Organochlorine contaminants in sea turtles from the Eastern Pacific     

Gardner SC  Pier MD  Wesselman R  Juárez JA 《Marine pollution bulletin》2003,46(9):1082-1089

We measured organochlorine residues in three species of sea turtles from the Baja California peninsula, Mexico. Seventeen of 21 organochlorine pesticides analyzed were detected, with heptachlor epoxide and gamma-hexachlorocyclohexane the most prevalent (14 (40%) and 11 (31%) of the 35 tissue samples, respectively). PCBs were detected in all but one of the 9 turtles studied, with congener 18 the most commonly detected (8 (23%) of the samples). The dioxin-like congeners 118 and 180 were detected in 4 (11%) and 3 (9%) of the samples, respectively. Percent contribution of congeners was negatively correlated to their octanol-water partition coefficients, with kidney and muscle containing more lower-chlorinated congeners than liver or adipose samples. Levels of organochlorines detected in the present study were low, potentially attributable to the feeding habits of the predominant species collected in this study (herbivorous) and/or the samples obtained in an unindustrialized region.  相似文献   

Transport and deposition of pyroclastic material from the ∼1000 A.D. caldera-forming eruption of Volcán Ceboruco, Nayarit, Mexico     

B. L. Browne  J. E. Gardner 《Bulletin of Volcanology》2005,67(5):469-489

The complex eruption sequence from the ∼1000 A.D. caldera-forming eruption of Volcán Ceboruco, known as the Jala Pumice, offers an exceptional opportunity to examine how pyroclastic material is transported and deposited from pyroclastic density currents over variable topography. Three main pyroclastic surge deposits (S1, S2, and S3) and two pyroclastic flow deposits (Marquesado and North-Flank PFDs) were emplaced during this eruption. Pyroclastic surge deposits are massive, planar, or cross-bedded, poor-to-well sorted, and display fluctuations in thickness, median diameter, sorting, and lithology as a function of distance, topography, and flow dynamics. Marquesado pyroclastic flow deposits reveal lateral variations from massive, poorly sorted deposits located within 5 km of Ceboruco to planar bedded, moderately well sorted deposits located >15 km away over the nearly horizontal topography to the south of Ceboruco. North-Flank pyroclastic flow deposits also reveal lateral variations from massive, poorly sorted deposits located within 4 km of Ceboruco to planar bedded, moderately well sorted deposits located 8 km away atop an escarpment that steeply rises 230 m from the northern valley floor. Field observations, granulometric analyses, component analyses, and crystal sedimentation calculations along flow-parallel sampling transects all suggest that both surges and flows were density stratified currents, where deposition occurred from a basal region of higher particle concentration that was supplied from an overlying dilute layer that transports particles in suspension. This supports the idea of a transition between “flow” and “surge” end members with variations in particle concentration. Topography greatly affects the transport and depositional capacity of the pyroclastic density currents as a result of “blocking”, either by topographic obstacles or by abrupt breaks at the base of volcano slopes, whereas the origin of Jala Pumice surge deposits (phreatomagmatic versus magmatic) appears to have little impact on their flow dynamics. Editorial responsibility: A.W. Woods This revised version was published in February 2005 with corrections to the title. An erratum to this article is available at .  相似文献   

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows     

Felipe Espinoza  Diego Morata  Ewan Pelleter  Ren  C. Maury  Manuel Su  rez  Yves Lagabrielle  Mireille Polv    Herv  Bellon  Joseph Cotten  Rita De la Cruz  Christelle Guivel 《Lithos》2005,82(3-4):315-343

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.  相似文献   

Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska   总被引：2，自引：0，他引：2  

Diana C. Roman  Katharine V. Cashman  Cynthia A. Gardner  Paul J. Wallace  John J. Donovan 《Bulletin of Volcanology》2006,68(3):240-254

