首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 31 毫秒
1.
The total rare-earth element values(ΣREE)of loess in the Xinjiang region vary over a range of 128-200 ppm ,with an average of 153ppm .The average REE content of loess lies between the earth‘s crust (155ppm) and sedimentary rocks(151ppm).The Xinjiang loess,with the REE distribu-tion patterns characterized by negative slopes ,is rich in the Ce-family elements, and has a distribu-tion pattern characteristic of sedimentary rocks.The North Xinjiang loess is relatively depleted in Tb,but rich in Yb and Lu.The South Xinjiang loess is relatively rich in light rare-earth elements.This is full proof that the Xinjiang loess comes partly from weathered materials(clay rock,sandstone)in the region studied.The REE distribution patterns in the Xinjiang loess are similar to those in the precipitated dust and Aeolian sand,indicating the same material source.The REE distribution pat-terns in the Xinjiang loess are also similar to those in loess from the middle Yellow River Valley,China and Taskent,the former USSR.This implies that loesses of the three locations(Xinjiang,the mid-dle Yellow River Valley and Taskent) come from a common material source.But the REE patterns in the Xinjiang loess are different from those in wall rocks (volcanic rock,K-bearing volcanic rock).Generally ,LREE/HREE,Eu/Eu* and Ce/Ce* ratios reflect the features of parent materials of loess,indicating that the parent rocks were probably in the early stage of alkaline weathering and the weathered materials existed in an oxidation environment with basic mediums under arid-climatic conditions before transport.As a result,the migration ability of the REE is weak.  相似文献   

2.
TL ages of 56 loess samples collected from Xinjiang and the middle reaches of the Yellow River were determined by using fine-grained quartz and man-made light source bleaching techniques.The results indicate that :1.The well-preserved loess sections in Xinjiang began depositing 400000 a ago.The loess/paleosol series may be comparable with that observed in the middle reaches of the Yellow River but the depositing time was probably delayed by 30000-50000a.2.The bottom boundary age of the Malan loess varies from one place to another.The TL dates can be divided into two group:70000-130000 a and 30000-50000 a.The TL data are con-sistent with the appearance of two warmer climate periods since the Pleistocene,indicating obvious regional differences in stratigraphic development of loess,i.e.,paleosol occurred in the warm climate period in the same location,but loess was deposited in other locations.The initial age of loess deposition tends to become older from west to east and from south to north .In contrast ,the cold cli-matic belt showed an opposite trend.The TL ages of loess provide strong evidence for the Quaternary stratigraphy throughout geological times and the shift tendency of climatic belt.3.The depositing rate of the Malan loess along the middle reaches of the Yellow River varies from place to place but the TL age shows a linear relationship with the depositing thickness.The de-positing rate of loess in the north is higher than that in the south,suggesting that loess materials are derived from desert areas of northern China.  相似文献   

3.
As have been determined, the ratios of oxides and the contents of CaCO3 show a tendency to increase from bottom to top in Luochuan loess section, whereas an opposite tendency is observed for the relative values of weathering leaching or accumulation of loess, Moreover, the limits of oxide ratios from less to greater than the average value coincide with the boundary between Wucheng and Lishi loess strata, as well as with the boundary of magnetic polarity reversal. The ratios of oxides and the variations of relative weathering-leaching or accumulation extents are synchronous with the fluctuation of CaCO3 contents. From this investigation, it is shown that the ratios of oxides in the superimposed loees and paleosols from the loess profile are found rhythmically varied. These Characteristics might be explained by the hypothesis of repeated climatic fluctuation from dry (loess) to humid (paleosol) during the Quaternary period.  相似文献   

