共查询到20条相似文献，搜索用时 203 毫秒
1.
山东谢家沟金矿脉岩特征及其与金矿成矿关系 总被引：3，自引：0，他引：3
谢家沟金矿位于焦家-新城断裂和招远-平度断裂之间,区内脉岩发育,主要类型有闪长玢岩、花岗闪长斑岩、闪长岩、石英闪长玢岩、辉石闪长岩、辉绿岩和煌斑岩等.按其与矿脉穿切关系划分为矿脉就位前脉岩、就位后脉岩,它们的地球化学特征表明这些脉岩具有良好的同源演化关系而且它们与成矿具有较为密切的时空关系. 相似文献
2.
3.
《矿物岩石地球化学通报》2017,(4)
白云金矿是辽东青城子矿集区北部典型的岩浆热液型金矿床,矿区发育有花岗斑岩、石英斑岩、闪长玢岩、煌斑岩和二长斑岩等脉岩,其中花岗斑岩和石英斑岩常产于金矿体的上下盘,与成矿空间关系密切。本文通过锆石U-Pb年代学测试,精确厘定花岗斑岩和石英斑岩的年龄分别是218.56±0.37 Ma和218.5±2.9 Ma,为印支期岩浆作用的产物;二长斑岩的年龄为164.44±0.38 Ma,属燕山期。综合研究表明,白云矿区金矿体与印支期花岗斑岩和石英斑岩可能是同一岩浆体系的产物。 相似文献
4.
西秦岭地区脉岩成因与金成矿关系——来自李坝金矿年代学、地球化学及Nd-Hf-S同位素的约束 总被引：3，自引：1，他引：2
甘肃李坝金矿位于西秦岭北成矿亚带礼岷金矿带东部,矿区内脉岩主要包括斜闪煌斑岩、云斜煌斑岩、闪长(玢)岩、细晶闪长岩、石英闪长岩、花岗(斑)岩、花岗细晶岩等。根据各脉岩与金矿的产出关系可划分为成矿前脉岩、成矿期脉岩和成矿后脉岩3类。不同种类、不同期次脉岩的成因及其对金成矿作用的制约存在不同认识。LA-ICP-MS锆石U-Pb定年结果显示,李坝金矿区花岗斑岩脉的年龄为(210±1)Ma(MSWD=0.15),与中川岩体同属晚三叠世构造岩浆活动的产物。成矿期花岗(斑)岩脉富碱、高钾,属于过铝质、高钾钙碱性系列,与成矿密切相关的煌斑岩脉同属高钾钙碱性系列。Nd-Hf同位素结果显示,李坝金矿区花岗斑岩脉的~(143)Nd/~(144)Nd比值为0.512 084±0.000 007,~(147)Sm/~(143)Nd比值为0.0903,ε_(Nd)(t)为-7.98,Nd同位素亏损地幔模式年龄T_(DM2)为1.64 Ga;锆石ε_(Hf)(t)=-6.30～+1.47,T_(DMC)为1.65～1.15 Ga,显示花岗斑岩脉的源区以古老的壳源物质为主,并有年轻物质的加入。硫同位素和矿床地球化学结果显示,黄铁矿的δ~(34)S值变化于4.3‰～11.6‰,平均值为8.45‰,表明其成矿硫源具有深源特点,金矿成矿物质来源于与脉岩有关的深部岩浆。综上,笔者认为矿区内脉岩与金矿化具有深部同源性,成矿同期的煌斑岩可能为金矿化提供部分成矿物质或成矿流体。 相似文献
5.
普朗斑岩铜矿床是云南中甸地区最大的斑岩型铜矿床,其成矿作用与普朗复式岩体存在密切的成因联系。对普朗复式岩体成矿的第1期石英闪长玢岩和第2期石英二长斑岩,以及不成矿的第3期闪长玢岩开展了锆石原位微量元素和磷灰石原位主量元素成分的研究。结果表明,锆石Ce/Ce~*值、Ce~(4+)/Ce~(3+)比值和Ce/Nd比值指示,不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩的岩浆相对氧化状态大致相当,且明显高于成矿的第2期石英二长斑岩。磷灰石Cl、OH和SO3成分指示,普朗复式岩体3期斑岩具有相似的岩浆含水量,但成矿的第1期石英闪长玢岩和第2期石英二长斑岩较不成矿的第3期闪长玢岩具有更高的岩浆挥发分Cl含量和硫逸度。岩浆的高氧逸度和硫逸度、富水和富挥发分Cl均是形成斑岩铜矿床的关键因素,普朗不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩和第2期石英二长斑岩均具有富水和高氧逸度特征,但第3期闪长玢岩较成矿的第1期石英闪长玢岩和第2期石英二长斑岩具有明显更低的岩浆挥发分Cl含量和硫逸度,这很可能是导致第1期石英闪长玢岩和第2期石英二长斑岩成矿,而第3期闪长玢岩不成矿的重要原因之一。 相似文献
6.
