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1.
岩石地球化学分析表明小龙潭斑岩高钾(K_2O/Na_2O=0.85~8.39)、富碱(K_2O+Na_2O=9.05%~12.45%),总体属于钾玄岩系列的岩石。岩石富集Rb、Ba、Th、LREE等大离子亲石元素而亏损Ti、Nb、Ta、HREE等高场强元素,具有较高的ΣLREE/ΣHREE比值和(La/Yb)N比值,具中等程度Eu负异常。从岩石地球化学特征分析,小龙潭富碱斑岩起源于金沙江洋壳俯冲交代作用形成的富集地幔,富碱斑岩可能与Cu、Mu、Ag成矿作用密切相关。 相似文献
2.
在野外地质工作基础上,运用岩石地球化学方法,通过主量元素、稀土元素和微量元素研究,探讨了水洞岭矿区石英角斑岩的岩石化学特征、形成环境及其与成矿的关系。研究表明:石英角斑岩的w(SiO2)=73.11%~79.30%,w(K2O)=1.20%~5.99%,w(Na_2O)=1.57%~4.61%,w(K_2O+Na_2O)=4.82%~8.67%,Na_2O/K_2O=0.45~3.49,ACNK=0.99~1.25。稀土元素总量w(ΣREE)=70.19×10~(-6)~198.75×10~(-6),轻稀土元素富集,重稀土元素亏损,轻重稀土元素分馏明显((La/Yb)N=3.65~8.20),Eu中度至轻度亏损(δEu=0.53~0.96);大离子亲石元素(Rb、Ba、Th、U、K)和Pb等元素富集,高场强元素(Nb、Ta、Ti、P)和Sr等元素亏损。综合表明水洞岭矿区石英角斑岩形成环境类似于洋壳俯冲成因的火山弧环境。 相似文献
3.
呼斯特岩体为可克萨拉铁铜矿成矿岩体,由石英闪长岩、花岗闪长岩、二长花岗岩及正长花岗岩组成,时代均为晚泥盆世。岩石SiO_2含量为63.30%~69.16%,具有较高的全碱含量,且总体富钾、贫钠,(K_2O+Na_2O平均值为7.28%;K_2O/Na_2O平均值为1.08),ACNK均值为1.06,属准铝质-弱过铝质高钾钙碱性系列。岩体高LREE/HREE值平均为8.32,弱-中等负Eu异常(δEu=0.45~0.79,平均为0.71),富集大离子亲石元素(LILEs:Rb、Th、K、Zr),相对亏损高场强元素(HFSEs:Nb、Ta、Ti),总体显示火山弧花岗岩特点。矿区未发现与295Ma(辉钼矿Re-Os年龄)配套的具有后造山或是陆内地球化学特征的岩体。因此,呼斯特岩体地球化学特征佐证该岩体年龄仍是目前间接提供可克萨拉铁铜矿成矿时代的唯一依据。区内早二叠世辉钼矿化与可克萨拉铁铜矿化应是2次成矿事件的产物。 相似文献
4.
碧罗雪山花岗岩体位于三江成矿带中段的左贡岩浆弧带内,由花岗闪长岩、二长花岗岩、钾长花岗岩和少量暗色包体组成。花岗岩类SiO_2含量67.10%~74.67%,富钾(K_2O/Na_2O=1.32~2.67)和低CaO(0.83%~2.6%),铝过饱和指数A/CNK=1.07~1.26,标准矿物中出现刚玉(1.06~3.38)。以上特征表明,该岩体为强过铝质高钾钙碱性S型花岗岩。稀土元素配分曲线呈右倾型,具弱至中等负Eu异常(δEu=0.38~0.97),相对亏损Nb、Ta、P、Ti等高场强元素,富集Cs、Rb、Th、U、K等大离子亲石元素。研究表明花岗岩为富含长石的砂屑岩部分熔融形成,形成于挤压环境向伸展环境转换的后碰撞阶段,为临沧花岗岩基的北延部分。 相似文献
5.