4.
Statistical data on major,trace and rare-earth elements in wolframite from the quartz vein-and greisen-type tin deposits in the Dupangling orefield reveal(1)The components in wolframite can be divided into two relatively independent groups:the WO3-Nb-Ta-Sc-REE group,in which WO3 is negatively correlated with the others and the FeO-MnO-Sn group,in which MnO is negatively corre-lated with the other two;(2)In general ,REE fractionation is not significant,reflected mainly by the separation of Eu from other REE‘s.LREE and HREE increase or decrease simultaneously ,with HREE being more variable;(3)Nb,Ta,Sc,REE substitute for W, and Sn may enter into wolframite lattice accompanied by Fe-Mn substitution;(4)In contrast to wolframite in quartz veins,which is poor in REE,Nb,Ta and has high δEu values and LREE/HREE and Nb/Ta ratios,wolframite in greisen is rich in REE, Nb,Ta,Sc and has low δEu values and LREE/HREE and Nb/Ta ratios ;and (5)The contents and ratios of trace elements and REE parti-tioning parameters of wolframite can be used as guide for prospecting.  相似文献   

5.
Well-developed dissolution pores occur in the dolomites of the Sinian Dengying Formation, which is an important oil and gas reservoir layer in the Sichuan Basin and adjacent areas in southern China. The pores are often filled with quartz, and some dolomites have been metasomatically altered to siliceous chert. Few studies have documented the characteristics, source or origin of silica-rich fluids and their effects on the dolomite reservoir. The peak homogenisation temperatures(T_h) of fluid inclusions in pore-filling quartz are between 150℃ and 190℃, with an average of 173.7℃. Gases in the inclusions are mainly composed of CO_2, CH_4 and N_2. Compared with host dolomite, pore-filling quartz and metasomatic chert contain higher amounts of Cr, Co, Mo, W and Fe, with average concentrations of 461.58, 3.99, 5.05, 31.43 and 6666.83 ppm in quartz and 308.98, 0.99, 1.04, 13.81 and 4703.50 ppm in chert, respectively. Strontium levels are lower than that in the host dolomite, with average concentrations in quartz and chert of 4.81 and 11.06 ppm, respectively. Rare earth element compositions in quartz and chert display positive Eu anomalies with a maximum δEu of 5.72. The δD_(SMOW) values of hydrogen isotopes in water from quartz inclusions vary from-85.1‰ to-53.1‰ with an average of-64.3‰, whereas the δ~(18)O_(SMOW) values range from 7.2‰ to 8.5‰ with an average of 8.2‰. The average ~(87)Sr/~(86)Sr ratios in quartz and chert are 0.711586 and 0.709917, respectively, which are higher than that in the host dolomite. The fluid inclusions, elemental and isotopic compositions demonstrate that the formation of quartz and chert was related to silica-rich hydrothermal fluid and that the fluid was the deep circulation of meteoric water along basement faults. Interactions with silica-rich hydrothermal fluids resulted in densification of dolomite reservoirs in the Dengying Formation through quartz precipitation and siliceous metasomatism. However, it increased the resistance of the host dolomite to compaction, improving the ability to maintain reservoir spaces during deep burial. Evidence for silica-rich hydrothermal activity is common in the Yangtze Platform and Tarim Basin and its influence on deep dolomite reservoirs should be thoroughly considered.  相似文献   

6.
Quaternary volcanic rocks often coexist with loess,as observed in the same geologic sections in the Shandong Peninsula and northern parts of Jiangsu and Anhui provinces.The development age of Shandong loess in close to that in the middle reaches of the Yellow River.Loess strata are of synchronous implication in the loess belt of North China.So the ages of volcanic activities can be es-timated approximately from the stratigraphic relations between loess layers and volcanic rocks.The re-sults of dating of the Quaternary volcanic rocks,baked layers and the TL dates of loess samples sug-gest that the Quaternary volcanic activity can be divided into 4 stages in the region studied,with the ages being 1.15-1.03,0.86-0.72,0.55-0.33 and 0.02 Ma B.P.respectively .The occurrence of tephra in the Shandong loess sections is possible due to multiple episodes of volcanism during the Quaternary time.  相似文献   

