Denitrification coupled to pyrite oxidation and changes in groundwater quality in a shallow sandy aquifer     

Yan-Chun Zhang  Caroline P. Slomp  Hilde F. Passier 《Geochimica et cosmochimica acta》2009,73(22):6716-6726

This study focuses on denitrification in a sandy aquifer using geochemical analyses of both sediment and groundwater, combined with groundwater age dating (³H/³He). The study sites are located underneath cultivated fields and an adjacent forested area at Oostrum, The Netherlands. Shallow groundwater in the region has high nitrate concentrations (up to 8 mM) due to intense fertilizer application. Nitrate removal from the groundwater below cultivated fields correlates with sulfate production, and the release of dissolved Fe²⁺ and pyrite-associated trace metals (e.g. As, Ni, Co and Zn). These results, and the presence of pyrite in the sediment matrix within the nitrate removal zone, indicate that denitrification coupled to pyrite oxidation is a major process in the aquifer. Significant nitrate loss coupled to sulfate production is further confirmed by comparing historical estimates of regional sulfate and nitrate loadings to age-dated groundwater sulfate and nitrate concentrations, for the period 1950-2000. However, the observed increases in sulfate concentration are about 50% lower than would be expected from complete oxidation of pyrite to sulfate, possibly due to the accumulation of intermediate oxidation state sulfur compounds, such as elemental sulfur. Pollutant concentrations (NO₃, Cl, As, Co and Ni) measured in the groundwater beneath the agricultural areas in 1996 and 2006 show systematic decreases most likely due to declining fertilizer use.  相似文献   

Numerical Simulation of a Solar Active Region. I: Bastille Day Flare     

Alain Vincent  Paul Charbonneau  Caroline Dubé 《Solar physics》2012,278(2):367-391

We present three-dimensional unsteady modeling and numerical simulations of a coronal active region, carried out within the compressible single-fluid MHD approximation. We focus on AR 9077 on 14 July 2000, and the triggering of the X5.7 GOES X-ray class “Bastille Day” flare. We simulate only the lower corona, although we include a virtual photosphere and chromosphere below. The boundary conditions at the base of this layer are set using temperature maps from line intensities and line-of-sight magnetograms (SOHO/MDI). From the latter, we generate vector magnetograms using the force-free approximation; these vector magnetograms are then used to produce the boundary condition on the velocity field using a minimum energy principle (Longcope, Astrophys. J. 612, 1181, 2004). The reconnection process is modeled through a dynamical hyper-resistivity which is activated when the current exceeds a critical value (Klimas et al., J. Geophys. Res. 109, 2218, 2004). Comparing the time series of X-ray fluxes recorded by GOES with modeled time series of various mean physical variables such as current density, Poynting energy flux, or radiative loss inside the active region, we can demonstrate that the model properly captures the evolution of an active region over a day and, in particular, is able to explain the initiation of the flare at the observed time.  相似文献   

Best practices for the use of meteorite names in publications     

Philipp R. Heck  Christopher Herd  Jeffrey N. Grossman  Dmitry Badjukov  Audrey Bouvier  Emma Bullock  Hasnaa Chennaoui‐Aoudjehane  Vinciane Debaille  Tasha L. Dunn  Denton S. Ebel  Ludovic Ferrire  Laurence Garvie  Jrme Gattacceca  Matthieu Gounelle  Richard Herd  Trevor Ireland  Emmanuel Jacquet  Robert J. Macke  Tim McCoy  Francis M. McCubbin  Takashi Mikouchi  Knut Metzler  Mathieu Roskosz  Caroline Smith  Meenakshi Wadhwa  Linda Welzenbach‐Fries  Toru Yada  Akira Yamaguchi  Ryan A. Zeigler  Michael Zolensky 《Meteoritics & planetary science》2019,54(7):1397-1400

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Fracturing and fluid‐flow during post‐rift subsidence in carbonates of the Jandaíra Formation,Potiguar Basin,NE Brazil          下载免费PDF全文

