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101.
A seismic study of a segment of the convergent margin of Ecuador is presented. During the SISTEUR campaign a network of 24 Ocean Bottom Seismometers (OBS) was deployed on the Carnegie Ridge, one line along the main axes of the ridge and two lines across the strike of the edge of the ridge, during one month. This marine network was complemented with a land network of 20 stations distributed in two lines: one parallel to the margin and the other perpendicular to it.The seismic event recorded by these networks, were located using different crustal models defined from the wide-angle seismic data modeling. Relative location techniques were used to improve earthquake locations. Seismogram waveform modeling allowed us to constrain hypocentral location for events farther than ~50 km from the network. This modeling also provided additional information to constrain the focal mechanisms of these events. The upper limit of the Interplate Seismogenic Zone (ISZ) is estimated to be at a 10 km depth in the region. The background seismic activity of the upper plate provided new insights:1) A seismic cluster that reaches the base of the overriding plate is linked to the Jipijapa-Portoviejo fault. The reactivation of this Quaternary fault is confirmed by focal mechanisms that provide rupture planes parallel to its superficial projection (N10°–N25°).2) The focal mechanisms presented in this study are compatible with a homogeneous regional stress field corresponding to an E–W to ESE–WNW compression and an NNE–SSW extension. The presence of strike-slip deformation, with a reverse component, corresponds to the NNE escape of the North Andean Block. Normal faulting accommodating this movement suggests that this part of the North Andean Block cannot be considered as a rigid block.  相似文献   
102.
103.
Rare earth elements (REE) were analyzed in surface sediments from the Guadiana Estuary (SW Iberian Pyrite Belt). NASC (North American Shale Composite) normalized REE patterns show clearly convex curvatures in middle-REE (MREE) with respect to light- and heavy-REE, indicating acid-mixing processes between fluvial waters affected by acid mine drainage (AMD) and seawater. However, REE distributions in the mouth (closer to the coastal area) show slightly LREE-enriched and flat patterns, indicating saline-mixing processes typical of the coastal zone. NASC-normalized ratios (La/Gd and La/Yb) do not discriminate between both mixing processes in the estuary. Instead, a new parameter (E(MREE)) has been applied to measure the curvature in the MREE segment. The values of E(MREE)>0 are indicative of acid signatures and their spatial distribution reveal the existence of two decantation zones from flocculation processes related to drought periods and flood events. Studying REE fractionation through the E(MREE) may serve as a good proxy for AMD-pollution in estuarine environments in relation to the traditional methods.  相似文献   
104.
The European Union Water Framework Directive (WFD), a new regulation aiming to achieve and maintain a clean and well-managed water environment, refers to phytoplankton as one of the biological quality elements that should be regularly monitored, and upon which the reference conditions of water quality should be established. However, the use of phytoplankton as a biological quality element will result in several constraints, which are analyzed in this article with examples from Portuguese waters. Specifically, the establishment of reference conditions of water quality may be difficult in some water bodies for which no historical data exists. The sampling frequency proposed for phytoplankton monitoring does not seem suitable to assess phytoplankton succession, and may preclude the detection of algal blooms. Finally, the use of chlorophyll a as a proxy of phytoplankton biomass and abundance has been proposed by some authors, but it may overlook blooms of pico- and small nanophytoplankton, and overestimate the importance of large microphytoplankton. Furthermore, most studies in Portugal have used only inverted microscopy for phytoplankton observation and quantification; this method does not permit the distinction between autotrophic and heterotrophic cells, especially in samples preserved with Lugol's solution, and does not allow the observation of smaller-sized cells. Finally, some techniques, such as remote sensing and chemotaxonomic analysis, are proposed to be used as supplements in phytoplankton monitoring programs.  相似文献   
105.
