Geochemical evidence (C,N and Pb isotopes) of recent anthropogenic impact in south‐central Chile from two environmentally distinct lake sediment records     

Nathalie Fagel  Sebastien Bertrand  Nadine Mattielli  Delphine Gilson  Luis Chirinos  Gilles Lepoint  Roberto Urrutia 《第四纪科学杂志》2010,25(7):1100-1112

In this paper, we compare the elemental and isotopic (C, N, Pb) geochemistry of lake sediments from two contrasted environments in south‐central Chile. The first lake, Laguna Chica de San Pedro (LCSP), is situated in the urbanised area of the Biobio Region (36°S). The second lake, Lago Puyehue (40° S), is located 400 km to the southeast of LCSP and within an Andean national park. Our aim is to identify environmental impacts associated with increasing industrial activities and land degradation during the last 150 a. In LCSP, shifts in C/N atomic ratios, δ¹³C and δ¹⁵N from 1915–1937 to the late 1980s are attributed to successive land degradation episodes in the lake watershed. Based on a Pb isotopic mixing model, we estimate that up to 20% of lead in LCSP sediments is supplied from urban atmospheric pollution. By contrast, human impact in the watershed of Lago Puyehue is very limited. We observe no change in organic geochemistry during the last 150 a and lead contamination remains lower than 5%, even during the last decades. Although contamination levels are much higher in LCSP than in Lago Puyehue, a peak in anthropogenic Pb is recorded during the same period (1974–1976) at both sites. This maximum contamination level is consistent with increased industrial activity in the vicinity of Concepción. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Multi-scale characterization of a complex karst and alluvial aquifer system in southern Germany using a combination of different tracer methods     

Fahrmeier  Nikolai  Frank  Simon  Goeppert  Nadine  Goldscheider  Nico 《Hydrogeology Journal》2022,30(6):1863-1875

Water suppliers face major challenges such as climate change and population growth. To prepare for the future, detailed knowledge of water resources is needed. In southern Germany, the state water supplier Zweckverband Landeswasserversorgung provides 3 million people with drinking water obtained from a complex karst and alluvial aquifer system and the river Danube. In this study, a combination of different tracing techniques was used with the goal of a multi-scale characterization of the aquifer system and to gain additional knowledge about groundwater flow toward the extraction wells in the Danube Valley. For the small-scale characterization, selected groundwater monitoring wells were examined using single-borehole dilution tests. With these tests, a wide range of flow behavior could be documented, including fast outflow within just a few hours in wells with good connection to the aquifer, but also durations of many weeks in low-permeability formations. Vertical flow, caused by multiple flow horizons or uprising groundwater, was detected in 40% of the tested wells. A regional multi-tracer test with three injections was used to investigate the aquifer on a large scale. For the highly karstified connection between a swallow hole and a spring group, high flow velocities of around 80 m/h could be documented. Exceptionally delayed arrivals, 250 and 307 days after the injection, respectively showing maximum velocities of 0.44 and 0.39 m/h, were observed in an area where low-permeability sediments overlay the karst conduits. With the chosen methods, a distinct heterogeneity caused by the geological setting could be documented on both scales.

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Hf–Zr anomalies in clinopyroxene from mantle xenoliths from France and Poland: implications for Lu–Hf dating of spinel peridotite lithospheric mantle     

Hilary Downes  Caja de Vries  Nadine Wittig 《International Journal of Earth Sciences》2015,104(1):89-102

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Field Tracer Tests to Evaluate Transport Properties of Tryptophan and Humic Acid in Karst     

Simon Frank  Nadine Goeppert  Nico Goldscheider 《Ground water》2021,59(1):59-70

The monitoring of water quality, especially of karst springs, requires methods for rapidly estimating and quantifying parameters that indicate contamination. In the last few years, fluorescence-based measurements of tryptophan and humic acid have become a promising tool to assess water quality in near real-time. In this study, we conducted comparative tracer tests in a karst experimental site to investigate the transport properties and behavior of tryptophan and humic acid in a natural karst aquifer. These two tracers were compared with the conservative tracer uranine. Fluorescence measurements were conducted with an online field fluorometer and in the laboratory. The obtained breakthrough curves (BTCs) and the modeling results demonstrate that (1) the online field fluorometer is suitable for real-time fluorescence measurements of all three tracers; (2) the transport parameters obtained for uranine, tryptophan, and humic acid are comparable in the fast flow areas of the karst system; (3) the transport velocities of humic acid are slower and the resulting residence times are accordingly higher, compared to uranine and tryptophan, in the slower and longer flow paths; (4) the obtained BTCs reveal additional information about the investigated karst system. As a conclusion, the experiments show that the transport properties of tryptophan are similar to those of uranine while humic acid is partly transported slower and with retardation. These findings allow a better and quantitative interpretation of the results when these substances are used as natural fecal and contamination indicators.  相似文献   

Improved understanding of dynamic water and mass budgets of high-alpine karst systems obtained from studying a well-defined catchment area     