Compositional heterogeneity (56–64 wt% SiO₂ whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO₂) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10 years) between Augustine's recent eruptive pulses may also inhibit homogenization, as short repose periods and chemically heterogeneous magmas are observed at several volcanoes in the Cook Inlet region of Alaska.  相似文献   

Evaluation of two direct immunoassays for rapid detection of petroleum products on marine birds     

Fritcher DL  Mazet JA  Ziccardi MH  Gardner IA 《Marine pollution bulletin》2002,44(5):388-395

To reduce rehabilitation time and improve survival, a practical, objective test is needed to determine if marine birds are contaminated with oil before they enter captivity. The RaPID Assays and EnviroGard immunoassays for detection of polycyclic aromatic hydrocarbons (PAHs) in soil were evaluated for their ability to detect petroleum on feather samples from 30 intermediate fuel oil contaminated and 30 uncontaminated common murres (Uria aalge). Sensitivity, specificity, positive and negative predictive value, precision, and time required to run each assay were determined. The RaPID Assays was 96.7% sensitive and specific, while the EnviroGard assay was 93.3% sensitive, and 90.0% specific. Sensitivity decreased at higher dilutions for both assays. Intra-replicate variation was less than 20%. Our evaluation showed that these immunoassays are rapid and cost-effective methods for detecting oil-contamination on the plumage of seabirds, with the EnviroGard assay being more practical in most oil spill response situations due to ease of use and rapidity of results.  相似文献   

Field Evaluation of In Situ Chemical Oxidation Through Vertical Well-to-Well Recirculation of NaMnO₄     

K.S. Lowe  EG. Gardner  R.L. Siegrist 《Ground Water Monitoring & Remediation》2002,22(1):106-115

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Refractory organic carbon in particle-size fractions of arable soils I: distribution of refractory carbon between the size fractions   总被引：2，自引：0，他引：2  

Rita Kiem  Heike Knicker  Ingrid Kgel-Knabner 《Organic Geochemistry》2002,33(12)

Refractory compounds are responsible for the long-term sequestration of organic matter in soil. The aim of this study is to assess the storage of refractory compounds, i.e. compounds with long turnover times, across size separates in arable soils. The contents and distribution of organic carbon (OC) and nitrogen (N) in size fractions were examined for two contrasting treatment types from long-term agroecosystem experiments, i.e. C-depleted and fertilized plots. The soil organic carbon (SOC) pool of the C-depleted plots is considered to be relatively enriched in refractory compounds compared with the SOC in the fertilized counterparts. In two of the three long-term experiments, the relative retention of OC in separates <20 μm was considerably higher than in separates 2000–20 μm (OC contents in depleted plots compared with fertilized plots). Highest residual contents of OC were found in fractions <6 μm. In the third experiment, additionally to the very fine fractions, separates 250–20 μm retained a high proportion of OC. The behavior of N was analogous to that of OC: the highest relative residues in the depleted plots were found in fine separates. These results indicate that in the investigated arable soils, C and N compounds associated with fine separates are most stable. Refractory OC in arable soils may be largely stored in fine particle-size fractions.  相似文献   

Mineral fibres and environmental monitoring:A comparison of different analytical strategies in New Caledonia     

Jasmine Rita Petriglieri  Christine Laporte-Magoni  Peggy Gunkel-Grillon  Mario Tribaudino  Danilo Bersani  Orietta Sala  Monika Le Mestre  Ruggero Vigliaturo  Nicola Bursi Gandolfi  Emma Salvioli-Mariani 《地学前缘(英文版)》2020,11(1):189-202

