Anthropogenic vs. lithogenic origins of trace elements (As, Cd, Pb, Rb, Sb, Sc, Sn, Zn) in water column particles: northwestern Mediterranean Sea   总被引：1，自引：0，他引：1  

F. E. Grousset  C. R. Quetel  B. Thomas  O. F. X. Donard  C. E. Lambert  F. Guillard  A. Monaco 《Marine Chemistry》1995,48(3-4)

The distribution of heavy metal was analyzed in water column particles collected in autumn (October 1985) and spring (March 1986) by two series of sediment traps from a mooring located in the northeastern Mediterranean Sea continental slope. Four traps were set, at 50, 100, 300, 600 m depths on the mooring in 645 m deep water in the Lacaze-Duthier canyon. The total metal concentrations were determined by ICP-MS. Results show that Rb and Sc contents display typical shale values. As, Cd, Pb, Sb, Zn (normalized to Sc) display high enrichment factors (up to 50) over shale compositions. Distinctive temporal variability as well as the respective contributions of local (Têt, Aude) and remote (Rhône) rivers and Sahara-derived aerosols have been identified. Fluxes of most elements observed in the upper 100 m can be attributed to atmospheric fluxes. In the deepest traps (300 and 600 m) these fluxes are, however, mostly dominated by riverine particles advected from the continental shelf. Most of the trace-element enrichments are more likely to be related to the anthropogenic input rather than to biological cycling. Isotopic composition of lead determined by ICP-MS enabled to evaluate that the proportion of anthropogenic lead derived from European gasoline consumption ranged between 50 and 100%.  相似文献   

Non-linear effects in internal-tide beams, and mixing     

Theo Gerkema  Chantal Staquet  Pascale Bouruet-Aubertot 《Ocean Modelling》2006,12(3-4):302-318

A non-linear non-hydrostatic model (MIT-gcm) is used to study the generation and propagation of internal tides. The model domain covers a continental slope and neighbouring parts of the deep ocean and shelf. Uniformity in the along-slope direction is assumed. We focus on the non-linear evolution of the internal tide once generated. In particular, we show that in the main region of generation, over the upper part of the slope, small-scale features occur, indicative of breaking and mixing. Far from the generation region, non-linear processes are important in the reflection of the beam at the bottom, where higher harmonics are generated. This implies an energy transfer toward higher frequencies and the resulting shape of the energy spectra is consistent with observations. Turbulent and mixing processes are analysed by employing an adiabatic sorting method; thus, we calculate the development in time of the available potential energy, the variation in the background potential energy due to irreversible processes, and the distribution of the Cox number (the local turbulent diffusivity normalized by the background diffusivity) over the slope. With rotation, the transfer of energy to higher harmonics is reduced.  相似文献   

Variability of the axial morphology and of the gravity structure along the Central Spreading Ridge (North Fiji Basin): evidence for contrasting thermal regimes     

Eulàlia Gràcia  Chantal Tisseau  Márcia Maia  Thierry Tonnerre  Jean-Marie Auzende  Yves Lagabrielle 《Marine Geophysical Researches》1996,18(2-4):249-273

The Central Spreading Ridge (CSR) is located in the central part of the North Fiji Basin, a complex back-arc basin created 12 Ma ago between the Pacific and Indo-Australian plates. The 3.5 Ma old CSR is the best developed, for both structure and magmatism, of all the spreading centers identified in the basin, and may be one of the largest spreading systems of the west Pacific back-arc basins. It is more than 800 km long and 50–60 km wide, and has been intensively explored during the French-Japanese STARMER project (1987–1991).The CSR is segmented into three first order segments named, from north to south, N160°, N15° and N-S according to their orientation. This segmentation pattern is similar to that found at mid-ocean ridges. The calculated spreading rate is intermediate and ranges from 83 mm/yr at 20°30 S to 50 mm/yr at 17°S. In addition, there is a change in the axial ridge morphology and gravity structure between the northern and southern sections of the CSR. The axial morphology changes from a deep rift valley (N160° segment), to a dome split by an axial graben (N15° segment) and to a rectangular flat top high (N-S segment). The Mantle Bouguer Anomalies obtained on the northern part of the CSR (N160°/N15° segments) show bull's eye structures associated with mantle upwelling at the 16°50S triple junction and also in the middle of the segments. The Mantle Bouguer Anomalies of the southern part of the ridge (N-S segment) are more homogeneous and consistent with the observed smooth topography associated with axial isostatic compensation.At these intermediate spreading rates the contrast in bathymetry and gravity structure between the segments may reflect differences in heat supply. We suggest that the N160° and N15° segments are cold with respect to the hot N-S segment. We use a non-steady-state thermal model to test this hypothesis. In this model, the accretion is simulated as a nearly steady-state seafloor spreading upon which are superimposed periodic thermal inputs. With the measured spreading rate of 50 mm/yr, a cooling cycle of 200,000 yr develops a thermal state that permits to explain the axial morphology and gravity structure observed on the N160° segment. A spreading rate of 83 mm/yr and a cooling cycle of 120,000 yr would generate the optimal thermal structure to explain the characteristics of the N-S segment. The boundaries between the hot N-S segment and its cold bounding segments are the 18°10 S and 20°30 S propagating rifts. A heat propagation event along the N-S segment at the expense of the adjacent colder failing segments, can explain the sharp changes in the observed morphology and structure between the segments.  相似文献   

