Copper Isotopic Analysis in Geological and Biological Reference Materials by MC‐ICP‐MS     

Kaj Sullivan  Daniel Layton‐Matthews  Matthew Leybourne  James Kidder  Zoltn Mester  Lu Yang 《Geostandards and Geoanalytical Research》2020,44(2):349-362

The characterisation of relative copper isotope amount ratios (δ⁶⁵Cu) helps constrain a variety of geochemical processes occurring in the geosphere, biosphere and hydrosphere. The accurate and precise determination of δ⁶⁵Cu in matrix reference materials is crucial in the effort to validate measurement methods. With the goal of expanding the number and variety of available geological and biological materials, we have characterised the δ⁶⁵Cu values of ten reference materials by MC‐ICP‐MS using C‐SSBIN model for mass bias correction. SGR‐1b (Green River shale), DOLT‐5 (dogfish liver), DORM‐4 (fish protein), TORT‐3 (lobster hepatopancreas), MESS‐4 (marine sediment) and PACS‐3 (marine sediment) have for the first time been characterised for δ⁶⁵Cu. Additionally, four reference materials (with published δ⁶⁵Cu values) have been characterised: BHVO‐1 (Hawaiian basalt), BIR‐1 (Icelandic basalt), W‐2a (diabase) and Seronorm? Trace Elements Serum L‐1 (human serum). The reference materials measured in this study possess complex and varied matrices with copper mass fractions ranging from 1.2 µg g^?1 to 497 µg g^?1 and δ⁶⁵Cu values ranging from ?0.20‰ to 0.52‰ with a mean expanded uncertainty of ± 0.07‰ (U, k = 2), covering much of the natural copper isotope variability observed in the environment.  相似文献   

A physical model of the high-frequency seismic signal generated by debris flows     

Maxime Farin  Victor C. Tsai  Michael P. Lamb  Kate E. Allstadt 《地球表面变化过程与地形》2019,44(13):2529-2543

We propose a physical model for the high-frequency (>1 Hz) spectral distribution of seismic power generated by debris flows. The modeled debris flow is assumed to have four regions where the impact rate and impulses are controlled by different mechanisms: the flow body, a coarser-grained snout, a snout lip where particles fall from the snout on the bed, and a dilute front composed of saltating particles. We calculate the seismic power produced by this impact model in two end-member scenarios, a thin-flow and thick-flow limit, which assume that the ratio of grain sizes to flow thicknesses are either near unity or much less than unity. The thin-flow limit is more appropriate for boulder-rich flows that are most likely to generate large seismic signals. As a flow passes a seismic station, the rise phase of the seismic amplitude is generated primarily by the snout while the decay phase is generated first by the snout and then the main flow body. The lip and saltating front generate a negligible seismic signal. When ground properties are known, seismic power depends most strongly on both particle diameter and average flow speed cubed, and also depends on length and width of the flow. The effective particle diameter for producing seismic power is substantially higher than the median grain size and close to the 73rd percentile for a realistic grain size distribution. We discuss how the model can be used to estimate effective particle diameter and average flow speed from an integrated measure of seismic power. © 2019 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd. © 2019 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.  相似文献   

GGR Biennial Critical Review: Analytical Developments Since 2014          下载免费PDF全文

Kathryn L. Linge  L. Paul Bédard  Roxana Bugoi  Jacinta Enzweiler  Klaus Peter Jochum  Rüdiger Kilian  Jingao Liu  Johanna Marin‐Carbonne  Silke Merchel  Frans Munnik  Luiz F.G. Morales  Claire Rollion‐Bard  A. Kate Souders  Paul J. Sylvester  Ulrike Weis 《Geostandards and Geoanalytical Research》2017,41(4):493-562

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.  相似文献   

Simplified seismic performance assessment and implications for seismic design     

Timothy J.Sullivan  David P.Welch  Gian Michele Calvi 《地震工程与工程振动(英文版)》2014,(Z1)

