Arsenic mobility in alteration products of sulfide-rich, arsenopyrite-bearing mine wastes, Snow Lake, Manitoba, Canada   总被引：2，自引：0，他引：2  

Kristin A. Salzsauler  Nikolay V. Sidenko  Barbara L. Sherriff 《Applied Geochemistry》2005,20(12):2303-2314

The Arsenopyrite Residue Stockpile (ARS) in Snow Lake, Manitoba contains approximately 250,000 tons of cyanide treated, refractory arsenopyrite ore concentrate. The residue was deposited between 1950 and 1959 in an open waste rock impoundment, and remained exposed until 2000, when the pile was capped with layers of waste rock and clay. During the time when the ARS was exposed to the atmosphere, arsenopyrite, pyrrhotite, pyrite and chalcopyrite were oxidized producing scorodite, jarosite and two generations of amorphous Fe sulfo-arsenates (AISA). These secondary phases attenuated some of the As released to pore water during oxidation in the upper layers of the ARS. The imposition of the cap prevented further oxidation. The secondary As minerals are not stable in the reduced environment that currently dominates the pile. Therefore, As currently is being released into the groundwater. Water in an adjacent monitoring well has concentrations of >20 mg/L total As with relative predominance of As(III).  相似文献   

Obsidian from the northern sector of the Main Ethiopian Rift: implications for archeology     

Agazi Negash  Mulugeta Alene  Asfawossen Asrat  Barbara Nash 《第四纪科学杂志》2021,36(4):664-671

Obsidian is abundant in the Main Ethiopian Rift (MER). Petrological and geochemical features of obsidian from four volcanic centers in the MER, namely Birenti, Dofen, Fentale and Kone, are presented. Compositional and petrological variability is noted among the Dofen and Fentale obsidian, but not in those from Kone and Birenti where each have separate but uniform elemental composition. The Fentale and Kone obsidian were source materials for the artifacts of a number of Middle Stone Age and Later Stone Age/Neolithic sites in the region. We have yet to determine whether Dofen and Birenti were sources for archeological artifacts. The study also shows that volcanic episodes from a single center do not necessarily result in compositional variability.  相似文献   

Impacts of a large Sahelian city on groundwater hydrodynamics and quality: example of Niamey (Niger)     

Aïssata B. Hassane  Christian Leduc  Guillaume Favreau  Barbara A. Bekins  Thomas Margueron 《Hydrogeology Journal》2016,24(2):407-423

The management of groundwater resources is very important in the semiarid Sahel region, which is experiencing rapid urban development. Impacts of urbanization on groundwater resources were investigated in the unconfined aquifer of the Continental Terminal beneath the city of Niamey, Niger, using water level and chemical data. Hydrodynamic and chemical changes are best described by a combination of factors including the historical development of the city, current land use, water-table depth and topography. Seasonal groundwater recharge occurs with high spatial variability, as indicated by water-level monitoring in all wells, but there was no interannual trend over the 5-year study period. Groundwater salinity shows high spatial variability and a minor rising trend. The highest salinity is in the old city centre, with Na–NO₃ dominant, and it increases seasonally with recharge. Salinity is much lower and more variable in the suburbs (Ca–HCO₃, Ca–NO₃, and Na–NO₃ dominant). Nitrate is the main ionic contaminant and is seasonally or permanently above the international guidelines for drinking water quality in 36 % of sampled wells, with a peak value of 112 mg L^?1 NO₃–N (8 meq L^?1). Comparison of urban and rural sites indicates a long-term increase in groundwater recharge and nitrate enrichment in the urban area with serious implications for groundwater management in the region.  相似文献   

Isotopic signatures for the assessment of snow water resources in the Moroccan high Atlas mountains: contribution to surface and groundwater recharge     

Angoran Baudelaire N’da  Lhoussaine Bouchaou  Barbara Reichert  Lahoucine Hanich  Yassine Ait Brahim  Abdelghani Chehbouni  El Hassane Beraaouz  Jean-Luc Michelot 《Environmental Earth Sciences》2016,75(9):755

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Changes in phosphorus content,phosphatase activity and some physicochemical and microbiological parameters of soil within the range of impact of illegal dumping sites in Bydgoszcz (Poland)     

Joanna Lemanowicz  Agata Bartkowiak  Barbara Breza-Boruta 《Environmental Earth Sciences》2016,75(6):510

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Assessment of the content of heavy metals and potential pathogenic microorganisms in soil under illegal dumping sites     

Agata Bartkowiak  Barbara Breza-Boruta  Joanna Lemanowicz 《Environmental Earth Sciences》2016,75(21):1401

