共查询到19条相似文献，搜索用时 734 毫秒
1.
The aim of this study is to shed light on the hydrogeochemical characteristics of karst underground waters at shallow depth in Guiyang City, Guizhou Province with an emphasis on the geochemistry of major elements. Guiyang City bears abundant underground waters and it is also an important representative of the karst areas throughout the world. Ca^2 and Mg^2 are the dominant cations, accounting for 81% -99.7% of the total, and HCO3^- and SO4^2- are the dominant anions. Weathering of limestones and dolostones is the most important factor controlling the hydrogeochemistry of underground waters, and weathering of sulfate and evaporite rocks is less important. Moreover, the precipitation and human activities also have a definite influence on the hydrogeoehemistry of underground waters in the region studied. 相似文献
2.
Abstract Karst areas have much higher ecological vulnerability and are easy to be contaminated by polychlorinated biphenyls(PCBs) which are introduced as health risk pollutants.PCBs concentrations were used to understand the transport behavior of PCBs conducted in the karst Nanshan Underground River,China.Water and sediments from the underground river water,and sediments and soil from the surface of the corresponding watershed were collected monthly in 2011 and 2012 and PCBs were analyzed.Seasonal variations were found in concentrations of PCBs both in the waters and sediments.PCBs concentrations varied from 0.3 to 29.9 ng·L-1 in the groundwater,while from 0.1 to 366.1 ng·g-1 in the underground sediments.Correlations were found in concentrations of PCBs in waters and sediments between the underground river and surface systems which indicate that the surface systems play a major role for the transport of PCBs and contamination in the underground river systems.Karst features are liable for the transport behavior.The underground river waters transport PCBs at mean 3 g·day-1. 相似文献
3.
As viewed from space remote-sensing images (e.g. Google Earth images) of South Guizhou and North Guangxi, the authors found that macroscopic karst landscape on the Earth’s surface is strongly controlled by the Conjugated shear joint of “X” type. Joints of this kind constitute a huge infiltration network and act as channel-ways for the permeation of meteoric waters from the surface, thus, leading to the dissolution of carbonate rocks nearby. As a result, the karst landscape is formed, which is dominated by linear karst valleys. An “X” karst valley network structure appears in the area where horizontal strata are distributed, and a feather-like network structure appears in the area where vertical strata are distributed, respectively. When the water permeates downwards to the underground-water level, it will flow horizontally along the strike of “X” joints toward the local base level of erosion to form an “X” network system of underground conduits in the area where horizontal strata are distributed, but it is relatively complex, because of the joining of other joints. This is the first time we have made use of Google Earth images to study the karst environment. Therefore, it has been successful in research on the Earth’s geomorphology, which could only rely on aerial photos and satellite photos in the past. Google Earth images provide low-cost and applicable imaging materials for the study of Earth’s geomorphology and karst rocky desertification and its control. 相似文献
4.
Zhongliang WANG Congqiang LIU Zhaozhou ZHU 《中国地球化学学报》2006,25(B08):171-171
Due to the unique chemical properties that are similar but still progressively change, the rare earth elements （REEs） are useful tracers of various geochemical processes in the lithosphere and hydrosphere. However, despite many studies of REE geochemistry in the ocean, the aqueous geochemistry of REEs in lake waters has been poorly documented. In the present study, two special karst lakes are chosen as case studies to investigate the distributions of dissolved REEs in lake water. Although the two lakes, Hongfeng and Aha, are both alkaline and have high pH from 7.9 to 8.7 and high carbonate concentrations, the Aha Lake has been more severely affected by acidic mining drainage with high Fe, Mn and SO42 concentrations. In the present study, the concentrations of dissolved rare-earth elements in lake waters were determined by inductively coupled plasma mass spectrometry. The result shows that the concentrations of dissolved REEs in the studied alkaline karst lakes, as compared to the concentrations of REEs in seawater, are much lower than the other investigated terrestrial surface waters in previous studies. The key factor controlling dissolved REE distributions is pH value which is negatively correlated with REE concentrations. Due to high concentration of carbonate ion and alkaline character of water chemistry, the shale （PAAS） normalized patterns of dissolved REEs show marked HREE enrichment in all water samples. This is primarily the result of the preferential formation of stronger carbonate complexes with the HREEs. In alkaline or intermediate waters, REE-carbonate complexes are the dominant and typical species, which account for about more than 90% of the total dissolved REEs. 相似文献
5.
