Influence of high-pressure processing on the structure and memory effect of synthetic layered double hydroxides     

Jaqueline C. Rodrigues  Tania Maria Haas Costa  Márcia R. Gallas  Celso C. Moro 《Physics and Chemistry of Minerals》2009,36(8):439-446

We investigate the structural evolution of synthetic layered double hydroxides (LDH) samples, processed at room temperature and high-pressure (up to 7.7 GPa) in a toroidal chamber with two pressure-transmitting media, lead and graphite, using X-ray diffraction, thermogravimetry and N₂-adsorption isotherms techniques. The X-ray patterns of compacted samples show a decrease in the peak intensities. For both pressure-transmitting media, our samples revealed a reduction of the basal d-spacing for the (003) plane when processed at 7.7 GPa. The expected high-pressure-induced amorphization was not observed. Surprisingly, we find high-pressure processing to have a strong influence on the memory effect of the LDH, due essentially to the reduction of the surface area and pore closing. Even when immersed in water, our samples did not recover the LDH structure, when either calcined at 450°C and compacted at 7.7 GPa, or calcined at 700°C and immediately compacted at 2.5 and 7.7 GPa.  相似文献   

Clay minerals from the sedimentary cover from the Northwest Iberian shelf     

A. Oliveira  F. Rocha  A. Rodrigues  J. Jouanneau  A. Dias  O. Weber  C. Gomes 《Progress in Oceanography》2002,52(2-4)

The Northern Iberian margin is a typical example of a continental margin subjected to seasonal highly energetic regime (waves and tides) and receiving inputs of continental sediments via riverine discharges. The principal goal of this study has been to use clay minerals as indicators of sedimentary dynamics in the open shelf system. The distributions of clay mineral in the top layer of the sedimentary cover are shown to be related to their continental sources, but also reflect the influences of winter storms and longshore currents in determining the pathways of sediment transport.The mineralogical composition of the material issuing from the rivers is very similar to the general mineralogical composition of the fine fractions of the seabed sediments. Those deposits that are directly influenced by riverine discharges have higher contents of kaolinite (>20%), whereas those that are not have higher contents of illite (>80%). The available data indicate no significant quantities of terrigenous particles are being discharged from the Spanish rias. Therefore, we conclude that physical processes are controlling the clay mineral distributions and that, despite contributions from the Minho River, the main source of fine detrital particles to the shelf region is the Douro River discharge. These particles settle on the middle shelf, below the 60 m isobath. During storm events these particles are re-suspended and advected northwards to the Galician shelf or into deeper domains. Thus the distributions of the clays indicate there is a net transport of fine sediments both northwards and off-shelf.  相似文献   

Assessment of the influence of horizontal diaphragms on the seismic performance of vernacular buildings     

Javier Ortega  Graça Vasconcelos  Hugo Rodrigues  Mariana Correia 《Bulletin of Earthquake Engineering》2018,16(9):3871-3904

The awareness and preservation of the vernacular heritage and traditional construction techniques and materials is crucial as a key element of cultural identity. However, vernacular architecture located in earthquake prone areas can show a particularly poor seismic performance because of inadequate construction practices resulting from economic restraints and lack of resources. The horizontal diaphragms are one of the key aspects influencing the seismic behavior of buildings because of their major role transmitting the seismic actions to the vertical resisting elements of the structure. This paper presents a numerical parametric study adopted to understand the seismic behavior and resisting mechanisms of vernacular buildings according to the type of horizontal diaphragm considered. Detailed finite element modeling and nonlinear static (pushover) analyses were used to perform the thorough parametric study aimed at the evaluation and quantification of the influence of the type of diaphragm in the seismic behavior of vernacular buildings. The reference models used for this study simulate representative rammed earth and stone masonry vernacular buildings commonly found in the South of Portugal. Therefore, this paper also contributes for a better insight of the structural behavior of vernacular earthen and stone masonry typologies under seismic loading.  相似文献   

Flash flood in the mountainous region of Rio de Janeiro state (Brazil) in 2011: part I—calibration watershed through hydrological SMAP model     

Cavalcante  Marianna Rodrigues Gullo  da Cunha Luz Barcellos  Priscila  Cataldi  Marcio 《Natural Hazards》2020,100(3):1117-1136

Natural Hazards - Flooding and water logging possess severe hazards to human population in many parts of the world. Mumbai, the study area, is one of the cities in India and has been frequently...  相似文献   

