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中国是全球铁矿石第一消费大国,每年进口铁矿石量已超过9亿t,进口量超过全球铁矿石贸易量的60%,对全球铁矿主要类型特征及重要分布区带总结和潜力分析研究具有重要的理论和现实意义。本文总结了全球铁矿资源的禀赋特征,将全球铁矿床分为BIF相关型、沉积型、火山成因型、岩浆型、接触交代-热液型（矽卡岩型）5种成因类型,重点总结分析了BIF相关型和火山成因型铁矿地质特征、成因和找矿标志等。根据铁矿床产出的大地构造单元、地层层序、含矿建造特征及矿床类型、成矿时代等综合因素,在全球主要大地构造单元中共圈出33个铁矿分布区,47个铁矿重要分布区带,并对各重要分布区带的资源潜力进行了探讨。 相似文献
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中国锰矿资源特征及潜力预测 总被引：1，自引：0，他引：1
中国的锰矿资源丰富,截止到2016年,保有储量达15.5亿t,位居世界第六位。中国锰矿主要集中分布在南方的泛扬子古陆、北部的燕辽、西部的天山和祁连山等地区。中新元古代、早古生代（寒武纪、奥陶纪）、晚古生代-早中生代是中国锰矿形成的重要时代。在锰矿成矿规律研究的基础上,提出了如下方案：（1）以成矿作用作为一级分类要素,含矿岩系作为二级分类要素的8种成因类型划分方案;（2）根据锰资源潜力评价工作需要,将成因类型和工业类型相结合,以成矿作用和预测要素为一级要素,含矿岩系为二级要素的3种预测类型划分方案。其中,海相沉积型、风化壳型和古天然气渗漏沉积型锰矿是中国具有找矿潜力的主要锰矿床类型。基于此,将全国锰矿划分为11个Ⅲ级锰矿成矿带,对优选出的7个主要锰矿远景区的含锰层位、成矿特征、主攻类型、资源潜力进行了分析。最后,针对目前中国锰矿资源面临的问题,提出了下一步工作部署的建议和意见。 相似文献
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国外锰矿资源、类型、地质特征及其对我国锰矿找矿的借鉴 总被引：1，自引：0，他引：1
本文所论述的内容限于陆地范围的锰矿床。世界锰矿资源达70亿吨,主要分布在南非、苏联,其次为澳大利亚、加蓬、巴西、印度、墨西哥和加纳等。世界重要锰矿床约150个,其超过1亿吨储量的有11处。本文据成矿作用、含锰建造、锰质来源及成矿条件等因素,将锰矿床分为5大类11个类型:海相沉积矿床(碎屑泥质岩型、碳酸盐岩型)、火山沉积矿床(绿岩硅质岩型、斑岩硅质岩型)、变质矿床(锰榴石英岩型或条带状含铁建造型)、热液矿床(接触交代型、裂隙充填型)和风化矿床(锰帽型、残积型、淋滤型),并综合其地质特征分列成表,各类型借以典型实例精要叙述。据世界锰矿资源、矿床类型、成矿时代,地质特征和控矿因素等特点,对我国锰矿找矿工作可引以为诫的是要注意前寒武纪(早元古代)变质锰矿床矿化信息的捕捉,要注意老第三纪(主要渐新世)地台型海相泥质岩型锰矿化线索的探寻,要重视火山沉积型锰矿的找矿,要继续加强表生风化型锰矿床的找矿和要注意铁、锰、铜和金矿的综合找矿。 相似文献
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莫能锰矿为元古代形成的与含铁建造密切相关的锰矿床。本文系统总结了区域地质背景、锰矿床地质特征,并对含锰地层的岩相古地理进行了分析,认为含矿岩系为滨外浅海陆棚沉积。在此基础上,初步建立了矿床的成因模式,提出矿床成因属浅海沉积变质型。与世界上最大的锰矿田卡拉哈里锰矿田进行对比后,认为它们在成矿背景、成矿时代、矿床特征、岩相古地理条件及后生改造等方面均有相似之处,莫能锰矿具有成为大型锰矿床的找矿潜力。 相似文献
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江西省武宁县境内分布了众多的小型铁、锰矿床(点),前人称之为“武宁式”铁矿。通过对黄连坑锰矿区地层的含矿性、控矿构造及容矿构造、矿体特征、矿石类型等地质特征的论述,认为震旦系地层是“初始矿源层”,滑脱构造对成矿物质起迁移、富集及容矿作用。并与萍—乐断陷盆地内的沉积加热液叠改型乐华锰矿床进行了对比分析,二者在矿体规模、矿石类型、锰品位等方面存在显著差别,应属不同成因类型的矿床。初步认为黄连坑锰矿床属构造控矿、风化淋滤成因。 相似文献
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根据铜矿床的成因类型,对全国177个铜矿床的自然重砂矿物进行统计分析。结果显示,自然重砂矿物对于铜矿床成因类型具有较好的指示意义。不同成因类型铜矿床的自然重砂矿物组合不同,尤其是岩浆型、斑岩型、矽卡岩型、火山岩型铜矿床均具有特征自然重砂指示矿物。除了铜矿物、铅锌矿物、黄铁矿、白钨矿等各类型铜矿床共有自然重砂矿物外,铬铁矿、镍黄铁矿、辉石、橄榄石等为岩浆型铜矿床的特征指示矿物,自然金、辉钼矿、磷灰石、磷钇矿等可以指示斑岩型铜矿床;锆石、锡石和石榴子石是矽卡岩型铜矿床的特征指示矿物;火山岩型铜矿床则以雄黄、雌黄作为特征指示矿物。这些研究对于建立不同成因类型铜矿的自然重砂找矿模型具有重要意义。 相似文献
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非洲锰矿床成矿规律、开发利用与勘查建议 总被引：1，自引：0，他引：1
锰矿是我国重要的战略矿产资源,需求量不断增长,长期依赖国外资源保障供需关系。本文总结分析了非洲锰矿资源的特点、矿床类型与成矿规律等地质特征与勘查开发利用及贸易现状。分析表明：非洲是全球探明锰矿储量和资源量最多的地区,具有分布集中,规模大、品位高、杂质少的特点;锰矿床类型主要有条带状含铁建造（BIF）型、海相沉积型、海相火山-沉积型、陆相（湖相三角洲）沉积型、岩浆热液型等五大类,普遍遭受表生风化淋滤（溶蚀）作用改造;主要分布在卡普瓦尔克拉通、刚果克拉通西北部的加蓬地块和西非克拉通南缘的马恩-莱奥地盾中;成矿时代主要集中于前寒武纪,尤其是2.2~2.0Ga;非洲锰矿资源的勘查开发程度较高,其中南非是非洲锰矿勘查程度最高的国家,中非、北非国家的勘查开发程度较低;南非是全球最大的锰矿石生产国和锰矿产品出口国,目前占全球出口量的68.19%以上,我国是非洲锰矿产的最大出口地,占其出口总量的70.19%。建议：我国在非洲的勘查应重点关注非洲中部的条带状含铁建造（BIF）型锰矿和海相火山-沉积型锰矿;在非洲已有的中企基础上,组建大型的集团公司,建立多元的锰矿资源供应体系。 相似文献
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锰的用途非常广泛,世界上90%~95%的锰应用于冶金工业,其余应用于电池工业、陶瓷工业、化学工业等。根据成矿作用过程中的含矿岩系特征,将世界锰矿划分为海相沉积型、火山(热液)-沉积型、变质型、热液型和表生型5类,以海相沉积型、变质型和表生型为主。截至2019年,世界锰的储量达8.12亿t,但分布极不均匀,主要集中在南非、巴西、乌克兰、澳大利亚、加蓬、中国、印度、加纳等国,而优质锰矿石主要分布在南非、澳大利亚、加蓬、加纳。时间上,将锰的成矿作用分为7期,其中元古宙和新生代是主要的成矿期。空间上,锰矿床主要分布在南非德兰士瓦群、乌克兰尼科波尔盆地、澳大利亚格鲁特岛和皮尔巴拉克拉通、中国泛扬子区、西非克拉通等。目前,锰的生产主要集中在南非的卡拉哈里和波斯特马斯堡锰矿田、澳大利亚的格鲁特岛、加蓬的莫安达锰矿、加纳的恩苏塔锰矿等地。 相似文献