We investigated the weathering-pedogenesis of carbonate rocks and its environmental effects in subtropical regions of China. The investigation demonstrated that the weathering- pedogenesis of carbonate rocks is the process of a joint action of corrosion and illuviation and metasomatism in subtropical region. It is characterized by multi-stage, multi-path and multi-style. With the persisting development of weathering-pedogenesis of carbonate rocks, metasomatic pedogenesis progressively became the main process of the weathering-pedogenesis and the dominant style of formation of minerals. And it proceeds through the whole process of evolution of the weathering-pedogenesis of carbonate rocks. The stage evolution of weathering-pedogenesis of carbonate rocks and the fractionation evolution of newly produced minerals are characterized by obvious vertically zoning structures and the rules of gradation of elements geochemical characteristics in the carbonate rocks weathering profiles. The geochemical process of weathering-pedogenesis of carbonate rocks can be divided into three geochemical evolution stages, i.e., the Ca, Mg-depletion and Si, Al-enrichment stage; the Fe, Mn enrichment stage and the Si-depletion and Al-enrichment stage in the subtropical regions. Consistent with the three geochemical evolution stages, the sequence of formation and evolution of minerals can be divided into the clay mineral stage; the Fe, Mn oxide and the gibbsite stage. The influence of weathering-pedogenesis of carbonate rocks on the chemical forms of heavy elements is mainly affected via newly produced components and minerals in the process of weathering-pedogenesis, e.g., iron oxide minerals and organic matters. The important mechanism for the mobilization, transport and pollution of F and As is affected the selective adsorption and desorption of F and As on the surface of iron oxide minerals in the subtropical karst zones, i.e., the selective adsorption and desorption on mineral surfaces of newly produced minerals in the process of weath 相似文献
6.
Hongmei LU Shijie LU Yuanhua PENG 《中国地球化学学报》2006,25(B08):175-176
The sampling method of karst soil is always the one used for non-karst area. However, if the samples can represent the plot, it still needs further investigation due to high degree of spatial variability of karst soil. The study results of soil from the Maolan karst virgin forest in Guizhou Province elucidated that only the surface area-weighted samples could represent plot soils in the karst ecosystem. The remediation of karst rocky desertification has currently become a national issue, but soil degradation research on rocky desertification genesis types and processes is still insufficient. Soil physical, chemical, biological characteristics and enzymes activities from plots of different rocky desertification genesis types and grades in the Cha＇eryan catchment in the Huajiang Gorge area, Guizhou, were studied. The results showed that woodcutting and land reclamation influenced soil biogeochemical characteristics, and the influence of different disturbing ways was huge. The author suggested a soil degradation index system which could illustrate the rocky desertification genesis type and extent. The degraded modes of woodcutting and reclamation sequence were different, both had no synchronism with rocky desertification grades divided by current landscape index. Only soil of serious grade degraded evidently in wood cutting sequence. On the contrary, soils of slight, medium and serious grades degraded evidently in the reclamation sequence. 相似文献
7.
