共查询到18条相似文献，搜索用时 205 毫秒
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根据国内外许多钾盐矿床大量样品测定的结果：通常石盐（岩）的37Cl／35Cl比值和δ37Cl（％）值高于钾石盐（岩）；钾石盐高于光卤石（岩）。例如：西班牙Catalonia盆地钾盐矿床，其石盐岩为0．31958—0．31941和＋1．002─＋0．470‰，钾石盐岩为0．31913和─0．407‰，光卤石岩为0．31887和─1．221‰，等等。这说明了这些蒸发岩是在水体浓缩的不同阶段形成的，是氯同位素分馏作用长期不断进行的结果。其氯同位素组成与Br、K和Mg含量有着密切关系。困而在我国找钾过程中，可将氯同位素组成及Br、K、Mg含量结合起来作为找钾标志考虑。 相似文献
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基于Ｎ－Ｐ－Ｋ三元复肥的物理化学基础，首次测定了四元体系ＫＣｌ－ＫＨ２ＰＯ４－ＣＯ（ＮＨ２）２在２９８．２Ｋ时的溶度及饱和溶液的折光率，绘制了体系的溶度图和折光率－组成图。 相似文献
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呼伦贝尔盟盐湖众多，主要集中分布于新巴尔虎旗附近、乌尔逊河沿岸和呼伦湖以南三个成盐区．呼盟地区盐湖盐类矿物主要有芒硝、泡碱、石膏和石盐．在矿物组成上，东部和西部有较大差异，东部为芒硝、泡碱和石盐，无石膏沉积，西部则是芒硝、石膏和石盐，无泡碱沉积．盐湖卤水主要由Ｋ＋、Ｎａ＋、Ｃａ_（２＋）、Ｍｇ_（２＋）、Ｃｌ－、ＳＯ_（２－）、ＣＯ_３（２－）和ＨＣＯ_３－组成，并含有一定量的溴、硼、碘等微量元素．呼盟地区盐湖矿物以芒硝为主，天然碱、石膏次之，石盐较少．盐湖矿床以小型为主，埋藏较浅，易于开采，矿层组份简单，易于加工利用． 相似文献
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用锂离子选择电极和经典Ａｇ－ＡｇＣｌ电极测定了２９８．１５Ｋ下ＬｉＣｌ－Ｌｉ２Ｂ４Ｏ７－Ｈ２Ｏ体系中离子强度范围为０．０１～２．５０ｍｏｌ．ｋｇ＾－１,不同Ｌｉ２Ｂ４Ｏ７离子强度分数的ＬｉＣｌ的平均活度系数。由实验数据,用迭代法及多元线性回归法,求取了Ｌｉ２Ｂ４Ｏ７的化学计量离解平均常数Ｋｍ,热力学离解平衡常数Ｋ及Ｐｉ－ｔｚｅｒ离子作用参数,并与实验值比较标准偏差为０．０５００,同时该实验结果在０ 相似文献
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Clay mineral occurrence and burial transformations: reservoir potential of the Permo‐Triassic sediments of the Iberian Range 
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下载免费PDF全文 The diagenetic evolution of Permian (Autunian and Saxonian) and Triassic (Buntsandstein) sandstones and mudrocks have been studied over 1000 m sequence from the Sigüenza 44‐3 drill core in the Iberian Range, Spain. We compare and contrast the diagenetic processes in these different lithologies and the timing of clay mineral formation. Moreover, we establish the relationship between clay mineral diagenesis and reservoir potential. Both the Permian and Triassic successions are characterised by conglomerates, sandstones and interbedded mudstones of fluvial origin that change upwards into distal deposits of a fluvio‐deltaic system. The clay minerals are illite, illite‐smectite mixed layers, kaolinite and dickite. The illite content in all sequences is not related to diminished feldspars; it is owing to the initial detrital mineralogical composition of the Autunian sandstones. The effect of feldspar alteration to kaolin minerals has a strong influence on the lost of porosity‐permeability in the Saxonian facies. In contrast, illite and mixed layers illite‐smectite are the main clay rims preserving porosity in the Buntsandstein sandstones. However, fibrous illite is the dominant pore‐filling in the Permian Autunian facies, closing porosity and permeability. Kaolinite and dickite show opposite trends: dickite increases yet kaolinite decreases from Triassic to Permian sandstones. Dickite replaced kaolinite during burial‐thermal evolution of the succession. The δD and δ18O isotopic signatures from silt and clay fractions indicate a