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Low-grade carbonate-rich manganese ore of sedimentary origin in the giant Kalahari Manganese Field, South Africa, is upgraded to high-grade todorokite–manganomelane manganese ore by supergene alteration below the unconformity at the base of the Cenozoic Kalahari Formation. Incremental laser-heating 40Ar/39Ar dating of samples from the supergene altered manganese ore suggest that chemical weathering processes below the Kalahari unconformity peaked at around 27.8 Ma, 10.1 Ma and 5.2 Ma ago. Older ages are dominant in the upper part of the weathering profile, while younger ages are characteristic of the deeper part of the profile. Younger ages partially overprint older ages in the upper part of the weathering profile and demonstrate the downward progression of the weathering front by as little as 10 cm per million years. The oldest age obtained in the weathering profile, namely 42 Ma, is considered a minimum estimate for the onset of the post African I cycle of weathering and erosion that followed the break up of Gondwanaland and formation of the Cretaceous to early Cenozoic African land surface. The youngest ages, recorded at around 5 Ma, in turn, correspond well to the Pliocene transition from humid to arid climatic conditions in Southern Africa. 相似文献
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Enrichment iron ore of the Hamersley Province, currently estimated at a resource of over 40 billion tonnes (Gt), mainly consists of BIF (banded iron-formation)-hosted bedded iron deposits (BID) and channel iron deposits (CID), with only minor detrital iron deposits (DID). The Hamersley BID comprises two major ore types: the dominant supergene martite–goethite (M-G) ores (Mesozoic–Paleocene) and the premium martite–microplaty hematite ores (M-mplH; ca 2.0 Ga) with their various subtypes. The supergene M-G ores are not common outside Australia, whereas the M-mplH ores are the principal worldwide resource. There are two current dominant genetic models for the Hamersley BID. In the earlier 1980–1985 model, supergene M-G ores formed in the Paleoproterozoic well below normal atmospheric access, driven by seasonal oxidising electrochemical reactions in the vadose zone of the parent BIF (cathode) linked through conducting magnetite horizons to the deep reacting zone (anode). Proterozoic regional metamorphism/diagenesis at ～80–100°C of these M-G ores formed mplH from the matrix goethite in the local hydrothermal environment of its own exhaled water to produce M-mplH ores with residual goethite. Following general exposure by erosion in the Cretaceous–Paleocene when a major second phase of M-G ores formed, ground water leaching of residual goethite from the metamorphosed Proterozoic ores resulted in the mainly goethite-free M-mplH ores of Mt Whaleback and Mt Tom Price. Residual goethite is common in the Paraburdoo M-mplH-goethite ores where erratic remnants of Paleoproterozoic cover indicate more recent exposure. Deep unweathered BIF alteration residuals in two small areas of the Mt Tom Price M-mplH deposits have been used since 1999 for new hypogene–supergene modelling of the M-mplH ores. These models involve a major Paleoproterozoic hydrothermal stage in which alkaline solutions from the underlying Wittenoom Formation dolomite traversed the Southern Batter Fault to leach matrix silica from the BIF, adding siderite and apatite to produce a magnetite–siderite–apatite ‘protore.’ A later heated meteoric solution stage oxidised siderite to mplH + ankerite and magnetite to martite. Weathering finally removed residual carbonates and apatite leaving the high-grade porous M-mplH ore. Further concepts for the Mt Tom Price North and the Southern Ridge Deposits involving acid solutions followed, but these have been modified to return essentially to the earlier hypogene–supergene model. Textural data from erratic ‘metasomatic BIF’ zones associated with the above deposits are unlike those of the typical martite–microplaty hematite ore bodies. The destiny of the massive volumes of dissolved silica gangue and the absence of massive silica aureoles has not been explained. Petrographic and other evidence indicate the Mt Tom Price metasomatism is a localised post-ore phenomenon. Exothermic oxidation reactions in the associated pyrite-rich black shales during post-ore removal by groundwater of remnant goethite in the ores may have resulted in this very localised and erratic hydrothermal alteration of BIF and its immediately associated pre-existing ore. 相似文献
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D. F. Lascelles 《Australian Journal of Earth Sciences》2013,60(8):1105-1125
All the major worldwide direct-shipping iron ore deposits associated with banded iron formations (BIF) are characteristically deeply weathered. They extend to considerable depths below the water table and show well-preserved primary structures and textures, but characteristically most deposits contain no evidence of chert bands being present prior to weathering. Recent studies have found evidence of hydrothermal and/ or metamorphic influences in the development of certain ore deposits and new genesis models such as the supergene-modified hypogene model have been postulated for major high-grade iron ore deposits. Nevertheless, there are many high-grade deposits that show no evidence of hypogene alteration and for which a hypogene or metamorphic genesis is unreasonable that are automatically ascribed to supergene enrichment, commonly erroneously attributed to lateritic weathering in tropical environments. Laterite (sensu lato) is a soil formation in which primary textures are destroyed and is underlain by a pallid zone showing the preservation of chert and the depletion, not enrichment, of iron oxides and thus is totally incompatible with the formation of the high-grade ore deposits. Various theories and models that purported to explain the conditions under which such a uniquely BIF-related dissolution of quartz and residual accumulation of hematite could occur by supergene processes typically conflict with current understanding of groundwater hydrology, chemistry, weathering processes and soil formation.Supergene enrichment of ore is universal in the leaching of gangue minerals such as iron silicates, carbonates and apatite and supergene enrichment of BIF to low-grade ore is common in near surface environments above the water table such as ferrugenised BIF outcrops, detrital ore deposits, and some shallow ore deposits that have been subjected to prolonged exposure to fresh meteoric water. In all cases of supergene enrichment traces of the chert bands are visible and the dissolution or replacement processes for the removal of quartz are clear, in direct contrast to the most important deep saprolite ore deposits that show no trace of chert bands.The widespread acceptance of an inappropriate and untenable supergene enrichment model inhibits search for the true origin of the ore and our ability to predict and find concealed high-grade ore deposits. 相似文献
