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1.
王秉璋  陈静  罗照华  陈发彬  王涛  郭贵恩 《岩石学报》2014,30(11):3213-3228
祁漫塔格地区是青藏高原北部最重要的多金属矿集区,晚二叠世-早侏罗世岩浆作用与成矿作用关系密切,以祁漫塔格东段为研究区分析讨论了祁漫塔格及临区晚二叠世-早侏罗世花岗岩特点,从晚二叠世-早侏罗世可以识别出4个阶段5个花岗岩组合.(1)晚二叠世弱过铝质高钾钙碱性系列二长花岗岩+正长花岗岩组合与偏铝质-弱过铝质钙碱性系列英云闪长岩+花岗闪长岩组合,LA-ICP-MS U-Pb年龄在252.0~258.5Ma,普遍含暗色铁镁质微粒包体;(2)中三叠世闪长岩+英云闪长岩+花岗闪长岩+(二长花岗岩)组合,LA-ICP-MS U-Pb年龄在226.9~238.6Ma,富含暗色铁镁质微粒包体,为偏铝质-弱过铝质钙碱性-高钾钙碱性系列岩石,Sr含量一般在400×10-6~537×10-6,δEu在0.67~0.95;(3)晚三叠世石英闪长岩+英云闪长岩+花岗闪长岩+二长花岗岩组合,LA-ICP-MS U-Pb年龄在211.7~214.1Ma,为偏铝质高钾钙碱性系列岩石,Sr含量一般在341×10-6~515×10-6,δEu在0.69~0.95之间;(4)晚三叠世-早侏罗世正长花岗岩组合,LA-ICP-MS U-Pb年龄在199.5~204.4Ma,为偏铝质高钾钙碱性系列岩石,Sr含量在54×10-6~195×10-6.晚二叠世花岗岩组合为大陆边缘弧火成岩构造组合,与古特提斯洋俯冲相关;中三叠世花岗岩组合出露面积巨大,构成了印支期北昆仑岩浆弧的主体,形成于俯冲-碰撞转换阶段,与俯冲岩石圈板片的断离相关,这一事件在东昆仑具有普遍意义,是东昆仑造山带最具规模的地幔物质注入与壳幔岩浆混合事件,晚三叠世花岗岩组合形成于后碰撞阶段,是加厚陆壳底部幔源玄武质岩浆底侵作用的结果.  相似文献   

2.
该区花岗质岩石主要岩性为石英闪长岩、英云闪长岩、花岗闪长岩、二长花岗岩和正长花岗岩。通过对石英闪长岩锆石SHRIMP U-Pb定年[1],所获得年龄为(313±5)Ma~(323±4)Ma,属于晚石炭世侵入体;前进场和达青二长花岗岩各单元岩体均侵入了该区早二叠世寿山沟组海陆交互相碎屑沉积岩,侵入接触关系明确,红柱石角岩发育。测得前进场岩体和达青岩体锆石SHRIMP U-Pb年龄分别为(280.8±3.6)Ma和(281.5±0.5)Ma,说明岩体形成于早二叠世晚期;乌兰陶勒盖正长花岗岩岩体获得了259Ma、羊角林高勒二长花岗岩为246~216Ma的U-Pb同位素年龄,说明在晚二叠世—三叠世又有一次侵入高峰。石炭—二叠纪裂谷发育时期,部分跨入三叠纪,先后有3次侵入高峰,即晚石炭世的石英闪长岩、早二叠世的英云闪长岩—二长花岗岩、晚二叠世—三叠纪的二长花岗岩-正长花岗岩。  相似文献   

3.
基于东昆仑造山带祁漫塔格构造走廊域晚古生代—早中生代侵入岩类的野外地质学、岩石学、时空分布和同位素定年资料,可以识别出5个构造岩浆阶段和5个构造岩浆带。研究区的岩浆活动主要集中于早中二叠世阶段、晚二叠世晚期—中三叠世早期、中三叠世、晚三叠世和晚三叠世—早侏罗世。早中二叠世阶段的岩浆活动产物为花岗闪长岩+(斑状)二长花岗组合、石英闪长岩+斑状石英闪长岩组合及闪长岩+石英闪长岩组合,晚二叠世晚期—中三叠世早期(254.1~240.6Ma)为(斑状)二长花岗岩+正长花岗岩组合;中三叠世(安尼期晚期—拉丁初期)为闪长岩+石英闪长岩+花岗闪长岩+英云闪长岩组合;晚三叠世(212~225Ma)为石英二长闪长岩+花岗闪长岩+(斑状)二长花岗岩+正长花岗岩组合;晚三叠世—早侏罗世(瑞替—郝塘期)代表性的岩石组合为石英二长岩+(斑状)正长花岗岩+碱长花岗岩。这些火成岩组合有规律地分布在构造走廊域内,是揭示东昆仑造山带构造演化的关键所在。  相似文献   