New data collected along the slopes of Little and Great Bahama Bank and the abyssal plain of the Bahama Escarpment provides new insights about contour current‐related erosive structures and associated deposits. The Bahamian slope shows abundant evidence of bottom current activity such as furrows, comet‐like structures, sediment waves and drifts. At a seismic scale, large erosion surfaces and main periods of drift growth resulted from current acceleration related to plate tectonic processes and progressive opening and closure of gateways and long‐term palaeoclimate evolution. At present‐day, erosion features and contourite drifts are either related to relatively shallow currents (<1000 m water depth) or to deep currents (>2500 m water depth). It appears that the carbonate nature of the drifts does not impact the drift morphology at the resolution addressed in the present study. Classical drift morphologies defined in siliciclastic environments are found, such as mounded, plastered and separated drifts. In core, contourite sequences show a bi‐gradational trend that resembles classical contourite sequences in siliciclastic deposits showing a direct relationship with a change in current velocity at the sea floor. However, in a carbonate system the peak in grain size is associated with increased winnowing rather than increased sediment supply as in siliciclastic environments. In addition, the carbonate contourite sequence is usually thinner than in siliciclastics because of lower sediment supply rates. Little Bahama Bank and Great Bahama Bank contourites contain open‐ocean input and slope‐derived debris from glacial episodes. Inner platform, platform edge and open ocean pelagic input characterize the classical periplatform ooze during interglacials. In all studied examples, the drift composition depends on the sea floor topography surrounding the drift location and the type of sediment supply. Carbonate particles are derived from either the slope or the platform in slope and toe of slope drifts, very deep contourites have distant siliciclastic sources of sediment supply. The recent discovery of the importance of a large downslope gravitary system along Bahamian slopes suggests frequent interactions between downslope and along‐slope (contour currents) processes. The interlayering of mass flow deposits and contourites at a seismic scale or the presence of surface structures associated with both contour currents and mass flow processes shows that both processes act at the same location. Finally, contour currents have an important impact on the repartition of deep‐water coral mounds. Currents can actively interact with mounds as a nutrient and oxygen supplier or have a passive interaction, with mounds solely being obstacles orienting erosion and deposition.  相似文献   
106.
The production of biosolids in three Spanish wastewater treatment plants (WWTPs) has been investigated. Biosolids produced from the treatment of urban wastewater in Spain are usually intended for agricultural use. The reliable production of biosolids mainly depends on both the quantity of suspended solids and the organic load influent to the treatment systems. The quality of the generated biosolids was independent of both the amount of treated water and the treatment process applied, with 20 to 25% dried matter, and 60 to 75%, 7% and 4% of organic matter, N and P, respectively, of the total matter. The biosolids contained ca. 11 to 19 g/kg of total metals in the dry matter, with Fe, Zn, Cu and Mn representing 97% of all of the metals present, and Hg being the minority metal. Such biosolids had the ability to concentrate the organic matter and metals from the wastewater up to 417 and 869 times, respectively, and thus, can be used in agricultural practice.  相似文献   
107.
Mangrove water biogeochemistry has been frequently studied under tropical climates, but less is known regarding mangroves in semi-arid climates. In this study, we examine the carbon and nutrient biogeochemistry in a mangrove tidal creek and in the main branch of a semi-arid estuary in New Caledonia. Porewater seepage represents a source of nutrients (DON, NH4 +, and DIP), carbon (DOC and CO2), and alkalinity for the water column, but seawater dilution of the mangrove inputs is observed. Spatial and tidal variations in CO2 fluxes along the tidal creek suggest that porewater seepage is a driver of CO2 emission into the atmosphere. Large seasonal and spatial differences in the biogeochemical functioning of the main channel are observed and are mainly related to the seasonal rainfall pattern. During the rainy season, the watershed influences the entire estuary, which exhibits a typical positive circulation. During the dry season, the estuary turns into a salt-plug region with positive and negative circulations in the upper and lower reaches, respectively. In this case, the upper and lower reaches seem to function independently, and the biogeochemical functioning of their water column is not controlled by the same processes. Surprisingly, pCO2@27 °C values tend to be higher during the dry season, as do the total alkalinity (TAlk) values, while the pH values exhibit an opposite trend. Moreover, the TAlk values are higher in the lower reaches during the wet season and in the upper reaches during the dry season. These results indicate high in situ biogeochemical reactions and high porewater influence during the dry season, likely because of a low flushing rate and high water residence time after salt plug establishment. Although our results suggest that salt plugs may significantly affect the water column’s biogeochemistry and may promote CO2 emissions of mangrove-derived carbon, further investigations, especially mass balance studies, are required to quantify their role in the biogeochemical functioning of such estuarine systems.  相似文献   
108.
