Application of laser ablation ICPMS to trace the environmental history of chum salmon Oncorhynchus keta     

Arai T  Hirata T  Takagi Y 《Marine environmental research》2007,63(1):55-66

Trace element levels in otoliths of chum salmon Oncorhynchus keta were examined by means of laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). A close linear relationship in the Sr:Ca ratios between EPMA (X-ray analysis with an electron microprobe) and LA-ICPMS analyses was found (p<0.0001), suggesting that the latter technique could be used to separate the marine and freshwater life phases. Mg:Ca, Cr:Ca, Zn:Ca and Ba:Ca ratios in either the core region or the oceanic growth zone of the otoliths varied among sites. These differences suggest that elemental compositions may reflect environmental variability among spawning (breeding) or habitat sites. Thus, those element ratios demonstrate the potential to be used to distinguish between fish spawning (breeding) sites and habitats for this species of salmon.  相似文献   

Hydrous peridotites with Ti-rich chromian spinel as a low-temperature forearc mantle facies: evidence from the Happo-O’ne metaperidotites (Japan)   总被引：1，自引：0，他引：1  

Mohamed Zaki Khedr  Shoji Arai 《Contributions to Mineralogy and Petrology》2010,159(2):137-157

The Happo-O’ne peridotite complex is situated in the northeastern part of the Hida Marginal Tectonic Zone, central Japan, characterized by the high-P/T Renge metamorphism, and is considered as a serpentinite mélange of Paleozoic age. Peridotitic rocks, being massive or foliated, have been subjected to hydration and metamorphism. Their protoliths are mostly lherzolites to harzburgites with subordinate dunites. We found a characteristic mineral assemblage, olivine + orthopyroxene + tremolite + chlorite + chromian spinel, being stable at low-T, from 650 to 750°C, and high-P, from 16 to 20 kbar, tremolite–chlorite peridotites of the tremolite zone. Olivines are Fo₈₈–Fo_91, and orthopyroxenes (Mg# = 0.91) show low and homogenous distributions of Al₂O₃ (up to 0.25 wt%), Cr₂O₃ (up to 0.25 wt%), CaO (up to 0.36 wt%) and TiO₂ (up to 0.06 wt%) due to the low equilibration temperature. Chromian spinels, which are euhedral and enclosed mainly in the orthopyroxenes, have high TiO_2, 3.1 wt% (up to 5.7 wt%) on average, and high Cr# [=Cr/(Cr + Al) atomic ratio], 0.95 on average but low Fe³⁺ [=Fe³⁺/(Cr + Al + Fe³⁺) atomic ratio, <0.3]. The bulk-rock chemistry shows that the Happo-O’ne metaperidotites with this peculiar spinel are low in TiO₂ (0.01–0.02 wt%), indicating no addition of TiO₂ from the outside source during the metamorphism; the high TiO₂ of the peculiar spinel has been accomplished by Ti release from Ti-bearing high-T pyroxenes during the formation of low-T, low-Ti silicates (<0.1 wt% TiO₂) during cooling. Some dunites are intact from hydration: their olivine is Fo₉₂ and spinel shows high Cr#, 0.72. The Happo-O’ne metaperidotites (tremolite–chlorite peridotites), being in the corner of the mantle wedge, are representative of a hydrous low-T, high-P mantle peridotite facies transitional from a higher T anhydrous peridotite facies (spinel peridotites) formed by in situ retrograde metamorphism influenced by fluids from the subducting slab. They have suffered from low-T (<600°C) retrogressive metamorphism to form antigorite and diopside during exhumation of the Renge metamorphic belt.  相似文献   

Eocene continental dyke swarm from Central Iran (Khur area)     