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Potential Salinity and Temperature Futures for the Chesapeake Bay Using a Statistical Downscaling Spatial Disaggregation Framework     

Barbara A. Muhling  Carlos F. Gaitán  Charles A. Stock  Vincent S. Saba  Desiree Tommasi  Keith W. Dixon 《Estuaries and Coasts》2018,41(2):349-372

Estuaries are productive and ecologically important ecosystems, incorporating environmental drivers from watersheds, rivers, and the coastal ocean. Climate change has potential to modify the physical properties of estuaries, with impacts on resident organisms. However, projections from general circulation models (GCMs) are generally too coarse to resolve important estuarine processes. Here, we statistically downscaled near-surface air temperature and precipitation projections to the scale of the Chesapeake Bay watershed and estuary. These variables were linked to Susquehanna River streamflow using a water balance model and finally to spatially resolved Chesapeake Bay surface temperature and salinity using statistical model trees. The low computational cost of this approach allowed rapid assessment of projected changes from four GCMs spanning a range of potential futures under a high CO₂ emission scenario, for four different downscaling methods. Choice of GCM contributed strongly to the spread in projections, but choice of downscaling method was also influential in the warmest models. Models projected a ~2–5.5 °C increase in surface water temperatures in the Chesapeake Bay by the end of the century. Projections of salinity were more uncertain and spatially complex. Models showing increases in winter-spring streamflow generated freshening in the Upper Bay and tributaries, while models with decreased streamflow produced salinity increases. Changes to the Chesapeake Bay environment have implications for fish and invertebrate habitats, as well as migration, spawning phenology, recruitment, and occurrence of pathogens. Our results underline a potentially expanded role of statistical downscaling to complement dynamical approaches in assessing climate change impacts in dynamically challenging estuaries.  相似文献   

Community-based responses to climate hazards: typology and global analysis     

Paterson  Barbara  Charles  Anthony 《Climatic change》2019,152(3-4):327-343

Climatic Change - The severity and frequency of climate change hazards are increasing around the world. Because the impacts are most acutely felt in local communities, it is critical to improve...  相似文献   

Vulnerabilities,competition and rights in a context of climate change toward equitable water governance in Peru's Rio Santa Valley     

Barbara Deutsch Lynch 《Global Environmental Change》2012,22(2):364-373

As glacial retreat changes the hydrology of Peru's Rio Santa, water demand is growing, pollution is worsening, and competition for water among economic sectors, political jurisdictions and upstream and downstream water users is intensifying. The vulnerability of highland communities, food producers, and poor urban neighborhoods in the Santa watershed in the face of these changes is magnified by inequities in water governance, giving rise to water conflict. Peru's new water regime defines water as an economic good and seeks to centralize control over water. This article analyzes implications of this regime for ensuring equity and managing conflict. It concludes that Peru's water regime is more likely to address equity issues when faced with concerted citizen action.  相似文献   

Palaeo-environmental and dietary analysis of intestinal contents of a mammoth calf (Yamal Peninsula,northwest Siberia)     

Bas van Geel  Daniel C. Fisher  Adam N. Rountrey  Jan van Arkel  Joost F. Duivenvoorden  Aline M. Nieman  Guido B.A. van Reenen  Alexei N. Tikhonov  Bernard Buigues  Barbara Gravendeel 《Quaternary Science Reviews》2011,30(27-28):3935-3946

Intestinal samples from the one-month-old Siberian mammoth calf ‘Lyuba’ were studied using light microscopy and ancient DNA to reconstruct its palaeo-environment and diet. The palynological record indicates a ‘mammoth steppe’. At least some pollen of arboreal taxa was reworked, and thus the presence of trees on the landscape is uncertain. In addition to visual comparison of 11 microfossil spectra, a PCA analysis contributed to diet reconstruction. This yielded two clusters: one of samples from the small intestine and the other of large-intestine samples, indicating compositional differences in food remains along the intestinal tract, possibly reflecting different episodes of ingestion. Based on observed morphological damage we conclude that the cyperaceous plant remains and some remains of dwarf willows were originally eaten by a mature mammoth, most likely Lyuba’s mother. The mammoth calf probably unintentionally swallowed well-preserved mosses and mineral particles while eating fecal material deposited on a soil surface covered with mosses. Coprophagy may have been a common habit for mammoths, and we therefore propose that fecal material should not be used to infer season of death of mammoths. DNA sequences of trnL and rbcL genes amplified from ancient DNA extracted from intestinal samples confirmed and supplemented plant identifications based on microfossils and macro-remains. Results from different extraction methods and barcoding markers complemented each other and show the value of longer protocols in addition to fast and commercially available extraction kits.  相似文献