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1.
W. F. Tan L. A. Wang C. Huang J. E. Green 《International Journal of Environmental Science and Technology》2013,10(3):465-472
Municipal solid waste incineration fly ash blended with pine sawdust and shale, using a neotype trefoil rotary kiln to form lightweight aggregates, is an effective and a potential means method of fly ash disposal. The optimum sintering conditions of Trefoil rotary kiln were determined in terms of an orthogonal test by measuring the pellets’ bulk density, granule strength, 1 h water absorption. As far as the kinetics is concerned, an integral method of Coats–Redfern was introduced to analyze the kinetics characteristics of the mixture samples. Also, the kinetic triplets (apparent activation energy, pre-exponential factor and reaction order) were estimated by the reaction of kinetics model functions. It is shown that the optimum sintering conditions are as follows: (a) preheating temperature of 500 °C, (b) sintering temperature of 1130 °C, (c) holding time of 4 min. The optimum reaction models of the four stages are Avrami–Erofeev, Mample, Avrami–Erofeev and There-dimensional diffusion (Jander), respectively. 相似文献
2.
One of the effective utilization strategies for fly ash and waste sludge is to use it as a fill material to raise low lying areas. Bearing capacity and settlement are the required input for the design of foundations on such fills. To determine the bearing capacity, plate load tests were carried out on the compacted beds of fly ash, fly ash-waste sludge and fly ash-waste sludge–cement. The tests were conducted by keeping 90, 95 and 100 % relative compaction, fresh and fresh submerged conditions, aged (28 days) and aged (28 days) submerged conditions as variables of the tests. The load-settlement curves were plotted for fly ash and mix blends. The minimum load was obtained for fly ash under submerged condition, further the test results show that the fly ash becomes flowable on submergence. On the other hand when the fly ash was mixed with waste sludge and cement, the load carrying capacity was found to improve to a greater extent. Test beds prepared with fly ash–cement-waste sludge under as compacted condition (fresh) show very high load carrying capacity (1600–2180 kN/m2). An analytical method has also been validated for fly ash–cement-waste sludge mix which was developed to estimate the settlement of footing resting on fly ash taking into account the pre-consolidation stresses. The non linearity of load-settlement behavior was appropriately modeled, on the basis of available plate load test data incorporated in the method. The method requires as input, the pre-consolidation stress and Young’s modulus of compacted mix of fly ash-waste sludge–cement. A comparison of load-settlement values observed in plate load tests and predicted values for the mix 47 %FA + 45 %S + 8 %C, using the proposed method shows good agreement. Hence, this relationship may also be useful to the field engineers to check the reported load-settlement values for such types of mixes in the field. 相似文献
3.
In order to recycle the incineration fine bottom ash generated from municipal solid waste as a fine aggregate construction
material(<4.75 mm), a series of uniaxial compression tests were carried out according to the mixing ratio of bottom ash, the
curing temperature, the water–cement ratio, the mixing ratio of expanded poly styrene (EPS), and the curing time. As the results
of tests, the compression strengths cured 28 days of all specimens prepared with different mixing ratios are ranged between
87 and 220 kg/cm2. The water content of the hardened cement mortar is not much different with the curing time. Also, the water content is increased
with increasing the mixing ratio of bottom ash, the water–cement ratio, and the mixing ratio of EPS. The unit weight of the
hardened cement mortar is decreased with increasing the mixing ratio of bottom ash and the mixing ratio of EPS. The compression
strength of the hardened cement mortar is decreased with increasing the mixing ratio of bottom ash. The compression strength
of the hardened cement mortar cured at 30 ± 2°C and 40 ± 2°C is bigger than that of the cement mortar cured at normal temperature
(20 ± 2°C). However, the compression strength of the hardened cement mortar cured at 30 ± 2°C is bigger than that of the cement
mortar cured at 40 ± 2°C. The compression strength is increased at the range from 0.55 to 0.6 of water–cement ratio, and then
the compression strength is decreased over 0.65 of water–cement ratio. Meanwhile, the compression strength of the hardened
cement mortar is decreased with increasing the mixing ratio of EPS. 相似文献
4.
The production and utilization of coal is based on well-proven and widely used technologies. Fly ash, a coal combustion byproduct,
has potential to produce a composite material with controlled and superior properties. The major challenges with the production
of fly ash are in its huge land coverage, adverse impact on environment etc. It puts pressure on the available land particularly
in a densely populated country like India. In India the ash utilization percentage has not been very encouraging in spite
of many attempts. Stabilization of fly ash is one of the methods to transfer the waste material into a safe construction material.
