Texture development of polycrystalline anhydrite experimentally deformed in torsion     

Florian Heidelbach  Iona C. Stretton  Karsten Kunze 《International Journal of Earth Sciences》2001,90(1):118-126

A polycrystalline aggregate of anhydrite was deformed in torsion to a maximum shear strain of 8.1 at 700°C and a maximum shear strain rate of 5᎒^-3 s^-1. The crystallographic preferred orientation (CPO or texture) was investigated as a function of shear strain/shear strain rate in a radial profile from the centre to the edge of the sample. A deformation texture developed at shear strains of 1.5-2 (corresponding to shear strain rates of 1 to 1.3᎒^-3 s^-1) and reached a stable position relative to the kinematic frame at a shear strain of 3.7 (2.3᎒^-3 s^-1). Further shear strain only led to a small increase in texture strength but no change in the orientation relative to the kinematic frame. The CPO is very similar to naturally observed textures and can be explained by the activity of the {001}<010> and {012}<121> slip systems. Although independent mechanical data indicate that a change of mechanism from dislocation- to diffusion-controlled creep occurred at a shear strain of approximately 1.5, the texture does not weaken, but rather increases, in strength with higher shear strains.  相似文献   

Model for kinetic effects on calcium isotope fractionation (δCa) in inorganic aragonite and cultured planktonic foraminifera     

Nikolaus Gussone  Alexander Heuser  Martin Dietzel  Florian Böhm  David W. Lea  Thomas F. Nägler 《Geochimica et cosmochimica acta》2003,67(7):1375-1382

The calcium isotope ratios (δ⁴⁴Ca = [(⁴⁴Ca/⁴⁰Ca)_sample/(⁴⁴Ca/⁴⁰Ca)_standard −1] · 1000) of Orbulina universa and of inorganically precipitated aragonite are positively correlated to temperature. The slopes of 0.019 and 0.015‰ °C⁻¹, respectively, are a factor of 13 and 16 times smaller than the previously determined fractionation from a second foraminifera, Globigerinoides sacculifer, having a slope of about 0.24‰ °C⁻¹. The observation that δ⁴⁴Ca is positively correlated to temperature is opposite in sign to the oxygen isotopic fractionation (δ¹⁸O) in calcium carbonate (CaCO₃). These observations are explained by a model which considers that Ca²⁺-ions forming ionic bonds are affected by kinetic fractionation only, whereas covalently bound atoms like oxygen are affected by kinetic and equilibrium fractionation. From thermodynamic consideration of kinetic isotope fractionation, it can be shown that the slope of the enrichment factor α(T) is mass-dependent. However, for O. universa and the inorganic precipitates, the calculated mass of about 520 ± 60 and 640 ± 70 amu (atomic mass units) is not compatible with the expected ion mass for ⁴⁰Ca and ⁴⁴Ca. To reconcile this discrepancy, we propose that Ca diffusion and δ⁴⁴Ca isotope fractionation at liquid/solid transitions involves Ca²⁺-aquocomplexes (Ca[H₂O]_n²⁺ · mH₂O) rather than pure Ca²⁺-ion diffusion. From our measurements we calculate that such a hypothesized Ca²⁺-aquocomplex correlates to a hydration number of up to 25 water molecules (490 amu). For O. universa we propose that their biologically mediated Ca isotope fractionation resembles fractionation during inorganic precipitation of CaCO₃ in seawater. To explain the different Ca isotope fractionation in O. universa and in G. sacculifer, we suggest that the latter species actively dehydrates the Ca²⁺-aquocomplex before calcification takes place. The very different temperature response of Ca isotopes in the two species suggests that the use of δ⁴⁴Ca as a temperature proxy will require careful study of species effects.  相似文献   

High-resolution monitoring of biogeochemical gradients in a tar oil-contaminated aquifer     

Bettina Anneser  Florian Einsiedl  Rainer U. Meckenstock  Lars Richters  Frank Wisotzky  Christian Griebler 《Applied Geochemistry》2008