Distinct export dynamics for dissolved and particulate phosphorus reveal independent transport mechanisms in an arable headwater catchment          下载免费PDF全文

Rémi Dupas  Chantal Gascuel‐Odoux  Nicolas Gilliet  Catherine Grimaldi  Gérard Gruau 《水文研究》2015,29(14):3162-3178

This paper investigates particulate phosphorus (PP) and soluble reactive phosphorus (SRP) concentrations at the outlet of a small (5 km²) intensively farmed catchment to identify seasonal variability of sources and transport pathways for these two phosphorus forms. The shape and direction of discharge‐concentration hystereses during floods were related to the hydrological conditions in the catchment during four hydrological periods. Both during flood events and on an annual basis, contrasting export dynamics highlighted a strong decoupling between SRP and PP export. During most flood events, discharge‐concentration hystereses for PP were clockwise, indicating mobilization of a source located within or near the stream channel. Seasonal variability of PP export was linked to the availability of stream sediments and the export capacity of the stream. In contrast, hysteresis shapes for SRP were anticlockwise, which suggests that SRP was transferred to the stream via subsurface flow. Groundwater rise in wetland soils was likely the cause of this transfer, through the hydrological connectivity it created between the stream and P‐rich soil horizons. SRP concentrations were the highest when the relative contribution of deep groundwater from the upland domain was low compared with wetland groundwater. Hence, soils from non‐fertilized riparian wetlands seemed to be the main source of SRP in the catchment. This conceptual model of P transfer with distinct hydrological controls for PP and SRP was valid throughout the year, except during spring storm events, during which PP and SRP exports were synchronized as a consequence of overland flow and erosion on hillslopes. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Benchmarking sustainability in cities: The role of indicators and future scenarios     

Christopher T. Boyko  Mark R. Gaterell  Austin R.G. Barber  Julie Brown  John R. Bryson  David Butler  Silvio Caputo  Maria Caserio  Richard Coles  Rachel Cooper  Gemma Davies  Raziyeh Farmani  James Hale  A. Chantal Hales  C. Nicholas Hewitt  Dexter V.L. Hunt  Lubo Jankovic  Ian Jefferson  Joanne M. Leach  D. Rachel Lombardi  Christopher D.F. Rogers 《Global Environmental Change》2012,22(1):245-254

Scenarios are a useful tool to help think about and visualise the future and, as such, are utilised by many policymakers and practitioners. Future scenarios have not been used to explore the urban context in much depth, yet have the potential to provide valuable insights into the robustness of decisions being made today in the name of sustainability. As part of a major research project entitled Urban Futures, a toolkit has been developed in the UK to facilitate the use of scenarios in any urban context and at any scale relevant to that context. The toolkit comprises two key components, namely, (i) a series of indicators comprising both generic and topic area-specific indicators (e.g., air quality, biodiversity, density, water) that measure sustainability performance and (ii) a list of characteristics (i.e., 1–2-sentence statements about a feature, issue or small set of issues) that describe four future scenarios. In combination, these two components enable us to measure the performance of any given sustainability indicator, and establish the relative sensitivity or vulnerability of that indicator to the different future scenarios. An important aspect of the methodology underpinning the toolkit is that it is flexible enough to incorporate new scenarios, characteristics and indicators, thereby allowing the long-term performance of our urban environments to be considered in the broadest possible sense.  相似文献   