4.
扬子克拉通西缘康定杂岩中的片麻状花岗岩主要由英云闪长岩、花岗闪长岩、灰白色细粒二长花岗岩和少量的粉红色粗粒二长花岗岩组成.其中英云闪长岩和花岗闪长岩形成于797~795Ma,灰白色细粒二长花岗岩SHRIMP锆石定年产生一个206Pb/238U权重平均767±24Ma,被解释为该期花岗质岩浆的结晶年龄.英云闪长岩、花岗闪长岩和灰白色细粒二长花岗岩和其中的闪长岩包体表现为右斜式稀土配分模式,具有很高的(La/Yb)N比值,无Eu异常,在原始地幔标准化的多元素蜘蛛网状图上表现了明显的Nh、Ta、P和Ti负异常.而粉红色粗粒二长花岗岩却表现了平坦的稀土配分模式,具有强烈的负Eu异常和强烈的Nh、Ta、sr、P和Ti负异常,但是富集大离子亲石元素.所有这些片麻状花岗岩具有εNd(t)=-0.57~+5.67,绝大部分样品εNd(t)>0.结合地质学、岩石学、地球化学和Sm-Nd同位素特征,康定杂岩中英云闪长岩、花岗闪长岩和灰白色细粒二长花岗岩形成于来自亏损地幔的初生地壳玄武质岩石和相关的杂砂岩在高压条件下的部分熔融,而粉红色粗粒二长花岗岩的岩浆导源于表壳岩低压条件下的部分熔融.结合这些片麻状花岗岩的岩石成因和构造鉴别,表明扬子克拉通西缘康定杂岩中新元古代片麻状花岗岩形成于安第斯型活动大陆边缘.  相似文献   

5.
珲春小西南岔地区白垩纪花岗岩主要有英云闪长岩和花岗闪长岩两种类型。英云闪长岩属于中钾钙碱性系列(Na2O/K2O=1.99~2.76),具有高Al2O3(15.46%~17.13%)、Sr(559×10-6~731×10-6)、Sr/Y(40~78)、La/Yb(16~21),低Y(9×10-6~14×10-6)、Yb(0.8×10-6~1.3×10-6)的特征,与埃达克质岩石地球化学特征类似。花岗闪长岩为高钾钙碱性系列,Na2O/K2O=1.01~1.56,w(Sr)=312×10-6~410×10-6w(Yb)=1.23×10-6~2.13×10-6、Sr/Y=13~32,属正常的高钾钙碱性花岗岩。两类花岗岩的源区均为玄武质下地壳物质,英云闪长质岩浆形成压力较高(> 1.0 GPa),深度大于33 km,花岗闪长质岩浆形成压力相对较低(0.8~1.0 GPa),岩浆来源深度为26~33 km。  相似文献   

6.
加容检德工卡侵入岩序列由石英闪长岩-英云闪长岩-花岗闪长岩-正长花岗岩组成。岩石化学成分表现为从中基性到酸性的演化及岩浆向富硅、富碱方向演化。稀土元素特征表现为轻稀土元素富集;微量元素特征表现为富集大离子亲石元素Rb、K、Ba、Th,而Sr、Nb、Ta略显亏损,Ti、P较强亏损。构造环境为同碰撞花岗岩,时代为早白垩世。  相似文献   