Ghodrat Torabi  Shoji Arai  Hamideh Abbasi 《Petrology》2014,22(6):617-632

The Eocene dyke swarm with east-west general trend intrudes the Cretaceous sedimentary rocks in ～25 km north of the Khur city (Central Iran). Some of the studied dykes can be followed for over 7 km, but the majority of exposures in the area are less than 5 km long. The dykes commonly exhibit a chilled contact with the wall rocks. These dykes are trachybasalt and basalt in composition. The trachybasalt dykes are much more abundant. The basaltic dykes cross cut the trachybasalt dykes in some locations, indicating that trachybasalt dykes are older than the basaltic ones. Primary igneous minerals of the basaltic dykes are olivine (chrysolite), clinopyroxene (diopside, augite), plagioclase (labradorite), sanidine, magnetite, orthopyroxene (enstatite), spinel and phlogopite, and secondary minerals are zeolite (natrolite and mesolite), chlorite (diabantite), calcite and serpentine. The trachybasalt dykes are composed of clinopyroxene (diopside), plagioclase (labradorite), sanidine, mica (biotite and phlogopite), amphibole (magnesio-hastingsite) and magnetite as primary minerals, and chlorite and calcite as secondary ones. Whole rocks geochemical data of the studied dykes indicate their basic and calc-alkaline nature and suggest that these two set of dykes were derived from the same parental magma. The chondrite-normalized REE patterns and the primitive mantle-normalized multi-elemental diagram of the Khur dykes show enrichment of light rare earth elements (LREE) relative to heavy rare earth elements (HREE), and negative anomalies of high field strength elements (HFSE) (e.g. Ti, Nb and Ta). These rocks show enrichment of the large ion lithophile elements (LILE) (e.g. Cs, Ba, Th and U) and depletion of the HREE and Y relative to MREE, Zr and Hf. In the chondrite-normalized REE diagram, the basalts show elevated REE abundances relative to the trachybasalt samples. Geochemical analyses of the studied samples suggest a spinel lherzolite from the mantle as the source rock and confirm the role of subduction in their generation. The chemical characteristics of the Khur dykes resemble those of continental arc rocks, and they were possibly formed by subduction of the Central-East Iranian microcontinent (CEIM) confining oceanic crust and decompression melting of a lithospheric subcontinental mantle spinel lherzolite enriched by subduction.  相似文献   

Podiform chromitite formation in a low-Cr/high-Al system: An example from the Southwest Indian Ridge (SWIR)   总被引：1，自引：0，他引：1  

Betchaida D. Payot  Shoji Arai  Henry J. B. Dick  Natsue Abe  Yuji Ichiyama 《Mineralogy and Petrology》2014,108(4):533-549

Recent reassessment of abyssal peridotites obtained during the dredging of the oblique supersegment and the easternmost subsection of the Southwest Indian Ridge by the R/V Knorr Cruise 162 and the R/V Yokosuka YK98-07 revealed the occurrence of dunites containing podiform chromitites and dunites with variable chromite concentration closely associated with lherzolite and harzburgite. The size of the chromitite pods varies from a few mm to 2 cm in width. Chromites in the podifom chromitites have very low Cr# (=0.22–0.23) and low TiO₂ (<0.17 wt%). They are almost free of silicate inclusions except for a few euhedral sulfide grains which occur far from cracks and lamellae and are considered primary in origin. The lherzolite which possibly represents the wallrock hosting the dunites with podiform chromitites also show low spinel Cr#(=0.16) and low Cr# in the clinopyroxenes (=0.09–0.10) and orthopyroxenes (=0.07–0.09). The small size of the SWIR podiform chromitites is strongly controlled by the low Cr/Al available in the wallrock and the invading melt. The presence of sulfide inclusions and the absence of PGEs further attest to the low Cr/Al (i.e. low refractoriness) in the system involved in the genesis of the SWIR podiform chromitites. Lastly, the discovery of podiform chromitites in the SWIR implies that the formation of podiform chromitite at mid-oceanic ridges, regardless of its spreading rate, is highly possible.  相似文献   

Lower Oligocene Calc-Alkaline Spessartitic Lamprophyres from Central Iran (East of Anarak Area); an Evidence from the Eastern Branch of Neotethys Subduction-Related Mantle Enrichment     

Nazari  Gh. H.  Torabi  Gh.  Arai  Sh.  Morishita  T. 《Geotectonics》2019,53(6):786-805

Geotectonics - The Lower Oligocene Kal-e-kafi (East of Anarak, Central Iran) lamprophyres occur as stocks and dikes, which cross-cut the Eocene volcanic and Cretaceous sedimentary rocks. The...  相似文献   