This investigation is a step in that direction. This paper presents the results of an investigation on compressive strength
and bearing ratio characteristics of surface coal mine overburden material and fly ash mixes stabilized with lime for coal
mine haul road construction. Tests were performed with different percentages of lime (2, 3, 6 and 9%). The effects of lime
content and curing period on the bearing ratio and tensile strength characteristics of the stabilized overburden and fly ash
mixes are highlighted. Unconfined compressive strength test results cured for 7, 28 and 56 days are presented to develop correlation
between different tensile strengths and unconfined compressive strength. Empirical models are developed to estimate bearing
ratio and tensile strength of mine overburden–fly ash–quick lime mixtures from unconfined compressive strength test results. 相似文献
5.
A. Mofarrah T. Husain C. Bottaro 《International Journal of Environmental Science and Technology》2014,11(1):159-168
This study investigated the potential application of heavy oil burning fly ash as a precursor to prepare activated carbon. The raw fly ash obtained from a power plant is cleaned by nitric acid/hydrochloric acid and activated at 550–800 °C with hold times of 30 and 60 min to obtain fly ash activated carbon. The phosphoric acid is used as a chemical agent to improve the surface characteristics of the cleaned fly ash. The effects of process variables such as amount of chemical reagents, activation time and temperature were investigated according to two-levels full factorial design. The resultant activated carbons were characterized in terms of Brunauer, Emmett and Teller surface area and total and pore volume. The maximum specific surface area was found of 148.30 m2/g at 800 °C temperatures with 60 min holding time. The test showed that the surface area and pore volumes of the material are also significantly enhanced by the activation process. 相似文献
6.
Nuno Cristelo Stephanie Glendinning Lisete Fernandes Amândio Teixeira Pinto 《Acta Geotechnica》2013,8(4):395-405
This paper studies the effects of sodium-based alkaline activators and class F fly ash on soil stabilisation. Using the unconfined compressive strength test (UCS), the effectiveness of this binder is compared with that of a common cement-based binder. Influence of the activator/ash ratio, sodium oxide/ash ratio and sodium hydroxide concentration was also analysed. Sodium hydroxide concentrations of 10, 12.5 and 15 molal were used for the alkaline-activated specimens (AA), with activator/ash ratios between 1 and 2.5 and ash percentages of 20, 30 and 40 %, relatively to the total solids (soil + ash). UCS was determined at curing periods of 7, 28, 90 and 365 days, and the most effective mixtures were analysed for mineralogy with XRD. The results showed a clear increase in strength with decreasing activator/ash ratio (up to a maximum of 43.4 MPa), which is a positive result since the activator is the most expensive component in the mixture. Finally, UCS results of the cement and AA samples, at 28 days curing, were very similar. However, AA results proved to be just between 20 and 40 % of the maximum UCS obtained at 1 year curing, while cement results at 28 days are expected to be between 80 and 90 % of its maximum. 相似文献
7.
Mohammad H. Gorakhki Christopher A. Bareither 《Geotechnical and Geological Engineering》2018,36(1):27-47
The objective of this study was to evaluate the effect of fly ash amendment on the compression behavior of mine tailings. Natural and synthetic (i.e., laboratory prepared) mine tailings were used to assess the effects of tailings composition and tailings solids content on compressibility. Three types of off-specification fly ashes and Type I–II Portland cement were used as cementitious binders. Tailings-fly ash mixtures were prepared at solids content of 60–75% (water content = 33–67%), water-to-binder ratios of 2.5 and 5, and were cured for 0.1 days (2 h), 7, and 28 days. Bi-linear compression curves on semi-log plots were observed in most of the binder-amended tailings specimens. The break in slope on the compression curve was identified as the breaking stress, whereupon cementitious bonds were broken. The breaking stress increased with an increase in fly ash content, which was attributed to a lower water-to-binder ratio and void volume-to-binder volume ratio that produced more effective particle bonding. Breaking stress also increased with an increase in CaO content and CaO-to-SiO2 ratio of fly ash, which resulted in more effective bonding between particles. The effect of curing time on the breaking stress of fly ash amended specimens was characterized by (1) an increase in breaking stress via increase in curing time and cementitious bond formation or (2) a constant breaking stress with curing time due to competing mechanisms during loading. Specimens cured under a vertical stress showed an increase in breakings stress with applied load water removal prior to cementitious bond formation that reduced the water-to-binder ratio and led to more effective cementation. 相似文献
8.