Simon Frank  Nadine Goeppert  Nico Goldscheider 《水文研究》2021,35(4):e14033

Large areas of Europe, especially in the Alps, are covered by carbonate rocks and in many alpine regions, karst springs are important sources for drinking water supply. Because of their high variability and heterogeneity, the understanding of the hydrogeological functioning of karst aquifers is of particular importance for their protection and utilisation. Climate change and heavy rainfall events are major challenges in managing alpine karst aquifers which possess an enormous potential for future drinking water supply. In this study, we present research from a high-alpine karst system in the UNESCO Biosphere Reserve Großes Walsertal in Austria, which has a clearly defined catchment and is drained by only one spring system. Results show that (a) the investigated system is a highly dynamic karst aquifer with distinct reactions to rainfall events in discharge and electrical conductivity; (b) the estimated transient atmospheric CO₂ sink is about 270 t/a; (c) the calculated carbonate rock denudation rate is between 23 and 47 mm/1000a and (d) the rainfall-discharge behaviour and the internal flow dynamics can be successfully simulated using the modelling package KarstMod. The modelling results indicate the relevance of matrix storage in determining the discharge behaviour of the spring, particularly during low-flow periods. This research and the consequent results can contribute and initiate a better understanding and management of alpine karst aquifers considering climate change with more heavy rainfall events and also longer dry periods.  相似文献   

Spatial coherency analysis of seismic ground motions from a rock site dense array implemented during the Kefalonia 2014 aftershock sequence          下载免费PDF全文

A. Svay  V. Perron  A. Imtiaz  I. Zentner  R. Cottereau  D. Clouteau  P.‐Y. Bard  F. Hollender  F. Lopez‐Caballero 《地震工程与结构动力学》2017,46(12):1895-1917

The objective of studies presented in this paper is to analyse the spatial incoherency of seismic ground motions using signals from a velocimeter dense array located on a rock site, recording the aftershock sequence of the two M6 Kefalonia earthquakes that occurred in January/February 2014 (Kefalonia island, Greece). The analyses are carried out with both horizontal and vertical components of velocigrams for small separation distances of stations (<100 m). The coherencies of seismic ground motions identified from strong motion windows are compared with those identified from coda parts of signals. It is realized that there is no significant difference between the coherencies estimated from those two parts of signals. The influence of earthquake event number on the result of coherencies and the dispersions of coherencies estimated from different earthquake events are presented. Finally, coherencies estimated from the dense array are compared with several coherency models proposed and widely used in the literature. The possibility of modifying some parameters of those existing coherency models to fit with in situ coherencies are discussed and presented. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

Enrichment of seismic ground motion databases using Karhunen–Loève expansion     

Irmela Zentner  Fabrice Poirion 《地震工程与结构动力学》2012,41(14):1945-1957

Best estimate seismic analysis are generally based on time‐domain simulations of structural responses. The seismic load is then modeled by a stochastic process representing ground motion. For this purpose, the analyst can use recorded accelerograms or work with synthetically generated ones. The number of ground motion time‐histories available for a given scenario and site condition is limited and generally not sufficient for carrying out more advanced probabilistic structural response analysis. It is then necessary to have at our disposal methods that allow for generating synthetic accelerograms that realistically characterize earthquake ground motions. However, most of the methods proposed in literature for generating synthetic accelerograms do not accurately reproduce the natural variability of ground motion parameters (such as PGA, cumulative absolute velocity, and Arias intensity) observed for recorded time histories. In this paper, we introduce a new method for generating synthetic ground motion, based on Karhunen‐Loève decomposition and a non‐Gaussian stochastic model. The proposed method enables the structural analyst to simulate ground motion time histories featuring the properties mentioned above. To demonstrate its capability, we study the influence of the simulation method on different ground motion parameters and on soil response spectra. We finally compute fragility curves to illustrate the practical application of the proposed method. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

A conversation with Werner Käss (Germany) about his contributions to tracer hydrogeology and characterisation of mineral waters and spas     

Nico Goldscheider  Nadine Goeppert 《Hydrogeology Journal》2009,17(6):1543-1546

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IFKIS-Hydro: an early warning and information system for floods and debris flows     

Hans Romang  Massimiliano Zappa  Nadine Hilker  Matthias Gerber  François Dufour  Valérie Frede  Dominique Bérod  Matthias Oplatka  Christoph Hegg  Jakob Rhyner 《Natural Hazards》2011,56(2):509-527

IFKIS-Hydro is an information and warning system for hydrological hazards in small- and medium-scale catchments. The system collects data such as weather forecasts, precipitation measurements, water level gauges, discharge simulations and local observations of event-specific phenomena. In addition, IFKIS-Hydro incorporates a web-based information platform, which serves as a central hub for the submission and overview of data. Special emphasis is given to local information. This is accomplished particularly by human observers. In medium-scale catchments, discharge forecast models have an increasing importance in providing valuable information. IFKIS-Hydro was developed in several test regions in Switzerland and the first results of its application are available now. The system is constantly extended to additional regions and may become the standard for warning systems in smaller catchments in Switzerland.  相似文献