Effect of climate change and increased atmospheric CO2 on hydrological and nitrogen cycling in an intensive agricultural headwater catchment in western France     

Jordy Salmon-Monviola  Pierre Moreau  Cyril Benhamou  Patrick Durand  Philippe Merot  François Oehler  Chantal Gascuel-Odoux 《Climatic change》2013,120(1-2):433-447

Climate change and increased atmospheric CO₂ concentration can impact hydrological and nitrogen cycling at the catchment scale. The objective of this study is to assess these impacts in an intensive agricultural headwater catchment in western France. A calibrated and validated agro-hydrological model was driven by output of the climate model ARPEGE under the A1B emission scenario over 30-year simulation periods. Our study indicated that with climate warming and increased atmospheric CO₂, the main trends in water balance were a decrease in annual actual evapotranspiration (AET), a decrease in annual discharge and wetland extent, and a decrease in spring and summer of groundwater recharge and soil-water content. Not considering the effects of increased atmospheric CO₂ in the agro-hydrological model led to overestimating discharge decrease and underestimating AET decrease and wetland extent. Climate change could influence N cycling by increasing soil N mineralisation, increasing soil denitrification in wetlands and upstream areas, and decreasing NO₃–N load to streams. Since wetlands appear to be sensitive to climate change, improving modelling to better predict their responses is an important issue, especially to help plan sustainable management of these vulnerable areas.  相似文献   

Characterization of Oscillatory Motions in the Stable Atmosphere of a Deep Valley     

Yann Largeron  Chantal Staquet  Charles Chemel 《Boundary-Layer Meteorology》2013,148(3):439-454

In a valley sheltered from strong synoptic effects, the dynamics of the valley atmosphere at night is dominated by katabatic winds. In a stably stratified atmosphere, these winds undergo temporal oscillations, whose frequency is given by $N \sin {\alpha }$ N sin α for an infinitely long slope of constant slope angle $\alpha $ α , $N$ N being the buoyancy frequency. Such an unsteady flow in a stably stratified atmosphere may also generate internal gravity waves (IGWs). The numerical study by Chemel et al. (Meteorol Atmos Phys 203:187–194, 2009) showed that, in the stable atmosphere of a deep valley, the oscillatory motions associated with the IGWs generated by katabatic winds are distinct from those of the katabatic winds. The IGW frequency was found to be independent of $\alpha $ α and about $0.8N$ 0.8 N . Their study did not consider the effects of the background stratification and valley geometry on these results. The present work extends this study by investigating those effects for a wide range of stratifications and slope angles, through numerical simulations for a deep valley. The two oscillatory systems are reproduced in the simulations. The frequency of the oscillations of the katabatic winds is found to be equal to $N$ N times the sine of the maximum slope angle. Remarkably, the IGW frequency is found to also vary as $C_\mathrm{w}N$ C w N , with $C_\mathrm{w}$ C w in the range $0.7$ 0.7 – $0.95$ 0.95 . These values for $C_\mathrm{w}$ C w are similar to those reported for IGWs radiated by any turbulent field with no dominant frequency component. Results suggest that the IGW wavelength is controlled by the valley depth.  相似文献   

Water and nutrient predictions in ungauged basins: set-up and evaluation of a model at the national scale     

Johan Strömqvist  Berit Arheimer  Joel Dahné  Chantal Donnelly  Göran Lindström 《水文科学杂志》2013,58(2):229-247