Giovanni Bertotti  Kevin Bisdom  Brigit Oskam  Hubert B. Vonhof  Francisco H. R. Bezerra  Caroline L. Cazarin 《Basin Research》2017,29(6):836-853

Pervasive fracture networks are common in many reservoir‐scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates deposited during the early post‐rift stage of the Potiguar rift (NE Brazil). The Jandaíra Formation in the present onshore domain experienced <1.5 km thermal subsidence and, following Tertiary exhumation, forms outcrops over an area of >1000 km². The carbonates have a gentle, <5?, dip to the NE and are affected by few regional, low displacement faults or folds. Despite their simple tectonic history, carbonates display ubiquitous open fractures, sub‐vertical veins, and sub‐vertical as well as sub‐horizontal stylolites. Combining structural analysis, drone imaging, isotope studies and mathematical modelling, we reconstruct the fracturing history of the Jandaíra Formation during and following subsidence and analyse the impact fractures had on coeval fluid flow. We find that Jandaíra carbonates, fully cemented after early diagenesis, experienced negligible deformation during the first few hundreds of meters of subsidence but were pervasively fractured when they reached depths >400–500 m. Deformation was accommodated by a dense network of sub‐vertical mode I and hybrid fractures associated with sub‐vertical stylolites developed in a stress field characterised by a sub‐horizontal σ₁ and sub‐vertical σ₂. The development of a network of hybrid fractures, rarely reported in the literature, activated the circulation of waters charged in the mountainous region, flowing along the porous Açu sandstone underlying the Jandaíra carbonates and rising to the surface through the fractured carbonates. With persisting subsidence, carbonates reached depths of 800–900 m entering a depth interval characterised by a sub‐vertical σ₁. At this stage, sub‐horizontal stylolites developed liberating calcite which sealed the sub‐vertical open fractures transforming them in veins and preventing further flow. During Tertiary exhumation, several of the pre‐existing veins and stylolites opened and became longer, and new fractures were created typically with the same directions of the older features. The simplicity of our model suggests that most rocks in passive margin settings might have followed a similar evolution and thus display similar structures.  相似文献   

A rational method for development of limit state for liquefaction evaluation based on shear wave velocity measurements     

C. Hsein Juang  Caroline J. Chen 《国际地质力学数值与分析法杂志》2000,24(1):1-27

This papers presents a new approach for developing a limit state for liquefaction evaluation based on field performance data. As an example to illustrate the new approach, a database that consists of, among many other features, in situ shear wave velocity measurements and field observations of liquefaction/non‐liquefaction in historic earthquakes is analysed. This database is first used to train a neural network to classify liquefaction/non‐liquefaction based on soil resistance parameters and load parameters. The successfully trained and tested neural network is then used to establish a limit state, a multiple dimension boundary that separates ‘zone’ of liquefaction from ‘zone’ of non‐liquefaction. The limit state yields cyclic resistance ratio for a given set of soil resistance parameters. Examination of all cases in the database show that the developed limit state has a high degree of accuracy in predicting the occurrence of liquefaction/non‐liquefaction. The developed neural network model can accurately predict the cyclic resistance ratio of soils. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Albini,Paola: the great 1667 Dalmatia earthquake. An in-depth case study     

Caroline Finkel 《Journal of Seismology》2017,21(5):1291-1293

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Surficial fractures in the Navajo sandstone,south-western USA: the roles of thermal cycles,rainstorms, granular disintegration,and iterative cracking     

David B. Loope  Garrison R. Loope  Caroline M. Burberry  Clinton M. Rowe  Gerald C. Bryant 《地球表面变化过程与地形》2020,45(9):2063-2077