西秦岭与赛什塘铜矿床有关的花岗质岩石岩浆源区特征及大地构造背景探讨 总被引：2，自引：1，他引：1
西秦岭赛什塘铜矿区内出露的三叠纪花岗质岩石有闪长玢岩、石英闪长岩、石英闪长玢岩、花岗斑岩和石英斑岩,其岩浆源区与形成构造环境可为古特提斯洋演化和区域成矿作用研究提供证据。岩石地球化学特征共同表明,这些花岗质岩石属于准铝质钙碱性-高钾钙碱性系列,为I型花岗岩;Mg#值变化较大(39~68),LREE富集,HREE亏损,(La/Yb)N比值介于8.50~22.9,具有Eu负异常,δEu介于0.28~0.78,同时富集大离子亲石元素Cs、Rb、K、Pb,亏损高场强元素Nb、Ta、Ti,呈现出与典型俯冲作用密切相关岛弧花岗岩相一致地球化学特征。石英闪长玢岩和石英斑岩SHRIMP锆石U-Pb年龄分别为219.0±2.3Ma和220.0±2.0Ma,锆石εHf(t)分别为-4.5~-2.1和-2.5~+1.0,对应二阶段模式年龄分别为1392~1544Ma和1190~1415Ma。结合前人对西秦岭三叠纪花岗岩以及其南侧阿尼玛卿蛇绿混杂带研究成果,本文认为赛什塘铜矿区花岗质岩石与西秦岭同时期花岗岩形成于与古特提斯洋向北俯冲密切相关的大陆边缘弧环境,其岩浆源区为中元古代下地壳变基性岩,且岩浆可能受到地幔物质混染。 相似文献
7.
为讨论石湖金矿的形成与麻棚花岗岩体、石英闪长玢岩脉之间的联系,对花岗闪长岩、石英闪长玢岩进行了U--Pb年代学研究,并分别对花岗闪长岩、石英闪长玢岩、矿化蚀变岩和围岩的地球化学进行了系统测定。麻棚花岗岩体U--Pb年龄为(124.8±1.4)Ma(MSWD=0.74),石英闪长玢岩脉年龄为(127.3±1.1)Ma(MSWD=1.15),但二者地球化学特征表现不同,应有不同起源。地球化学特征表明,麻棚花岗岩与矿化蚀变岩具有较一致的稀土、微量元素配分型式,而与围岩差别大,说明金矿的成矿流体来源与麻棚花岗岩关系密切。此外,花岗闪长岩具高钾钙碱性,且重稀土亏损、轻稀土富集、弱Eu异常、高Sr--Ba和高Sr/Y、La/Yb比值,表明麻棚岩体的形成有幔源岩浆的混入。笔者认为成矿流体和成矿物质来源为幔源岩浆底侵和混合,并以花岗岩浆为载体而迁移上升。结合矿床地质特征,初次提出闪长玢岩脉与矿体时空关系密切,这应是闪长玢岩脉作为隔流体层对来自麻棚花岗岩体的成矿流体具有一定的封闭作用,使得矿化、蚀变富集产出,即岩脉封闭作用。石湖金矿的成岩成矿机制与中生代期间岩石圈减薄的地球动力学背景密切相关,应是一种非造山型金矿。 相似文献
8.
广西大厂矿区脉岩的地球化学特征及其构造和成矿意义 总被引：3，自引：0，他引：3
位于丹池成矿带的大厂锡矿是我国著名的超大型锡多金属矿田和重要的锡矿产出地。大厂矿区的花岗斑岩和(石英)闪长玢岩脉岩,位于主要矿床的两侧,成群成带分布。花岗斑岩和闪长玢岩是在燕山晚期黑云母花岗岩之后同期或充填时间前后相差不大形成的。花岗斑岩和闪长玢岩均穿过矿体,与围岩的接触带内包含围岩角砾和矿化。花岗斑岩的SiO2、Al2O3、CaO和MgO含量较高,K2O+Na2O含量较低。岩石的氧化度较低,暗示成岩部位较深,属相对还原的成岩环境,其侵位固结前经过充分的演化分异,对成矿有利;闪长玢岩具有碱、铝、钛、镁、铁含量都较高的特点,岩石的氧化度较高。脉岩来源于地壳的重熔;脉岩沿南北向断裂充填形成,侵入时间晚于成矿期;矿床分带特征与脉岩的成岩环境一致;脉岩中丰富的主成矿元素和微量元素及其变化趋势,表明其提供了成矿物质或者其所充填的断裂曾是矿液运移通道,在成矿后才被充填,脉岩本身也为成矿物质提供了来源;石英闪长玢岩具有埃达克质岩特征,可能是由底侵的玄武质下地壳熔融形成,推测有底侵的玄武质下地壳熔融形成的岩浆参与岩脉旁侧多金属矿床的成矿。 相似文献
9.
