-Pb年龄及Lu-Hf同位素组成 总被引：12，自引：9，他引：3
胶东是我国最重要的金矿集区,也是环太平洋中、新生代金成矿系统的重要组成部分,其内花岗质岩石分布广泛,95%以上的金资源储量赋存在晚侏罗世玲珑型花岗岩和早白垩世早期郭家岭型花岗质岩中。关于花岗岩类的成因,尤其是早白垩世花岗质岩的岩石类型及其源区仍存有争议。新城金矿床位于胶东西北部焦家断裂带北段,是迄今为止在胶东矿集区内发现的赋存在早白垩世花岗质岩中最大的金矿床,其内已探明金资源储量大于200t。该金矿床的赋矿围岩为新城花岗岩体,由中细粒石英二长岩和中粗粒似斑状二长花岗岩组成,形成于127~132Ma。进一步的地质观察表明中粗粒似斑状二长花岗岩两侧的岩石粒度逐渐变细,斑晶逐渐变小,长英质矿物增多,明显不同于中粗粒似斑状二长花岗岩,应为中细粒似斑状二长花岗岩。论文对该中细粒似斑状二长花岗岩进行了系统的岩石地球化学、锆石LA-ICP-MS定年和Lu-Hf同位素组成研究,并进一步探讨了该类岩石的地球化学类型、形成时代、岩浆源区性质及其与新城花岗岩体的关系。岩石地球化学研究表明中细粒似斑状二长花岗岩具有高的SiO2(71.18%~73.72%)、全碱(K2O+Na2O=7.07%~8.64%)、Ba(793×10-6)、Sr(729×10-6)和轻稀土含量(71.14×10-6),低的Al2O3(13.57%~15.73%)、MgO(0.22%~0.39%)、Rb(91.7×10-6)、Th(7.4×10-6)、U(4.51×10-6)、Nb(4.49×10-6)、Ta(0.26×10-6)、Y(3.67×10-6)和重稀土含量(7.47×10-6),无明显的铕异常,明显亏损Nb、Ta、P、Ti等高场强元素,显示出典型的高Ba-Sr花岗岩所具有的地球化学特征,属高BaSr花岗岩。锆石LA-ICP-MS定年结果表明中细粒似斑状二长花岗岩形成于123±1Ma,而石英二长岩和中粗粒似斑状二长花岗岩的锆石LA-ICP-MS年龄为127±2Ma~132±1Ma,3种类型岩石具有相似的主量元素组成及稀土和微量元素分布模式,表明新城花岗岩体的形成时代应为123±1Ma~132±1Ma。Lu-Hf同位素测试结果显示中细粒似斑状二长花岗岩岩浆锆石的εHf(t)为-20.76~-18.66,二阶段模式年龄tDM2为2351~2479Ma;在εHf(t)-锆石U-Pb年龄图解中,所有数据点均落在球粒陨石演化线之下的壳源区域。金矿床已有石英二长岩、中粗粒似斑状二长花岗岩和区域玲珑型花岗岩Hf同位素组成及该中细粒似斑状二长花岗岩中2个太古代(2629±14Ma、2402±18Ma)和3个中生代(150±7Ma、151±1Ma、147±1Ma)的继承锆石年龄,表明新城金矿床内中细粒似斑状二长花岗岩应来源于前寒武纪变质基底岩石,岩浆上升过程中遭受了上地壳(主要是玲珑黑云母花岗岩)的混染。 相似文献
7.