The detailed understanding of in situ biodegradation of petroleum hydrocarbons in porous aquifers requires knowledge on biogeochemical gradients, the distribution of individual redox species and microorganisms. The generally limited spatial resolution of conventional monitoring wells, however, hampers appropriate characterization of small-scale gradients and thus localization of the relevant processes. Groundwater sampling across a BTEX plume in a sandy aquifer by means of a novel high-resolution multi-level well (HR-MLW) is presented here. The presence of distinct and steep biogeochemical gradients is demonstrated in the centimeter and decimeter scale, which could not be resolved with a conventional multi-level well. The thin BTEX plume with a vertical extension of only 80 cm exhibited a decline of contaminant concentrations by two orders of magnitude within a few centimeters in the upper and lower fringe zone. The small-scale distribution of sulfate, sulfide and Fe(II) in relation to the contaminants and elevated δ³⁴S and δ¹⁸O values of groundwater sulfate strongly indicated sulfate and iron reduction to be the dominant redox processes involved in biodegradation. High microbial activities and biomass especially at the plume fringes and the slope of chemical gradients supported the concept that the latter are regulated by microbial processes and transverse dispersion, i.e. vertical mixing of electron donors and acceptors. Transverse dispersion therefore was suggested to be a driving factor controlling biodegradation in porous aquifers, but not exclusively limiting natural attenuation processes at this site. Broad overlapping zones of electron donors and electron acceptors point towards additional factors limiting anaerobic biodegradation in situ. The identification of small-scale gradients substantially contributed to a better understanding of biodegradation processes and hence is a prerequisite for the development of reliable predictive mathematical models and future remediation strategies.  相似文献   

Triassic stratigraphy,facies and evolution of the Arabian shelf in the northern United Arab Emirates     

Florian Maurer  Roberto Rettori  Rossana Martini 《International Journal of Earth Sciences》2008,97(4):765-784

This study provides a reconstruction of the Late Permian and Triassic depositional history of the Arabian shelf in the northern United Arab Emirates based on facies analysis and foraminiferal biostratigraphy. The presented data show that sedimentation occurred in three major sequences. From the Late Permian to Olenekian carbonates and evaporites were deposited in restricted lagoons and tidal flats. After a hiatus, sedimentation resumed and continued until the Late Ladinian/Carnian, leading to the deposition of a carbonate platform dominated by peritidal dolostones. A period of shelf exposure and erosion, spanning from the Carnian to Norian, was followed by the third major sequence with sedimentation into the Early Jurassic. During this third depositional sequence sedimentation changed from pure carbonate into mixed carbonate–siliciclastic deposits. This transition reflects the global regression of the sea in the Late Triassic (Triasina hantkeni Zone) and the increased erosion of large parts of the Arabian hinterland. A comparison of the evolution of the Arabian shelf in the study area with chronostratigraphic reference schemes for the Arabian Plate reveals remarkable differences in the distribution of Middle and Upper Triassic sequences. These are most likely the result of poor biostratigraphic control on previously studied formations in the region.  相似文献   

Water-assisted migmatization of metagraywackes in a Variscan shear zone, Aiguilles-Rouges massif, western Alps   总被引：2，自引：0，他引：2  

Florian Genier  Franois Bussy  Jean-Luc Epard  Lukas Baumgartner 《Lithos》2008,102(3-4):575-597

Migmatitic rocks developed in metagraywackes during the Variscan orogeny in the Aiguilles-Rouges Massif (western Alps). Partial melting took place 320 Ma ago in a 500 m-wide vertical shear zone. Three leucosome types have been recognised on the basis of size and morphology: (1) large leucosomes > 2 cm wide and > 40 cm long lacking mafic selvage, but containing cm-scale mafic enclaves; (2) same as 1 but with thick mafic selvage (melanosome); (3) small leucosomes < 2 cm and < 40 cm) with thin dark selvages (stromatic migmatites). Types 1 + 2 have mineralogical and chemical compositions in keeping with partial melting experiments. But Type 3 leucosomes have identical plagioclase composition (An_19–28) to neighbouring mesosome, both in terms of major- and trace-elements. Moreover, whole-rock REE concentrations in Type 3 leucosomes are only slightly lower than those in the mesosomes, unlike predicted by partial melting experiments. The main chemical differences between all leucosome types can be related to the coupled effect of melt segregation and late chemical reequilibration.

Mineral assemblages and thermodynamic modelling on bulk-rock composition restrict partial melting to  650 °C at 400 MPa. The large volume of leucosome (20 vol.%) thus generated requires addition of 1 wt.% external water. Restriction of extensive migmatization to the shear zone, without melting of neighbouring metapelites, also points to external fluid circulation within the shear zone as the cause of melting.  相似文献   

Pioneer vegetation as an indicator of the geochemical parameters in abandoned mine sites using hyperspectral airborne data     

Christian Götze  Florian Beyer  Cornelia Gläßer 《Environmental Earth Sciences》2016,75(7):613

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Insight into nitrous oxide production processes in the western North Pacific based on a marine ecosystem isotopomer model   总被引：2，自引：0，他引：2  