新疆准噶尔北缘玉勒肯哈腊苏斑岩铜矿床年代学研究 总被引：7，自引：3，他引：4
玉勒肯哈腊苏铜矿是近几年准噶尔北缘卡拉先格尔斑岩铜矿带发现的又一个中型斑岩铜矿,其成岩成矿年代学的研究可以对矿床模型构建、区域成矿规律的总结提供制约。矿区侵入岩发育,矿化主要受闪长玢岩控制,少部分赋存在似斑状黑云母石英二长岩和北塔山组火山岩、火山碎屑岩中。本文利用锆石LA-ICP-MSU-Pb法和辉钼矿Re-Os法对矿区岩体和矿化进行了成岩成矿年代学研究。结合前人的研究,认为矿区存在5次主要岩浆侵入事件:382Ma石英闪长岩侵入,379Ma形成含矿闪长玢岩,375～374Ma形成似斑状黑云石英二长岩,348Ma形成黑云母石英斑岩脉,266Ma形成二长斑岩,前三次岩浆侵入活动对应构造环境为板块俯冲阶段,后二次岩浆侵入活动为后碰撞阶段。9件辉钼矿样品Re-Os同位素等时线年龄为373.9±2.2Ma,表明铜钼成矿时代为中泥盆世晚期,与闪长玢岩侵入有关。 相似文献
10.
内蒙古阿拉善地区朱拉扎嘎金矿是新近发现的特大型层控改造型金矿床,该矿床以产于中元古界地层中和巨大的找矿潜力而引人注目。容矿岩石主要为钙质粉砂岩、粉砂质板岩。曾采用颗粒锆石U-Pb法和~(40)Ar/~(39)Ar法对成矿期花岗斑岩、成矿后期闪长玢岩和含金石英-硫化物矿体进行了年龄测定,获得成矿期花岗斑岩锆石U-Pb年龄为(304±5)Ma,成矿后期闪长玢岩为(258.6±5.7)Ma,金矿体中石英的~(40)Ar/~(39)Ar年龄为(282.3±0.9)Ma。现采用SHRIMP锆石U-Pb法对成矿期花岗斑岩和成矿后期闪长玢岩进行了重新测年,结果表明花岗斑岩的形成时代为(280±6)Ma,闪长玢岩的形成时代为(279.7±5.2)Ma,两者的年龄差仅0.3 Ma,从而限定了朱拉扎嘎金矿的形成年龄,非常接近于280 Ma(279.7～280 Ma)。 相似文献
11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
12.
针对兖州煤田下组煤深部开采受奥灰高承压水威胁以及当地大型煤化工企业生产用水量大的现状,在已进行的水文地质勘探及放水试验基础上,评价奥灰富水性,并采用有限差分法进行奥灰疏水降压数值模拟研究,提出水煤共采观点。研究结果表明:兖州煤田深部奥灰水压高,合理布置水煤共采孔,可以实现奥灰水位的有效疏降,疏降中心区水位最大降深可达110 m,突水系数显著下降,提高了下组煤开采的安全性;同时可提供煤化工43200 m3/d的供水量,能达到可持续的、水资源保护性的供水效果,实现下组煤的水煤共采。 相似文献
13.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
14.
15.
16.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
17.
The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements. 相似文献
18.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
19.
Todd Dunn 《Contributions to Mineralogy and Petrology》1987,96(4):476-484
The crystal/liquid partition coefficients of Lu, Hf, Ti, Mn and Ca have been measured between olivine, clinopyroxene and basaltic melt. The Ti, Mn, and Ca partition coefficients were determined at natural abundance levels. The Lu and Hf partition coefficients were determined at doping levels ranging from 0.5 to 1.5 wt% “trace element” as oxide in order to allow analysis by electron microprobe. Olivine/liquid partition coefficients for Lu, Hf, Ti, Mn, and Ca were determined at 1 bar and temperatures from 1150 to 1177° C. Clinopyroxene/liquid partition coefficients were determined for Lu, Hf, Ti, and Mn at pressures of 10, 15, and 20 kbars and temperatures from 1250 to 1290° C. The olivine/liquid partition coefficients of Hf, Lu, Ti, and Ca are small. D(Hf-ol) is zero within the analytical uncertainty. Both D(Lu-ol) and D(Mn-ol) decrease with increasing temperature, but D(Ti-ol) and D(Ca-ol) are constant over the narrow temperature range studied. The partition coefficient results are summarized below.
| T°C 相似文献
20.
Stratiform quartz-sulphide lodes in Ingladhal occur in a typical Precambrian green-stone-belt environment comprising metabasalts, tuff, chert and cherty iron-sulphide formation. Unusually high cobalt contents of metavolcanics and of sulphide minerals in orebodies suggest a consanguinity between ores and rocks. 90% of total nickel, 70% of total cobalt but only 30% of total copper in rocks occur in silicate phases and thus indicate an early separation of copper from cobalt and nickel. Unusually high non-sulphide copper in barren bedded cherts implies availability of Cu-rich solution prior to their lithification. Pyrite in sediments, in volcanics, and in orebodies is characterized by a distinctive pattern of Co-Ni distribution in each case. Partitioning of Co and Ni between coexisting sulphide pairs is complex, but gross equilibrium is indicated. Very high trace metal content of orebody pyrite sharply contrasts with very low such values in pyrite from adjacent sediments and points to a higher temperature of formation of orebodies. 相似文献
|
|---|