Deep (> 5 m) sheeting fractures in the Navajo sandstone are evident at numerous sites in southern Utah and derive from tectonic stresses. Strong diurnal thermal cycles are, however, the likely triggers for shallow (< 0.3 m) sheeting fractures. Data from subsurface thermal sensors reveal that large temperature differences between sensors at 2 and 15 cm depth on clear summer afternoons are as great as those that trigger sheeting fractures in exposed California granite. Extensive polygonal patterns in the Navajo sandstone are composed of surface-perpendicular fractures and were produced by contractile stresses. Numerous studies have shown that porewater diminishes the tensile strength of sandstone. Based on our thermal records, we propose that cooling during monsoonal rainstorms triggers polygonal fracturing of temporarily weakened rock. On steep outcrops, polygonal patterns are rectilinear and orthogonal, with T-vertices. Lower-angle slopes host hexagonal patterns (defined by the dominance of Y-vertices). Intermediate patterns with rectangles and hexagons of similar scale are common. We posit that outcropping fractures are advancing downward by iterative steps, and that hexagons on sandstone surfaces (like prismatic columns of basalt) have evolved from ancestral orthogonal polygons of similar scale. In lava flows, fractures elongate intermittently as they follow a steep thermal gradient (the source of stress) as it rapidly moves through the rock mass. In our model, a steep, surficial thermal gradient descends through unfractured sandstone, but at the slow pace of granular disintegration. Through time, as the friable rock on stable slopes erodes, iterative cracking advances into new space. Hexagonal patterns form as new fractures, imperfectly guided by the older ones, propagate in new directions, and vertices drift into a configuration that minimizes the ratio of fracture length to polygon area. © 2020 John Wiley & Sons, Ltd.  相似文献   

Tidal response to sea level rise and bathymetric changes in the German Wadden Sea     

Wachler  Benno  Seiffert  Rita  Rasquin  Caroline  Kösters  Frank 《Ocean Dynamics》2020,70(8):1033-1052

Ocean Dynamics - Tidally dominated coasts are directly affected not only by projected rise in mean sea level, but also by changes in tidal dynamics due to sea level rise and bathymetric changes. By...  相似文献   

Simultaneous LC–MS/MS Determination of Imidazolinone Herbicides Together with Other Multiclass Pesticide Residues in Soil          下载免费PDF全文

Gisele L. Martins  Caroline A. Friggi  Osmar D. Prestes  Michele C. Vicari  Daniela A. Friggi  Martha B. Adaime  Renato Zanella 《洁净——土壤、空气、水》2014,42(10):1441-1449

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Surface wave array tomography in SE Tibet from ambient seismic noise and two-station analysis – II. Crustal and upper-mantle structure     

Huajian Yao  Caroline Beghein  Robert D. van der Hilst 《Geophysical Journal International》2008,173(1):205-219

We determine the 3-D shear wave speed variations in the crust and upper mantle in the southeastern borderland of the Tibetan Plateau, SW China, with data from 25 temporary broad-band stations and one permanent station. Interstation Rayleigh wave (phase velocity) dispersion curves were obtained at periods from 10 to 50 s from empirical Green's function (EGF) derived from (ambient noise) interferometry and from 20 to 150 s from traditional two-station (TS) analysis. Here, we use these measurements to construct phase velocity maps (from 10 to 150 s, using the average interstation dispersion from the EGF and TS methods between 20 and 50 s) and estimate from them (with the Neighbourhood Algorithm) the 3-D wave speed variations and their uncertainty. The crust structure, parametrized in three layers, can be well resolved with a horizontal resolution about of 100 km or less. Because of the possible effect of mechanically weak layers on regional deformation, of particular interest is the existence and geometry of low (shear) velocity layers (LVLs). In some regions prominent LVLs occur in the middle crust, in others they may appear in the lower crust. In some cases the lateral transition of shear wave speed coincides with major fault zones. The spatial variation in strength and depth of crustal LVLs suggests that the 3-D geometry of weak layers is complex and that unhindered crustal flow over large regions may not occur. Consideration of such complexity may be the key to a better understanding of relative block motion and patterns of seismicity.  相似文献