近年来对青藏高原中拉萨地块西部中生代岩浆作用的源区、成因和演化等问题的研究较少。本文针对中拉萨地块西部噶尔县左左乡两个中酸性岩体进行了岩石学、锆石U-Pb年代学、微量元素和锆石Hf同位素,以及主量元素和微量元素地球化学研究。左左乡北侧岩体寄主花岗闪长岩和闪长质包体获得同期(163Ma和160Ma)的年龄,属于晚侏罗世;南侧岩体花岗岩年龄为142～147Ma,属于早白垩世。北侧与南侧的中酸性岩石均属于准铝质-弱过铝质高钾钙碱性I型花岗岩,富集大离子亲石元素和轻稀土元素,亏损高场强元素。晚侏罗世岩体寄主岩具有较为富集的锆石Hf同位素成分(ε_(Hf)(t)=-16.8～-13.6),可能来源于古老下地壳的部分熔融;包体具有相似的Hf同位素成分(ε_(Hf)(t)=-15.7～-13.6),结合晚侏罗世寄主岩与包体较高的MgO(4.13%～6.90%)、Cr(146×10~(-6)～370×10~(-6))和Ni(31×10~(-6)～113×10~(-6))含量,说明包体代表的中基性岩浆可能源于古老富集地幔的熔融,并且在晚侏罗世寄主花岗闪长岩与闪长质包体所代表的两种岩浆间发生过充分的岩浆混合作用。南侧早白垩世花岗岩具有较负且变化范围大的ε_(Hf)(t)值(-8.2～-4.8和-3.8～+0.2),指示早白垩世岩浆活动中有更多亏损地幔物质或新生地壳物质的加入,并且亏损地幔物质或新生地壳物质与拉萨地块古老地壳物质熔融形成的酸性岩浆发生了岩浆混合,经历岩浆混合后中酸性岩浆又发生了角闪石、长石的分离结晶,最终形成南侧早白垩世岩体的一系列中酸性岩石。研究区早白垩世亏损地幔物质或新生地壳物质的增多可能与南向俯冲的班公湖-怒江板片的回转有关。 相似文献
8.
以桐柏—大别造山带南缘七尖峰花岗岩体为研究对象,进行了详细的同位素年代学和元素-同位素地球化学研究,对其岩石成因和桐柏—大别造山带南缘早白垩世构造背景与钼成矿作用进行了探讨。锆石LA-ICP-MS UPb定年结果表明,七尖峰花岗岩形成年龄为(140±1) Ma,说明其为早白垩世岩浆活动的产物。地球化学研究表明,七尖峰花岗岩具有高SiO2(72.88%～73.60%)、低MgO(0.33%～0.36%),高Sr(620×10-6～642×10-6)、Sr/Y(107～111)比值,低Y(5.65×10-6～5.95×10-6)、Yb(0.52×10-6～0.59×10-6)、无Eu负异常的地球化学特征,是典型的埃达克岩。岩体富K2O、贫Cr和Ni,具有富集的Sr-Nd同位素组成(ISr=0.7075～0.7078,εNd(t)=-15.5～-15.1),锆石εHf(t)值在-19.9～-13.2变化,对应的两阶段Nd和Hf模式年龄分别介于2.15～2.19 Ga和2.00～2.43 Ga,暗示七尖峰花岗岩是由古老的加厚下地壳含石榴石角闪岩部分熔融形成。结合前人的研究成果,认为桐柏—大别造山带白垩纪存在两期与钼成矿密切相关的岩浆事件,早期(130 Ma)与加厚下地壳部分熔融有关,晚期(130 Ma)则形成于非加厚地壳部分熔融,证明桐柏—大别造山带南缘早白垩世(约130 Ma)经历了从碰撞挤压地壳加厚到碰撞后伸展地壳减薄的构造垮塌演化过程。 相似文献
9.
