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1.
大别山超高压变质带是华北与扬子板块俯冲碰撞作用的产物。迄今为止,报导的超高压变质岩除镁铁、超镁铁质岩石外,主要为火山-沉积岩,然而除上述岩石外,大别山南部出露大量花岗质片麻岩。作者在近期对大别山东南部变质花岗岩岩石学研究中发现:变质花岗岩中含有Gt+Ru+Phe±Acg+Aug±Di+Pl+Na-Amp+Or+Q组合,与钠长石共生的霓石或透辉石可能是早期矿物硬玉或富硬玉质绿辉石退变的,而岩石中石榴石分带特征,即内带以铁铝榴石(43.06%)和钙铝榴石(46.28%)为主,外带则以锰铝榴石(30.40%)和钙铝榴石(35.67%)为主,这些都表明它们是由高压向低压退化变质之产物。因此,变质花岗岩可能早期存在着这样的榴辉岩相峰期矿物组合Jd/omp+Q/CS+Phe+Ru+Gt+Or,这个组合由于后期的压力降低而退变为中低压的矿物组合。  相似文献   

2.
通过对大别山北部石榴二辉麻粒岩中的变质结构及变质反应特征的研究,认为石榴二辉麻粒岩在变质作用过程中,经历了四个主要的变质演化作用阶段:(1)S1阶段以早期的残留矿物,并呈包体的形式产于石榴石中为特征,以Cpx+Q(Cs)+Ru+Gt组合为代表,T=612~750℃,表明石榴二辉麻粒岩曾经历过榴辉岩相阶段的变质作用;(2)S2阶段是以Opx+Cpx+Gt+Amp+Q+Ti+Mt矿物组合为牲,其相应的T=837~887℃,P=1.03~0.95Gpa,此时的变质条件为麻粒岩相;(3)S3阶段,矿物组合为Cpx+Gt+Amp+Pl+Mt,T=530~660℃,P=0.85~0.95Gpa,此时的温故知新压条件代表岩石已经进入了角闪岩相阶段;和(4)晚期的低角闪岩相阶段S4,其形成的温压条件为T=495℃,P=0.56~0.70Gpa。  相似文献   

3.
卢良兆  董永胜 《岩石学报》1998,14(2):140-151
根据显微构造和矿物微区化学成分的详细研究,确定了胶东早元古代荆山群富铝片麻岩中存在平衡组合Grt-Crd-Bt-Sil-Kfs-Pl-Qtz,反映变质峰期Grt+Sil+Qtz→Crd,Bt+Sil+Qtz→Grt+Crd+Kfs+H2O和Pl(An)→Grt(Grs)+Sil+Qtz①等转换反应和Fe-Mg交换反应均基本保持平衡状态。实验资料和地质温压计估算确定其峰期P-T-X关系:P为0.60~0.70GPa,T为700℃~750℃,XGrtMg为0.21~0.26,XCrtCa为0.044~0.053,XCrdMg为0.65~0.72,XBtMg为0.50~0.57,XPlAn为0.285~0.388。但Grt、Bt和Pl又都有明显的微区成分变化,反映峰期后降温过程各种交换反应的效应,其封闭温度在500℃~600℃之间,压力为0.40~0.50GPa。研究确立逆时针的PTt轨迹,其样式反映早元古代陆缘壳内拗陷带的闭合过程。  相似文献   

4.
蔓箐沟地区石榴基性麻粒岩发育多期变质反应结构。矿物组合演化可划分三个阶段:①峰期阶段(M1),以包裹于石榴石中的Opx+Cpx±Hb+Pl±Qz和由Gt+Opx+Cpx±Hb+Pl±Qz组成基质矿物组合为代表;②退变早期近等温减压阶段(M2),形成蠕虫状后成合晶Opx+Hb+Pl±Mt;③退变晚期阶段(M3),则形成细粒、黄绿色Hb+中酸性Pl的较低温组合。并揭示该区石榴基性麻粒岩从中下部地壳的麻粒岩相变质,到快速抬升至中浅部地壳发生的近等温减压及晚期降温退变的复杂pT演化历史。  相似文献   

5.
太行山太古宙变质杂岩中富铝片麻岩的变质作用   总被引:15,自引:2,他引:15  
刘树文  梁海华 《岩石学报》1997,13(3):303-312
太行山太古宙变质杂岩中富铝片麻岩主要分布在湾子岩系的底部,常常与大理岩密切伴生或者以似层状体产于花岗质片麻岩中。依据岩石结构和反应关系将变质作用分为早期、中期和晚期三个阶段。早期矿物组合为Gt(石榴石)+St(十字石)+Pl(斜长石)+Ms(白云母)+Bi(黑云母)+Ru(金红石)+Qz(石英)±K-fs(钾长石);中期矿物组合为Gt+Ged(铝直闪石)+Bi+Pl+Ilm(钛铁矿)+Co(刚玉)+Sil1(毛发状夕线石)+Qz+K-fs±Ms;晚期矿物组合为Hc+K-fs+Sil2(针柱状夕线石)。矿物温度压力计和内部一致性热力学计算结果表明早期矿物组合形成于680℃和0.8GPa左右,刚玉、铝直闪石和毛发状夕线石组合形成于730℃~750℃和0.7GPa左右的很窄的P-T范围内,夕线石和尖晶石矿物组合的形成温度与前一组合相似或略高,压力偏低。在P-T空间上上述矿物组合的演化构成了一条近等温减压(ITD型)的PTt轨迹。  相似文献   