7.
报道了红石山-百合山蛇绿构造混杂岩带南侧大红山地区发现的一套泥盆纪弧花岗岩,并论述其地质特征、岩石学、地球化学、年代学及其岩石成因和构造背景。该套弧花岗岩由英云闪长岩、花岗闪长岩及石英二长岩组成,整体经历了强烈的区域动热变质作用,普遍发育透入性的新生面理构造。据岩石地球化学特征,该套弧花岗岩可分为钠质的T_1G_1(英云闪长岩+花岗闪长岩)和钾质的QM(石英二长岩),T_1G_1具有高铝型TTG的特征(Al_2O_3平均15.22%,大于15%),QM则为一套高钾钙碱性系列岩石,属于低Sr高Yb的浙闽型花岗岩(Sr含量平均121.64×10~(-6),Yb含量平均2.95×10~(-6))。二者均具有轻稀土元素和大离子亲石元素明显富集、重稀土元素和高场强元素明显亏损,以及非常明显的"TNT"异常(Nb、Ta、Ti亏损)特征,指示该套弧花岗岩形成于成熟度较高的岛弧背景。锆石U-Pb测年结果显示,这套弧花岗岩的侵位时代为364~399 Ma。结合区域地质背景和时空演化配置,认为该套弧花岗岩为北山造山带雀儿山岛弧(D)的残留。该发现为北山造山带北带古生代弧-盆演化体制的研究提供了新的证据和线索。  相似文献   

8.
陈宣华 《地质学报》2011,85(2):157-171
柴达木盆地东部是连接秦岭、祁连、昆仑三大造山带的关键构造部位,发育了以晚二叠世-中三叠世(P-T)花岗岩类为主的古特提斯域深成岩浆活动.岩石地球化学分析表明,柴达木盆地东部基底P-T花岗岩类形成于大洋环境,主要为I型花岗岩类.该期花岗岩类可分为两个时间演化系列,早期为钾长花岗岩-花岗闪长岩-英云闪长岩-闪长岩系列,晚期...  相似文献   

9.
锆石LA-ICP-MS U-Pb测年结果表明,阿拉善盟北部宗乃山岩基包括中二叠世钾长花岗岩(272±1 Ma)和早三叠世闪长岩(249±1 Ma)、花岗闪长岩(247±1 Ma)。中二叠世钾长花岗属于准铝质和钾玄质系列,为高分异I型花岗岩。早三叠世闪长岩属钙碱性系列,而花岗闪长岩为弱过铝质,钙碱性系列,属于I型花岗岩。宗乃山地区这些中酸性侵入岩都显示出轻稀土元素相对富集和重稀土元素相对亏损的特征,并且具有微弱-中等的Eu负异常。在原始地幔标准化图解中,都相对富集大离子亲石元素(K、Rb、Ba和Sr等),亏损高场强元素(Ta、Nb、P和Ti等)。宗乃山地区侵入岩的锆石绝大部分具有正的εHf(t)值(+0.3~+11.6)和相对年轻的地壳模式年龄(tCDM=1 275~533Ma),表明源区主要为新生地壳物质。这些特征与同一构造带上沙拉扎山地区的侵入岩十分类似,而明显不同于具有古老基底的阿拉善地块内发育的侵入岩,因此宗乃山-沙拉扎山构造带具有亲中亚造山带的特征,中亚造山带与阿拉善地块的界线应位于宗乃山-沙拉扎山构造带以南。  相似文献   

10.
哈里努登岩体位于阿拉善地块北缘,主要由花岗闪长岩、黑云母二长花岗岩组成。锆石LA-ICP-MS U-Pb测年显示其形成时代为284.0Ma±1.8Ma,并非以往认为的志留纪。岩石SiO2含量为67%~72%,CaO为2.2%~4.4%,Na2O为3.7%~4.3%,K2O为2.1%~2.9%,具有较高的全碱含量,属钙碱性—高钾钙碱性系列,Al2O3含量为14.5%~17.2%,为准铝—弱过铝质(A/CNK=0.90~1.07),总体显示出I型花岗岩的特征。稀土元素总量较低(35.2×10-6~130.6×10-6),轻稀土元素相对富集,Eu呈正异常(δEu=1.04~1.90)。在原始地幔标准化图解中,大离子亲石元素(K、Rb、Ba、Sr)富集,亏损高场强元素(Ta、Nb、P、Yb、Y等),显示出弧花岗岩的特征。结合区域背景分析,阿拉善北缘在早二叠世时可能还存在与弧物质有关的岩浆活动。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

14.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

15.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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20.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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