Phase relation of CaSO<Subscript>4</Subscript> at high pressure and temperature up to 90 GPa and 2300 K     

Taku Fujii  Hiroaki Ohfuji  Toru Inoue 《Physics and Chemistry of Minerals》2016,43(5):353-361

Calcium sulfate (CaSO₄), one of the major sulfate minerals in the Earth’s crust, is expected to play a major role in sulfur recycling into the deep mantle. Here, we investigated the crystal structure and phase relation of CaSO₄ up to ~90 GPa and 2300 K through a series of high-pressure experiments combined with in situ X-ray diffraction. CaSO₄ forms three thermodynamically stable polymorphs: anhydrite (stable below 3 GPa), monazite-type phase (stable between 3 and ~13 GPa) and barite-type phase (stable up to at least 93 GPa). Anhydrite to monazite-type phase transition is induced by pressure even at room temperature, while monazite- to barite-type transition requires heating at least to 1500 K at ~20 GPa. The barite-type phase cannot always be quenched from high temperature and is distorted to metastable AgMnO₄-type structure or another modified barite structure depending on pressure. We obtained the pressure–volume data and density of anhydrite, monazite- and barite-type phases and found that their densities are lower than those calculated from the PREM model in the studied P–T conditions. This suggests that CaSO₄ is gravitationally unstable in the mantle and fluid/melt phase into which sulfur dissolves and/or sulfate–sulfide speciation may play a major role in the sulfur recycling into the deep Earth.  相似文献   

Temporal variations in the current structure and volume transport of the Coastal Oyashio revealed by direct current measurement     

Akira Kusaka  Yugo Shimizu  Toru Sato  Jiro Yoshida 《Journal of Oceanography》2016,72(4):601-615

Direct current measurements by a shipboard and bottom-mounted acoustic Doppler current profiler and concurrent hydrographic observations with a CTD were conducted off southeastern Hokkaido, Japan, between January and May 2005 to reveal temporal variations in the current structure and volume transport of the Coastal Oyashio (CO). The CO, which has a baroclinic jet structure with southwestward speeds exceeding 90 cm s^?1 and a width of 7–8 km, was associated with a surface-to-bottom density front and was formed on the offshore side of the shelf break. The volume transport of CO (T _CO) was estimated by integrating the fluxes of lower-density water that was trapped against the coast along the density front represented by the 26.2 σ _θ isopycnal line. This transport decreased monotonously from 0.79 Sv (1 Sv = 10⁶ m³ s^?1) in January to 0.21 Sv in March and subsequently to 0.12 Sv in May, possibly due to the decay of the East Sakhalin Current Water in the Okhotsk Sea. Accompanied by a decrease in T _CO, the location of the jet structure associated with the density front moved toward the coast while the maximum speed of the jet decreased and the tilt of the front became more horizontal. Consequently, more saline offshore Oyashio water flowed into the deep part of the shelf area, and the current structure altered from relatively barotropic in winter to baroclinic in spring. This study is the first to estimate the observed volume transport of the CO from direct current measurements.  相似文献   

The effects of possible contamination by sample holders on samples to be returned by Hayabusa2     

Naoki Shirai  Yuzuru Karouji  Kazuya Kumagai  Masayuki Uesugi  Kaori Hirahara  Motoo Ito  Naotaka Tomioka  Kentaro Uesugi  Akira Yamaguchi  Naoya Imae  Takuji Ohigashi  Toru Yada  Masanao Abe 《Meteoritics & planetary science》2020,55(7):1665-1680

Chemical compositions of materials used for new sample holders (vertically aligned carbon nanotubes [VACNTs] and polyimide film), which were developed for the analysis of Hayabusa2‐return samples, were determined by instrumental neutron activation analysis and/or instrumental photon activation analysis, to estimate contamination effects from the sample holders. The synthetic quartz plate used for the sample holders was also analyzed. Ten elements (Na, Al, Cr, Mn, Fe, Ni, Eu, W, Au, and Th) and 14 elements (Na, Al, K, Sc, Ti, Cr, Zn, Ga, Br, Sb, La, Eu, Ir, and Au) could be detected in the VACNTs and polyimide film, respectively. The VACNT data show that contamination by this material with respect to the Murchison meteorite is negligible in terms of the elemental ratios (e.g., Fe/Mn, Na/Al, and Mn/Cr) used for the classification of meteorites due to the extremely low density of VACNTs. However, for the Au/Cr ratio, even small degrees (1.7 wt%) of contamination by VACNTs will change the Au/Cr ratio. Elemental ratios used for the classification of meteorites are only influenced by large amounts of contamination (>60 wt%) of polyimide film, which is unlikely to occur. In contrast, detectable effects on Ti isotopic compositions are caused by >0.1 and >0.3 wt% contamination by VACNTs and polyimide film, respectively, and Hf isotopic changes are caused by >0.1 wt% contamination by VACNTs. The new sample holders (VACNTs and polyimide film) are suitable for chemical classification of Hayabusa2‐return samples, because of their ease of use, applicability to multiple analytical instruments, and low contamination levels for most elements.  相似文献   

