Microscopy and rock magnetism of fine grain-size titanomagnetite from the Jacupiranga Alkaline Complex,Brazil: unearthing Ti-magnesioferrite nanoparticles     

Luis M. Alva-Valdivia  María de la Luz Rivas-Sánchez  Jesús Arenas-Alatorre  Avto Goguitchaishvili  Omar Ferreira Lopes 《Geofísica Internacional》2013,52(2):93-110

Very fine samples from the mineralized zones of the Jacupiranga complex at the Cajati mine were selected for crystallographic identification of Ti-magnesioferrite (TMf) nanostructures embedded in titanomagnetite (TM) using high-resolution transmission electron microscopy (TEM). A magnetic concentrate obtained of pyroxenite samples (sites 4 to 7) was reduced and divided into fractions of distinct range sizes: 26±2 μm, 19±1 μm, 13±1 μm, 9±1 μm, 6±1 μm and 6-0.1 μm. The mineralized samples of carbonatite and pyroxenite were characterized by X-ray diffraction, transmitted and reflected light microscope, and scanning electron microscope with multielemental analysis. The finest magnetic concentrate sample (MC₆) was analyzed under high-resolution transmitted electron microscopy (TEM) and high angle annular dark field and Raman spectroscopy. Magnetic properties were measured for the distinct granulometric fractions, showing drastic changes when grain sizes go beyond the frontier from micro to nanometer sizes. Frequency-dependent magnetic susceptibility percentage (÷_fd%) report higher values (10.2%) for the finer fractions (6±1 μm and 6-0.1 μm) attributed to dominant fractions of superparamagnetic particles. Nanometer and < 6 μm grain size TMf in TM particles require a magnetic field up to 249 mT to reach saturation during the isothermal remanent magnetization experiment. Coercivity and remanent magnetization of these samples increase when the particle size decreases, probably due to parallel coupling effects. Magnetic susceptibility versus temperature experiments were conducted two times on the same (< 35 nm) sample, showing that the repetition during the second heating is probably due to the formation of new TMf nanoparticles and growth of those already present during the first heating process.  相似文献   

Geological and anthropogenic influences on sediment metal composition in the upper Paracatu River Basin, Brazil   总被引：1，自引：1，他引：0  

Daniel Santos Mulholland  Geraldo Resende Boaventura  Daniel Ferreira Araújo 《Environmental Earth Sciences》2012,67(5):1307-1317

This work reports a geochemical study of sediments from the upper Paracatu River Basin. The objective is to define the influences of Au, Zn, and Pb mineral deposits and mining activities on the sediment metal sources, distribution, and accretion. The samples were analyzed using ICP/OES, AAS, and XRD techniques and were treated with principal components analysis and the geo-accumulation index. The main geochemical processes that control the sediment composition are pyrite oxidation, muscovite weathering, carbonate dissolution, and the erosion of oxisols enriched with Zn and Pb. The upper Rico Stream has high Al, Fe, Cu, Cr, Co, and Mn concentrations due erosion of oxisols and pyrite oxidation and muscovite alteration present in the parental rock. The artisanal alluvial gold mining increased the primary rock-minerals?? weathering and Hg sediment concentration. The lower Escuro River and Santa Catarina Stream are enriched with Zn and Pb due the erosion of metal-rich soils formed over galena, sphalerite, calamine, and willemite mineral deposits located upstream. Elements such as Ca, Mg, and Ba have low concentrations throughout the sampled area due the high solubility of these metals-bearing minerals. The dispersion of metals is limited by the basin geomorphology and their affinity to silt-clayey minerals and Fe and Mn oxides and hydroxides in circumneutral pH waters.  相似文献   

Ontogenic shifts in predatory roles involving two invasive species     

Pedro Manuel Anastácio  Emília Pereira Leite  Margarida Ferreira  Luís Vicente  Alexandra Marçal Correia 《Limnologica》2011,41(3):228-234

The red swamp crayfish, Procambarus clarkii, and the eastern mosquitofish, Gambusia holbrooki have been introduced worldwide, but the interactions between these invasive species are not well known. The effects of crayfish presence, crayfish size and water depth on the consumption of G. holbrooki by P. clarkii were analyzed, as were the effects of mosquitofish presence and water depth on the consumption of recently hatched crayfish (RHC) by mosquitofish. To better understand this subject we conducted aquaria and open air mesocosm experiments simulating a rice field section. Aquarium experiments showed that P. clarkii consumes G. holbrooki and that G. holbrooki consumes RHC. Adult crayfish size did not significantly affect the consumption of mosquitofish and water depth had no effect on the consumption of G. holbrooki by P. clarkii and vice versa. In the outdoor mesocosm experiments P. clarkii caused no statistically significant effect on G. holbrooki numbers or biomass when compared with controls without crayfish. In spite of this, the analysis of crayfish stomach contents clearly demonstrated that several G. holbrooki individuals were consumed, indicating that crayfish can profit from the presence of G. holbrooki. Results from our study suggest that in shallow pools there are strong interactions between the two invasive species since adult crayfish predate mosquitofish and mosquitofish predate recently hatched crayfish. Therefore, there are bidirectional trophic interactions between these invasive species which change depending on their relative size. We believe that these interactions should become more relevant in confined areas such as small shallow pools formed during the late summer and autumn.  相似文献   

