Distribution of Cd,Pb, Zn and Cu and their chemical speciations in soils from a peri-smelter area in northeast China   总被引：2，自引：0，他引：2  

Ping Du  Nandong Xue  Li Liu  Fasheng Li 《Environmental Geology》2008,55(1):205-213

An exploratory study on soil contamination of heavy metals was carried out surrounding Huludao zinc smelter in Liaoning province, China. The distribution of total heavy metals and their chemical speciations were investigated. The correlations between heavy metal speciations and soil pH values in corresponding sites were also analyzed. In general, Cd, Zn, Pb, Cu and As presented a significant contamination in the area near the smelter, comparied with Environmental Quality Standards for Soils in China. The geoaccumulation index showed the degree of contamination: Cd > Zn > Pb > Cu > As. There was no obvious pollution of Cr and Ni in the studied area. The speciation analysis showed that the dominant fraction of Cd and Zn was the acid soluble fraction, and the second was the residual fraction. Pb was mostly associated with the residual fraction, which constituted more than 50% of total concentration in all samples. Cu in residual fraction accounted for a high percentage (40–80%) of total concentration, and the proportion of Cu in the oxidizable fraction is higher than that of other metals. The distribution pattern of Pb and Zn was obviously affected by soil pH. It seemed that Pb and Zn content in acid solution fraction increased with increasing soil pH values, while Cd content in acid soluble fraction accounted for more proportion in neutral and alkaline groups than acidic one. The fraction distribution patterns of Cu in three pH groups were very similar and independent of soil pH values. And the residual fraction of Cu took a predominant part (50%) of the total content.  相似文献   

Experimental study on the deterioration and natural remediation of the Ariake Sea tidal mud caused by the sea laver treatment acid practice and the upward seepage of pore water liquid     

Yan-Jun Du  Song-Yu Liu  Shigenori Hayashi 《Environmental Geology》2008,55(4):889-900

This study presents a laboratory study of the following two aspects: (1) the influence of sea laver treatment acid on the geoenvironmental properties of Ariake Sea tidal mud, and (2) the natural remediation effect on the sea laver treatment acid contaminated Ariake Sea tidal mud caused by the upward seepage of pore water liquid in the mud. Firstly, the mechanisms of the transport of sea laver treatment acid in the Ariake Sea tidal mud and the generation mechanisms of the upward seepage flow in the Ariake Sea tidal mud are discussed. Secondly, a series of one-dimensional laboratory infiltration tests were carried out to investigate the deterioration of the Ariake Sea tidal mud caused by the sea laver acid treatment practice. Test results reveal that the acid treatment practice caused considerable change in the geochemical properties of the mud in terms of increase in sulfide content and decrease in pH value. After the treatment by the sea laver treatment acid, the sulfide content of the mud even exceeded the safe limit value for the benthos, which represents undesirable living condition for benthos. Thirdly, series of laboratory fresh seawater infiltration tests for the deteriorated Iida site mud were conducted to illustrate this natural remediation efficiency. It is found that with the infiltration of the fresh seawater, the sulfide content of the Iida site mud was considerably reduced and pH value increased to an acceptable range for benthos living in the tidal flat mud. With the increase in the infiltration time and the hydraulic gradient, the remediation efficiency could be increased.  相似文献   

Assessment of frozen-ground conditions for engineering geology along the Qinghai–Tibet highway and railway, China     

Huijun Jin  Zhi Wei  Shaoling Wang  Qihao Yu  Lanzhi Lü  Qingbai Wu  Yanjun Ji 《Engineering Geology》2008,101(3-4):96-109

The Qinghai–Tibet Highway and Railway (the Corridor) across the Qinghai–Tibet Plateau traverses 670 km of permafrost and seasonally frozen-ground in the interior of the Plateau, which is sensitive to climatic and anthropogenic environmental changes. The frozen-ground conditions for engineering geology along the Corridor is complicated by the variability in the near-surface lithology, and the mosaic presence of warm permafrost and talik in a periglacial environment. Differential settlement is the major frost-effect problem encountered over permafrost areas. The traditional classification of frozen ground based on the areal distribution of permafrost is too generalized for engineering purposes and a more refined classification is necessary for engineering design and construction. A proposed classification of 51 zones, sub-zones, and sections of frozen ground has been widely adopted for the design and construction of foundations in the portion of the Corridor studied. The mean annual ground temperature (MAGT), near-surface soil types and moisture content, and active faults and topography are most commonly the primary controlling factors in this classification. However, other factors, such as local microreliefs, drainage conditions, and snow and vegetation covers also exert important influences on the features of frozen ground. About 60% of the total length of the Corridor studied possesses reasonably good frozen-ground conditions, which do not need special mitigative measures for frost hazards. However, other sections, such as warm and ice-rich or -saturated permafrost, particularly in the sections in wetlands, ground improvement measures such as elevated land bridges and passive or proactive cooling techniques need to be applied to ensure the long-term stability of thermally unstable, thick permafrost subsoils, and/or refill with non-frost-susceptible soils. Due to the long-history of the construction and management of the Corridor by various government departments, adverse impacts of construction and operation on the permafrost environment have been resulted. It is recommended that an integrated, executable plan for the routing of major construction projects within this transportation corridor be established and long-term monitoring networks installed for evaluating and mitigating the impact from anthropogenic and climatic changes in frozen-ground conditions.  相似文献   