Best practices for the use of meteorite names in publications     

Philipp R. Heck  Christopher Herd  Jeffrey N. Grossman  Dmitry Badjukov  Audrey Bouvier  Emma Bullock  Hasnaa Chennaoui‐Aoudjehane  Vinciane Debaille  Tasha L. Dunn  Denton S. Ebel  Ludovic Ferrire  Laurence Garvie  Jrme Gattacceca  Matthieu Gounelle  Richard Herd  Trevor Ireland  Emmanuel Jacquet  Robert J. Macke  Tim McCoy  Francis M. McCubbin  Takashi Mikouchi  Knut Metzler  Mathieu Roskosz  Caroline Smith  Meenakshi Wadhwa  Linda Welzenbach‐Fries  Toru Yada  Akira Yamaguchi  Ryan A. Zeigler  Michael Zolensky 《Meteoritics & planetary science》2019,54(7):1397-1400

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Latitudinal and local variations of the life history characteristics of the thalassinidean decapod, Upogebia yokoyai: A hypothesis based on trophic conditions     

Miho Yamasaki  Takahiro Nanri  Shino Taguchi  Yoshitake Takada  Masayuki Saigusa 《Estuarine, Coastal and Shelf Science》2010

Mean total length of the eldest cohort (MTLe) of the thalassinidean decapod, Upogebia yokoyai sampled at 16 sites showed a latitudinal variation from south-west islands of the Ryukyu Archipelago (24° N) to the Seto-Inland Sea of Japan (34° N). Local variations were however also found from sites in the same latitudes. The level of the organic content in each habitat showed a positive correlation with MTLe. We hypothesized that MTLe is strongly affected by the trophic condition, resulting in the local variations. To test this hypothesis, two estuaries with different organic content were compared; Kodono River (Kochi Prefecture, 33° N) which was relatively oligotrophic and Sakata River (Hiroshima Prefecture, 34° N) which was highly eutrophicated. The Kodono River population showed slow growth after settlement, and growth stopped in May to June. This population survived for only one or two years, resulting in small MTLe. On the other hand, the Sakata River population showed fast growth from August to December. This population survived for three years, resulting in large MTLe. Maturation was estimated to occur two years after settlement in both populations. Low salinities may partially affect MTLe. Habitats in the Seto-Inland Sea (33.5–34.8° N) were eutrophicated, but many habitats in the subtropical islands (24–31° N) were relatively oligotrophic. Latitudinal variation of MTLe was reflected by the geographical difference in trophic condition. A negative relationship between population density and growth was found, which was explained in terms of reduced survival of recruits in the eutrophicated habitats.  相似文献   

Ferric iron partitioning between plagioclase and silicate liquid: thermodynamics and petrological applications     

Toru Sugawara 《Contributions to Mineralogy and Petrology》2001,141(6):659-686

A series of Fe and Mg partition experiments between plagioclase and silicate liquid were performed in the system SiO₂-Al₂O₃-Fe₂O₃-FeO-MgO-CaO-Na₂O under oxygen fugacities from below the IW buffer up to that of air. A thermodynamic model of plagioclase solid solution for the (CaAl,NaSi,KSi)(Fe³⁺,Al³⁺)Si₂O₈-Ca(Fe²⁺,Mg)Si₃O₈ system is proposed and is calibrated by regression analysis based on new and previously reported experimental data of Fe and Mg partitioning between plagioclase and silicate liquid, and reported thermodynamic properties of end members, ternary feldspar and silicate liquid. Using the derived thermodynamic model, FeO^t, MgO content and Mg/(Fe^t+Mg) in plagioclase can be predicted from liquid composition with standard deviations of ǂ.34 wt% (relative error =9%) and ǂ.08 wt% (14%) and ǂ.7 (8%) respectively. Calculated Fe³⁺-Al exchange chemical potentials of plagioclase, m_{Fe^{3 +} ( Al )- 1} ^Pl{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Pl}} agree with those calculated using reported thermodynamic models for multicomponent spinel, m_{Fe^{3 +} ( Al )- 1} ^Sp{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Sp}} and clinopyroxene, m_{Fe^{3 +} ( Al )- 1} ^Cpx{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Cpx}} . The FeO^t content of plagioclase coexisting with spinel or clinopyroxene is affected by Fe³⁺/(Fe³⁺+Al) and Mg/(Fe+Mg) of spinel or clinopyroxene and temperature, while it is independent of the anorthite content of plagioclase. Three oxygen barometers based on the proposed model are investigated. Although the oxygen fugacities predicted by the plagioclase-liquid oxygen barometer are scattered, this study found that plagioclase-spinel-clinopyroxene-oxygen and plagioclase-olivine-oxygen equilibria can be used as practical oxygen barometers. As a petrological application, prediction of plagioclase composition and f_O2 are carried out for the Upper Zone of the Skaergaard intrusion. The estimated oxygen fugacities are well below QFM buffer and consistent with the estimation of oxidization states in previous studies.  相似文献   