江西彭山锡多金属矿集区隐伏花岗岩体的岩石地球化学、锆石U-Pb年代学和Hf同位素组成 总被引：8，自引：7，他引：1
本文对江西彭山锡多金属矿集区隐伏花岗岩体进行了详细的锆石U-Pb年代学、Hf同位素组成和岩石地球化学研究。SHRIMP和LA-ICP-MS锆石U-Pb定年表明,该岩体年龄为128~129Ma,属燕山晚期岩浆活动的产物。详细的地球化学分析显示,彭山隐伏花岗岩体具有高硅(SiO2=75.42%~76.46%)、富碱(Na2O+K2O=7.93%~8.35%,K2O/Na2O=1.32~1.61)的特征,极度贫Mg(普遍MgO=0~0.07%),贫Ca(CaO=0.37%~0.69%),弱过铝质(A/CNK=1.04~1.11),富集Rb、Th、U等大离子亲石元素及Hf、Nb等高场强元素,强烈亏损Sr、Ba、Eu、P、Ti。稀土总量偏低(∑REE=41.18×10-6~85.06×10-6),强烈的Eu负异常(Eu/Eu*=0.05~0.11)。104×Ga/Al比值变化于2.75~4.04,平均值为3.19。这些特征均不同于典型的A型和S型花岗岩。岩石学和地球化学特征指示该岩体可能是一个高分异的I型花岗岩。该花岗岩中锆石εHf(t)值偏高,主要集中在-0.6~-4.5,显示在成岩过程中有地幔组分的参与,属壳幔混源花岗岩,推测该岩体的形成可能与燕山晚期华南岩石圈伸展拉张环境有关。 相似文献
10.
粤北雪山嶂A型花岗岩的形成时代、地球化学特征及其成因 总被引：1，自引：0，他引：1
LA-ICP-MS锆石U-Pb定年结果显示,雪山嶂花岗斑岩形成于早白垩世晚期(103Ma)。岩石地球化学特征具有铝质A型花岗岩的特征:相对均一的硅、富碱更富钾[w(Na2O+K2O)=8.38%~9.40%,K2O/Na2O=2.05~2.57]、富铁而贫镁,具有高的104×Ga/A1比值(2.59~2.94)和Zr+Nb+Ce+Y含量(366.6×10-6~398.7×10-6)。雪山嶂花岗斑岩具有比较均一的Sr,Nd同位素组成(ISr=0.709 8~0.710 1,εNd(t)=-7.68~-6.18),锆石原位Hf同位素组成为:(176 Hf/177 Hf)i=0.282 65~0.282 92,εHf(t)=-2.66~+6.84,相应的Hf同位素两阶段模式年龄TDM2变化于0.79Ga~1.40Ga之间。综合分析表明,雪山嶂A型花岗岩可能源自中元古代地壳变沉积岩的部分熔融,且在岩浆形成和演化过程中有幔源组分的参与。古太平洋板块俯冲后撤作用可能是形成雪山嶂A型花岗岩的动力学机制。 相似文献
11.
Police, politics, and the right to the city 总被引：1，自引：0，他引：1
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete. 相似文献
12.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
13.
I. M. Gorokhov M. A. Semikhatov M. M. Arakelyants E. A. Fallick N. N. Mel’nikov T. L. Turchenko T. A. Ivanovskaya T. S. Zaitseva E. P. Kutyavin 《Stratigraphy and Geological Correlation》2006,14(3):260-274
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation. 相似文献
14.
Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA 总被引：1，自引：0，他引：1
Joseph L. Domagalski Steven P. Phillips E. Randall Bayless Celia Zamora Carol Kendall Richard A. WildmanJr Janet G. Hering 《Hydrogeology Journal》2008,16(4):675-690
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area. 相似文献
15.
扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究 总被引：7，自引：3，他引：4
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。 相似文献
16.
Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean 总被引：2，自引：0，他引：2
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston
situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine
fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and
at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological
(i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates)
controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution
sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were
<20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf
of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is
lost to sediments. 相似文献
17.
18.
V. Yu. Prokof’ev L. D. Zorina V. A. Kovalenker N. N. Akinfiev I. A. Baksheev A. N. Krasnov G. A. Yurgenson N. V. Trubkin 《Geology of Ore Deposits》2007,49(1):31-68
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type. 相似文献
19.
山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义 总被引：10，自引：0，他引：10
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。 相似文献