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中国锰矿成矿规律初探-陈毓川院士八十华诞专辑 总被引：3，自引：0，他引：3
中国锰矿资源较丰富,资源量排名在世界上位列第5.中国锰矿种类多样,有海相沉积型、火山-沉积型、碳酸盐岩中热水沉积型(或“层控”型)、与岩浆作用有关的热液型、受变质型及表生型.其中,海相沉积型占资源量的71.4％,表生型占15.7％,是最主要的两种类型.中国锰矿广泛分布于“泛扬子区”、华北陆块的燕辽地区以及天山和祁连山部分地区,尤以“泛扬子区”为最,并具分布广泛又相对集中的总体特征.中国的成锰时代多,中—新元古代、早古生代(寒武纪、奥陶纪)、晚古生代—早中生代是中国锰矿形成的重要时代.中国锰矿时-空分布的主要特征是“北锰南迁”:中元古代锰矿主要产于华北陆块的燕辽裂谷带,新元古代—古生代锰矿主要产于“泛扬子区”的大陆边缘盆地或台内盆地中.大型、超大型锰矿床或锰矿田的形成,受控于非构造期盆地性质、古海洋结构、古海水性质及海平面升降等因素,其形成环境存在一定的相似性及同源性. 相似文献
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The BIF-hosted iron ore system represents the world's largest and highest grade iron ore districts and deposits. BIF, the precursor to low- and high-grade BIF hosted iron ore, consists of Archean and Paleoproterozoic Algoma-type BIF (e.g., Serra Norte iron ore district in the Carajás Mineral Province), Proterozoic Lake Superior-type BIF (e.g., deposits in the Hamersley Province and craton), and Neoproterozoic Rapitan-type BIF (e.g., the Urucum iron ore district).The BIF-hosted iron ore system is structurally controlled, mostly via km-scale normal and strike-slips fault systems, which allow large volumes of ascending and descending hydrothermal fluids to circulate during Archean or Proterozoic deformation or early extensional events. Structures are also (passively) accessed via downward flowing supergene fluids during Cenozoic times.At the depositional site the transformation of BIF to low- and high-grade iron ore is controlled by: (1) structural permeability, (2) hypogene alteration caused by ascending deep fluids (largely magmatic or basinal brines), and descending ancient meteoric water, and (3) supergene enrichment via weathering processes. Hematite- and magnetite-based iron ores include a combination of microplaty hematite–martite, microplaty hematite with little or no goethite, martite–goethite, granoblastic hematite, specular hematite and magnetite, magnetite–martite, magnetite-specular hematite and magnetite–amphibole, respectively. Goethite ores with variable amounts of hematite and magnetite are mainly encountered in the weathering zone.In most large deposits, three major hypogene and one supergene ore stages are observed: (1) silica leaching and formation of magnetite and locally carbonate, (2) oxidation of magnetite to hematite (martitisation), further dissolution of quartz and formation of carbonate, (3) further martitisation, replacement of Fe silicates by hematite, new microplaty hematite and specular hematite formation and dissolution of carbonates, and (4) replacement of magnetite and any remaining carbonate by goethite and magnetite and formation of fibrous quartz and clay minerals.Hypogene alteration of BIF and surrounding country rocks is characterised by: (1) changes in the oxide mineralogy and textures, (2) development of distinct vertical and lateral distal, intermediate and proximal alteration zones defined by distinct oxide–silicate–carbonate assemblages, and (3) mass negative reactions such as de-silicification and de-carbonatisation, which significantly increase the porosity of high-grade iron ore, or lead to volume reduction by textural collapse or layer-compaction. Supergene alteration, up to depths of 200 m, is characterised by leaching