Benthic Carbon Mineralization and Nutrient Turnover in a Scottish Sea Loch: An Integrative In Situ Study   总被引：1，自引：1，他引：0  

Ronnie N. Glud  Peter Berg  Henrik Stahl  Andrew Hume  Morten Larsen  Bradley D. Eyre  Perran L. M. Cook 《Aquatic Geochemistry》2016,22(5-6):443-467

Based on in situ microprofiles, chamber incubations and eddy covariance measurements, we investigated the benthic carbon mineralization and nutrient regeneration in a ~65-m-deep sedimentation basin of Loch Etive, UK. The sediment hosted a considerable amount of infauna that was dominated by the brittle star A. filiformis. The numerous burrows were intensively irrigated enhancing the benthic in situ O₂ uptake by ~50 %, and inducing highly variable redox conditions and O₂ distribution in the surface sediment as also documented by complementary laboratory-based planar optode measurements. The average benthic O₂ exchange as derived by chamber incubations and the eddy covariance approach were similar (14.9 ± 2.5 and 13.1 ± 9.0 mmol m^?2 day^?1) providing confidence in the two measuring approaches. Moreover, the non-invasive eddy approach revealed a flow-dependent benthic O₂ flux that was partly ascribed to enhanced ventilation of infauna burrows during periods of elevated flow rates. The ratio in exchange rates of ΣCO₂ and O₂ was close to unity, confirming that the O₂ uptake was a good proxy for the benthic carbon mineralization in this setting. The infauna activity resulted in highly dynamic redox conditions that presumably facilitated an efficient degradation of both terrestrial and marine-derived organic material. The complex O₂ dynamics of the burrow environment also concurrently stimulated nitrification and coupled denitrification rates making the sediment an efficient sink for bioavailable nitrogen. Furthermore, bioturbation mediated a high efflux of dissolved phosphorus and silicate. The study documents a high spatial and temporal variation in benthic solute exchange with important implications for benthic turnover of organic carbon and nutrients. However, more long-term in situ investigations with like approaches are required to fully understand how environmental events and spatio-temporal variations interrelate to the overall biogeochemical functioning of coastal sediments.  相似文献   

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy          下载免费PDF全文

Jesse D. Ward  Mark Bowden  C. Tom Resch  Steven Smith  Bruce K. McNamara  Edgar C. Buck  Gregory C. Eiden  Andrew M. Duffin 《Geostandards and Geoanalytical Research》2016,40(1):135-148

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.  相似文献   

Adsorption of copper (II) on mesoporous silica: the effect of nano-scale confinement     

Andrew W. Knight  Austen B. Tigges  Anastasia G. Ilgen 《Geochemical transactions》2018,19(1):13

Nano-scale spatial confinement can alter chemistry at mineral–water interfaces. These nano-scale confinement effects can lead to anomalous fate and transport behavior of aqueous metal species. When a fluid resides in a nanoporous environments (pore size under 100 nm), the observed density, surface tension, and dielectric constant diverge from those measured in the bulk. To evaluate the impact of nano-scale confinement on the adsorption of copper (Cu²⁺), we performed batch adsorption studies using mesoporous silica. Mesoporous silica with the narrow distribution of pore diameters (SBA-15; 8, 6, and 4 nm pore diameters) was chosen since the silanol functional groups are typical to surface environments. Batch adsorption isotherms were fit with adsorption models (Langmuir, Freundlich, and Dubinin–Radushkevich) and adsorption kinetic data were fit to a pseudo-first-order reaction model. We found that with decreasing pore size, the maximum surface area-normalized uptake of Cu²⁺ increased. The pseudo-first-order kinetic model demonstrates that the adsorption is faster as the pore size decreases from 8 to 4 nm. We attribute these effects to the deviations in fundamental water properties as pore diameter decreases. In particular, these effects are most notable in SBA-15 with a 4-nm pore where the changes in water properties may be responsible for the enhanced Cu mobility, and therefore, faster Cu adsorption kinetics.  相似文献   

Upstream—Downstream Shifts in Peak Recruitment of the Native Olympia Oyster in San Francisco Bay During Wet and Dry Years     

Andrew L. Chang  Lindsay J. Sullivan  Steven G. Morgan  Matthew C. Ferner 《Estuaries and Coasts》2018,41(1):65-78