Abstract

A dynamic water quality model, HYPE, was applied to a large, data-sparse region to study whether reliable information on water quantity and water quality could be obtained for both gauged and ungauged waterbodies. The model (called S-HYPE) was set up for all of Sweden (～450 000 km²), divided into sub-basins with an average area of 28 km². Readily available national databases were used for physiographic data, emissions and agricultural practices, fixed values for representative years were used. Daily precipitation and temperature were used as the dynamic forcing of the model. Model evaluation was based on data from several hundred monitoring sites, of which approximately 90% had not been used in calibration on a daily scale. Results were evaluated using the Nash-Sutcliffe efficiency (NSE), correlation and relative errors: 92% of the spatial variation was explained for specific water discharge, and 88% and 59% for total nitrogen and total phosphorus concentrations, respectively. Day-to-day variations were modelled with satisfactory results for water discharge and the seasonal variation of nitrogen concentrations was also generally well captured. In 20 large, unregulated rivers the median NSE for water discharge was 0.84, and the corresponding number for 76 partly-regulated river basins was 0.52. In small basins, the NSE was typically above 0.6. These major achievements relative to previous similar experiments were ascribed to the step-wise calibration process using representative gauged basins and the use of a modelling concept, whereby coefficients are linked to physiographic variables rather than to specific sites.

Editor D. Koutsoyiannis

Citation Strömqvist, J., Arheimer, B., Dahné, J., Donnelly, C. and Lindström, G., 2012. Water and nutrient predictions in ungauged basins: set-up and evaluation of a model at the national scale. Hydrological Sciences Journal, 57 (2), 229–247.  相似文献   

Isotope and trace element geochemistry of Colorado Plateau volcanics   总被引：5，自引：0，他引：5  

Chantal Alibert  Annie Michard  Francis Albarde 《Geochimica et cosmochimica acta》1986,50(12):2735-2750

Basalts from the San Francisco Peaks and North Rim of Grand Canyon, nephelinites from the Hopi Buttes and Navajo minettes (Colorado Plateau) have been analyzed for trace element contents and Sr, Nd, Pb isotope compositions. The ages increase eastward from the Quaternary (basalt) to 5 Ma (nephelinite) and 30 Ma (minette) as does the depth of melt generation inferred from xenolith mineralogy and major element geochemistry.

The three rock types present an enrichment of incompatible elements (although minettes present negative concentration spikes for Nb, Zr, Ti, Ba, Sr) relative to other magma types. The chondrite-normalized Ce/Yb ratio changes from 8–22 (basalt) to 25–30 (nephelinite) and 33–60 (minette) and reflects small degrees of partial melting of a mantle source with a garnet/clinopyroxene ratio increasing with depth. The negative Eu anomaly present in minette, the low Sr/Nd and high Pb/Ce suggest the presence of a recycled continental crust component in their mantle source.

The ⁸⁷Sr/⁸⁶Sr ratio varies from 0.7032-0.7045 (basalt and nephelinite) to 0.7052-0.7071 (minette), while ε_Nd is remarkably more constant at +0.8 to +3.7 (nephelinite) and −2.6 to +2.2 (basalt and minette). Good linear correlations are observed in both ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb diagrams with basalt being the least and nephelinite the most radiogenic and indicate a 2.3 ±0.1 Ga age and a Th/U of 3.4.

Three lithospheric source components are indicated: a) an OIB-type depleted mantle source, b) an end-member with unradiogenic Sr, Nd and Pb for basalt and nephelinite and c) a recycled crustal component for minette.  相似文献   

Aspects of stratospheric long-term changes induced by ozone depletion     

Chiara Cagnazzo  Chantal Claud  Sylvia Hare 《Climate Dynamics》2006,27(1):101-111

The effect of the stratospheric ozone depletion on the thermal and dynamical structure of the middle atmosphere is assessed using two 5-member ensembles of transient GCM simulations; one including linear trends in ozone, the other not, for the 1980–1999 period. Simulated temperatures and observations are in good agreement in terms of mean values, autocorrelations and cross correlations. Annual-mean and seasonal temperature trends have been calculated using the same statistical analysis. Simulations show that ozone trends are responsible for reduced wave activity in the Arctic lower stratosphere in February and March, confirming both the role of dynamics in controlling March temperatures and a recently proposed mechanism whereby Arctic ozone depletion causes the reduction in wave activity entering the lower stratosphere. Changes in wave activity are consistent with an intensification of the polar vortex at the time of ozone depletion and with a weakened Brewer–Dobson circulation: A decrease of the dynamical warming/cooling associated with the descending/ascending branch of the wintertime mean residual circulation at high/low latitudes has been obtained through the analysis of temperature observations (1980–1999). Ozone is responsible of about one third of the decrease of this dynamical cooling at high latitudes. An increase in the residual mean circulation is seen in the observations for the 1965–1980 period.  相似文献