6.
怀安—大同一带基性麻粒岩变质反应序列与水活度   总被引:1,自引:5,他引:1  
刘福来 《岩石学报》1997,13(1):27-43
晋冀蒙三省交界的怀安-大同一带基性麻粒岩有保存完好的变质反应结构。依据岩相学特征,可在基性麻粒岩中区分出四个世代的矿物组合:①峰前阶段(M1)以包裹在石榴石或紫苏辉石中的Hb+Pl±Qz、Cpx+Hb+Pl±Qz组合为代表,T为600℃~700℃,P为0.70~0.82GPa,相应的aH2O值为0.50~0.62;②峰期阶段(M2)以三联点结构的基质矿物为特征,组合为Opx+Cpx+Hb+Pl±Qz、Gt+Opx+Cpx+Hb+Pl±Qz,T为750℃~850℃,P为0.84~1.05GPa,相应的水活度降至0.39~0.52;③峰后近等温减压阶段(M3)以石榴石普遍转变为Opx+Pl±Mt及角闪石转变为Opx+Cpx后成合晶为特征,T为700℃~780℃,P为0.50~0.70GPa,相应的aH2O值降至0.08~0.11;④至降温阶段(M4),以无水矿物石榴石、辉石退变为Hb+Pl组合为代表,T为530℃~630℃,P为0.30~0.42GPa,aH2O值再次升至0.37~0.40。研究表明,矿物组合演化和所发生的(脱水)变质反应不仅受PT条件的控制,而且与体系水活度密切相关  相似文献   

7.
辽西建平变质杂岩区蠕虫状后成合晶的成因与意义   总被引:2,自引:2,他引:2  
季建清  陈曼云 《岩石学报》1996,12(4):514-529
建平变质杂岩中发育蠕虫结构的后成合晶,它受与石榴石共生的矿物组合、变质流体中水活度和变质岩原岩的制约。这种后成合晶可出现四种矿物组合:(1)Opx+Pl+少量Cpx,(2)Opx+Mt+Pl+Q+少量Cpx,(3)Hb+Pl,(4)Cord+Opx±Pl。它们是在建平变质杂岩受中元古代三座庙序列侵入岩侵位作用影响发生的相当于辉石角岩相接触热变质作用中形成的,温压条件为720℃~780℃,0.64~0.70GPa。这些后成合晶的结构特征、矿物学特征、变质反应前后体积变化、岩体热传导模型的时间域的半定量估算等都表明它们是在压力降低,热扰动历史较为短暂(介于2.85Ma和11.40Ma之间)的非平衡条件下形成的  相似文献   

8.
胶南隆起含榴辉石高压变质带为大别超高压带的东延部分,超高压变质作用的主要矿物共生组合为Grt+Ky+Rut+Jd+Q;Sp+Zo+Ab±Grt±Omp;变质作用的温压条件为T=600~700℃,P=2.3~2.6GPa。超高压岩石及高压岩石均经历了两期退变质作用,且具有相似的顺时钟P-T演化轨迹。  相似文献   

9.
日照岚山头榴辉岩的成因及演化的PTt轨迹   总被引:2,自引:0,他引:2  
岚山头含柯石英榴辉岩呈透镜状构造块体产于晚元古代含霓石碱长花岗质片麻岩中,其原岩为玄武岩浆分离结晶晚期堆积的辉长岩。该榴岩曲型的共生矿物组合可划分为4个世代:(1)Cpx1+Mu1(OrPhen1)+Qz+Pl1;(2)Cpx2(Om1)+Gr1+Ky+Cs;(3)Cpx3(Om2)+Gr2+Phen2+Ky+Zo+Qz;(4)Pl2+Tl+Mrg+Phen3+Czo+Qz。它们分别反映4个变质演  相似文献   

10.
皮尔斯比率图解在腾冲新生代火山岩研究中的应用   总被引:1,自引:0,他引:1  
腾冲新生代火山岩属钙碱性系列,可分为四个喷发期,构成两个岩浆旋回:N_2-Q_1为玄武岩—英安岩;Q_3—Q_4为玄武岩—安山岩。应用皮尔斯比率图解对其进行研究表明:分离结晶作用是岩石化学成分变异的主要因素;第一旋回的玄武岩浆可能起源于上地幔的部分熔融,经(Pl+Cpx±O1±Mt)矿物组合的分离结晶而形成英安岩浆。英安岩浆在形成或演化过程中受到了地壳物质的轻度混染。该旋回具有张性构造环境中双峰式火成岩套的特点。第二旋回的玄武岩浆可能起源于早期俯冲洋壳的部分熔融,经(Mt+Pl+Cpx±Opx)矿物组合的分离结晶而形成安山岩浆,为安山岩成因的分离结晶模式提供了一个良好的实例。该旋回具有典型的弧火山岩的特点。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

20.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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