Understanding the conditions that drive variation in recruitment of key estuarine species can be important for effective conservation and management of their populations. The Olympia oyster (Ostrea lurida) is native to the Pacific coast of North America and has been a target of conservation efforts, though relatively little information on larval recruitment exists across much of its range. This study examined the recruitment of Olympia oysters at biweekly to monthly intervals at four sites in northern San Francisco Bay from 2010 to 2015 (except 2013). Mean monthly temperatures warmed at all sites during the study, while winter (January–April) mean monthly salinity decreased significantly during a wet year (2011), but otherwise remained high as a result of a drought. A recurring peak in oyster recruitment was identified in mid-estuary, in conditions corresponding to a salinity range of 25–30 and >16 °C at the time of settlement (April–November). Higher average salinities and temperatures were positively correlated with greater peak recruitment. Interannual variation in the timing of favorable conditions for recruitment at each site appears to explain geographic and temporal variation in recruitment onset. Higher winter/spring salinities and warmer temperatures at the time of recruitment corresponded with earlier recruitment onset within individual sites. Across all sites, higher winter/spring salinities were also correlated with earlier onset and earlier peak recruitment. Lower winter salinities during 2011 also resulted in a downstream shift in the location of peak recruitment.  相似文献   

Characterization,modeling, and remediation of karst in a changing environment     

Zexuan Xu  Nicolas Massei  Ingrid Padilla  Andrew Hartmann  Bill Hu 《Environmental Earth Sciences》2018,77(12):476

This introductory editorial paper provides a review and prospective outlook of the achievements and challenges in karst research under a changing environment. A brief discussion of the past and future karst research has been focused on: (1) data and new technologies; (2) modeling of karst flow and reactive transport; (3) responses of karst hydrosystems to climate variability and changes across scales.  相似文献   

Characterization of fluid inclusions from mineralized pegmatites of the Damara Belt,Namibia: insight into late-stage fluid evolution and implications for mineralization     

Ashworth  Luisa  Kinnaird  Judith Ann  Nex  Paul Andrew Martin  Erasmus  Rudolph Marthinus  Przybyłowicz  Wojciech Józef 《Mineralogy and Petrology》2018,112(6):753-765

Mineralogy and Petrology - Mineralized NYF and LCT pegmatites occur throughout the northeast-trending Neoproterozoic Damara Belt, Namibia. Mineralization in the pegmatites varies geographically,...  相似文献   

Estimating urban above ground biomass with multi-scale LiDAR     

Phil Wilkes  Mathias Disney  Matheus Boni Vicari  Kim Calders  Andrew Burt 《Carbon balance and management》2018,13(1):10

  相似文献   

Testing for similarity in area‐based spatial patterns: Alternative methods to Andresen's spatial point pattern test          下载免费PDF全文

Andrew Palmer Wheeler  Wouter Steenbeek  Martin A. Andresen 《Transactions in GIS》2018,22(3):760-774

Andresen's spatial point pattern test (SPPT) compares two spatial point patterns on defined areal units; it identifies areas where the spatial point patterns diverge and aggregates these local (dis)similarities to one global measure. We discuss the limitations of the SPPT and provide two alternative methods to calculate differences in the point patterns. In the first approach we use differences in proportions tests corrected for multiple comparisons. We show how the size of differences matters, as with large point patterns many areas will be identified by SPPT as statistically different, even if those differences are substantively trivial. The second approach uses multinomial logistic regression, which can be extended to identify differences in proportions over continuous time. We demonstrate these methods by identifying areas where pedestrian stops by the New York City Police Department are different from violent crimes for 2006–2016.  相似文献   

MARLI: a mobile application for regional landslide inventories in Ecuador     

Sellers  Chester Andrew  Buján  Sandra  Miranda  David 《Landslides》2021,18(12):3963-3977

The regions of Central and South America most susceptible to the occurrence of landslides will become even more vulnerable in the context of climate change. The Josefina disaster, in 1993, demonstrated both the vulnerability of local infrastructures and communities in the Paute River basin (Ecuador). Since this natural phenomena, several landslide inventories and susceptibility studies were developed, revealing the vulnerability of the Paute River basin to unstable terrain and the need for further studies throughout the basin. Despite this, no studies have been done since then to update the information generated. This paper describes a Mobile Application for Regional Landslide Inventories (MARLI), a simple but efficient open-access platform to report landslide events using the Open Data Kit system. Its design makes reporting fast, simple and cost-effective with an added benefit, and a specialized knowledge is not required for its use. MARLI was tested for the collection of landslides in Cuenca (Ecuador). From the data taken in the field, it was possible to analyze the performance and suitability of collected data and compare the results with regional inventories in the same area. Additionally, these results can be used for the elaboration and update of large-scale inventories or the training of automatic identification systems of landslides and later evaluation of their precision in a small-medium scale. Likewise, this product constitutes a fundamental input for the formulation of mitigation strategies, to formulate the appropriate response and in time, also the elaboration of reconstruction plans before the increase in the occurrence of such phenomena.

  相似文献   

Stochastic Local Interaction Model: An Alternative to Kriging for Massive Datasets     

Hristopulos  Dionissios T.  Pavlides  Andrew  Agou  Vasiliki D.  Gkafa  Panagiota 《Mathematical Geosciences》2021,53(8):1907-1949

Mathematical Geosciences - Classical geostatistical methods face serious computational challenges if they are confronted with large spatial datasets. The stochastic local interaction (SLI) approach...  相似文献