REE Geochemical Study of the Permian—Triassic Marine Sedimentary Environment in Guizhou Province 总被引：2，自引：1，他引：2
This paper deals with the REE geochemical characteristics of Permian-Triassic marine carbonate rocks in Guizhou Province.It is found that there are two broad categories of strati-graphic units in the region studied in accordance with their ΣREE contents and REE distribu-tion patterns: one is characterized by LREE enrichment and slight Ce depletion,with the REE distribution patterns similar to those of North American shales,and the other featrures relative HREE enrichment and relatively remarkable Ce depletion,with the REE distribution patterns close to those of pelagic sediments.In terms of their different ΣREE contents,five types of stratigraphic units can be distinguished.Incorporation of detrital minerals,REE complexing ca-pability,oxidation-reduction conditions of the media are the main factors affecting the REE com-position and REE distribution patterns of marine carbonate rocks in the region studied.In the light of REE geochemical characteristics of carbonate rocks,coupled with sedimentary facies analysis,this paper discusses the characteristics of the Permian-Triassic marine sedimentary environment in Guizhou Province and its evolutional rules. 相似文献
8.
Limin REN Bing QIN Wenchun TANG Zhendong MA Yikeng HU 《中国地球化学学报》2006,25(B08):10-10
Mercury is a pollutant of concern due to its toxic and bioaccumulative properties. Studies on the distribution and hazard of mercury in the environment are mainly focused on its forms, toxicity and the environment standard, and progresses and results have been achieved. But these studies in the past were concentrated on the scales of laboratory or smaller districts merely, such as a small unit of mineral area, vegetable base, paddy field, lake, etc. Multi-target regional geochemical survey carried out by China Geological Survey from the 1990s to now is a fundamental and commonweal geological survey, large-scale and systematical inquisition and research were conducted in 19 provinces （or municipalities directly under the Central Government） in the eastern overlay region of China, and the purpose is to provide the basic geochemical data for national economic construction, adjustment of industrial and agricultural structures and sustainable social development. Geochemical studies aim at investigating soils in these regions and 52 elements have been tested, producing a great amount of data at the same time. Methods： based on the data from 3061 samples of surface soil and 832 samples of deep soil from the project of multi-purpose geochemical survey in the Chengdu Basin, Sichuan, China, this paper describes the correlation relationship between Hg and other 48 elements and their spatial distribution in surface and deep soils of these areas by applying the method of linear regression and factor analysis. 相似文献
9.
In recent years,more and more attention has been paid to the problem of the cryosphere changes on the Tibetan Plateau,and it has gradually become a hot issue for scholars. Known as the“water tower of Asia”,the Tibetan Plateau is the source of many major rivers in Asia. Under the combined influence of climate change and human activities,water resources on the Tibetan Plateau have undergone profound changes,especially soil water,as an important component of water resources,which plays an important role in regulating vegetation and crop growth,rainfall and runoff. However,global warming leads to the degradation of permafrost and seasonal⁃ ly frozen soil,which affects the original water cycle process and the spatial and temporal pattern of water re⁃ sources by changing the properties of soil water storage and water transport. In the Tibetan Plateau,where there are few data,it is difficult to directly study the soil water cycle process under freezing-thawing by using original data. Therefore,it is an important means to simulate the variation characteristics of soil water and temperature under freezing-thawing in seasonally frozen soil regions of the Tibetan Plateau by using coupling model of soil water and heat. Aiming at the key problem of the difference of soil temperature and moisture characteristics in typical seasonally frozen soil regions under different meteorological conditions,this paper simulated the charac⁃ teristics of soil moisture and temperature change in Maqu,Naqu（Nagqu）and Shiquanhe from 2017 to 2018 by using SHAW（Simultaneous Heat and Water）model and three soil moisture characteristic curve models. The simulation effect and variation characteristics of soil moisture and temperature under different meteorological conditions were analyzed,and the influence of soil moisture characteristic curve model on the simulation effect was studied. The results show that SHAW model can well simulate the temporal variation and vertical distribu⁃ tion of soil temperature and moisture under different meteorological conditions. The simulation effect of soil tem⁃ perature is better than that of soil moisture. The average NSE,R2 and RMSE of soil temperature are 0. 