mixture of meteoric and marine waters, and suggest a minimum temperature range between 60 and 150 °C for diagenetic pore fluids. The Permian δD values (?24‰ to ?44‰) are relatively similar to Buntsandstein values (?24‰ to ?37‰). However, the Permian δ18O values (+7.6 and +15.3, average of +13.3‰) are generally higher by ca. 6.2‰ compared to the Buntsandstein data (4.8–10.1‰, average +7.1‰). Such a variation is interpreted as the result of mesodiagenetic pore fluid changes. The extensive dickitisation of kaolinite is attributed to increased hydrogen ions resulting from maturation of organic matter. The vitrinite reflectance of organic matter and the modelled thermal history suggest a maximum burial of 3400 m, accomplished 70 Ma ago. The Permo‐Triassic reached the gas window shortly before major uplift, at 65 Ma, when further maturation and hydrocarbon expulsion ceased. 相似文献
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The Paleoproterozoic (Statherian) Thelon Basin is located in the Churchill Province of the Canadian Shield, formed following the Trans‐Hudson Orogeny. Basin formation followed an interval of felsic volcanism and weathering of underlying bedrock. The diagenetic evolution of the Thelon lasted about one billion years and was punctuated by fluid movement influenced by tectonic events. Early quartz cements formed in well‐sorted, quartz‐rich facies during diagenetic stage 1; fluids in which these overgrowths formed had δ18O values near 0‰ (Vienna Standard Mean Ocean Water). Uranium‐rich apatite cement (P1) also formed during diagenetic stage 1 indicating that oxygenated, uranium‐bearing pore water was present in the basin early in its diagenetic history. Syntaxial quartz cement (Q1) formed in water with δ18O from ?4 to ?0.8‰ in diagenetic stage 2. Diagenetic stage 3 occurred when the Thelon Formation was at ca. 5 km depth, and was marked by extensive illitization, alteration of detrital grains, and uranium mineralization. Basin‐wide, illite crystallized at ～200 °C by fluids with δ18O values of 5–9‰ and δD values of ?60 to ?31‰, consistent with evolved basinal brines. Tectonism caused by the accretion of Nena at ca. 1600 Ma may have provided the mechanism for brine movement during deep burial. Diagenetic stage 4 is associated with fracturing and emplacement of mafic dikes at ca. 1300 Ma, quartz cement (Q3) in fractures and vugs, further illitization, and recrystallization of uraninite (U2). Q3 cements have fluid inclusions that suggest variable salinities, δ18O values of 1.5–9‰, and δD values of ?97 to ?83‰ for stage 4 brines. K‐feldspar and Mg‐chlorite formed during diagenetic stage 5 at ca. 1000 Ma in upper stratigraphic sequences, and in the west. These phases precipitated from low‐temperature, isotopically distinct fluids. Their distribution indicates that the basin hydrostratigraphy remained partitioned for >600 Ma. 相似文献