7.
The atmospheric concentration of methane is steadily increasin.Lacking of precise estimates of source and sink strengths for the atmospheric methane severely limits the current understanding of the global methane cycle.Agood budget of atmospheric methane can enhance our understanding of the global carbon cycle and global climate change,The known estimates of the main source and sink strengths are gresented in this paper,In terms of carbon isotopic studies,it is evidenced that the earth‘s primodial methane,which was trapped in the earth during its formation,may be another source of methane,with extensive,earth‘s degassing which is calleld the “breathing“ process of the earth and played an important role in the formation of the promitive atmosphere,large amounts of methane were carried from the deep interior to the surface and then found its way into the atmosphere.  相似文献   

8.
黄土的热释光年代——光晒退的实验测定和结果修正   总被引:2,自引:0,他引:2  
李虎侯 《地球化学》1984,(2):180-185
In the present paper the shine-fading posibility of TL storage in quartz crystals is discussed with an artificial light source and also explained with the energy banal theory.In terms of the concept of “trap”, the author has substantiated the nature of TL storage in quartz crystals. A method for revising the residual TL stored in quartz crystals is proposed, and has been justified by the determined ages of six loess samples from different localities.  相似文献   

9.
The loess plateau in northwestern China with an area of 640 000km~2, which has developed the loess deposits with a thickness up to 200m in typical areas, is regarded as a huge carbon stock like the karst area in southwestern China, and plays an important role in regional(even global) carbon cycle. But the spring discharging from loess is poorly known compared with karst spring so far. The objective of this study is to ascertain the characteristics and origin of spring at Qiushe Village, Lingtai County, Gansu Province by hydro-chemical and isotopic methods. The results show that the springs including LGQ, HMQ, YYQ and CZQ are the depression spring and belong to the same shallow aquifer with the well water JZJ. There are not distinct seasonal/diurnal-scale variations on the hydro-chemical characteristics of the spring water(LGQ, HMQ, YYQ, CZQ) and groundwater(JZJ). The hydro-chemical type of groundwater is Ca·Mg-HCO_3. The D and O isotope ratios indicate that the precipitation is the main recharge source of groundwater in study area. And the results of tritium(TU) and Cl concentration suggest that the recharge cycle of groundwater may be more than 60 yrs. Our study shows that the water cycle in loess plateau including rainfall, infiltration, recharge and discharge exerts a continuous impact on carbon stock in loess, which should be paid more attention to in future research on the quantitative reconstruction of paleoclimate.  相似文献   

10.
Widespread and thick loess deposit in the northeastern Tibetan Plateau records paleoclimatic changes over the Quaternary period. In this study, we investigate a loess section located in a high terrace of the Huangshui River in the Xining Basin, and collect samples at 20-cm intervals by digging a well of 16-m depth (including paleosol S1 and SO and several loess interlayers over the last glacial-interglacial cycle and the Holocene). Concentration of some active elements (Sr and Ca) and inert elements (Rb, Zr, Ti) in these loess samples are measured. The results show that ratios of those elements (oxide), such as Rb/Sr, Ti/Sr, and Zr/CaO ratios, would indicate sensitively paleoclimatic changes, especially the history of precipitation over the last glacial-interglacial and the Holocene. Moreover, the curves of Rb/Sr, Ti/Sr, and Zr/CaO ratios had almost the same variable trends from the bottom to the top and also closely correlated with values of magnetic susceptibility and the global marine δ^18O record. But compared with the curves of magnetic susceptibility, the changes of ratios of these elements (oxide) are clearer and easy to understand. Therefore, the ratios of these typical chemical elements in the loess deposit may be used as an excellent index to investigate the history of paleoclimate, particularly precipitation changes in the northeastern Tibetan Plateau.  相似文献   