88,0. 96 and 2. 20 ℃,respectively. The mean NSE,R2 and RMSE of soil moisture are 0. 60,0. 72 and 0. 03 m3·m-3,respec⁃ tively. In terms of different meteorological conditions,the simulation effect of soil temperature in relatively dry region was significantly better than that in humid region,while the simulation effect of soil water in relatively hu⁃ mid region was significantly better than that in arid region. From different depths in soil,the simulation effect of soil temperature decreases gradually with the increase of depth,while the simulation effect of soil moisture in the middle and lower layers is better than that in the surface layer. From the view of different soil moisture character⁃ istic curve models,different soil water characteristic curve models have no significant effect on soil temperature simulation effect,but there are significant differences in soil moisture simulation effect. In addition,there are great differences and uncertainties in simulating soil temperature and moisture in different freezing-thawing stag⁃ es. With the increasing trend of climate warming,permafrost and seasonally frozen soil on the Tibetan Plateau may continue to degrade,may change the current water resources pattern,resulting in frequent extreme weather events. Therefore,from the perspective of numerical simulation,this paper verified the applicability of soil moisture and heat coupling model in soil temperature and moisture simulation under different meteorological con⁃ ditions,revealed the influence of precipitation and temperature on soil temperature and moisture simulation at different depths in seasonally frozen soil regions,and analyzed the differences in simulation effects of different soil moisture characteristic curve models. The results provide reference for the study of soil water resources vari⁃ ation under freezing-thawing conditions. © 2023 Chinese Journal of General Practitioners. All rights reserved. 相似文献
10.
Houyi ZHENG Congqiang LIU Zhongliang WANG 《中国地球化学学报》2006,25(B08):174-174
Bedrock weathering and atmospheric deposition are the two primary sources of base cations （K^＋, Na^＋, Ca^2＋ and Mg^2＋） to forest ecosystems. Therefore, the key problem is to understand the relative inputs from these two sources and the cycling in the ecosystem. This study focuses on the effects of acid deposition on cation cycling in a small-forested karstic catchment in Guizhou Province. Sr isotope ratios were used as a tracer for understanding the transport process between the different cation pools： rock, soil, surface water, atmospheric deposition and plant. The samples of wet deposition, total deposition, throughfall, surface and ground waters, vegetation, and soil were monthly collected. The exchangeable Sr^2＋ and Ca^2＋ in soil samples were extracted by using 1 M ammonium acetate. The leaf-tissue samples were ashed at 550℃, and the residue was digested in ultrapure HClO4 and HNO3. All water samples were filtrated through 0.45 μm aperture filter paper. Base cation concentrations and Sr isotopic composition were analyzed for all the samples. The results show that acid deposition （average pH 4.9） frequently occurred in the studied region. Cation abundance follows an increasing manner from rainwater, throughfall, to surface water or ground water samples, suggesting that acid deposition at first eiuviates Ca^2＋ , Mg^2＋ and Sr^2＋ from leaf, then the exchangeable cations from soil, and at last cations accumulate in surface water or ground water. 相似文献
11.
Ping Yang Yi-Qun Tang Nian-Qing Zhou Jian-Xiu Wang Tian-Yu She Xiao-Hui Zhang 《Environmental Earth Sciences》2011,63(3):543-549
The loss of surface soil and water in the karst rocky desertification area of carbonate rock in Chenqi village, Puding County,
Guizhou Province was monitored in this study. The results show that the major form of surface soil loss in the area is the
loss of soil through underground channels. A creep test of red clay formed by loss through underground channels was conducted.
The results of the test show that the creep curve of the red clay samples includes two stages: attenuation creep stage and
stable creep stage. The creep law for the red clay samples in the karst cave can be described by Buger’s model. The parameters
of Buger’s equation were deduced by fitting the creep curve, which provides the reference for analyzing the surface soil loss
leaking through the underground channels. 相似文献
12.