Coastal ridge constructive processes at a multi-decadal scale in Barreta Island (southern Portugal)     

Xabier Herrero  Susana Costas  Katerina Kombiadou 《地球表面变化过程与地形》2020,45(2):411-423

Multiple ridges across prograding coasts may display variable geometries, commonly expressed through varying elevations. Changes in ridge elevation have been traditionally related to the occurrence of fluctuating progradation rates, which might, in turn, be driven by shifting environmental conditions. Here, we explore the geometry and growth mechanisms of multiple ridges, generated at Barreta Island (Ria Formosa, southern Portugal), as a consequence of the rapid progradation of the island over the last 70 years, following the artificial fixation of the downdrift Faro-Olhão inlet with jetties in 1955. The variability in the morphology of these features was analysed in combination with available wind and wave data, in order to better distinguish growth mechanisms and understand the main parameters determining the final geometry of the observed ridges. The results suggest that (1) most of the identified ridges fall in the beach ridge classification, as they have been mostly built by marine processes, and (2) the parameters derived from, or closely related to wave climate variability (e.g. progradation rates, storm occurrence) can jointly explain most of the observed morphological changes, while aeolian processes played a secondary role. Indeed, ridge geometry appears mainly controlled by progradation rates, with higher ridges associated with lower progradation rates. Progradation rate, in turn, is mostly related to longshore wave power, storminess, and the occurrence storm groups. Yet, the final configuration of ridges can also be affected by runup levels and onshore winds. Therefore, establishing the relation between ridge geometry and wave climate is not a straightforward task, because of the complex processes and interactions that control coastal morphodynamics. © 2019 John Wiley & Sons, Ltd.  相似文献   

A Phenomenological Model for Particle Retention in Single,Saturated Fractures     

Sandrina Rodrigues  Sarah Dickson 《Ground water》2014,52(2):277-283

Fractured aquifers are some of the most poorly characterized subsurface environments despite posing one of the highest risks to the protection of potable groundwater. This research was designed to improve the understanding of the factors affecting particle transport through fractures by developing a phenomenological model based on laboratory‐scale transport data. The model presented in this research employed data from over 70 particle tracer tests conducted in single, saturated, variable‐aperture fractures that were obtained from the natural environment and fractured in the laboratory or cast from epoxy in the laboratory. The particles employed were Escherichia coli RS2‐GFP and microspheres. The tracer experiments were conducted in natural (dolomitic limestone and granite) as well as epoxy replicas of the natural fractures. The multiple linear regression analysis revealed that the most important factors influencing particle retention in fractures are the ratio of the ionic strength of solution to collector charge, the ratio of particle to collector charge, and the ratio of advective to diffusive forces as described by the Peclet number. The model was able to reasonably (R² = 0.64) predict the fraction of particles retained; however, it is evident that some factors not accounted for in the model also contributed to retention. This research presents a novel approach to understanding particle transport in fractures, and illustrates the relative importance of various factors affecting the transport mechanisms. The utility of this model lies in the increased understanding of particle transport in fractures, which is extremely useful for directing future research.  相似文献   

Early contamination of European flounder (Platichthys flesus) by PCDD/Fs and dioxin-like PCBs in European waters     

Margarida Nunes  Filipe Martinho  Anaïs Vernisseau  Philippe Marchand  Bruno Le Bizec  Henk W. van der Veer  Henrique N. Cabral  Fernando Ramos  Miguel A. Pardal 《Marine pollution bulletin》2014

Contamination levels and profiles of 7 polychlorinated-p-dioxins, 10 polychlorinated furans (PCDD/Fs) and 12 dioxin-like polychlorinated biphenyls (dl-PCBs) were investigated in juvenile European flounder (Platichthys flesus) captured in different nursery areas in the northeastern Atlantic coast across its geographical distribution range. The toxic equivalent concentrations (WHO-TEQ_fish) were also determined in order to evaluate which P. flesus population was more exposed to dioxin-like toxicity. Juveniles caught in the Sørfjord (Norway) showed the lowest WHO-TEQ_fish concentration (0.052 pg WHO-TEQ_fish g⁻¹ wet weight) whereas the highest value was observed in fish from the Wadden Sea (The Netherlands; 0.291 pg WHO-TEQ_fish g⁻¹ ww), mainly due to the greater contribution of 2,3,7,8-tetrachlorodibenzo-p-dioxin, the most toxic congener. Nonetheless, when comparing the results with existent tissue residue-based toxicity benchmarks, no adverse effects resulting from PCDD/Fs and dl-PCBs are expected to occur in flounder from the studied systems.  相似文献   