Chisato Yoshikawa  Hitomi Abe  Maki N. Aita  Florian Breider  Keichi Kuzunuki  Sakae Toyoda  Nanako O. Ogawa  Hisami Suga  Naohiko Ohkouchi  Sebastian O. Danielache  Masahide Wakita  Makio C. Honda  Naohiro Yoshida 《Journal of Oceanography》2016,72(3):491-508

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Permeability Evolution in Natural Fractures Subject to Cyclic Loading and Gouge Formation     

Daniel Vogler  Florian Amann  Peter Bayer  Derek Elsworth 《Rock Mechanics and Rock Engineering》2016,49(9):3463-3479

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Advances in understanding calcite varve formation: new insights from a dual lake monitoring approach in the southern Baltic lowlands     

Patricia Roeser  Nadine Dräger  Dariusz Brykała  Florian Ott  Sylvia Pinkerneil  Piotr Gierszewski  Christin Lindemann  Birgit Plessen  Brian Brademann  Michał Kaszubski  Michał Fojutowski  Markus J. Schwab  Michał Słowiński  Mirosław Błaszkiewicz  Achim Brauer 《Boreas: An International Journal of Quaternary Research》2021,50(2):419-440

We revise the conceptual model of calcite varves and present, for the first time, a dual lake monitoring study in two alkaline lakes providing new insights into the seasonal sedimentation processes forming these varves. The study lakes, Tiefer See in NE Germany and Czechowskie in N Poland, have distinct morphology and bathymetry, and therefore, they are ideal to decipher local effects on seasonal deposition. The monitoring setup in both lakes is largely identical and includes instrumental observation of (i) meteorological parameters, (ii) chemical profiling of the lake water column including water sampling, and (iii) sediment trapping at both bi-weekly and monthly intervals. We then compare our monitoring data with varve micro-facies in the sediment record. One main finding is that calcite varves form complex laminae triplets rather than simple couplets as commonly thought. Sedimentation of varve sub-layers in both lakes is largely dependent on the lake mixing dynamics and results from the same seasonality, commencing with diatom blooms in spring turning into a pulse of calcite precipitation in summer and terminating with a re-suspension layer in autumn and winter, composed of calcite patches, plant fragments and benthic diatoms. Despite the common seasonal cycle, the share of each of these depositional phases in the total annual sediment yield is different between the lakes. In Lake Tiefer See calcite sedimentation has the highest yields, whereas in Lake Czechowskie, the so far underestimated re-suspension sub-layer dominates the sediment accumulation. Even in undisturbed varved sediments, re-suspended material becomes integrated in the sediment fabric and makes up an important share of calcite varves. Thus, while the biogeochemical lake cycle defines the varves’ autochthonous components and micro-facies, the physical setting plays an important role in determining the varve sub-layers’ proportion.  相似文献   

Hydrochemistry and environmental isotopes of spring water and their relation to structure and lithology identified with remote sensing methods in Wadi Araba,Egypt     

Wannous  Manal  Theilen-Willige  Barbara  Troeger  Uwe  Falk  Marianne  Siebert  Christian  Bauer  Florian 《Hydrogeology Journal》2021,29(6):2245-2266

Springs located at the historical sites of Wadi Araba (Eastern Desert of Egypt) and emerging from the escarpments of the Northern and Southern Galala Plateaus were investigated. A combination of methods, including hydrochemistry, stable and radioisotope composition, and structural analyses based on satellite data, provided information about the structure of the subsurface and the derived groundwater flow paths. Satellite images reveal karst features within the northern plateau, e.g. conical landforms. Karstic caves were documented along both escarpments. Chemical analysis of floodwater from Wadi Araba indicates higher concentrations of terrestrial salts compared to floodwaters from central and southern parts of the desert. δ¹⁸O and δ²H signatures in spring waters resemble those of floodwater and fall on the global meteoric water line, confirming their fast infiltration with minor influence of evaporation. The aquifer feeding the springs of the Northern Galala Plateau has low retention and the springs dry out quickly, even after heavy rainfall. Contrastingly, ³H activities in springs emerging from the Southern Galala Plateau refer to much slower subsurface passage. With respect to ³H content (3.8 TU) in recent flood waters, the spring water at Southern Galala Plateau contains about 40% recently recharged groundwater. However, its largest spring—the St. Antony spring—discharges water with a radiocarbon age of about 15,000 years. In combination with this spring’s constant and high discharge over a period of several months, that age estimate suggests a large reservoir with moderate to high retention.

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