青藏高原古特提斯洋早石炭世弧后拉张:来自A型花岗岩的证据 总被引：4，自引：2，他引：2
本文报道了羌塘中部冈玛错钾长花岗岩的锆石U-Pb定年、岩石地球化学和锆石Hf同位素分析结果。钾长花岗岩中的锆石具岩浆生长环带,未见继承的老核,并且锆石Th/U比值大于0.5(0.58~1.05),显示出典型岩浆成因的锆石特征。锆石LA-ICP-MS定年结果为352.4±1.9Ma,表明其形成时代为早石炭世。钾长花岗岩富硅(Si O_2=74.17%~77.88%),低铝(Al2O3=10.50%~11.98%),贫镁(Mg O=0.23%~0.36%),富碱(Na_2O+K_2O=5.74%~7.24%),Na_2OK_2O,K_2O/Na_2O=0.53~0.71,A/CNK=0.87~1.06,富集轻稀土元素和Zr、Hf、Rb、Th和U等元素,亏损Sr、Eu、P和Ti等元素,10000Ga/Al=3.12~4.14,显示出A2型花岗岩的地球化学特征。钾长花岗岩中锆石的εHf(t)值和Hf同位素两阶段模式年龄分别变化于+4.40~+12.14和549~985Ma,显示出正的、不均一的同位素组成,可能形成于壳-幔混合作用,其中幔源端元应当是伸展环境下上涌的地幔岩浆,而壳源端元则可能是扬子板块新元古代的新生地壳部分熔融形成的长英质岩浆。结合区域地质资料,认为该花岗岩可能形成于古特提斯洋壳对羌北-昌都板块北向俯冲引起的陆缘弧后拉张环境。 相似文献
6.
《世界地质》2017,(4)
对永甸地区的辽吉花岗岩进行年代学和地球化学分析。锆石U-Pb定年结果表明,永甸花岗岩形成于(2 180.4±5.3)Ma。永甸花岗岩富Si(SiO_2=72.20%~73.54%),富碱(K_2O+Na_2O=7.83%~8.35%),贫Ca、Mg、Al(CaO=0.28%~1.37%,MgO=0.07%~0.14%,Al_2O_3=12.22%~12.88%)。稀土配分模式曲线为右倾型,有较强的负Eu异常(Eu/Eu*=0.38~0.69)和较高的Ga/Al比值,而且岩体富集Zr、U、Y等高场强元素以及Rb、K等大离子亲石元素,贫Ba、Sr等元素,这些特征表明永甸花岗岩属于A_2型花岗岩。根据岩石地球化学特征,认为永甸花岗岩形成于弧后盆地环境,来源于减薄下地壳岩石的部分熔融。 相似文献
7.
内蒙古中部乌兰呼都格碱长花岗斑岩是白音乌拉-东乌珠穆沁旗晚古生代花岗岩带的组成部分。LA-ICP-MS锆石U-Pb定年方法获得该碱长花岗斑岩的侵位年龄为289~290 Ma,表明其形成于早二叠世。岩石高硅(SiO_2=73.54%~75.17%)、富碱(Na_2O+K_2O=7.66%~8.40%)和富铝(Al_2O_3=13.55%~14.68%),贫铁镁(TFe_2O_3=0.66%~1.65%,MgO=0.25%~0.36%)和贫钙(CaO=0.27%~0.46%)。强烈富集大离子亲石元素(LILEs)Rb、Ba、Th、U和K,亏损高场强元素(HFSEs)Nb、Ta、Ti,具显著的Sr、P负异常和Pb正异常,显示弧岩浆的地球化学特征。岩石稀土总量较低且变化范围大(∑REE=78.78~130.53μg/g),富集轻稀土元素,轻、重稀土元素分异较明显,具弱Eu负异常(δEu=0.59~0.93);稀土元素分布模式表现为右陡倾且相互平行、重稀土分布较平坦。Sr-Nd同位素组成为低(~(87)Sr/~(86)Sr)i(0.70355~0.70375)、正εNd(t)(+1.04~+3.12),反映亏损地幔源区特征。岩石学和地球化学特征表明乌兰呼都格碱长花岗斑岩属于I型花岗岩,形成于后碰撞伸展构造环境,是俯冲板片断离作用触发石炭纪弧地壳镁铁质岩石部分熔融的产物,在岩浆上升演化过程中可能经历了钾长石、钛铁矿和磷灰石的分离结晶作用。乌兰呼都格I型花岗岩的厘定显示内蒙古中部苏尼特左旗北部地区早二叠世处于后碰撞伸展演化阶段。 相似文献
8.