Erosion-creep-collapse mechanism of underground soil loss for the karst rocky desertification in Chenqi village,Puding county,Guizhou, China 总被引：10，自引：1，他引：9
Jianxiu Wang Baoping Zou Yan Liu Yiqun Tang Xinbao Zhang Ping Yang 《Environmental Earth Sciences》2014,72(8):2751-2764
Carbonate rocks distribute widely in China. The total area of the carbonate rocks is about 3,430,000 km2, and the exposed area of the carbonate is approximately 13 % of China’s territory. In 2003, soil loss in Yunnan, Guizhou, and Guangxi provinces reached 179,600 km2, which is almost 40.1 % of the total area, causing rocky desertification. In this study, the erosion-creep-collapse mechanism of underground soil loss for the karst rocky desertification in Chenqi village, Puding county, Guizhou province is proposed. The mechanism occurs under the following geological environment: slope surface undulation, underlying bedrock surface fluctuation and thin and inhomogeneous soil overlying, overlying soil generation by bedrock weathering, underground karst development, and large groundwater depth and lying water table under the bottom of soils. The erosion-creep-collapse mechanism of underground soil loss in the karst slopes is explained as follows: power loss due to human cultivation activities that destroy the soil structure, hydraulic force formed by rainfall infiltration, wet–dry cycle generated by rainfall, erosion effect caused by rainfall penetration, creeping and flowing of plastic-stream soil, and collapse. The erosion-creep-collapse mechanism of underground soil loss has seven steps: disturbance of soils filled in underground karst cave by human activities, internal soil erosion and partial collapse caused by hydraulic power, internal free surface formation within the soil in the filled karst cave, internal soil creeping, soil pipe formation, soil pipe collapse, and ground surface collapse and filling. Soil loss develops slowly, and sudden transportation occurs by collapse. Soil loss can be explained by the proposed mechanism, and soil loss can be prevented by controlling soil collapse. 相似文献
13.
14.
由于岩溶地区特有的地上地下二元水文结构,其岩溶水系统循环演化具有特殊性,因而水不仅会携带土壤发生地表流失,而且会发生地下漏失,造成该地区土壤流失量大,岩溶石漠化现象突出,治理难度大。本文以贵州贞丰-关岭花江高原峡谷石漠化治理示范区为研究区域,通过野外调查、水样分析及数值模拟方法,对该区岩溶水系统的补、径、排特征,水化学特征和水均衡量等进行分析模拟计算出地下水位、地下暗河流量变化情况,得到该区岩溶水均衡量,其结果基本反映了实际地下水系统排泄量变化及地下水流向特征,初步阐明该区域岩溶水系统循环演化特征,为岩溶石漠化地区的土壤地表流失和地下漏失的趋势研究及防治提供理论依据。 相似文献
15.
The Geochemical Features and Evolution of Laterite in the Karst Areas of Guizhou Province 总被引：4，自引：0，他引：4
Guizhou is one of the dominating karst regions,where laterite is widespread,in China.Seventy-two laterite samples were taken from twelve laterite sections in the karst areas of Guizhou Province,which are possessed of typical subtropical karst geomphological and ecological environmental features and have evolved completely from dolostones and limestones.In terms of the major,trace and REE deta for thd samples this paper discusses the geochemical characteristics of laterite in the karst areas with an attempt to disclose the geochemical process and evolutionary rule of laterite formation.There have been involved three important pedogenetic geochemical precesses in the formation of laterite in the karst areas:(1)enrichment of silicon and aluminum and depletion of calcium and magnesium;(2)enrichment of iron and manganese;and(3) enrichment of aluminum and depletion of silicon.During the formation and evolution of laterite,obvious enrichment and differentiation of trace elements such as Cu,Pb,Zn,Ni,Co,Cr,Pb,F,Cl,and As can be observed,but for the rare-earth elements,their enrichment is remarkable against a weak differentiation.The REE distribution patterns in the laterite are similar to those of its parental carbonate rocks. 相似文献
16.
According to the transport theory of soil solutes and the conditions of soil, geology and climate in the karst region of Guizhou
Province, a numerical simulation model of edaphic nitrogen element transport under field conditions is initially established.