http://dx.doi.org/10.1016/j.gsf.2016.11.007   总被引：1，自引：1，他引：0  

Tatsuyuki Arai  Shigenori Maruyama 《地学前缘(英文版)》2017,8(2):299-308

Lunar anorthosite is a major rock of the lunar highlands,which formed as a result of plagioclasefloatation in the lunar magma ocean(LMO).Constraints on the sufficient conditions that resulted in the formation of a thick pure anorthosite(mode of plagioclase 95 vol.%) is a key to reveal the early magmatic evolution of the terrestrial planets.To form the pure lunar anorthosite,plagioclase should have separated from the magma ocean with low crystal fraction.Crystal networks of plagioclase and mafic minerals develop when the crystal fraction in the magma(φ) is higher than ca.40-60 vol.%,which inhibit the formation of pure anorthosite.In contrast,when φ is small,the magma ocean is highly turbulent,and plagioclase is likely to become entrained in the turbulent magma rather than separated from the melt.To determine the necessary conditions in which anorthosite forms from the LMO,this study adopted the energy criterion formulated by Solomatov.The composition of melt,temperature,and pressure when plagioclase crystallizes are constrained by using MELTS/pMELTS to calculate the density and viscosity of the melt.When plagioclase starts to crystallize,the Mg~# of melt becomes 0.59 at 1291 C.The density of the melt is smaller than that of plagioclase for P 2.1 kbar(ca.50 km deep),and the critical diameter of plagioclase to separate from the melt becomes larger than the typical crystal diameter of plagioclase(1.8-3 cm).This suggests that plagioclase is likely entrained in the LMO just after the plagioclase starts to crystallize.When the Mg~# of melt becomes 0.54 at 1263 C,the density of melt becomes larger than that of plagioclase even for 0 kbar.When the Mg~# of melt decreases down to 0.46 at 1218 C,the critical diameter of plagioclase to separate from the melt becomes 1.5-2.5 cm,which is nearly equal to the typical plagioclase of the lunar anorthosite.This suggests that plagioclase could separate from the melt.One of the differences between the Earth and the Moon is the presence of water.If the terrestrial magma ocean was saturated with H_2O,plagioclase could not crystallize,and anorthosite could not form.  相似文献   

Subsidence of the Miyako‐Sone submarine carbonate platform,east of Miyako‐jima Island,northwestern Pacific Ocean     

Kohsaku Arai  Hideaki Machiyama  Shun Chiyonobu  Hiroki Matsuda  Keiichi Sasaki  Marc Humblet  Yasufumi Iryu 《Island Arc》2014,23(1):1-15

Bathymetric mapping and observations of the seafloor using a remotely operated vehicle (ROV, Hyper‐Dolphin 3K) were carried out on the slopes of the Miyako‐Sone submarine platform, east of Miyako‐jima in the Ryukyu Islands, northwestern Pacific Ocean. The bathymetric map indicates that terraces are present at water depths of approximately 140 m, 330 m, 400 m, and 680 m on the northwestern slope of the platform. A number of NW–SE trending lineaments, probably faults, extend perpendicular to the axis of the Ryukyu Island Arc. Two ROV surveys were conducted at water depths ranging from 519 m (on the slope) to 121 m (shallowest part of the platform). The surveys revealed that well‐indurated carbonate rocks are exposed at terrace margins and on upper slopes, and that the lower slopes are covered with modern sediments consisting of unconsolidated, coarse‐sand‐sized bioclastic carbonates. Calcareous nannofossils from the well‐indurated carbonate rocks indicate a Middle–Late Pleistocene age, which suggests that the rocks correlate with the Quaternary reef and fore‐reef deposits of the Ryukyu Group (Ryukyu Limestone) on the Ryukyu Islands. No siliciclastic deposits corresponding to the upper Miocene–lower Pleistocene Shimajiri Group (as exposed on Okinawa‐jima and Miyako‐jima islands) were recovered during the surveys. Coeval well‐indurated carbonate rocks, all of which formed in a similar sedimentary environment, have been downthrown towards the west due to displacements on the western sides of normal faults. Subsidence of the Miyako‐Sone submarine platform was the result of large vertical displacements on such normal faults. The timing of initial subsidence cannot be tightly constrained, but the presence of the youngest limestone at progressively lower levels towards the west suggests the subsidence continued until after 0.265 Ma.  相似文献   

Platinum-group elements distribution and spinel composition in podiform chromitites and associated rocks from the upper mantle section of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco     

Ahmed H. Ahmed  Shoji Arai  Yaser M. Abdel-Aziz  Moha Ikenne  Abdellatif Rahimi 《Journal of African Earth Sciences》2009,55(1-2):92