Dislocation microstructures in naturally deformed silicate garnets   总被引：1，自引：0，他引：1  

Jun-ichi Ando  Kiyoshi Fujino  Toru Takeshita 《Physics of the Earth and Planetary Interiors》1993,80(3-4):105-116

Dislocation microstructures of naturally deformed silicate garnets and olivines in garnet-peridotites and silicate garnets in eclogites from four localities have been observed with a transmission electron microscope (TEM) to clarify the dislocation characteristics of silicate garnets. We have obtained the following results: (1) dislocation densities of garnets in all the garnet-peridotites (ρ = 10⁵−10⁷ cm⁻²) are always nearly an order of magnitude lower than those of co-existing olivines; (2) dislocation densities of garnets in eclogites (ρ = 10⁵−10⁸ cm⁻²) which are embedded in garnet-peridotites are almost an order of magnitude higher than those of garnets in the surrounding garnet-peridotites; (3) the dominant Burgers vector, b, of mainly edge dislocations in garnet is 100 for specimens with dislocation density ρ = 10⁵−10⁶ cm⁻², while b=1/2111 for specimens with ρ = 10⁷−10⁸ cm⁻². Result (1) indicates that the observed dislocations in garnets were formed by plastic deformation under the same stresses as for co-existing olivines, and that there is a similar relationship between applied stress and dislocation density for garnets as for olivines. Result (2) suggests that the stress concentration occurred around eclogites embedded in garnet-peridotites, and the resulting differential stress in garnets in eclogites was further elevated by the interlocking of neighboring hard garnet grains. Finally, result (3) indicates that the dominant Burgers vector of mainly edge dislocations in garnet changes from 100 to 1/2111 with increasing applied differential stress.  相似文献   

Gonadal histology and serum vitellogenin levels of bigeye tuna Thunnus obesus from the Northern Pacific Ocean--absence of endocrine disruption bio-indicators     

Hashimoto S  Kurihara R  Strüssmann CA  Yamasaki T  Soyano K  Hara A  Shiraishi H  Morita M 《Marine pollution bulletin》2003,46(4):459-465

Endocrine disrupting chemicals such as organochlorines have been detected in a large number of marine fish. Histological observation of the gonads, measurement of serum vitellogenin (VTG) level and of liver polychlorinated biphenyl (PCB) content were performed to evaluate the reproductive health and the contamination with endocrine disruptors in bigeye tuna Thunnus obesus, collected in the northern Pacific Ocean in 1999 and 2000. Abnormalities commonly found in species affected by endocrine disruptors such as the presence of oocytes in the testis or elevated serum VTG levels were not found in any of males examined. Both males and females had only small amounts of liver PCB content. The results suggest that currently there is little if any risk of organochlorine contamination or endocrine disruption of gonadal function in bigeye tuna from the northern Pacific Ocean. However, further studies are necessary to evaluate the health status of the open sea fishery resources.  相似文献   

Floral changes in calcareous nannofossils and their paleoceanographic significance in the equatorial Pacific Ocean during the last 500 000 years     

Shun  Chiyonobu  Tokiyuki  Sato  Reika  Narikiyo  Makoto  Yamasaki 《Island Arc》2006,15(4):476-482

Abstract   The late Quaternary calcareous nannofossil assemblages from Ocean Drilling Program Holes 807A and 846B, located in the western and eastern equatorial Pacific Ocean, respectively, were analyzed to clarify changes in surface-water conditions during the last 500 000 years. The uppermost Quaternary sediments in both holes contain abundant nannofossils, and their assemblages are characterized by high species diversity. The absolute abundances of coccoliths (specimens/g) and relative numbers of small reticulofenestrids decreased drastically in both holes between 0.3 and 0.2 Ma, whereas the relative abundance of warm-water species and Florisphaera profunda increased suddenly at this time. These data indicate that upwelling around the western and eastern equatorial Pacific regions weakened after 0.2 Ma, which was caused by a decrease in trade-wind strength.  相似文献   

Relationship between faults and generation of inland shallow earthquakes: enlightenment of the M=7.2 southern Hyogo prefecture earthquake     

Toru Ouchi  Qing-Hua Huang 《地震学报(英文版)》1998,11(4):413-420

The M=7.2 southern Hyogo prefecture earthquake, which occurred on January 17, 1995, destroyed the region severely. Further researches are necessary to explain the problems obtained from this earthquake. We have discussed some characteristics correlating with this earthquake, such as distribution of aftershocks and disaster, relationship between fault and generation of inland shallow earthquakes, strong motion and so on. The tectonic movements of surface faults may be different from those of deep faults. Earthquakes may not be restricted directly by the tectonic movements of surface faults. The strong motion zone is often appeared in the region a little away from the both ends or from the single side of a fault instead of the region of a focal fault. Some mechanisms of strong motion have also been discussed.  相似文献