Experimental modelling of flocculation processes-the case of Paraiba do Sul Estuary     

Alfredo TRENTO  Susana VINZN 《国际泥沙研究》2014,29(3):378-390

The aggregation dynamics of fine sediments was analysed through laboratory tests using Couette and disk flocculators.It was shown that floc sizes tend to increase as concentrations grow both in fresh and salt water,in agreement with the aggregation theory,and that equilibrium diameters are slightly greater in salt environments for flocs developed either under shear stress or by differential sedimentation.Their transport and the aggregation processes were preliminarily studied in the estuary of the Paraiba do Sul River using a particle tracking model and field data.The floc breakup process by shear stress was included in the model.Yield stresses,which were determined by fractal dimensions and differential density,were accounted for.After the calibration of the collision efficiency coefficients,the numerical model was able to predict floc sizes comparable with those measured at the Paraiba do Sul estuary,which,in turn,were similar to those obtained during the laboratory experiments in the Couette flocculator.  相似文献   

Response reduction factor of irregular RC buildings in Kathmandu valley     

Hemchandra Chaulagain  Hugo Rodrigues  Enrico Spacone  Ramesh Guragain  Radhakrishna Mallik  Humberto Varum 《地震工程与工程振动(英文版)》2014,13(3):455-470

Most current seismic design includes the nonlinear response of a structure through a response reduction factor(R). This allows the designer to use a linear elastic force-based approach while accounting for nonlinear behavior and deformation limits. In fact, the response reduction factor is used in modern seismic codes to scale down the elastic response of a structure. This study focuses on estimating the actual ‘R' value for engineered design/construction of reinforced concrete(RC) buildings in Kathmandu valley. The ductility and overstrength of representative RC buildings in Kathmandu are investigated. Nonlinear pushover analysis was performed on structural models in order to evaluate the seismic performance of buildings. Twelve representative engineered irregular buildings with a variety of characteristics located in the Kathmandu valley were selected and studied. Furthermore, the effects of overstrength on the ductility factor, beam column capacity ratio on the building ductility, and load path on the response reduction factor, are examined. Finally, the results are further analyzed and compared with different structural parameters of the buildings.  相似文献   

Geophysical investigation using resistivity and GPR methods: a case study of a lubricant oil waste disposal area in the city of Ribeirão Preto,São Paulo,Brazil     

Alexandre Lisboa Lago  Vagner Roberto Elis  Welitom Rodrigues Borges  Giovanni Chaves Penner 《Environmental Geology》2009,58(2):407-417

Geophysics has been shown to be effective in identifying areas contaminated by waste disposal, contributing to the greater efficiency of soundings programs and the installation of monitoring wells. In the study area, four trenches were constructed with a total volume of about 25,000 m³. They were almost totally filled with re-refined lubricating oil waste for approximately 25 years. No protection liners were used in the bottoms and laterals of the disposal trenches. The purpose of this work is to evaluate the potential of the resistivity and ground penetrating radar (GPR) methods in characterizing the contamination of this lubricant oil waste disposal area in Ribeirão Preto, SP, situated on the geological domain of the basalt spills of the Serra Geral Formation and the sandstones of the Botucatu Formation. Geophysical results were shown in 2D profiles. The geophysical methods used enabled the identification of geophysical anomalies, which characterized the contamination produced by the trenches filled with lubricant oil waste. Conductive anomalies (smaller than 185 Ωm) immediately below the trenches suggest the action of bacteria in the hydrocarbons, as has been observed in several sites contaminated by hydrocarbons in previously reported cases in the literature. It was also possible to define the geometry of the trenches, as evidenced by the GPR method. Direct sampling (chemical analysis of the soil and the water in the monitoring well) confirmed the contamination. In the soil analysis, low concentrations of several polycyclic aromatic hydrocarbons (PAHs) were found, mainly naphthalene and phenanthrene. In the water samples, an analysis verified contamination of the groundwater by lead (Pb). The geophysical methods used in the investigation provided an excellent tool for environmental characterization in this study of a lubricant oil waste disposal area, and could be applied in the study of similar areas.  相似文献