In this model, NO−
3 and NH+
4 are regarded as soil solutes. Transformation mechanisms such as biological release, bio-immobilization, ammonium adsorption-desorption,
nitration-denitrification and factors of crop root uptaking are considered in this model. It is hoped that the data from this
model could directly be used to guide agricultural production in this region and offer feasible ways to improve the use of
nitrogen element, sustainable development of agriculture in karst mountainous areas and natural environment. 相似文献
17.
岩溶地下河是我国西南地区的重要水源,工业生产过程中产生的砷污染物,除通过落水洞等直接进入并污染地下水外,还会在表层岩溶带溶缝、溶隙内吸附、滞留及富集,并在特定条件下再次迁移,成为"稳定次生污染源".以广西某砷污染事件为例,采用窄缝槽物理模型装置进行砷的动态吸附、解吸实验,并结合地球化学模拟研究砷污染物在表层岩溶带土壤中的迁移规律.实验结果显示表层岩溶带对砷的吸附以物理吸附（扩散过程）为主,相比吸附过程而言解吸速率则显得缓慢,而酸溶液相比去离子水可促进砷的解吸过程.地球化学模拟结果表明土壤矿物中以针铁矿对砷的吸附贡献最大,而酸溶液通过溶蚀针铁矿等矿物削弱对砷的吸附能力.因此在西南岩溶地区,表层岩溶带系统一旦纳入砷污染物,则解吸过程缓慢,易形成砷污染物的滞留、富集;而酸雨作用下砷的解吸、迁移过程加快,则会提高地下水系统的污染风险. 相似文献
18.
通过叠加分析探究贵州省喀斯特洞穴位置与河网密度的空间关系,从岩性、构造、气候、地形方面解释两者关系的成因。针对洞穴点位河网密度的统计显示:洞穴点集中分布在河网密度中及偏小的区域,正态QQ图显示洞穴点河网密度大体呈正态分布。分析岩性、构造、气候和坡度等影响因素的结果显示:洞穴主要发育在碳酸盐岩区域,并在纯碳酸盐岩、碳酸盐岩夹非碳酸盐岩、非碳酸盐岩分区上表现出负相关性;断层、褶皱中心缓冲区域洞穴最多,并随距离增大洞穴数量减少;温润气候条件为洞穴及河网发育提供了充足水源,溶蚀强度加大,表现在洞穴密度随降雨量和气温的增长而增加;地形条件限制了水力路径和洞穴发育。多因素促使贵州省发育了成熟的地表、地下两套水循环系统,地表水促进溶洞发育,洞穴反过来限制地表径流发育,两者相互影响,使得洞穴与河网密度呈现集中分布的趋势。 相似文献
19.
Inference of creep mechanism in underground soil loss of karst conduits I. Conceptual model 总被引：5，自引：0，他引：5
Jie Zhou Yiqun Tang Ping Yang Xiaohui Zhang Nianqing Zhou Jianxiu Wang 《Natural Hazards》2012,62(3):1191-1215
Karst is widely distributed in the southwest of China, especially in Guizhou Province. The phenomenon of desertification in these areas is very serious. And soil erosion is the key link in the process of desertification. Through field monitoring, underground soil leakage is derived to the main mode of soil loss in this area. Shear strength tests and creep experiments were carried out with the aim of analyzing the creep mechanism in underground soil loss. It is shown that the water content can lead to the great influence on the shear strength of the brown clay. This variation has been combined with creep characteristics besides the structural geology, hydrology condition and brown clay distribution circumstance (field observation). A conceptual creep model of the brown clay sliding along the karst conduits has been unveiled to show the detailed inference of the creep mechanism in the underground soil loss: geology and hydrology control the development of the karst conduit system; and penetration of water induces the weakening of the shear strength of the surface soil and accelerates the creeping and sliding of the brown clay along the karst conduit system. This understanding of the creep mechanism has significant implications for the future management of the soil erosion in the karst area. 相似文献