11.
With increasing soil age, the contents of Sr, Ba and ratios of Sr/Be in soils tend to decrease, whereas the contents of V, Sc, Ni, Cr, Co and ratios of Fe/Ni and Fe/Co tend to increase, as evidenced from a study on soils of different ages, developed on basahs in the northern part of Hainan Island. Ba/Nb, significantly correlative with soil age, can be used to evaluate soil evolution. By using the mass-balance method, the element migration was discussed with Ti as an immobile element. The results showed that element leaching was most intensive in the early pedogenic period. In this period (Primosols) , over 90% of Ca, Mg, K and Na was leached out of soils till Ferrosol formation. The leaching of P occurred mainly at the beginning of soil development. About 60% of Si was mobilized in the stage of Cambosol formation and 80% in the stage of Ferralosol formation.  相似文献   

12.
Detailed studies have been conducted on the geology and geochemistry of the deposit and granite in the mining district in the last two decades, and by comparing this deposit with other typical epithermal deposits in the world, it is clear that the Erentaolegai silver deposit is a lower-sulfidation, adularia-sericite-type epithermal silver deposit and the bulk mineralogy of this deposit is consistent with low-sulfidation epithermal mineralization. Determined by the Rb-Sr isochron method, the age of magmatic intrusives in the mining district is 120 Ma. So, it can be concluded that the local areas were marginally subjected to the movement in Late Yanshanian and produced granitic magma, and about 29% mantle material, as is calculated, was involved in magmatism. The magma experienced crystallization-differentiation, resulting in the formation of granite and quartz porphyry; the latter was the product of violent granitic magma crystallization-differentiation, so silver was enriched in later petrogenetic stages and post-petrogenetic ore fluids from which Ag was derived dominantly. Oxygen and hydrogen isotopic characteristics indicate that meteoric waters on the Earth‘ s surface played an important role in the formation of granitic magma and the deposit: ( 1 ) contributing a lot to the fundamental complex partial melting;(2) contributing a lot to magma crystallization-differentiation, and bringing silver into the magma which is eventually responsible for the formation of quartz porphyry; and (3) contributing a lot to the formation of great amounts of ore fluid. The lead isotopic characteristics show that the silver and lead have an affinity for each other.  相似文献   

13.
Rare earth element (REE) contents, and Sr and Nd isotopic compositions were measured for three suites of mantle xenoliths from the Kuandian, Hannuoba and Huinan volcanoes in the north of the Sino-Korean Platform. From the correlations of Yb contents with Al/Si and Ca/Si ratios, the peridotites are considered to be the residues of partial melting of the primitive mantle. The chondrite-normalized REE compositions are diverse, varying from strongly LREE-depleted to LREE-enriched, with various types of REE patterns. Metasomatic alteration by small-volume silicate melts, of mantle peridotites previously variably depleted due to fractional melting in the spinel peridotite field, can account for the diversity of REE patterns. The Sr/ Ba versus La/Ba correlation indicates that the metasomatic agent was enriched in Ba over Sr and La, suggestive of its volatile-rich signature and an origin by fluid-triggered melting in an ancient subduction zone. The Sr and Nd isotopic compositions of these xenoliths, even from  相似文献   

14.
Abstract: The Gejiu tin polymetallic deposits are located in the southeastern part of Yunnan Province in China. A detailed electronic microprobe study has been carried out to document geochemical compositions of tourmalines from the deposits. The results indicate a systematic change of mineral geochemical compositions, which might be used as a mineral geochemical tracer for post-magmatic hydrothermal fluid, basin fluid and their mixture. The tourmalines from granite are schorl with Fe/(Fe+Mg) ratios of 0.912-1.00 and Na/(Na+Ca) ratios of 0.892-0.981. Tourmalines as an inclusion in quartz from the ore bodies are dravite with Fe/(Fe+Mg) ratios of 0.212-0.519 and Na/ (Na+Ca) ratios of 0.786-0.997. Tourmalines from the country rocks are dravite with Fe/(Fe+Mg) ratios of 0.313-0.337 and Na/(Na+Ca) ratio of 0.599-0.723. Tourmalines from cassiterite-tourmaline veins that occur in crannies within the country rocks show distinct optical zoning with alternate occurrence of dravite and schorl, Fe/(Fe+Mg)=0.374-0.843, Na/(Na+Ca)=0.538-0.987. It suggests that schorl in granite and dravite in carbonatite are related to magmatic fluid and basin fluid respectively. When magmatic fluid rose up and entered into crannies of the country rocks, consisting mainly of carbonatite, basin fluid would be constantly added to the magmatic fluid. The two types of fluid were mixed in structural crannies of the sedimentary basin accompanied with periodic geochemical oscillations to form material records in chemical composition zonings of tourmalines.  相似文献   