The last decade or so has seen the development of refined performance-based earthquake engineering(PBEE) approaches that now provide a framework for estimation of a range of important decision variables,such as repair costs,repair time and number of casualties. This paper reviews current tools for PBEE,including the PACT software,and examines the possibility of extending the innovative displacement-based assessment approach as a simplified structural analysis option for performance assessment. Details of the displacement-based s+eismic assessment method are reviewed and a simple means of quickly assessing multiple hazard levels is proposed. Furthermore,proposals for a simple definition of collapse fragility and relations between equivalent single-degree-of-freedom characteristics and multi-degree-of-freedom story drift and floor acceleration demands are discussed,highlighting needs for future research. To illustrate the potential of the methodology,performance measures obtained from the simplified method are compared with those computed using the results of incremental dynamic analyses within the PEER performance-based earthquake engineering framework,applied to a benchmark building. The comparison illustrates that the simplified method could be a very effective conceptual seismic design tool. The advantages and disadvantages of the simplified approach are discussed and potential implications of advanced seismic performance assessments for conceptual seismic design are highlighted through examination of different case study scenarios including different structural configurations.  相似文献   

Iron(III) accumulations in inland saline waterways,Hunter Valley,Australia: Mineralogy,micromorphology and pore-water geochemistry     

Lloyd S. Isaacson  Edward D. Burton  Richard T. Bush  David R.G. Mitchell  Scott G. Johnston  Bennett C.T. Macdonald  Leigh A. Sullivan  Ian White 《Applied Geochemistry》2009

Discharge of Fe(II)-rich groundwaters into surface-waters results in the accumulation of Fe(III)-minerals in salinized sand-bed waterways of the Hunter Valley, Australia. The objective of this study was to characterise the mineralogy, micromorphology and pore-water geochemistry of these Fe(III) accumulations. Pore-waters had a circumneutral pH (6.2–7.2), were sub-oxic to oxic (Eh 59–453 mV), and had dissolved Fe(II) concentrations up to 81.6 mg L⁻¹. X-ray diffraction (XRD) on natural and acid-ammonium-oxalate (AAO) extracted samples indicated a dominance of 2-line ferrihydrite in most samples, with lesser amounts of goethite, lepidocrocite, quartz, and alumino-silicate clays. The majority of Fe in the samples was bound in the AAO extractable fraction (Fe^Ox) relative to the Na-dithionite extractable fraction (Fe^Di), with generally high Fe^Ox:Fe^Di ratios (0.52–0.92). The presence of nano-crystalline 2-line ferrihydrite (Fe₅HO₃·4H₂O) with lesser amounts of goethite (α-FeOOH) was confirmed by scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED). In addition, it was found that lepidocrocite (γ-FeOOH), which occurred as nanoparticles as little as ∼5 lattice spacings thick perpendicular to the (0 2 0) lattice plane, was also present in the studied Fe(III) deposits. Overall, the results highlight the complex variability in the crystallinity and particle-size of Fe(III)-minerals which form via oxidation of Fe(II)-rich groundwaters in sand-bed streams. This variability may be attributed to: (1) divergent precipitation conditions influencing the Fe(II) oxidation rate and the associated supply and hydrolysis of the Fe(III) ion, (2) the effect of interfering compounds, and (3) the influence of bacteria, especially Leptothrix ochracea.  相似文献   

Assessing catch shares' effects evidence from Federal United States and associated British Columbian fisheries     

Dietmar Grimm  Ivan Barkhorn  David Festa  Kate Bonzon  Judd Boomhower  Valerie Hovland  Jason Blau 《Marine Policy》2012,36(3):644-657

What are the effects of transitioning traditionally managed fisheries to incentive-based catch shares fisheries? In a study of all major United States federal catch share fisheries and associated shared stock fisheries in British Columbia, catch shares result in environmental improvements, economic improvements, and a mixture of changes in social performance, relative to the race for fish under traditional management. Environmentally, compliance with total allowable catch increases and discards decrease. Economically, vessel yields rise, total revenues grow, and long-term stock increases are encouraged. Socially, safety increases, some port areas modestly consolidate, needed processing capacity often reduces, and labor markets shift from part time jobs to full time jobs with similar total employment. Newer catch shares address many social concerns through careful design.  相似文献   

Coming to the table: Early stakeholder engagement in marine spatial planning   总被引：1，自引：0，他引：1  

Morgan Gopnik  Clare Fieseler  Laura Cantral  Kate McClellan  Linwood Pendleton  Larry Crowder 《Marine Policy》2012