Atomistic simulation of the mechanisms of noble gas incorporation in minerals     

Z. Du  N.L. Allan  J.A. Purton 《Geochimica et cosmochimica acta》2008,72(2):554-573

Atomistic simulations have been carried out to investigate the mechanisms of noble gas incorporation in minerals using both the traditional two-region approach and the “supercell” method. The traditional two-region approach has been used to calculate defect energies for Ne, Ar, Kr and Xe incorporation in MgO, CaO, diopside and forsterite in the static limit and at one atmosphere pressure. The possibilities of noble gas incorporation via both substitution and interstitial mechanisms are studied. The favored mechanism varies from mineral to mineral and from noble gas to noble gas. In all minerals studied, the variation of the solution energies of noble gas substitution with atomic radius appears approximately parabolic, analogous to those for 1⁺, 2⁺, 3⁺ and 4⁺ trace element incorporation on crystal lattice sites. Noble gas solution energies thus also fall on a curve, similar to those previously observed for cations with different charges, but with much lower curvature.The “supercell” method has been used to investigate the pressure dependence of noble gas incorporation in the same systems. Results indicate a large variation of the solubility of the larger noble gases, Kr and Xe with pressure. In addition, explicit simulation of incorporation at the (0 0 1) surface of MgO shows that the solubility of the heavier noble gases may be considerably enhanced by the presence of interfaces.  相似文献   

The soilmodels.info project   总被引：1，自引：0，他引：1  

Gerd Gudehus  Angelo Amorosi  Antonio Gens  Ivo Herle  Dimitrios Kolymbas  David Mašín  David Muir Wood  Andrzej Niemunis  Roberto Nova  Manuel Pastor  Claudio Tamagnini  Gioacchino Viggiani 《国际地质力学数值与分析法杂志》2008,32(12):1571-1572

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西藏马攸木金矿床金银互化物的赋存状态   总被引：3，自引：0，他引：3  

孙燕  温春齐  多吉  霍艳 《地质与勘探》2008,44(5):42-46

马攸木金矿床是西藏近年发现的首例规模较大、矿石品位富、金成色高的岩金矿床.作者通过对马攸木金矿床矿石组构、矿石共生组合及矿物特征研究发现,金银互化物主要有自然金、含银自然金、银金矿、自然银.载金矿物为黝铜矿、针铁矿、脆硫锑铅矿及石英;金银互化物的赋存形式主要为包裹体金、裂隙金及粒间金.金银互化物的形成、富集与热液成矿作用及表生风化作用关系密切.  相似文献   

AnomalousD-region duringX-emission from flares and geomagnetic effect     

Ladislav Křivský 《Studia Geophysica et Geodaetica》1962,6(3):242-249

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On the types and dispersions of whistlers as observed in czechoslovakia     

František Jiříček 《Studia Geophysica et Geodaetica》1962,6(1):98-101

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中国全新世大暖期哺乳动物与气候波动   总被引：13，自引：0，他引：13  

计宏祥 《海洋地质与第四纪地质》1996,16(1):5-16

中国全新世哺乳动物群有众多地点，并已作了详细研究，绝大多数地点有＾１４Ｃ的年代测定，全新世一更新世的界线，作者根据哺乳动物及＾１４Ｃ年代测定，在１２－１０ｋａＢ．Ｐ之间，可作为二者之间的过渡层位，在１０ｋａＢ．Ｐ。可作为全新世的开始，中国的全新世大暖期出现于８．５－３．０ｋａＢ．Ｐ。在此期间内的哺乳动物偏南种类似为明显，如亚洲象，苏门犀及爪哇犀等，在５．６－３．０ｋａＢ．Ｐ。这一时期内的气候波动剧  相似文献   

棉兰老涡旋的数值模拟     

李荣凤  曾庆存  季仲贞 《热带海洋学报》1991,(4)

用一个水平分辨率比较高的非线性正压模式,对热带西太平洋海域里的海流进行了数值模拟。计算海流与观测结果颇相一致。结果表明:赤道以北、棉兰老岛以东附近海域中,棉兰老冷涡在一年的大部分时间里都得到发展,但是其范围、强度和中心位置在各个月份并不相同,显示出很强的季节变化;在哈马黑拉岛东北海域,6月份突然出现了一个反气旋式的涡旋;这个涡旋8月份发展得最强,一直持续到10月份,在11月份就消亡了。  相似文献