浙东地区岩浆岩广泛分布,受区域构造控制较明显,总体沿北东向余姚-丽水断裂带分布。本文对东园花岗岩体开展了详细的年代学和岩石地球化学研究。东园岩体主要由二长花岗岩、石英二长岩和少量花岗岩组成,主岩体二长花岗岩的LA-ICP-MS锆石U-Pb年龄为235.6±0.7 Ma(MSWD=0.97,2σ),花岗岩为238.1±0.8 Ma(MSWD=1.3,2σ),均属中三叠世产物。二长花岗岩和石英二长岩为准铝质-弱过铝质的钙碱性花岗岩,具高硅(62.94%~75.29%)、富碱(Na_2O+K_2O=8.17%~9.34%)且富钾(K_2O=4.54%~5.63%)的特征,轻重稀土分馏明显,具有较强的Eu正异常(δEu=0.94~2.43),明显亏损高场强元素(HFSE)Nb、P、Ti,而相对富集Th、Hf,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb,相对贫Ba。岩体属高(-中等)分异I型花岗岩,岩浆来源于具弧属性的加厚地壳部分熔融,形成于同碰撞向后碰撞阶段转变的大地构造环境,可能与太平洋板块向华南板块俯冲作用事件有关。 相似文献
9.
本文在对山西支家地银多金属矿床地质特征研究的基础上,对矿区出露的火山-次火山岩(流纹斑岩、石英斑岩、花岗岩)中的锆石做了系统的LA-ICP-MS U-Pb年龄测定:石英斑岩成岩年龄为135.4±0.8 Ma,流纹斑岩成岩年龄为136.2±0.6 Ma,花岗岩成岩年龄为136.2±0.7 Ma,其时代均为早白垩世,表明该区出露的火山–次火山岩属于同一期岩浆活动的产物。石英斑岩与成矿关系密切,其成岩年龄135 Ma可以近似作为支家地矿床的成矿年龄。流纹岩和石英斑岩在化学成分上表现为富硅(SiO_2=72.43%~78.48%)、高钾(K_2O/Na_2O值平均为25.17)、强过铝质(A/CNK=1.24~1.95),二者稀土元素和微量元素特征非常类似,微量元素明显富Rb、Th、K、La、Nd、Zr等、相对亏损大离子亲石元素Ba、Sr、Eu等元素,Ti含量较低,属轻稀土元素富集型的钾玄岩系列过铝质花岗岩类,花岗岩仅在P和K元素化学成分上与前2者相差比较大(石英斑岩和流纹岩富K,亏损P,而花岗岩反之)。矿区三类岩石地球化学特征显示其具后碰撞花岗岩的特征,推测其可能形成于后碰撞伸展环境。本次所获锆石U-Pb年龄,不仅丰富了研究区火山-次火山岩类的同位素年龄资料,也为建立中生代构造–岩浆–成矿事件提供了重要信息。 相似文献
10.
通过野外观测、锆石LA-ICP-MS U-Pb同位素测定及岩石地球化学等手段,详细地对延边地区明南洞岩体进行了研究。研究表明,延边地区明南洞岩体的成岩年龄为(180.5±0.7)Ma,为早侏罗世岩浆事件的产物。明南洞岩体中SiO_2含量为60.71%~67.72%,Al_2O_3含量为15.60%~17.44%,全碱(Na_2O+K_2O)值为6.79%~7.63%,K_2O/Na_2O值为0.61~1.01,A/CNK=0.94~1.01,属高钾钙碱性I型花岗岩,并具有富集轻稀土元素和大离子亲石元素,亏损重稀土元素和高场强元素的特征。以上特征表明,明南洞岩体具有显著的活动大陆边缘及火山弧花岗岩的特点。延边—太平岭地区的陆缘钙碱性、高钾钙碱性花岗岩到张广才岭—小兴安岭地区的双峰式火山岩组合,构成了平行洋壳俯冲方向的成分分带,指示了俯冲的方向,反映了早侏罗世古太平洋板块的俯冲作用。 相似文献
11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
12.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world. 相似文献
13.
《Geoforum》2017
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South. 相似文献
14.
15.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
16.
I. Bejarano-Ramirez Jose M. Jurado R. Muñiz-Valencia Á. Alcázar Silvia G. Ceballos-Magaña A. Olivos-Ortiz O. Rangel 《International Journal of Environmental Science and Technology》2017,14(6):1333-1342
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments). 相似文献
17.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability. 相似文献
18.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification
(e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes
of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application
inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen
constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter
are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system,
our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro
and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically
applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect
to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics
can be extracted from the new statistics; however, substantial additional information is also available. From the practical
point of view, E-classification is substantially faster than the Zingg method. 相似文献
19.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
20.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献