From 2009 to 2011, marine spatial planning (MSP) rapidly gained visibility in the United States as a promising ocean management tool. A few small-scale planning efforts were completed in state waters, and the Obama Administration proposed a framework for large-scale regional MSP throughout the U.S. Exclusive Economic Zone. During that same time period, the authors engaged a variety of U.S ocean stakeholders in a series of dialogs with several goals: to share information about what MSP is or could be, to hear stakeholder views and concerns about MSP, and to foster better understanding between those who depend on ocean resources for their livelihood and ocean conservation advocates. The stakeholder meetings were supplemented with several rounds of in-depth interviews and a survey. Despite some predictable areas of conflict, project participants agreed on a number of issues related to stakeholder engagement in MSP: all felt strongly that government planners need to engage outsiders earlier, more often, more meaningfully, and through an open and transparent process. Equally important, the project affirmed the value of bringing unlike parties together at the earliest opportunity to learn, talk, and listen to others with whom they rarely engage.  相似文献   

Seismic hazard disaggregation in performance‐based earthquake engineering: occurrence or exceedance?          下载免费PDF全文

Matthew J. Fox  Peter J. Stafford  Timothy J. Sullivan 《地震工程与结构动力学》2016,45(5):835-842

Seismic hazard disaggregation is commonly used as an aid in ground‐motion selection for the seismic response analysis of structures. This short communication investigates two different approaches to disaggregation related to the exceedance and occurrence of a particular intensity. The impact the different approaches might have on a subsequent structural analysis at a given intensity is explored through the calculation of conditional spectra. It is found that the exceedance approach results in conditional spectra that will be conservative when used as targets for ground‐motion selection. It is however argued that the use of the occurrence disaggregation is more consistent with the objectives of seismic response analyses in the context of performance‐based earthquake engineering. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Development through football in Africa: Neoliberal and postcolonial models of community development     

Kate Manzo 《Geoforum》2012,43(3):551-560

Informed by academic writings on non-governmental organisations (NGOs), critiques of neoliberal development, and postcolonial development theory, this paper explores the relationship between football and development through critical analysis of two contrasting initiatives. One is the Football for Hope Movement (FHM), which was the principal backer of the official campaign of the 2010 FIFA World Cup (FWC), called “20 Centres for 2010”. The second is the Katina 2009 football tournament held under the auspices of a community development project in Uganda sponsored by the Guardian newspaper and Barclays bank in the UK.The initial aim was to identify the particular development models at work within ‘development through football’ initiatives. While an established model of NGO-led community development is certainly apparent, different initiatives suggest a basic distinction between neoliberal and postcolonial variants. The paper identifies and explains the differences while showing how contrasting models become sites of struggle and overlap, to some extent, when translated into development practice. Ultimately, the investigation reveals how football is used as a magnet to draw young people deeper into the operational orbit of NGOs and their donors. The paper also draws attention to new actors and partnerships in international development – most notably the Guardian, whose transformation into a development actor suggests a novel ‘NGO-isation’ of the media itself.  相似文献   

Evaluation of the 15 July 2009 Fiordland,New Zealand Tsunami in the Source Region   总被引：1，自引：0，他引：1  

Gegar Prasetya  John Beavan  Xiaoming Wang  Martin Reyners  William Power  Kate Wilson  Biljana Lukovic 《Pure and Applied Geophysics》2011,168(11):1973-1987

We undertake detailed near-field numerical modelling of the tsunami generated by the 15 July 2009 earthquake (Mw 7.8) in Fiordland, New Zealand. High resolution bathymetry and topography data at Breaksea and Dusky Sounds, and Chalky and Preservation Inlets are derived mostly from digitised New Zealand nautical charts, Shuttle Radar Topographic Mission (SRTM) 3 arc-second data, and General Bathymetric Chart of the Ocean (GEBCO) 30 s data. A combination of continuous and campaign Global Positioning System (GPS), satellite radar (ALOS/PALSAR InSAR images) and seismology data are used to constrain the seafloor deformation for the initial tsunami condition. This source model, derived independently of DART observations, provides an excellent fit to observed tsunami elevations recorded by DART buoy 55015. The model results in the near field show maximum tsunami elevations in the range 0.5–2.0 m inside the sounds and inlets with maximum flow speeds of 3.0 m/s. Along the open coast, maximum tsunami elevations reach 2.0 m. The high flow speeds through the inlets may change the inlet stratifications and water mass inside the sounds. Media reports and field reconnaissance data show some tsunami evidence at Cormorant Cove, Duck and Goose Coves, and Passage Point.  相似文献