Pathogenic fungi: an unacknowledged risk at coastal resorts? New insights on microbiological sand quality in Portugal     

Sabino R  Veríssimo C  Cunha MA  Wergikoski B  Ferreira FC  Rodrigues R  Parada H  Falcão L  Rosado L  Pinheiro C  Paixão E  Brandão J 《Marine pollution bulletin》2011,62(7):1506-1511

Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci.  相似文献   

Estuarine ecological risk based on hepatic histopathological indices from laboratory and in situ tested fish     

Costa PM  Caeiro S  Lobo J  Martins M  Ferreira AM  Caetano M  Vale C  DelValls TÁ  Costa MH 《Marine pollution bulletin》2011,62(1):55-65

Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments.  相似文献   

Monitoring estuaries using non-permanent stations: practical aspects and data examples     

Erwan Garel  ��scar Ferreira 《Ocean Dynamics》2011,61(7):891-902

This paper deals with the performances of non-permanent environmental monitoring stations when recording at high-sampling interval (hour) over a long term (months, years) within estuarine waters. Information about data quality and system maintenance requirements are provided based on the experience gained with an autonomous station deployed during 2?years at the Guadiana Estuary (southern Portugal–Spain border). The station includes (1) a multi-parameter probe for water quality (temperature, conductivity, dissolved oxygen, turbidity, chlorophyll and pH) inserted in a tube through a surface-floating buoy; and, (2) a bottom-mounted current meter. The main issues for the continuous acquisition of valid data were biofouling on the optical (chlorophyll, turbidity, dissolved oxygen), conductivity sensors of the probe and high sediment dynamics at the bed. The definition of a detailed maintenance programme is required for the lengthening of (valid) data time series. The typical variability of the parameters is described at seasonal and tidal time scales and episodic events are identified (coastal upwelling and high freshwater inputs). These examples illustrate how integrated data analysis is fundamental to define and understand the changes induced by specific events on several interrelated parameters, and, more generally, how these systems can contribute to a better understanding of the hydro-ecological processes operating in estuaries.  相似文献   

Isotope geochemistry of Paleoproterozoic metacarbonates from Itatuba,Borborema Province,Northeastern Brazil: Evidence of marble melting within a collisional suture     

Roberto Ventura Santos  Edilton J. dos Santos  João Adauto de Souza Neto  Luis Christian Montreuil Carmona  Alcides Nóbrega Sial  Luis Henrique Mancini  Lauro Cézar Montefalco de Lira Santos  Gilzênia Henrique do Nascimento  Lucas UpaDafubigin Santos Mendes  Emerson Marcello Ferreira Anastácio 《Gondwana Research》2013,23(1):380-389

Strongly-deformed marbles may be easily confused with linear and elongated carbonatite intrusions. Both rocks may present similar texture and foliation to the host rock, or even cross cutting field relationships, which could be interpreted either as igneous or high-grade metamorphosed marble. Diagnostic criteria are even more complex when there is evidence of melting of the metasedimentary carbonate rock, such as has been described in the Himalayas and in the Eastern Ghats, India.In the Alto Moxotó Terrane, a high-grade gneissic domain of the Borborema Province, Northeastern Brazil, there are metacarbonates associated with banded gneisses and different metaplutonic rocks. Field evidence indicates the absence of other metasedimentary rocks associated with these marbles, thus suggesting that these carbonates were separated from other siliciclastic metasedimentary rocks. The presence of marble also suggests that it may represent the initial stage of a crustal carbon recycling into the mantle. These marbles present many field similarities to carbonatites (e.g., fluid-flow structure) and, together with metagranites and metamafic intrusions, may represent a major collisional tectonic suture.A detailed study of the carbon, oxygen and strontium isotopic composition of these marbles is presented. This study aims to identify the origin of the different isotopic components. It is argued that these rocks were subjected to temperature and pressure conditions that were sufficiently high to have melted them. The isotopic data presented here support this interpretation and indicate the mixing of two components: (i) one characterized by radiogenic Sr isotopes and mantle-like carbon isotopes, which is associated with the gneissic and mafic rocks, and (ii) another characterized by low ⁸⁷Sr/⁸⁶Sr ratios and highly positive δ¹³C values. Available geochemical data for the upper Paleoproterozoic indicate that the ⁸⁷Sr/⁸⁶Sr ratio of ocean water, varying between 0.7050 (2.25 ± 0.25 Ga) and 0.7047 (1.91 Ga), falls within the lower range of the samples from Itatuba and thus reinforces the interpretation that these marbles are sedimentary-derived and were partially contaminated by interaction with the host gneissic and mafic rocks.  相似文献   