Fly ash is a waste by-product obtained from the burning of coal by thermal power plants for generating electricity. When bulk
quantities are involved, in order to arrest the fugitive dust, it is stored wet rather than dry. Fly ash contains trace concentrations
of heavy metals and other substances in sufficient quantities to be able to leach out over a period of time. In this study
an attempt was made to study the leachabilities of a few selected trace metals: Cd, Cu, Cr, Mn, Pb and Zn from two different
types of class F fly ashes. Emphasis is also laid on developing an alternative in order to arrest the relative leachabilities
of heavy metals after amending them with suitable additives. A standard laboratory leaching test for combustion residues has
been employed to study the leachabilities of these trace elements as a function of liquid to solid ratio and pH. The leachability
tests were conducted on powdered fly ash samples before and after amending them suitably with the matrices lime and gypsum;
they were compacted to their respective proctor densities and cured for periods of 28 and 180 days. A marked reduction in
the relative leachabilities of the trace elements was observed to be present at the end of 28 days. These relative leachability
values further reduced marginally when tests were performed at the end of 180 days. 相似文献
9.
Deformation modulus of fly ash is one of the most important mechanical properties generally used in different design problems
and also as an input parameter to sophisticated numerical techniques employed to assess the response of different structures
resting on fly ash fill or embankment made of fly ash. Deformation modulus is usually expressed in terms of compressive strength.
This paper presents the deformation modulus of fly ash modified with lime alone or in combination with gypsum at different
strain levels. The values of deformation modulus obtained from both unconfined compression test and unconsolidated undrained
triaxial test results are presented herein. The specimens for unconfined compression test and for undrained triaxial tests
were cured up to 90 and 28 days, respectively. The effects of addition of lime (4–10%) and gypsum (0.5 and 1.0%) on the deformation
modulus of class F fly ash are highlighted. With addition of lime and gypsum, the class F fly ash achieved the deformation
modulus in the range of 190 MPa in UCS test and up to 300 MPa in triaxial test specimens tested under all round pressure of
0.4 MPa. Based on the present test results empirical relationships are developed to estimate deformation modulus of modified
fly ash from unconfined compressive strength and relationships between initial tangent modulus and secant modulus at different
strain levels are also developed. 相似文献
10.
Behavior of expansive soils stabilized with fly ash 总被引：6，自引：0，他引：6
Expansive soils cause serious problem in the civil engineering practice due to swell and shrinkage upon wetting and drying.
Disposal of fly ash, which is an industrial waste in both cost-effective and environment-friendly way receives high attention
in China. In this study, the potential use and the effectiveness of expansive soils stabilization using fly ash and fly ash-lime
as admixtures are evaluated. The test results show that the plasticity index, activity, free swell, swell potential, swelling
pressure, and axial shrinkage percent decreased with an increase in fly ash or fly ash-lime content. With the increase of
the curing time for the treated soil, the swell potential and swelling pressure decreased. Soils immediately treated with
fly ash show no significant change in the unconfined compressive strength. However, after 7 days curing of the fly ash treated
soils, the unconfined compressive strength increased significantly. The relationship between the plasticity index and swell-shrinkage
properties for pre-treated and post-treated soils is discussed. 相似文献
11.
Hydro-mechanical evaluation of stabilized mine tailings 总被引：3，自引：0，他引：3
12.
A. C. D. Royal Y. Makhover S. Moshirian D. Hesami 《Geotechnical and Geological Engineering》2013,31(2):767-781
Three mixtures of cement–bentonite slurry containing 28, 36 and 44 % PFA (as a proportion of cementitious materials) were tested using the unconfined compressive strength and triaxial apparatus to determine the stress–strain and shear strength relationships for samples cured for various periods. The samples were batched using 4 % bentonite and 20 % cementitious materials (by mass of water) and allowed to cure underwater once extruded from sealed moulds. Curing periods of 14, 28 and 90 days were selected to investigate the changes in behaviour at durations commonly specified (28 and 90 days) as well as providing insight into changing behaviour with curing (additional curing periods of 7 and 60 days were investigated on a smaller number of samples to increase understanding). Two rates of displacement were used (1.0 and 1.3 mm/min) and four confining pressures (0, 50, 100 and 200 kPa). Shear strength and strain at peak deviator stress of the samples do not appear to vary considerably with confining pressure. For samples containing 28 % PFA, the majority of physical properties exhibited by the cement–bentonite samples change with curing period up to 60 days, where after the properties become similar to those cured for 90 days. 相似文献
13.