Covered by ultrabasic units for more than a third of its surface,the New Caledonia(South West Pacific)is one of the largest world producers of Ni-ore from lateritic deposits.Almost all outcrops of geological units and open mines contain serpentine and amphibole,also as asbestos varieties.In this geological context,in which weathering processes had a great contribution in the production and dispersion of mineral fibres into the environment,the development of a routinely analytical strategy,able to discriminate an asbestiform fibre from a non-harmful particle,is a pivotal requisite.However,the acquisition of all these parameters is necessary for determining the risk associated to fibres exposition.A multidisciplinary routinely approach,based on the use of complementary simply-to-use but reliable analytical methods is the only possible strategy.In addition,the instrumental apparatus must be easily transportable on the field,directly on the mining site.The employment of specialized tools such as Polarized Light Microscopy associated to Dispersion Staining method(PLM/DS)and portable Raman spectroscopy for identification of environmental asbestos,are proved extremely effective in the improvement of the performance and rapidity of data acquisition and interpretation.Both PLM/DS and handheld Raman devices confirmed to be discriminant in the detection and characterization of asbestos fibres for both serpentine and amphibole.Furthermore,these techniques proved extremely effective even in the presence of strongly fibrous and altered samples.  相似文献   

Cyclone track forecasting based on satellite images using artificial neural networks     

Rita Kovordányi  Chandan Roy 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(6):513-521

Many places around the world are exposed to tropical cyclones and associated storm surges. In spite of massive efforts, a great number of people die each year as a result of cyclone events. To mitigate this damage, improved forecasting techniques must be developed. The technique presented here uses artificial neural networks to interpret NOAA-AVHRR satellite images. A multi-layer neural network, resembling the human visual system, was trained to forecast the movement of cyclones based on satellite images. The trained network produced correct directional forecast for 98% of test images, thus showing a good generalization capability. The results indicate that multi-layer neural networks could be further developed into an effective tool for cyclone track forecasting using various types of remote sensing data. Future work includes extension of the present network to handle a wide range of cyclones and to take into account supplementary information, such as wind speeds, water temperature, humidity, and air pressure.  相似文献   

Sources and transport of dissolved and particulate organic carbon in the Mississippi River estuary and adjacent coastal waters of the northern Gulf of Mexico   总被引：5，自引：0，他引：5  

Xu-Chen Wang  Robert F. Chen  George B. Gardner 《Marine Chemistry》2004,89(1-4):241

Dissolved organic carbon (DOC), stable carbon isotopic (δ¹³C) compositions of DOC and particulate organic carbon (POC), and elemental C/N ratios of POC were measured for samples collected from the lower Mississippi and Atchafalaya rivers and adjacent coastal waters in the northern Gulf of Mexico during the low flow season in June 2000 and high flow season in April 2001. These isotopic and C/N results combined with DOC measurements were used to assess the sources and transport of terrestrial organic matter from the Mississippi and Atchafalaya rivers to the coastal region in the northern Gulf of Mexico. δ¹³C values of both POC (−23.8‰ to −26.8‰) and DOC (−25.0‰ to −29.0‰) carried by the two rivers were more depleted than the values measured for the samples collected in the offshore waters. Strong seasonal variations in δ¹³C distributions were observed for both POC and DOC in the surface waters of the region. Fresh water discharge and horizontal mixing played important roles in the distribution and transport of terrestrial POC and DOC offshore. Our results indicate that both POC and DOC exhibited non-conservative behavior during the mixing especially in the mid-salinity range. Based on a simple two end-member mixing model, the comparison of the measured DOC-δ¹³C with the calculated conservative isotopic mixing curve indicated that there was a significant in situ production of marine-derived DOC in the mid- to high-salinity waters consistent with our in situ chlorophyll-a measurements. Our DOC-δ¹³C data suggest that a removal of terrestrial DOC mainly occurred in the high-salinity (>25) waters during the mixing. Our study indicates that the mid- to high- (10–30) salinity range was the most dynamic zone for organic carbon transport and cycling in the Mississippi River estuary. Variability in isotopic and elemental compositions along with variability in DOC and POC concentrations suggest that autochthonous production, bacterial utilization, and photo-oxidation could all play important roles in regulating and removing terrestrial DOC in the northern Gulf of Mexico and further study of these individual processes is warranted.  相似文献