of hypogene silica and carbonates, and dissolution precipitation of the iron oxyhydroxides.Carbonates in ore stages 2 and 3 are sourced from external fluids with respect to BIF. In the case of basin-related deposits, carbon is interpreted to be derived from deposits underlying carbonate sequences, whereas in the case of greenstone belt deposits carbonate is interpreted to be of magmatic origin. There is only limited mass balance analyses conducted, but those provide evidence for variable mobilization of Fe and depletion of SiO2. In the high-grade ore zone a volume reduction of up to 25% is observed.Mass balance calculations for proximal alteration zones in mafic wall rocks relative to least altered examples at Beebyn display enrichment in LOI, F, MgO, Ni, Fe2O3total, C, Zn, Cr and P2O5 and depletions of CaO, S, K2O, Rb, Ba, Sr and Na2O. The Y/Ho and Sm/Yb ratios of mineralised BIF at Windarling and Koolyanobbing reflect distinct carbonate generations derived from substantial fluid–rock reactions between hydrothermal fluids and igneous country rocks, and a chemical carbonate-inheritance preserved in supergene goethite.Hypogene and supergene fluids are paramount for the formation of high-grade BIF-hosted iron ore because of the enormous amount of: (1) warm (100–200 °C) silica-undersaturated alkaline fluids necessary to dissolve quartz in BIF, (2) oxidized fluids that cause the oxidation of magnetite to hematite, (3) weakly acid (with moderate CO2 content) to alkaline fluids that are necessary to form widespread metasomatic carbonate, (4) carbonate-undersaturated fluids that dissolve the diagenetic and metasomatic carbonates, and (5) oxidized fluids to form hematite species in the hypogene- and supergene-enriched zone and hydroxides in the supergene zone.Four discrete end-member models for Archean and Proterozoic hypogene and supergene-only BIF hosted iron ore are proposed: (1) granite–greenstone belt hosted, strike-slip fault zone controlled Carajás-type model, sourced by early magmatic (± metamorphic) fluids and ancient “warm” meteoric water; (2) sedimentary basin, normal fault zone controlled Hamersley-type model, sourced by early basinal (± evaporitic) brines and ancient “warm” meteoric water. A variation of the latter is the metamorphosed basin model, where BIF (ore) is significantly metamorphosed and deformed during distinct orogenic events (e.g., deposits in the Quadrilátero Ferrífero and Simandou Range). It is during the orogenic event that the upgrade of BIF to medium- and high-grade hypogene iron took place; (3) sedimentary basin hosted, early graben structure controlled Urucum-type model, where glaciomarine BIF and subsequent diagenesis to very low-grade metamorphism is responsible for variable gangue leaching and hematite mineralisation. All of these hypogene iron ore models do not preclude a stage of supergene modification, including iron hydroxide mineralisation, phosphorous, and additional gangue leaching during substantial weathering in ancient or Recent times; and (4) supergene enriched BIF Capanema-type model, which comprises goethitic iron ore deposits with no evidence for deep hypogene roots. A variation of this model is ancient supergene iron ores of the Sishen-type, where blocks of BIF slumped into underlying karstic carbonate units and subsequently experienced Fe upgrade during deep lateritic weathering. 相似文献
19.