垃圾焚烧飞灰水泥固化体强度稳定性研究 总被引：1，自引：0，他引：1
针对垃圾焚烧飞灰安全处置技术要求,采用水泥对其进行固化、稳定化处理,研究了不同水泥添加量、不同养护时间和渗沥液浸泡时间对固化体无侧限抗压强度及破坏特性的影响,并对垃圾渗沥液的侵蚀机制进行了分析。结果表明：当水泥添加量小于5%,养护时间小于3 d时,飞灰固化体在渗沥液浸泡下迅速解体,垃圾渗沥液的侵蚀对飞灰固化体的强度有较大的影响,浸泡后的固化体呈现出明显的应变软化特征,而未经浸泡的固化体的强度增长符合y=a[1-exp(-bt)]模式。随着水泥添加量及养护时间的增加,飞灰固化体无侧限抗压强度增加,破坏应变减小,而随着浸泡时间的增加,飞灰固化体的无侧限抗压强度先增大后减小,转折点大约在5～7 d,破坏应变近似呈线性增大。渗沥液对飞灰固化体的侵蚀主要是其成分抑制了固化体水化反应和破坏了水化产物。研究成果可为垃圾焚烧飞灰的安全处置技术提供理论依据和参数支持。 相似文献
14.
At present, nearly 100 million tonnes of fly ash is being generated annually in India posing serious health and environmental problems. To control these problems, the most commonly used method is addition of fly ash as a stabilizing agent usually used in combination with soils. In the present study, high-calcium (ASTM Class C—Neyveli fly) and low-calcium (ASTM Class F—Badarpur fly ash) fly ashes in different proportions by weight (10, 20, 40, 60 and 80 %) were added to a highly expansive soil [known as black cotton (BC) soil] from India. Laboratory tests involved determination of physical properties, compaction characteristics and swell potential. The test results show that the consistency limits, compaction characteristics and swelling potential of expansive soil–fly ash mixtures are significantly modified and improved. It is seen that 40 % fly ash content is the optimum quantity to improve the plasticity characteristics of BC soil. The fly ashes exhibit low dry unit weight compared to BC soil. With the addition of fly ash to BC soil the maximum dry unit weight (γdmax) of the soil–fly ash mixtures decreases with increase in optimum moisture content (OMC), which can be mainly attributed to the improvement in gradation of the fly ash. It is also observed that 10 % of Neyveli fly ash is the optimum amount required to minimize the swell potential compared to 40 % of Badarpur fly ash. Therefore, the main objective of the study was to study the effect of fly ashes on the physical, compaction, and swelling potential of BC soils, and bulk utilization of industrial waste by-product without adversely affecting the environment. 相似文献
15.
粉煤灰与生石灰加固软土的室内试验研究 总被引：20，自引：5，他引：15
粉煤灰是一种工业废弃物,与生石灰一样均可用来加固软土地基。笔者进行了粉煤灰与生石灰加固土的室内配方试验,分别将水泥或生石灰与粉煤灰按照不同的比例干拌均匀后,再与不同含水量的软土人工拌和均匀,测定了不同龄期的无侧限抗压强度;分析了石灰加固土强度与生石灰掺入比和龄期的关系及其压缩系数、压缩模量等的变化。并进一步分析了粉煤灰的加固机理,旨在为其进一步的研究和工程应用提供参考。 相似文献
16.
林彤 《水文地质工程地质》2003,(Z1)
粉煤灰是一种强度较高的工业废弃物,可用来加固软土地基。本文进行了粉煤灰加固土的室内配方试验,分别将生石灰或水泥与粉煤灰按照不同的比例干拌均匀后,再与不同含水量的软土人工拌和均匀,测定了4个龄期的无侧限抗压强度,并进一步分析了其加固机理,旨在为其进一步的研究和工程应用提供参考。 相似文献
17.