Estuaries are one of the most threatened ecosystems, with a great number of stressors related to pollution, hydromorphological changes, and invasive species. However, the response of the biological indicators proposed for their ecological status assessment is not always well established. When using estuarine vegetation (saltmarshes and seagrasses) as an indicator, there are several theoretical concepts regarding the relationships between the variations of this indicator and hydromorphological stressors. It is precisely these relationships which are presented in this work. To carry out this objective, based on the first intercalibration process, a set of metrics for saltmarsh and seagrass taxonomic compositions (e.g., loss of number of taxa and richness) and abundance (e.g., relative coverage and relative extent) have been selected and applied to different estuaries located in Northern Spain. Additionally, a methodology for the hydromorphological status assessment, based on the analysis of the anthropogenic changes in the hydrodynamic and morphological estuarine characteristics (e.g., the extension of land claim areas or changes in the estuarine perimeter), has been developed and applied to these transitional water bodies in order to find a gradient of pressured sites in which we seek correlations between the vegetation metrics and hydromorphological stressors. As a result, the response of the different vegetation indicators is variable. In some cases, a negative correlation of the indicator with the pressure degree exists, whereas in other cases, the relationship is not as clear. Nonetheless, according to the results, it can be suggested that the placing of anthropogenic structures diminishes the quality of the estuarine vegetation. Therefore, to maintain a suitable environment for the estuarine vegetation seems necessary in order to reduce the number of the hydrodynamic structures which are no longer in use.  相似文献   
109.
We present high‐precision measurements of the Mg isotopic compositions of a suite of types I and II chondrules separated from the Murchison and Murray CM2 carbonaceous chondrites. These chondrules are olivine‐ and pyroxene‐rich and have low 27Al/24Mg ratios (0.012–0.316). The Mg isotopic compositions of Murray chondrules are on average lighter (δ26Mg ranging from ?0.95‰ to ?0.15‰ relative to the DSM‐3 standard) than those of Murchison (δ26Mg ranging from ?1.27‰ to +0.77‰). Taken together, the CM2 chondrules exhibit a narrower range of Mg isotopic compositions than those from CV and CB chondrites studied previously. The least‐altered CM2 chondrules are on average lighter (average δ26Mg = ?0.39 ± 0.30‰, 2SE) than the moderately to heavily altered CM2 chondrules (average δ26Mg = ?0.11 ± 0.21‰, 2SE). The compositions of CM2 chondrules are consistent with isotopic fractionation toward heavy Mg being associated with the formation of secondary silicate phases on the CM2 parent body, but were also probably affected by volatilization and recondensation processes involved in their original formation. The low‐Al CM2 chondrules analyzed here do not exhibit any mass‐independent variations in 26Mg from the decay of 26Al, with the exception of two chondrules that show only small variations just outside of the analytical error. In the case of the chondrule with the highest Al/Mg ratio (a type IAB chondrule from Murchison), the lack of resolvable 26Mg excess suggests that it either formed >1 Ma after calcium‐aluminum‐rich inclusions, or that its Al‐Mg isotope systematics were reset by secondary alteration processes on the CM2 chondrite parent body after the decay of 26Al.  相似文献   
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