Seasonal Diet Shifts and Overlap Between Two Sympatric Catfishes in an Estuarine Nursery     

David Valença Dantas  Mario Barletta  Jonas de Assis Almeida Ramos  André Ricardo Araújo Lima  Monica Ferreira da Costa 《Estuaries and Coasts》2013,36(2):237-256

This study describes the seasonal feeding habits of different size classes of Cathorops spixii and Cathorops agassizii along an estuarine ecocline and the food overlap when different size classes occur together. These species were essentially zoobenthivorous, feeding mainly on Polychaeta Nereis sp., Copepoda Pseudodiaptomus acutus, Ostracoda Asterope sp., Gastropoda: Littorinidae, and Bivalvia Mytilus sp. and Anomalocardia brasiliana. However, during their life cycle and between different habitats and seasons, their trophic guild can change to zooplanktivore. The competition for resources was observed among C. spixii and C. agassizii, but was significantly reduced due to the seasonal diference in habitat use by different ontogenetic phases in the main channel of the estuary. The food niche separation was strongly influenced by environmental fluctuations, principally of salinity, resulting from rainfall and river inflow. High abundance of some preys, such as P. acutus (all estuary), Asterope sp. (upper and middle estuary), and Littorinidae (upper and lower estuary), could influence the significant diet overlap, principally during the rainy season, and call for more detailed studies of the benthic community structure. Moreover, dietary overlap was observed mainly between smaller sizes (intraspecific and/or interspecific) or between corresponding ontogenetic phases (interspecific), suggesting some differentiation in the diet in relation to the size class. Differences in prey type and size between the different ontogenetic phases of these ariids, principally among juveniles and adults, could be related to the size of the mouth, since adults are able to successfully capture larger preys or larger quantities of particular items.  相似文献   

Overview of integrative tools and methods in assessing ecological integrity in estuarine and coastal systems worldwide   总被引：9，自引：1，他引：8  

Borja A  Bricker SB  Dauer DM  Demetriades NT  Ferreira JG  Forbes AT  Hutchings P  Jia X  Kenchington R  Carlos Marques J  Zhu C 《Marine pollution bulletin》2008,56(9):1519-1537

In recent years, several sets of legislation worldwide (Oceans Act in USA, Australia or Canada; Water Framework Directive or Marine Strategy in Europe, National Water Act in South Africa, etc.) have been developed in order to address ecological quality or integrity, within estuarine and coastal systems. Most such legislation seeks to define quality in an integrative way, by using several biological elements, together with physico-chemical and pollution elements. Such an approach allows assessment of ecological status at the ecosystem level ('ecosystem approach' or 'holistic approach' methodologies), rather than at species level (e.g. mussel biomonitoring or Mussel Watch) or just at chemical level (i.e. quality objectives) alone. Increasing attention has been paid to the development of tools for different physico-chemical or biological (phytoplankton, zooplankton, benthos, algae, phanerogams, fishes) elements of the ecosystems. However, few methodologies integrate all the elements into a single evaluation of a water body. The need for such integrative tools to assess ecosystem quality is very important, both from a scientific and stakeholder point of view. Politicians and managers need information from simple and pragmatic, but scientifically sound methodologies, in order to show to society the evolution of a zone (estuary, coastal area, etc.), taking into account human pressures or recovery processes. These approaches include: (i) multidisciplinarity, inherent in the teams involved in their implementation; (ii) integration of biotic and abiotic factors; (iii) accurate and validated methods in determining ecological integrity; and (iv) adequate indicators to follow the evolution of the monitored ecosystems. While some countries increasingly use the establishment of marine parks to conserve marine biodiversity and ecological integrity, there is awareness (e.g. in Australia) that conservation and management of marine ecosystems cannot be restricted to Marine Protected Areas but must include areas outside such reserves. This contribution reviews the current situation of integrative ecological assessment worldwide, by presenting several examples from each of the continents: Africa, Asia, Australia, Europe and North America.  相似文献   

Spatial distribution of sedimentary linear alkylbenzenes and faecal steroids of Santos Bay and adjoining continental shelf, SW Atlantic, Brazil: origin and fate of sewage contamination in the shallow coastal environment   总被引：1，自引：0，他引：1  

Martins CC  Ferreira JA  Taniguchi S  Mahiques MM  Bícego MC  Montone RC 《Marine pollution bulletin》2008,56(7):1359-1363

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