The laterite nickel (Ni) ore smelting operation in Niquelândia (Goiás state, Brazil) produced large amounts of smelting wastes, stockpiled on dumps (slags) and in settling ponds (fly ash). In this study we present data on the chemistry, mineralogy and pH-dependent leaching behaviours of these two waste materials.Bulk chemical analyses indicated that both wastes contained significant amounts of potentially toxic elements (PTEs), with substantially higher concentrations in the case of the fly ash (up to 2.51 wt% Ni, 1870 mg/kg Cr and 488 mg/kg Co). The mineralogical investigations carried out using X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and electron microprobe (EPMA) indicated that the slag was mainly composed of silicate glass, olivine and pyroxene. In contrast, the fly ash was composed of Ni-bearing serpentine-like phases (originating from the furnace feed), Ni-bearing glass, olivine, pyroxene and spinel. The pH-dependent leaching behaviour was performed according the EU standard experimental protocol (CEN/TS 14997) in the pH range of 3–12. The leaching was highly pH-dependent for both materials, and the highest releases of PTEs occurred at pH 3. The slag generally exhibited an U-shaped leaching behaviour of the PTEs as a function of pH, and was found to release up to 48.0 mg/kg Ni, 25.6 mg/kg Cr, and 1.42 mg/kg Co. The fly ash was significantly more reactive, and exhibited its highest leaching level of PTEs between pH 3 and 7. The maximum observed release corresponded to 5750 mg/kg Ni, 4.35 mg/kg Cr, and 112 mg/kg Co. The leached Ni concentrations after 24 h of leaching in deionized water exceeded the limit for hazardous waste by more than 100x according to the EU legislation (40 mg/kg Ni). X-ray Absorption Near Edge Structure (XANES) and Extended X-ray Absorption Fine Structures (EXAFS) spectra indicated that Ni in the fly ash is predominantly bound in a serpentine-like phase, and during the fly ash experimental alteration it was mainly released from the second shell (corresponding to the atomic distances between Ni and Si, Mg, Fe in high-temperature silicates, glass, and partially dissolved serpentine). This study shows that disposal sites for the fly ash can represent a significant source of local pollution, and direct recycling of the fly ash in the smelting technology (as currently adopted at the Barro Alto new smelter and since few years also at the Niquelândia smelter) is the best environment-friendly option for handling of fly ash in the future. 相似文献
18.
Physical and engineering properties of soil are improved with various binders and binder combinations. Fly ash and lime are commonly used to improve the properties of expansive soils. An attempt has been made, in this paper, to examine the role of gypsum on the physical and strength behaviour of fly ash-lime stabilized soil. The change in strength behaviour is studied at different curing periods up to 90 days, and the mechanism is elucidated through pH, mineralogical, microstructural and chemical composition study. The strength of soil-fly ash mixture has improved marginally with the addition of lime up to 4 % lime and with curing period for 28 day. Significant increase in strength has been observed with 6 % lime and enhanced significantly after curing for 90 days. The variations in the strength of soil with curing period is due to cation exchange and flocculation initially, and binding of particles with cementitious compounds formed after curing. With addition of 1 % gypsum to soil-fly ash-lime, the strength gain is accelerated as seen at 14 day curing. The accelerated strength early is due to formation of compacted structure with growth of ettringite needles within voids. However, strength at curing for 28 day has been declined due to annoyance of clay matrix with the increase in size of ettringite needle; and again increased after curing for 90 days. The rearrangement of clay matrix and suppression of sulphate effects with formation of cementitious compounds are observed and found to be the main responsible factors for strength recovered. 相似文献
19.
近年来,水泥土被广泛应用于土体加固工程,其强度与加固效果密切相关。为研究膨润土和粉煤灰掺量对水泥土性能的影响,对25组不同膨润土和粉煤灰掺量的水泥土进行基本力学性能试验。通过抗压强度试验,发现当粉煤灰和膨润土掺量分别为40%和11%时,28 d的水泥土抗压强度最大,为7.30 MPa;当粉煤灰和膨润土掺量分别为20%和7%时,90 d的水泥土抗压强度最大,为7.19 MPa。通过室内直接剪切试验,发现当粉煤灰和膨润土掺量分别为20%和11%时,28 d的水泥土抗剪强度参数粘聚力c最大,为1144.8 kPa;当粉煤灰和膨润土掺量分别为30%和5%时,90 d的水泥土抗剪强度参数粘聚力c最大,为1753.71 kPa。研究成果可以为武汉地区的粉煤灰和膨润土双掺合剂改良水泥土的现场施工提供参考依据。 相似文献
20.
针对煤层回采顶板垮落法产生的采煤固废堆放量大、长壁胶结充填开采中采充失衡等问题,内蒙古察哈素煤矿31采区采用连采连充巷式胶结充填采煤工艺,采用“隔三采一”的回采方式及“三强一弱”的充填模式。充填材料配比对充填成本与效果具有重要影响,针对原胶结充填材料中水泥消耗大、粉煤灰消纳少的问题,基于泰波理论确定矸石最佳粒径级配系数n为0.5,在此基础上,利用响应面法(RSM)优化材料配比。基于RSM-BBD (Box–Behnken Design)设计13组试验,建立充填体3、7及28 d单轴抗压强度与水泥质量分数X1、粉煤灰质量分数X2、固料质量分数X3及3因素交互作用(水泥与粉煤灰交互作用X1X2、水泥与固料质量分数交互作用X1X3、粉煤灰与固料质量分数交互作用X2X3)的回归模型,模型P值均小于10-4,模型可靠性强。试验结果表明：不仅单一因素对强度影响显著,且各因素的交互作用也对强度有一定的影响。强度随X1与X 相似文献