15.
Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types:slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely corroded and replaced secondary calcic karstic rocks. The carbon, oxygen and strontium isotope compositions of the various karst rocks are analyzed systematically and compared to rocks without karst corrosion. The results indicate that(1) the Huanglong Formation in the eastern Sichuan Basin was a restricted bay supplied and controlled by freshwater in which mudmicrite and mud-dolomicrite exhibit low δ13C and δ18O values and high 87Sr/86 Sr ratios;(2) all types of karstic rocks in the paleokarst reservoirs of the Huanglong Formation in the research area are affected by atmospheric freshwater with the δ13C and δ18O values and 87Sr/86 Sr ratios in the original formation approaching those of atmospheric freshwater, which reflects ancient hydrological conditions, fluid properties, isotopic source and the fractionation effect;(3) the intensely corroded and replaced secondary limestone is affected by a variety of diagenetic fluids, often reflected by δ13C and δ18O values, while the 87Sr/86 Sr ratios exhibit the strong degree of the corrosion;(4) after comparing the 87Sr/86 Sr ratios of each type of karst rock, the diagenetic fluids are determined to be mainly atmospheric freshwater, and depending on the strength of corrosion, and the low 87Sr/86 Sr ratio fluids in the layer will participate in the karst process. The carbon, oxygen, and strontium isotopes of different karstic reservoirs can provide meaningful geochemical information for forecasting and evaluating the development and distribution rules of the Huanglong Formation at the margin of the eastern Sichuan Basin in time and space.  相似文献   

16.
The Langdu high-K calc-alkaline intrusions are located in the Zhongdian area, which is the southern part of the Yidun island arc. These intrusive rocks consist mainly of monzonite porphyry, granodiorite, and diorite porphyry. The K2O content of majority of these rocks is greater than 3%, and, in the K2O-SiO2 diagram, all the samples fall into the high-K calc-alkaline to shoshonitic fields. They are enriched in light rare earth elements (LREEs) and depleted in heavy rare earth elements (HREEs; LaN/YbN = 14.3-21.2), and show slightly negative Eu anomalies (δEu = 0.77-1.00). These rocks have high K, Rb, Sr, and Ba contents; moderate to high enrichment of compatible elements (Cr = 36.7-79.9 ppm, Co = 9.6-16.4 ppm, and MgO = 2.2%-3.4%); low Nb, Ta, and Ti contents, and characteristic of low high field strength elements(HFSEs) versus incompatible elements ratios (Nb/Th = 0.75, Nb/La = 0.34) and incompatible elements ratios (Nb/U = 3.0 and Ce/Pb = 5.1, Ba/Rb = 12.0). These rocks exhibit restricted Sr and Nd isotopic compositions, with (87Sr/86Sr) i values ranging from 0.7044 to 0.7069 and εNd(t) values from -2.8 to -2.2. The Sr-Nd isotope systematic and specific trace element ratios suggest that Langdu high-K calc-alkaline intrusive rocks derived from a metasomatized mantle source. The unique geochemical feature of intrusive rocks can be modeled successfully using different members of a slightly enriched mantle, a slab-derived fluid, and terrigenous sediments. It can be inferred that the degree of partial melting and the presence of specific components are temporally related to the tectonic evolution of the Zhongdian island arc. Formation of these rocks can be explained by the various degrees of melting within an ascending region of the slightly enriched mantle, triggered by the subduction of the Garzê-Litang ocean, and an interaction between the slab-derived fluid and the terrigenous sediments.  相似文献   