The distribution of platinum-group elements (PGEs), together with spinel composition, of podiform chromitites and serpentinized peridotites were examined to elucidate the nature of the upper mantle of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco. The mantle section is dominated by harzburgite with less abundant dunite. Chromitite pods are also found as small lenses not exceeding a few meters in size. Almost all primary silicates have been altered, and chromian spinel is the only primary mineral that survived alteration. Chromian spinel of chromitites is less affected by hydrothermal alteration than that of mantle peridotites. All chromitite samples of the Bou Azzer ophiolite display a steep negative slope of PGE spidergrams, being enriched in Os, Ir and Ru, and extremely depleted in Pt and Pd. Harzburgites and dunites usually have intermediate to low PGE contents showing more or less unfractionated PGE patterns with conspicuous positive anomalies of Ru and Rh. Two types of magnetite veins in serpentinized peridotite, type I (fibrous) and type II (octahedral), have relatively low PGE contents, displaying a generally positive slope from Os to Pd in the former type, and positive slope from Os to Rh then negative from Rh to Pd in the latter type. These magnetite patterns demonstrate their early and late hydrothermal origin, respectively. Chromian spinel composition of chromitites, dunites and harzburgites reflects their highly depleted nature with little variations; the Cr# is, on average, 0.71, 0.68 and 0.71, respectively. The TiO₂ content is extremely low in chromian spinels, <0.10, of all rock types. The strong PGE fractionation of podiform chromitites and the high-Cr, low-Ti character of spinel of all rock types imply that the chromitites of the Bou Azzer ophiolite were formed either from a high-degree partial melting of primitive mantle, or from melting of already depleted mantle peridotites. This kind of melting is most easily accomplished in the supra-subduction zone environment, indicating a genetic link with supra-subduction zone magma, such as high-Mg andesite or arc tholeiite. This is a general feature in the Neoproterozoic upper mantle.  相似文献   

Petrology and geochemistry of prograde deserpentinized peridotites from Happo-O’ne, Japan: Evidence of element mobility during deserpentinization     

Mohamed Zaki Khedr  Shoji Arai 《Journal of Asian Earth Sciences》2012,43(1):150-163

The prograde deserpentinized peridotites from the talc zone in the Happo-O’ne complex, central Japan, show differences in their field relation and mineral assemblage with the high-P retrograde peridotites of the other part of the complex. They show a mineral assemblage, olivine + talc + antigorite ± prograde tremolite ± chlorite, formed by thermal metamorphism around the granitic intrusion at T, 500-650 °C and P < 7 kbar. The olivine has numerous opaque inclusions and high Fo (91.5-96.5) relative to the retrograde olivine, reflecting its formation by deserpentinization. The prograde tremolite, which is low in Al₂O₃ (<1.0 wt.%), Cr₂O₃ (<0.35 wt.%), and Na₂O (<0.6 wt.%) but high in Mg# (up to 0.98) and SiO₂ (up to 59.9 wt.%), is different in size, shape and chemistry from the retrograde tremolite. The prograde peridotites display a U-shaped REE pattern (0.02-0.5 times PM), similar to diopside-zone retrograde metaperidotites, possible protoliths. They are enriched in LILE (e.g., Cs, Pb, Sr, Rb) relative to HFSE (e.g., Ta, Hf, Zr, Nb), like their protoliths, because of their local re-equilibration with the fluid released during dehydration of the protoliths. They have high contents of REE and some trace elements (e.g., Cs, Th, U, Ta) relative to their protoliths because of an external-element addition from the granitic magma. In-situ analyses of peridotitic silicates confirmed that the prograde tremolite and talc display a spoon-shaped primitive mantle (PM)-normalized REE pattern (0.1-3 times PM) in which LREE are higher than HREE contents. The prograde tremolite is depleted in Al, Na, Cr, Sc, V, Ti, B, HREE and Li, but is enriched in Si, Cs, U, Th, HFSE (Hf, Zr, Nb, Ta), Rb and Ba relative to the retrograde tremolite; the immobile-element depletion in this tremolite is inherited from its source (antigorite + secondary diopside), whereas the depletion of mobile elements (e.g., Li, B, Na, Al) is ascribed to their mobility during the deserpentinization and/or the depleted character of the source of tremolite. The enrichment of HFSE and LILE in the prograde tremolite is related to an external addition of these elements from fluid/melt of the surrounding granitic magma and/or in situ equilibrium with LILE-bearing fluid released during dehydration of serpentinized retrograde metaperidotites and olivine-bearing serpentinites (protoliths). The prograde olivine is higher in REE and most trace-element contents than the retrograde one due to the external addition of these elements; it is enriched in B, Co and Ni, but depleted in Li that was liberated during deserpentinization by prograde metamorphism.  相似文献   

Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting   总被引：2，自引：0，他引：2  

Shoji Arai  Hidenobu Okamura  Kazuyuki Kadoshima  Chima Tanaka  Kenji Suzuki  Satoko Ishimaru 《Island Arc》2011,20(1):125-137

We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall.  相似文献