The Wiluna West small (~ 130 Mt) high-grade bedded hematite ore deposits, consisting of anhedral hematite mesobands interbedded with porous layers of acicular hematite, show similar textural and mineralogical properties to the premium high-grade low-phosphorous direct-shipping ore from Pilbara sites such as Mt Tom Price, Mt Whaleback, etc., in the Hamersley Province and Goldsworthy, Shay Gap and Yarrie on the northern margin of the Pilbara craton. Both margins of the Pilbara Craton and the northern margin of the Yilgarn craton were subjected to sub-aerial erosion in the Paleoproterozoic era followed by marine transgressions but unlike the Hamersley Basin, the JFGB was covered by comparatively thin epeirogenic sediments and not subjected to Proterozoic deformation or burial metamorphism. The Joyner's Find greenstone belt (JFGB) in the Yilgarn region of Western Australia was exhumed by middle to late Cenozoic erosion of a cover of unmetamorphosed and relatively undeformed Paleoproterozoic epeirogenic sedimentary rocks that preserved the JFGB unaltered for nearly 2 Ga; thus providing a unique snapshot of the early Proterozoic environment.Acicular hematite, pseudomorphous after acicular iron silicate, is only found in iron ore and BIF that was exposed to subaerial deep-weathering in early Paleoproterozoic times (pre 2.2 Ga) and in the overlying unconformable Paleoproterozoic conglomerate derived from these rocks and is absent from unweathered rocks (Lascelles, 2002). High-grade ore and BIF weathered during later subaerial erosion cycles contain anhedral hematite and acicular pseudomorphous goethite. The acicular hematite was formed from goethite pseudomorphs of silicate minerals by dehydration in the vadose zone under extreme aridity during early Paleoproterozoic subaerial weathering.The principal high-grade hematite deposits at Wiluna West are interpreted as bedded ore bodies that formed from BIF by loss of chert bands during diagenesis and have been locally enriched to massive hematite by the introduction of hydrothermal specular hematite. No trace of chert bands are present in the deep saprolitic hematite and hematite–goethite ore in direct contrast to shallow supergene ore in which the trace of chert bands is clearly defined by goethite replacement, voids and detrital fill. Abundant hydrothermal microplaty hematite at Wiluna West is readily distinguished by its crystallinity.The genesis of the premium ore from the Pilbara Region has been much discussed in the literature and the discovery at Wiluna West provides a unique opportunity to compare the features that are common to both districts and to test genetic models. 相似文献
20.
A Mesoarchean greenstone belt (3.5–3.0 Ga) in the western part of the East Indian Shield comprising the Iron Ore Group of the Noamundi basin contains economic resources of both iron and manganese ores in the NNE plunging regional synclinorium. Manganese mineralization in the central and eastern parts of this synclinorium, particularly in Joda–Noamundi sector, has taken place in multiple cycles starting from syngenetic sedimentary and exhalative type through mobilization and remobilization in different stages of tectonism, deformation and hydrothermal activities to latest lateritic or supergene type. A relatively high temperature metamorphic jacobsite–hausmannite–bixbyite–braunite assemblage, low temperature hydrothermal pyrolusite–psilomelane–hollandite assemblage and supergene pyrolusite–manganomelane–groutite–polianite assemblage are present and were formed by recycling of manganese in different stages of mineralization. A detailed structural study of the manganese ore bodies as well as their ore petrographic and mineralogical characteristics with mineral chemistry has revealed systematic mineralization and their relation to deformational phases. Such recycling of manganese and its structural control of mineralization in different phases is unique of its kind in comparison with other Archean manganese deposits in the world. 相似文献