17.
Trace elements and rare earth elements (REE) of the sulfide minerals were determined by inductively-coupled plasma mass spectrometry. The results indicate that V, Cu, Sn, Ga, Cd, In, and Se are concentrated in sphalerite, Sb, As, Ge, and Tl are concentrated in galena, and almost all trace elements in pyrite are low. The Ga and Cd contents in the light-yellow sphalerites are higher than that in the brown and the black sphalerites. The contents of Ge, Tl, In, and Se in brown sphalerites are higher than that in light-yellow sphalerites and black sphalerites. It shows that REE concentrations are higher in pyrite than in sphalerite, and galena. In sphalerites, the REE concentration decreases from light-yellow sphalerites, brown sphalerites, to black sphalerites. The ratios of Ga/In are more than 10, and Co/Ni are less than 1 in the studied sphalerites and pyrites, respectively, indicating that the genesis of the Tianqiao Pb–Zn ore deposit might belong to sedimentary-reformed genesis associated with hydrothermal genesis. The relationship between LnGa and LnIn in sphalerite, and between LnBi and LnSb in galena, indicates that the Tianqiao Pb–Zn ore deposit might belong to sedimentary-reformed genesis. Based on the chondrite-normalized REE patterns, δEu is a negative anomaly (0.13–0.88), and δCe does not show obvious anomaly (0.88–1.31); all the samples have low total REE concentrations (<3 ppm) and a wide range of light rare earth element/high rare earth element ratios (1.12–12.35). These results indicate that the ore-forming fluids occur under a reducing environment. Comparison REE compositions and parameters of sphalerites, galenas, pyrites, ores, altered dolostone rocks, strata carbonates, and the pyrite from Lower Carboniferous Datang Formation showed that the ore-forming fluids might come from polycomponent systems, that is, different chronostratigraphic units could make an important contribution to the ore-forming fluids. Combined with the tectonic setting and previous isotopic geochemistry evidence, we conclude that the ore-deposit genesis is hydrothermal, sedimentary reformed, with multisources characteristics of ore-forming fluids.  相似文献   

18.
Photodegradation of chrysene, benzo (a) pyrene and benzo (g, h, i) perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. (1) The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. (2) The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo (a) pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo (g, h, i) perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. (3) The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. (4) Since the soluble humic substances in the suspended solids of the river have been dissolved in water,  相似文献   

19.
Mercury is an important pollutant in lakes. Methylmercury (MeHg), the most toxic mercury species, which can be formed from inorganic mercury in lakes, can be bioaccumulated into high concentration in food chain and result in a potential threat to human beings. Sediments play an important role for the Hg biogeochemistry in the aquatic systems: Mercury methylation has been shown to be fastest in the surfacial sediments, where the microbial activity is highest. The formation of MeHg in lakes suggests that sediments and/or near-shore wetlands can be the sources of MeHg in aquatic environments. The Baihua Reservoir, located in the suburb of Guiyang, was impounded in 1966. From the 1970s to the 1990s, Guizhou Organic Chemical Plant which used inorganic mercury as catalyst to produce acetic acid, was responsible for the discharge of waste water with high mercury content.  相似文献   

20.
The Middle–Lower Yangtze River Metallogenic Belt (MLYB) is known to contain abundant copper and iron porphyry-skarn deposits, with an increasing number of tungsten deposits and scheelite in Fe–Cu deposits being discovered in the MLYB during recent decades. The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood. We investigate four sets of scheelite samples from tungsten, iron and copper deposits, using CL imaging and LA–ICP–MS techniques to reveal internal zonation patterns and trace element compositions. The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies. The oxygen fugacity of ore-forming fluid increased in Donggushan, while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan, Guilinzheng and Gaojiabang. The scheelites from the Donggushan, Ruanjiawan, Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE, with Nb/La ratios ranging from 1.217 to 52.455, indicating that the four tungsten deposits are enriched in the volatile fluorine. A plot of (La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type, porphyry and skarn tungsten deposits. This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号