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利用2008—2015年CMORPH卫星与自动观测站的逐时降水量融合产品,分析了陕西地区5~10月降水量、降水频次、降水强度的日变化特征,以及陕西南北降水日变化上的差异。结果表明：（1）降水量和降水频次从南向北明显递减,地形作用下的纬向变化是陕西地区降水最重要的特征,但降水强度呈现出南北高、中间低的分布特征,两个高值中心分别位于陕南南部和陕北的东北部,EOF分析表明陕西南部夜雨特征明显。（2）陕西南部降水量和降水频次、降水强度日变化特征一致,均以夜晚至次日清晨为高值区, 而在中午前后达到最低值。陕西北部降水量、降水频次峰值则主要出现在上午,降水强度峰值出现在傍晚。区域对比分析表明,陕西南部降水量日变化主要来自于降水强度的贡献,而陕西北部日变化以降水频次的贡献为主。（3）陕西降水的南北分界线特征明显,34 °N以南地区降水日变化明显且降水主要集中在夜间。34~37 °N之间的中部地区降水日变化较弱,37 °N以北地区降水的日变化特征和陕西南部相反。（4）除榆林、渭南和商洛东部地区外,其他大部分地方白天的降水量都明显低于夜间的降水量,特别是陕南秦巴山区夜间降水量超过白天的一倍以上。 相似文献
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为研究人类活动影响下河流降水径流响应特征,以珠江三角洲典型城镇化流域石马河为研究对象,采集2017年1-12月日降水、河水样品和3场台风期间的时段降水、洪水样品,通过测定其氢氧稳定同位素组成（δD、δ 18O）,分析流域降水、径流氢氧同位素组成特征,并利用同位素二元混合模型,分割3场台风降水事件中事前水及事件水对流量过程的贡献。结果表明,研究区域大气降水δD、δ 18O的变化范围分别为-105.10‰~+9.98‰和-14.80‰~-0.55‰,年加权平均值为-57.88‰和-8.61‰,大气降水线为δD = 7.70δ 18O+8.61（R 2= 0.98）;河水δD、δ 18O的变化范围分别为-91.23‰~-15.96‰和-12.66‰~-4.01‰,δD-δ 18O基本落在局地大气降水线上,表明降水是石马河径流的主要来源。3场台风期间,事件水占洪水总径流量的比例分别为59.7%、55.0%和69.4%,均高于事前水占比。洪水涨水初期事前水和事件水同步增长,涨水后期事件水比例逐渐增大,洪峰期间比例大于80%,成为径流主导成分,表明流域城镇化过程中下垫面不透水面积的增加会显著改变水文循环过程。本研究成果可为珠江三角洲城镇化流域水文预报提供理论基础。 相似文献
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盐碱化湿地稻-鱼复合生态系统微生物特征 总被引：1，自引：0，他引：1
为揭示盐碱化湿地稻-鱼复合生态系统微生物群落结构特征,1994-1995年,对松嫩平原苏打盐碱化湿地稻-鱼复合生态系统水体与土壤中的微生物数量及种群组成进行了初步研究。结果表明,稻-鱼湿地水体中异养细菌数量显著高于稻田湿地(P<0.05),季节变化特点为秋季>夏季>春季。异养细菌的数量分布与鱼产量有显著相关关系(r=0.879)。稻-鱼湿地系统的土壤微生物数量明显高于稻田湿地(P<0.01)。稻-鱼湿地和稻田湿地分别检测出10个和11个属的异养细菌。稻-鱼湿地系统1个生长期细菌的平均生物量为0.973g/m3,生产量为307.5 kg/hm2,所提供的鱼产力为7.0 kg/hm2。 相似文献
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Oxygen isotopic composition and its application to the study of tracing oceanographical process in Bering Sea and Chukchi Sea 下载免费PDF全文
下载免费PDF全文 In this paper, the 18 O distribution of surface water from the central sea areas of the Bering Sea and the Chukchi Sea was studied. The δ 18 O value of surface water from the Bering Sea is averagely -0.5‰; the δ 18 O contents of the Chukchi Sea are distributionally lower in northeast and higher in southwest; the δ 18 O value at the margin of Canadian Basin is -2.8‰, and averagely -0.8‰ in the southern area of the Chukchi Sea. The δ 18 O vertical distribution in some deep water stations from the Chukchi Sea and the Bering Sea is also studied. In the southern margin of Canadian Basin, the δ 18 O value is -2‰ -3‰ for surface layer and rises to 0 at 100 m depth layer. In the Bering Sea, the δ 18 O is about -0.5‰ for surface layer and increases to 0 at the depth of 300 m. The NO tracer can reflect obviously three water masses vertically distributed in the central Bering Sea: the upper Bering water mass, the middle Bering water mass and the deep Pacific water mass. The distributive ranges of NO and temperature for the various water masses are T<7℃, NO>780 μmol/dm 3 and T≥7℃, NO>650 μmol/dm 3 for upper Bering water mass, T<4℃, 550相似文献